{"id":22881,"date":"2016-07-03T08:00:56","date_gmt":"2016-07-03T00:00:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=22881"},"modified":"2016-08-27T10:45:16","modified_gmt":"2016-08-27T02:45:16","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b8%a8%e7%9c%8b%e9%a1%b6%e7%ba%a7%e6%9c%9f%e5%88%8a%e5%ad%a6sem%e5%92%8ctem%e8%a1%a8%e5%be%81%e7%bb%93%e6%9e%9c%e6%8f%8f%e8%bf%b0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=22881","title":{"rendered":"\u5b66\u672f\u5e72\u8d27 | \u9ad8\u8d28\u91cf\u6587\u732e\u662f\u5982\u4f55\u5206\u6790SEM\u548cTEM\u8868\u5f81\u7ed3\u679c\u7684\uff1f"},"content":{"rendered":"

SEM&TEM\u4f5c\u4e3a\u6750\u6599\u5f62\u8c8c\u8868\u5f81\u7684\u57fa\u672c\u624b\u6bb5\uff0c\u6216\u662f\u4e00\u79cd\u6216\u662f\u4e24\u79cd\u65b9\u5f0f\u76f8\u7ed3\u5408\u51fa\u73b0\u5728\u9876\u7ea7\u671f\u520a\u7684\u6587\u7ae0\u4e2d\u3002\u901a\u5e38\u6211\u4eec\u7ed3\u5408\u6837\u54c1SEM&TEM\u56fe\u5bf9\u5176\u8fdb\u884c\u63cf\u8ff0\u65f6\uff0c\u9700\u8981\u7ed9\u51fa\u6837\u54c1\u7684\u57fa\u672c\u5f62\u8c8c<\/strong><\/span>\uff0c\u5982\uff1a\u7ea4\u7ef4\u72b6\u3001\u9488\u72b6\u3001\u76d8\u5f62\u3001\u7247\u72b6\u3001\u7403\u5f62\u7b49\uff1b\u5176\u6b21\uff0c\u9700\u8981\u6839\u636e\u6837\u54c1\u7684\u57fa\u672c\u5f62\u8c8c\u7ed9\u51fa\u5bf9\u5e94\u7684\u53c2\u6570<\/span><\/span><\/strong>\uff0c\u5982\uff1a\u7ea4\u7ef4\u7684\u957f\u5ea6\u3001\u7403\u5f62\u7ed3\u6784\u7684\u76f4\u5f84\u3001\u76d8\u72b6\u7ed3\u6784\u7684\u539a\u5ea6\u7b49\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u8fd8\u53ef\u4ee5\u4e0e\u5143\u7d20\u5206\u6790\u3001SAED\u76f8\u7ed3\u5408\uff0c\u8fdb\u4e00\u6b65\u5206\u6790\u6837\u54c1\u7684\u5143\u7d20\u5206\u5e03\u3001\u6676\u4f53\u7ec4\u6210\u3002\u4e0b\u9762\u5c06\u4ece\u5355\u4e00\u7684SEM\u3001SEM&TEM\u3001SEM&TEM&HRTEM\u591a\u79cd\u8868\u5f81\u76f8\u7ed3\u5408\u8fd9\u4e09\u4e2a\u90e8\u5206\u8fdb\u884c\u7efc\u5408\u89e3\u6790\u9876\u7ea7\u671f\u520a\u4e2d\u6709\u5173\u56fe\u7247\u662f\u5982\u4f55\u8fdb\u884c\u63cf\u8ff0\u7684\u3002<\/p>\n

\u4e00\u3001\u7b80\u5355\u7684SEM\u5206\u6790<\/strong><\/span>
\n\u4e0b\u9762<\/span>\u4ee5Electrochemistry\u4e2d\u201cImprovement in the Electrochemical Properties of Intercalated Metal-Organic Framework Electrode Materials by Controlling Crystal Growth<\/a>\u201d\u6587\u7ae0\u4e3a<\/span>\u4f8b\u3002<\/p>\n

\u5728\u8be5\u6587\u4e2d\u4f5c\u8005\u901a\u8fc7\u9009\u7528\u4e0d\u540c\u6eb6\u5242\u63a7\u5236\u63d2\u5165\u5f0fiMOF\u7535\u6781\u6750\u65992,6-Naph(COOLi)2\u7684\u8868\u9762\u6676\u4f53\u751f\u957f\u3002<\/p>\n

\"\u56fe\u72471\"<\/p>\n

Fig.1 \u5728\u4e0d\u540c\u6eb6\u6db2\u4e2d\u5408\u6210\u76842,6-Naph(COOLi)2 SEM\u56fe (a)\uff1a\u6c34\u6eb6\u6db2\uff1b(b)\u7532\u9187<\/p>\n

\u8be6\u89e3\uff1a<\/strong><\/span>
\n\u6587\u7ae0\u5bf9\u4e8eSEM\u56fe\u7684\u63cf\u8ff0\uff0c\u9996\u5148\u7740\u91cd\u5728\u5bf9\u4e8e\u6837\u54c1\u5f62\u8c8c\u7684\u63cf\u8ff0\u3002a\u56fe\u4e2d\u4ece\u6c34\u6eb6\u6db2\u4f53\u7cfb\u5236\u5907\u7684\u6837\u54c1\u5f62\u6210\u4e86\u76d8\u72b6\u6676\u4f53\uff0cb\u56fe\u4e2d\u4ece\u7532\u9187\u4f53\u7cfb\u4e2d\u5236\u5907\u7684\u6837\u54c1\u5f62\u6210\u4e86\u9488\u72b6\u6676\u4f53\uff1b\u5176\u6b21\uff0c\u662f\u5bf9\u4e8e\u6837\u54c1\u5c3a\u5bf8\u7684\u63cf\u8ff0\uff0ca\u56fe\u4e2d\u5f62\u6210\u7684\u76d8\u72b6\u6676\u4f53\u539a\u7ea65\u201310 \u00b5m \uff0c\u76f4\u5f84\u4e3a100 \u00b5m\uff0cb\u56fe\u4e2d\u5f62\u6210\u7684\u9488\u72b6\u6676\u4f53\u957f10\u03bcm\u3002<\/strong><\/p>\n

\u4e8c\u3001SEM\u3001TEM\u76f8\u7ed3\u5408\u8fdb\u884c\u5206\u6790<\/strong><\/span>
\n\u6b64\u5904\u4ee5Angew. Chem. Int. Ed.\u4e2d\u201cConfining Sulfur in Double-Shelled Hollow Carbon Spheres for Lithium\u2013Sulfur Batteries<\/a>\u201d\u8fd9\u7bc7\u6587\u7ae0\u4e3a<\/span>\u4f8b\u3002<\/p>\n

\u8be5\u6587\u7ae0\u901a\u8fc7\u5c06\u786b\u5305\u88f9\u5728\u5177\u6709\u9ad8\u8868\u9762\u79ef\u548c\u5b54\u9699\u7387\u7684\u53cc\u58f3\u201c\u8f6f\u201d\u78b3\u4e2d\u7a7a\u7403\uff08DHCSs\uff09\u4e2d\u5236\u5907\u51fa\u4e00\u79cd\u65b0\u578b\u7684\u78b3-\u786b\u7eb3\u7c73\u590d\u5408\u6750\u6599\u3002\u5f53\u6b64\u590d\u5408\u6750\u6599\u7528\u4f5c\u9502\u786b\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u65f6\uff0c\u53ef\u4ee5\u5448\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/span><\/p>\n

\"nfig001\"
\nFig.2 (a) DHCSs TEM\u56fe\uff1b(b) DHCS-S\u590d\u5408\u6750\u6599FESEM\u56fe\uff1b
\nDHCS-S\u590d\u5408\u6750\u6599TEM\u56fe: (c)\u4f4e\u500d\uff0c(d)\u9ad8\u500d\uff1b(e)\u5355\u4e2aDHCS-S\u7403TEM\u56fe\u548cEDS\u56fe\u3002<\/p>\n

\u8be6\u89e3\uff1a<\/strong><\/span>
\n\u4eceA\u56fe\u4e2d\u53ef\u4ee5\u770b\u51faDHCSs\u4e2d\u4e24\u58f3\u4e4b\u95f4\u95f4\u8ddd\u4e3a50-100nm\uff1b\u5c06B\u3001C\u4e0eA\u56fe\u5bf9\u6bd4\u53ef\u4ee5\u770b\u51fa\uff0c\u7ecf\u9ad8\u6e29\u786b\u6d78\u6e0d\u540e\u5236\u5907\u7684DHCS-S\u7eb3\u7c73\u590d\u5408\u6750\u6599\u4e0eDHCSs\u5177\u6709\u76f8\u4f3c\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u3002\u5728D\u56fe\u4e2d\u53ef\u4ee5\u770b\u5230\u66f4\u6e05\u6670\u7684\u53cc\u58f3\u7ed3\u6784\uff0c\u5728\u7a7a\u5fc3\u7403\u7684\u5185\u90e8\u6216\u5916\u90e8\u5e76\u6ca1\u6709\u53d1\u73b0\u660e\u663e\u7684\u786b\u9897\u7c92\uff0c\u8fd9\u8868\u660e\u786b\u5df2\u7ecf\u5747\u5300\u5730\u5206\u6563\u5230\u78b3\u57fa\u8d28\u4e2d\u3002<\/strong><\/p>\n

\u4eceE\u56fe\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u78b3\u548c\u786b\u4e3b\u8981\u5206\u5e03\u5728\u4e24\u4e2a\u78b3\u58f3\u4e4b\u95f4\u7684\u533a\u57df\u4e2d\uff0c\u5728\u4e2d\u5fc3\u533a\u57df\u8f83\u5f31\u7684\u4fe1\u53f7\u8868\u660e\u5185\u8154\u4fdd\u6301\u4e2d\u7a7a\u72b6\u6001\u4e0d\u53d8\u3002\u6b64\u5916\uff0c\u8fd9\u4e24\u4e2a\u5143\u7d20\u7684\u76f8\u4f3c\u5206\u5e03\u8868\u660e\u786b\u5bf9\u78b3\u5177\u6709\u8f83\u9ad8\u7684\u4eb2\u548c\u529b\uff0c\u5e76\u4e14\u786b\u5f88\u597d\u5730\u5206\u5e03\u5728\u7531\u591a\u5b54\u78b3\u57fa\u8d28\u5f62\u6210\u7684\u53cc\u58f3\u7ed3\u6784\u4e2d\u3002\u6587\u7ae0\u4e2d\u4e0d\u6b62\u662f\u5355\u7eaf\u5730\u5bf9\u6837\u54c1\u7684SEM\u3001TEM\u8fdb\u884c\u4e86\u5206\u6790\uff0c\u8fd8\u5c06\u5176\u4e0e\u6837\u54c1\u7684\u7ed3\u6784\u7ed3\u5408\u8d77\u6765\u8fdb\u884c\u4e86\u7efc\u5408\u8ba8\u8bba\u3002<\/strong><\/p>\n

\u4e09\u3001SEM\u3001TEM\u3001HRTEM\u3001SAED\u591a\u79cd\u8868\u5f81\u76f8\u7ed3\u5408\u8fdb\u884c\u7efc\u5408\u5206\u6790<\/strong><\/span>
\n\u4e0b\u56fe\u9009\u81eaElectrochimica Acta\u4e2dHigh electrochemical performances of\u00a0<\/a><\/span>\u03b1<\/i><\/em>-MoO3<\/sub>@MnO2\u00a0<\/sub><\/a>core-shell nanorods as lithium-ion battery anodes<\/a>\uff0c\u5176\u5185\u5bb9\u4e3b\u8981\u662f\u4ecb\u7ecd\u7528\u4e24\u6b65\u6cd5\u5408\u6210<\/span>\u03b1<\/i><\/em>-MoO3<\/sub>@MnO2<\/sub>\u6838\u58f3\u7eb3\u7c73\u68d2\uff0c\u5e76\u4e14\u7814\u7a76\u5176\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u65f6\u8f83\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/span><\/p>\n

\"mno2moo3-0909-wangq\"<\/p>\n

Fig.3\u56fe\u4e2d\u03b1-MoO3<\/sub>@MnO2<\/sub>\u6838\u58f3\u7eb3\u7c73\u68d2SEM\u56fe\uff1a(a)\u4f4e\u500d\uff0c(b)\u9ad8\u500d;
\n(c)TEM\u56fe, (d)\/(e) HRTEM\u56fe\uff0c(f)SAED\u56fe<\/p>\n

\u8be6\u89e3\uff1a<\/strong><\/span>
\n\u6587\u4e2d\u9996\u5148\u6839\u636e<\/strong>\u03b1<\/i><\/em>-MoO3<\/sub>@MnO2<\/sub><\/strong>\u6838\u58f3\u7eb3\u7c73\u68d2\u7684SEM\u56fe\uff0c\u4ecb\u7ecd\u4e86\u5176\u5c3a\u5bf8\u5927\u5c0f\u548c\u8868\u9762\u5f62\u8c8c\uff0c\u7eb3\u7c73\u68d2\u76f4\u5f84\u4e3a250nm\uff0c\u8868\u9762\u5448\u73b0\u7c97\u7cd9\u72b6\u6001\uff0c\u88ab\u5747\u5300\u5730\u6d82\u8986\u6709\u8bb8\u591a\u7684MnO2<\/sub>\u7eb3\u7c73\u7ebf\u3002\u5176\u6b21\uff0c\u4ecec\u56fe\u4e2d\u53ef\u4ee5\u66f4\u6e05\u695a\u5730\u8bc1\u5b9e\u5728\u03b1<\/i><\/em>-MoO3<\/sub>\u7eb3\u7c73\u68d2\u7684\u6574\u4e2a\u8868\u9762\u4e0a\u786e\u5b9e\u5747\u5300\u5730\u6d82\u5e03\u4e86MnO2<\/sub>\u7eb3\u7c73\u7ebf\uff0cMnO2<\/sub>\u7684\u5e73\u5747\u539a\u5ea6\u572846nm\u3002\u800c\u4e14\uff0c\u4eced\u3001e\u56fe\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\u4e24\u79cd\u4e0d\u540c\u7684\u6676\u4f53\u7ed3\u6784\uff0cd = 0.37 nm \u548cd = 0.40\u9762\u95f4\u8ddd\u5904\u5206\u522b\u5bf9\u5e94\u4e8e\u03b1<\/i><\/em>-MoO3<\/sub>\u6676\u4f53\u7684\uff08001\uff09\u548c\uff08100\uff09\u6676\u9762\u3002\u518d\u6839\u636ef\u4e2d\u4e00\u4e2a\u5c5e\u4e8e\u03b1-MoO3\u5730SAED\u56fe\u6848\uff0c\u800c\u53e6\u4e00\u7ec4SAED\u56fe\u6848\u4e3a\u03b2-MnO2<\/sub>\u56fe\u6848\u3002<\/strong><\/p>\n

\u7efc\u5408\u4e0a\u8ff0\u7ed3\u679c\u5f97\uff0c\u03b1<\/i><\/em>-MoO3<\/sub>@MnO2<\/sub> \u6838\u58f3\u7eb3\u7c73\u68d2\u7531\u03b1-<\/i><\/em>MoO3<\/sub>@MnO2<\/sub>\u4e24\u76f8\u7ec4\u6210\u3002\u5c06SEM\u3001TEM\u3001HRTEM\u53caSAED\u7b49\u591a\u79cd\u8868\u5f81\u624b\u6bb5\u76f8\u7ed3\u5408\uff0c\u53ef\u4ee5\u66f4\u52a0\u8be6\u7ec6\u5730\u8bf4\u660e\u6837\u54c1\u7684\u5f62\u8c8c\u7ed3\u6784\uff0c\u5206\u6790\u5176\u6676\u4f53\u7ec4\u6210\u3002<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u7ec4 NeverSayBye \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6b22\u8fce\u4f18\u79c0\u7855\u3001\u535a\u58eb\u751f\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u5e72\u8d27\u5c0f\u7ec4\uff0c\u4e00\u8d77\u4f20\u64ad\u5b66\u672f\u77e5\u8bc6\uff0c\u5c55\u73b0\u4f60\u7684\u624d\u534e\uff0c\u52a9\u529b\u6750\u6599\u79d1\u7814\uff0c\u4f18\u79c0\u7a3f\u4ef6\u4e00\u7ecf\u5f55\u7528\uff0c\u6211\u4eec\u4f1a\u5949\u4e0a\u7a3f\u916c\uff0c\u8d76\u5feb\u79c1\u4fe1\u7ba1\u7406\u5458\u8d1f\u8d23\u4eba\u201c\u6de1\u5e74\u534e\uff08QQ:601416321\uff09\u201d\u62a5\u540d\u5427\uff01<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\u00a0tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

SEM&TEM\u4f5c\u4e3a\u6750\u6599\u5f62\u8c8c\u8868\u5f81\u7684\u57fa\u672c\u624b\u6bb5\uff0c\u6216\u662f\u4e00\u79cd\u6216\u662f\u4e24\u79cd\u65b9\u5f0f\u76f8\u7ed3\u5408\u51fa\u73b0\u5728\u9876\u7ea7\u671f\u520a\u7684\u6587\u7ae0\u4e2d\u3002\u901a\u5e38\u6211\u4eec\u7ed3\u5408\u6837\u54c1SEM&TEM\u56fe\u5bf9\u5176\u8fdb\u884c\u63cf\u8ff0\u65f6\uff0c\u9700\u8981…<\/p>\n","protected":false},"author":174,"featured_media":22885,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-22881","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22881"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/174"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=22881"}],"version-history":[{"count":41,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22881\/revisions"}],"predecessor-version":[{"id":36721,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22881\/revisions\/36721"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/22885"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=22881"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=22881"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=22881"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}