{"id":226964,"date":"2021-09-11T06:30:52","date_gmt":"2021-09-10T22:30:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=226964"},"modified":"2021-09-10T18:22:14","modified_gmt":"2021-09-10T10:22:14","slug":"nature-reviews-chemistry%ef%bc%9an-%e6%9d%82%e7%8e%af%e5%8d%a1%e5%ae%be%e7%9a%84%e5%8c%96%e5%ad%a6%e5%8f%8a%e5%ba%94%e7%94%a8%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=226964","title":{"rendered":"Nature Reviews Chemistry\uff1aN-\u6742\u73af\u5361\u5bbe\u7684\u5316\u5b66\u53ca\u5e94\u7528\u7814\u7a76\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n<p>N-\u6742\u73af\u5361\u5bbe\uff08NHC\uff09\u88ab\u5f52\u7c7b\u4e3a\u6709\u673a\u5b9e\u4f53\uff0c\u5176\u7279\u5f81\u662f\u5728\u6c2e\u6742\u73af\u7cfb\u7edf\u5185\u7684\u4ef7\u58f3\u4e2d\u53ea\u67096\u4e2a\u7535\u5b50\u7684\u4e8c\u4ef7\u78b3\u539f\u5b50\uff08\u56e0\u6b64\u79f0\u4e3a\u5361\u5bbe\uff09\u3002\u4e0e\u5927\u591a\u6570\u78b3\u7cfb\u76f8\u6bd4\uff0cNHC\u662f\u4e00\u79cd\u7a33\u5b9a\u7684\u5316\u5408\u7269\uff0c\u901a\u5e38\u53ef\u4ee5\u5206\u79bb\u548c\u50a8\u5b58\u3002\u5927\u591a\u6570\u78b3\u7cfb\u672c\u8d28\u4e0a\u4e0d\u7a33\u5b9a\uff0c\u5728\u6ca1\u6709\u4efb\u4f55\u5176\u4ed6\u7a33\u5b9a\u7279\u5f81\u7684\u60c5\u51b5\u4e0b\uff0c\u4ec5\u4f5c\u4e3a\u6709\u673a\u8fc7\u7a0b\u4e2d\u7684\u77ac\u6001\u4e2d\u95f4\u4f53\u5b58\u5728\uff08\u4f8b\u5982\u73af\u4e19\u70f7\u5316\u548cC-H\u63d2\u5165\uff09\u3002\u5c3d\u7ba1N-\u6742\u73af\u5361\u5bbe\u5728\u4e09\u5341\u5e74\u524d\u5c31\u5df2\u7ecf\u88ab\u5206\u79bb\u51fa\u6765\u5e76\u8fdb\u884c\u4e86\u8868\u5f81\uff0c\u4f46\u5b83\u4f5c\u4e3a\u591a\u529f\u80fd\u3001\u6a21\u5757\u5316\u548c\u5f3a\u914d\u4f4d\u7684\u90e8\u5206\u4ecd\u7136\u5f15\u8d77\u4e86\u79d1\u5b66\u5bb6\u4eec\u7684\u5174\u8da3\u3002\u5728\u8fc7\u53bb\u5341\u5e74\u4e2d\uff0c\u7531\u4e8e\u5bf9\u5176\u884c\u4e3a\u7684\u57fa\u672c\u8ba4\u8bc6\u65e5\u76ca\u5b8c\u5584\uff0c\u65b0\u5361\u5bbe\u6846\u67b6\u7684\u51fa\u73b0\u548c\u4ee4\u4eba\u4fe1\u670d\u7684\u53ef\u6301\u7eed\u6027\u95ee\u9898\uff0cN-\u6742\u73af\u5361\u5bbe\u5728\u51e0\u4e2a\u4e0d\u540c\u9886\u57df\u7684\u5229\u7528\u7387\u5927\u5e45\u589e\u52a0\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u5fb7\u56fd\u660e\u65af\u7279\u5927\u5b66<\/strong><strong>Frank Glorius<\/strong><strong>\u6559\u6388\u548c\u67cf\u6797\u81ea\u7531\u5927\u5b66<\/strong><strong>Matthew N. Hopkinson<\/strong><strong>\u6559\u6388<\/strong>\u8054\u5408\u7efc\u8ff0\u4e86N-\u6742\u73af\u5361\u5bbe\u7684\u5386\u53f2\u3001\u6027\u8d28\u53ca\u5176\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u3001\u8868\u9762\u5316\u5b66\u3001\u4e3b\u65cf\u5316\u5b66\u548c\u6709\u673a\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u3002\u91cd\u70b9\u653e\u5728\u8fc7\u53bb\u4e03\u5e74\u51fa\u73b0\u7684\u53d1\u5c55\u548c\u5c55\u671b\u672a\u6765\u7684\u65b9\u5411\u4e0a\u3002\u8be5\u8bba\u6587\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201c<strong>Recent advances in the chemistry and applications of N-heterocyclic carbenes<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520a<strong>Nature Reviews Chemistry<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001<\/strong><strong>N-<\/strong><strong>\u6742\u73af\u5361\u5bbe\u7684\u5408\u6210\u548c\u5e94\u7528\u65f6\u95f4\u8868<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/4-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/4-1-300x160.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u57fa\u4e8eN-\u6742\u73af\u5361\u5bbe\uff08NHC\uff09\u7684\u8868\u9762\u6539\u6027\u7684\u6700\u65b0\u8fdb\u5c55\u7684\u4e3b\u8981\u7279\u5f81\u3002<\/p>\n<p>\uff08b\uff09NHC\u5728\u91d1\u5c5e\u8868\u9762\uff08\u626b\u63cf\u96a7\u9053\u663e\u5fae\u955c\u56fe\u50cf\uff09\u3001\u7eb3\u7c73\u68d2\uff08\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u56fe\u50cf\uff09\u548c\u7eb3\u7c73\u56e2\u7c07\uff08X\u5c04\u7ebf\u884d\u5c04\u7ed3\u6784\uff09\u7a33\u5b9a\u7684\u5b9e\u4f8b\u3002<\/p>\n<p><strong>\u56fe\u4e94\u3001<\/strong><strong>N-<\/strong><strong>\u6742\u73af\u78b3\u5316\u7269\u5f15\u8d77\u7684\u4e3b\u65cf\u5316\u5b66\u7684\u8fdb\u5c55<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226969\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-1.jpg\" alt=\"\" width=\"600\" height=\"512\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-1-300x256.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5f00\u58f3\u548c\u95ed\u58f3\u7269\u79cd\u7a33\u5b9a\u5316\u7684\u90e8\u5206\u4f8b\u5b50\u3002<\/p>\n<p>\uff08b\uff09\u6a21\u4eff\u8fc7\u6e21\u91d1\u5c5e\u5143\u7d20\u6b65\u9aa4\u7684N-\u6742\u73af\u78b3\u5316\u7269\uff08NHCs\uff09\u5bf9\u60f0\u6027\u952e\u7684\u6fc0\u6d3b\u3002<\/p>\n<p>\uff08c\uff09\u9009\u5b9a\u7684\u4e3b\u65cf\u52a0\u5408\u7269\u4f5c\u4e3a\u914d\u4f53\u3002<\/p>\n<p><strong>\u56fe\u516d\u3001<\/strong><strong>N-<\/strong><strong>\u6742\u73af\u78b3\u5316\u7269\u7684\u6709\u673a\u50ac\u5316\u5e94\u7528\u53ca\u5c55\u671b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226970\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/6.jpg\" alt=\"\" width=\"600\" height=\"770\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/6.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/6-234x300.jpg 234w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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href=\"https:\/\/www.nature.com\/articles\/s41570-021-00321-1\" target=\"_blank\" rel=\"noopener\">Recent advances in the chemistry and applications of N-heterocyclic carbenes<\/a> (<em>Nature Reviews Chemistry.<\/em> 2021, DOI: 10.1038\/s41570-021-00321-1)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7814\u7a76\u80cc\u666f\u3011 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