{"id":227144,"date":"2021-09-13T06:12:00","date_gmt":"2021-09-12T22:12:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=227144"},"modified":"2021-09-12T20:12:13","modified_gmt":"2021-09-12T12:12:13","slug":"%e8%83%bd%e6%ba%90%e5%82%ac%e5%8c%96%e6%96%b0%e6%9d%90%e6%96%99%e9%a2%91%e5%87%ba%ef%bc%8c%e5%8d%95%e5%8e%9f%e5%ad%90%e6%9c%aa%e6%9d%a5%e4%b9%8b%e8%b7%af%e4%bd%95%e5%8e%bb%e4%bd%95%e4%bb%8e%ef%bc%9f","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=227144","title":{"rendered":"\u80fd\u6e90\u50ac\u5316\u65b0\u6750\u6599\u9891\u51fa\uff0c\u5355\u539f\u5b50\u672a\u6765\u4e4b\u8def\u4f55\u53bb\u4f55\u4ece\uff1f"},"content":{"rendered":"
\u4e2d\u56fd\u79d1\u5b66\u62a5\u62a5\u9053\uff0c\u57282020\u5e74\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u63d0\u4f9b\u5173\u952e\u6280\u672f\u7684\u201c5\u4e07\u5428\/\u5e74\u4e59\u70ef\u6c22\u7532\u9170\u5316\u751f\u4ea7\u6b63\u4e19\u9187\u5de5\u4e1a\u5316\u88c5\u7f6e\u201d\u5728\u5b81\u6ce2\u5b9e\u73b0\u5168\u6d41\u7a0b\u4e00\u6b21\u6295\u4ea7\u6210\u529f\u3002\u88ab\u8ba4\u4e3a\u662f\u5355\u539f\u5b50\u50ac\u5316\u9886\u57df\u7814\u7a76\u7684\u91cd\u8981\u91cc\u7a0b\u7891\uff0c\u7834\u89e3\u4e86\u56f0\u6270\u50ac\u5316\u754c80\u591a\u5e74\u7684\u96be\u9898\uff0c\u800c\u5728\u540c\u5e74\u768410\u670813\u65e5\uff0c\u5728\u5317\u4eac\u53ec\u5f00\u7684\u201d\u5355\u539f\u5b50\u50ac\u5316\u201c\u9999\u5c71\u79d1\u5b66\u4f1a\u8bae\u4e0a\uff0c\u4e0e\u4f1a\u4e13\u5bb6\u8ba4\u4e3a\uff0c\u4f5c\u4e3a\u4e00\u4e2a\u7531\u4e2d\u56fd\u79d1\u5b66\u5bb6\u9996\u6b21\u63d0\u51fa\u7684\u65b0\u6982\u5ff5\uff0c\u201c\u5355\u539f\u5b50\u50ac\u5316\u201d\u5df2\u7ecf\u6210\u4e3a\u50ac\u5316\u548c\u6750\u6599\u79d1\u5b66\u9886\u57df\u65b0\u7684\u7814\u7a76\u524d\u6cbf\u548c\u70ed\u70b9\uff0c\u5e94\u5c3d\u65e9\u5e03\u5c40\uff0c\u4ee5\u5e94\u5bf9\u8be5\u9886\u57df\u57fa\u7840\u79d1\u5b66\u3001\u5de5\u4e1a\u5e94\u7528\u4e0a\u9762\u4e34\u7684\u6311\u6218\u3002\u90a3\u4e48\uff0c\u5355\u539f\u5b50\u5728\u5927\u725b\u624b\u4e2d\u53c8\u662f\u5982\u4f55\u7ee7\u7eed\u53d1\u5149\u53d1\u70ed\u7684\uff1f<\/p>\n
1. Nature\u00a0<\/b><\/strong><\/b>Catalysis<\/b><\/strong>\uff1a\u4e00\u79cd\u975e\u5747\u76f8\u94f1\u5355\u539f\u5b50\u4f4d\u70b9\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u533a\u57df\u9009\u62e9\u6027\u7684\u7c7b\u5361\u5bbe<\/b><\/strong>O<\/b><\/strong>–<\/b><\/strong>H<\/b><\/strong>\u952e\u63d2\u5165<\/b><\/strong><\/p>\n \u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5408\u6210\u4e2d\uff0c\u7c7b\u5361\u5bbe\u7f9f\u57fa\u63d2\u5165\u6cd5\u662f\u4e00\u79cd\u6709\u6548\u4e14\u901a\u7528\u7684\u78b3\u6c27\u952e\u5f62\u6210\u9014\u5f84\uff0c\u800c\u78b3\u6c27\u952e\u7684\u5f62\u6210\u53ef\u4ee5\u589e\u5f3a\u9187\u7c7b\u4f4d\u70b9\u7684\u9009\u62e9\u6027\u529f\u80fd\u5316\uff0c\u867d\u7136\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\u5177\u6709\u5f88\u5927\u7684\u6f5c\u529b\uff0c\u4f46\u4e5f\u540c\u65f6\u5b58\u5728\u8f83\u5927\u7684\u6311\u6218\u6027\u3002\u4ee5\u8fd9\u79cd\u5408\u6210\u65b9\u6cd5\u4e3a\u57fa\u70b9\uff0c\u534e\u4e1c\u7406\u5de5\u8d75\u6770\u7279\u8058\u526f\u7814\u7a76\u5458\uff0c\u6e05\u534e\u5927\u5b66\u738b\u5b9a\u80dc\u6559\u6388\u548c\u7f8e\u56fd\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4F. Dean\u00a0Toste\u5171\u540c\u63d0\u51fa\u4e86\u4e00\u79cd\u9009\u62e9\u6027\u7c7b\u5361\u5bbeO-H\u63d2\u5165\u7b56\u7565\uff0c\u7814\u7a76\u4eba\u5458\u5c06\u5747\u5300\u5206\u6563\u5728\u7532\u9187\u6eb6\u6db2\u4e2d\u7684\u54aa\u5511\u9aa8\u67b6-8\u6cb8\u77f3\u5f15\u5165\u5230\u542b\u6709\u6c2f\u5316\u94f1\u548c\u5355\u4f53PZS\u7684\u6eb6\u6db2\u4e2d\uff0c\u5728\u4e09\u7532\u80fa\u7684\u5f15\u53d1\u4e0b\uff0c\u4e24\u79cd\u524d\u9a71\u4f53\u5728ZIF-8\u8868\u9762\u8fdb\u884c\u805a\u5408\uff0c\u5f97\u5230\u4e09\u5143\u590d\u5408\u6750\u6599\uff0c\u5e76\u5177\u6709\u591a\u9762\u4f53\u5f62\u8c8c\u3002\u4e4b\u540e\u901a\u8fc7\u70ed\u89e3\u624b\u6bb5\u83b7\u5f97\u4e86\u8d1f\u8f7d\u5728\u6742\u539f\u5b50\u63ba\u6742\u7684\u78b3\u4e0a\u7684Ir\u5355\u539f\u5b50\u50ac\u5316\u5242\u3002\u8be5\u50ac\u5316\u5242\u5bf9\u4e8e\u915a\u7c7bO-H\u952e\u4e0a\u7684\u8102\u80aa\u65cf\u5b98\u80fd\u5316\u7684\u9009\u62e9\u6027\u9ad8\u8fbe99:1\u3002\u672c\u5de5\u4f5c\u5c06\u6709\u673a\u5408\u6210\u7b56\u7565\u4e0e\u7eb3\u7c73\u6750\u6599\u50ac\u5316\u5242\u6709\u6548\u7684\u7ed3\u5408\uff0c\u5de7\u5999\u7684\u5f15\u5165\u4e86\u5de5\u7a0b\u5316\u7684\u975e\u5747\u76f8\u94f1\u5355\u539f\u5b50\u50ac\u5316\u5242\uff0c\u4e3a\u6709\u673a\u8f6c\u5316\u65b9\u5411\u63d0\u4f9b\u4e86\u673a\u4f1a\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>heterogeneous<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>iridium<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>single<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>atom<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>site<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>catalyst<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>for<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>highly<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>regioselective<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>carbenoid<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>O<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>H<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>bond<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>insertion<\/i><\/b><\/em><\/strong>\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nature<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>Catalysis<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n \u56fe 1\u00a0\u94f1\u5355\u539f\u5b50\u50ac\u5316\u5242\u7684\u5408\u6210\u53ca\u5f62\u8c8c\u8868\u5f81<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41929-021-00637-7<\/p>\n 2. Nature\u00a0<\/b><\/strong><\/b>Chemistry<\/b><\/strong>\uff1a<\/b><\/strong>\u57fa\u4e8e\u78b3\u57fa\u5e95\u7684\u9ad8\u8f7d\u91cf\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u6750\u6599\u7684\u666e\u9002\u6027\u5408\u6210\u7b56\u7565<\/b><\/strong><\/p>\n \u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u539f\u5b50\u5229\u7528\u7387\u548c\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u4f4d\u70b9\uff0c\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u53ef\u8c03\u914d\u7684\u914d\u4f4d\u7ed3\u6784\uff0c\u5728\u5404\u79cd\u7535\u50ac\u5316\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u6d3b\u6027\u3002\u73b0\u6709\u7684\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u201c\u81ea\u4e0a\u800c\u4e0b\u201d\u6cd5\u548c\u201c\u81ea\u4e0b\u800c\u4e0a\u201d\u6cd5\uff0c\u5355\u539f\u5b50\u6750\u6599\u4e2d\u7684\u91d1\u5c5e\u539f\u5b50\u5bc6\u5ea6\u8f83\u4f4e\uff0c\u9650\u5236\u4e86\u5176\u5de5\u4e1a\u5e94\u7528\u524d\u666f\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u3001\u52a0\u62ff\u5927\u5149\u6e90\u548c\u7f8e\u56fd\u83b1\u65af\u5927\u5b66\u4e09\u4e2a\u5355\u4f4d\u5171\u540c\u5408\u4f5c\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u7684\u590f\u5ddd\u6559\u6388\u4e3a\u7b2c\u4e00\u4f5c\u8005\u548c\u901a\u8baf\u4f5c\u8005\u3002\u8be5\u56e2\u961f\u521b\u65b0\u6027\u5730\u4f7f\u7528\u6bd4\u8868\u9762\u5927\u3001\u70ed\u7a33\u5b9a\u6027\u9ad8\u7684\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u4f5c\u4e3a\u78b3\u57fa\u5e95\uff0c\u5bf9\u5176\u8fdb\u884c-NH2<\/sub>\u57fa\u56e2\u4fee\u9970\uff0c\u4f7f\u5176\u5bf9\u91d1\u5c5e\u79bb\u5b50\u5177\u6709\u9ad8\u914d\u4f4d\u6d3b\u6027\u3002\u5f15\u5165\u91d1\u5c5e\u79bb\u5b50\u540e\u53ef\u5f97\u5230\u4ee5\u91d1\u5c5e\u79bb\u5b50\u4f5c\u4e3a\u8282\u70b9\u3001\u529f\u80fd\u5316\u77f3\u58a8\u70ef\u91cf\u5b50\u70b9\u4f5c\u4e3a\u7ed3\u6784\u5355\u5143\u7684\u4ea4\u8054\u7f51\u7edc\uff0c\u6700\u540e\u70ed\u89e3\u5373\u53ef\u5f97\u5230\u9ad8\u8f7d\u91cf\u7684\u91d1\u5c5e\u5355\u539f\u5b50\u6750\u6599\u3002\u76f8\u8f83\u4e8e\u4f20\u7edf\u201c\u81ea\u4e0a\u800c\u4e0b\u201d\u548c\u201c\u81ea\u4e0b\u800c\u4e0a\u201d\u7684\u5355\u539f\u5b50\u50ac\u5316\u5242\u5408\u6210\u65b9\u6cd5\uff0c\u8be5\u7814\u7a76\u62a5\u9053\u7684\u65b9\u6cd5\u65e2\u4fdd\u8bc1\u4e86\u9ad8\u542b\u91cf\u91d1\u5c5e\u79bb\u5b50\u521d\u59cb\u951a\u5b9a\u65f6\u7684\u9ad8\u5206\u6563\u6027\u53c8\u80fd\u6709\u6548\u6291\u5236\u540e\u7eed\u70ed\u89e3\u8fc7\u7a0b\u57fa\u5e95\u70e7\u7ed3\u91cd\u6784\u5f15\u8d77\u7684\u91d1\u5c5e\u539f\u5b50\u56e2\u805a\u3002\u6b64\u65b9\u6cd5\u53ef\u4ee5\u666e\u9002\u6027\u7684\u7528\u4e8e\u591a\u79cd\u8fc7\u6e21\u91d1\u5c5e\u5355\u539f\u5b50\u6750\u6599\u5408\u6210\uff0c\u5b9e\u73b0\u4e86\u9ad8\u8fbe 40\u00a0wt.% \u6216 3.8\u00a0at.% \u7684\u9ad8\u8fc7\u6e21\u91d1\u5c5e\u539f\u5b50\u8d1f\u8f7d\uff0c\u6bd4\u76ee\u524d\u62a5\u9053\u7684\u5355\u539f\u5b50\u8d1f\u8f7d\u91cf\u63d0\u5347\u4e86\u51e0\u500d\u751a\u81f3\u6570\u5341\u500d\u3002\u8be5\u5de5\u4f5c\u4ee5\u201cG<\/i><\/b><\/em><\/strong>eneral<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>synthesis<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>of<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>single<\/i><\/b><\/em><\/strong>–<\/i><\/b><\/em><\/strong>atom<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>catalysts<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>with<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>high<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>metal<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>loading<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>using<\/i><\/b><\/em><\/strong>\u00a0<\/i><\/b><\/em><\/strong>graphene<\/i><\/b><\/em><\/strong><\/b><\/strong><\/p>\n
<\/b><\/strong><\/p>\n