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\u6b64\u9879\u7814\u7a76\u5f97\u5230\u4e86\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u6d59\u6c5f\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u6e29\u5dde\u5e02\u91cd\u5927\u7814\u7a76\u89c4\u5212\u652f\u6301\u3002<\/p>\n \u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41467-021-25597-1<\/p>\n DOI: 10.1038\/s41467-021-25597-1<\/p>\n \u82f1\u6587\u9898\u76ee<\/p>\n Artificial sodium-selective ionic device based on crown-ether crystals with subnanometer pores<\/p>\n \u82f1\u6587\u6458\u8981<\/p>\n Biological sodium channels ferry sodium ions across the lipid\u00a0membrane while rejecting potassium ions and other metal ions. Realizing such ion selectivity in an artificial solid-state ionic device will enable new separation technologies but remains highly challenging. In this work, we report an artificial sodium-selective ionic device, built on synthesized porous crown-ether crystals which consist of densely packed\u00a00.26-nm-wide pores. The Na+<\/sup>\u00a0selectivity of the artificial sodium-selective ionic device reached 15 against K+<\/sup>\u2009, which is comparable to the biological counterpart, 523 against Ca2+<\/sup>\u2009, which is nearly two orders of magnitude higher than the biological one, and 1128 against Mg2+<\/sup>\u2009. The selectivity may arise from the size effect and molecular recognition effect. This work may contribute to the understanding of the structure-performance relationship of ion selective nanopores.<\/p>\n \u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":" \u751f\u7269\u79bb\u5b50\u901a\u9053\u5728\u8bb8\u591a\u751f\u547d\u6d3b\u52a8\u4e2d\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u4ed6\u4eec\u53ef\u4ee5\u7cbe\u51c6\u8bc6\u522b\u76ee\u6807\u79bb\u5b50\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u79bb\u5b50\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u94a0\u901a\u9053\u7684Na+\/K+\u9009\u62e9\u6027\u4e3a~10-102\uff0cNa+\/Ca2…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-226826","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226826"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=226826"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226826\/revisions"}],"predecessor-version":[{"id":226849,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226826\/revisions\/226849"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=226826"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=226826"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=226826"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
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