{"id":226812,"date":"2021-09-05T06:30:45","date_gmt":"2021-09-04T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=226812"},"modified":"2021-09-04T22:28:20","modified_gmt":"2021-09-04T14:28:20","slug":"10%e7%af%87%e7%bb%8f%e5%85%b8%e6%96%87%e7%8c%ae%e5%91%8a%e8%af%89%e4%bd%a0%e9%98%bb%e6%8a%97%e8%b0%b1%e5%88%b0%e5%ba%95%e6%80%8e%e4%b9%88%e7%94%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=226812","title":{"rendered":"10\u7bc7\u7ecf\u5178\u6587\u732e\u544a\u8bc9\u4f60\u963b\u6297\u8c31\u5230\u5e95\u600e\u4e48\u7528"},"content":{"rendered":"<p>\u7535\u5316\u5b66\u963b\u6297\u8c31\u662f\u7535\u5316\u5b66\u76f8\u5173\u9886\u57df\u5e94\u7528\u6781\u4e3a\u666e\u904d\u7684\u8868\u5f81\u6280\u672f\u4e4b\u4e00\uff0c\u53ef\u4ee5\u7528\u4e8e\u5206\u6790\u7535\u6781\u8fc7\u7a0b\u52a8\u529b\u5b66\u3001\u53cc\u7535\u5c42\u548c\u6269\u6563\u7b49\uff0c\u63ed\u793a\u7535\u6781\u6750\u6599\u3001\u56fa\u4f53\u7535\u89e3\u8d28\u3001\u5bfc\u7535\u9ad8\u5206\u5b50\u4ee5\u53ca\u8150\u8680\u9632\u62a4\u7b49\u6750\u6599\u7684\u53cd\u5e94\u8fc7\u7a0b\u673a\u7406\u3002\u672c\u6587\u6574\u7406\u4e8610\u7bc7\u5178\u578b\u7684\u5229\u7528\u963b\u6297\u8c31\u6765\u89e3\u6790\u9502\u7535\u6c60\u3001\u71c3\u6599\u7535\u6c60\u548c\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u8bba\u6587\uff0c\u8fd9\u4e9b\u6587\u732e\uff08\u9664\u7efc\u8ff0\u6587\u7ae0\uff09\u7684\u5171\u540c\u70b9\u662f\uff0c\u5177\u5907\u7406\u8bba\u4e0e\u5b9e\u9a8c\u7ed3\u5408\uff0c\u5b9e\u9a8c\u8bbe\u8ba1\u72ec\u7279\uff0c\u5b9e\u73b0\u65b0\u7684\u673a\u7406\u8ba4\u8bc6\u3002\u901a\u8fc7\u6b64\u6587\u7ae0\uff0c\u5e0c\u671b\u5e2e\u52a9\u5927\u5bb6\u66f4\u597d\u5730\u5b66\u4e60\u548c\u5229\u7528\u963b\u6297\u8c31\u3002<\/p>\n<p><strong>\u4e00<\/strong><strong>. <\/strong><strong>\u9502\u7535\u6c60<\/strong><\/p>\n<p><strong>1. Electrochimica Acta<\/strong><strong>\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8001\u5316\u8fc7\u7a0b\u2014\u78f7\u9178\u94c1\u9502<\/strong><strong>\/<\/strong><strong>\u4ecb\u5b54\u78b3\u5fae\u73e0\u77f3\u58a8\u7535\u6781\u7684\u7269\u7406\u6a21\u578b\u548c\u5b9e\u9a8c\u7814\u7a76<\/strong><\/p>\n<p><strong>\u745e\u5178\u7687\u5bb6\u7406\u5de5\u5b66\u9662<\/strong><strong>G\u00f6ran Lindbergh<\/strong><strong>\u56e2\u961f<\/strong>\u7814\u7a76\u4e86\u78f7\u9178\u94c1\u9502\/\u4ecb\u5b54\u78b3\u5fae\u73e0\u77f3\u58a8\u7535\u6c60\u7684\u8001\u5316\u60c5\u51b5\uff0c\u8fd9\u4e9b\u7535\u6c60\u572822\u2103\u4e0b\u7ecf\u5386\u4e86\u7efc\u5408\u6027\u6df7\u5408\u9a71\u52a8\u5faa\u73af\u6216\u65e5\u5386\u8001\u5316\u3002\u7814\u7a76\u4eba\u5458\u9488\u5bf9\u65b0\u9c9c\u7535\u6781\u548c\u8001\u5316\u7535\u6781\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u5b9e\u9a8c\u7814\u7a76\u548c\u6bd4\u8f83\u3002\u4f7f\u7528\u7535\u5316\u5b66\u963b\u6297\u8c31(EIS)\u6a21\u578b\u786e\u5b9a\u7535\u6781\u7279\u6027\uff0c\u76f8\u5173\u6570\u636e\u6765\u81ea\u4e8e\u7535\u6781\u5bb9\u91cf\u548c\u626b\u63cf\u7535\u6781\u663e\u5fae\u955c(SEM)\u7ed3\u679c\uff0c\u62df\u5408\u6210\u4e09\u7535\u6781EIS\u6d4b\u91cf\u7cfb\u7edf\u3002\u6a21\u578b\u62df\u5408\u7684\u7ed3\u679c\u9610\u91ca\u4e86\u5bf9\u7535\u6781\u6027\u80fd\u8870\u51cf\u7684\u8be6\u7ec6\u4e86\u89e3\uff0c\u5e76\u4e0e\u5168\u7535\u6c60\u7684\u8001\u5316\u884c\u4e3a\u8054\u7cfb\u8d77\u6765\u3002\u7ed3\u679c\u663e\u793a\uff0c\u65e5\u5386\u8001\u5316\u5bf9\u7535\u6c60\u963b\u6297\u7684\u5f71\u54cd\u53ef\u4ee5\u5ffd\u7565\u4e0d\u8ba1\uff0c\u800c\u5faa\u73af\u8001\u5316\u589e\u52a0\u963b\u6297\u4e3b\u8981\u662f\u7531\u4e8e\u78f7\u9178\u94c1\u9502\u6b63\u6781\u7684\u7ed3\u6784\u53d8\u5316\u548c\u4e24\u4e2a\u7535\u6781\u4e0a\u7684\u7535\u89e3\u8d28\u5206\u89e3\u4ea7\u7269\u3002\u6b64\u5916\uff0c\u5168\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u4e3b\u8981\u539f\u56e0\u662f\u7535\u89e3\u8d28\u5206\u89e3\u5bfc\u81f4\u7684\u53ef\u5faa\u73af\u9502\u7684\u635f\u5931\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226911\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/1-2.png\" alt=\"\" width=\"501\" height=\"441\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/1-2.png 501w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/1-2-300x264.png 300w\" sizes=\"(max-width: 501px) 100vw, 501px\" \/><\/p>\n<p>\u56fe1 \u4e09\u7535\u6781\u7535\u6c60\u7684\u793a\u610f\u56fe\uff0c\u7ea2\u8272\u865a\u7ebf\u8868\u793a\u4e3a1D\u6a2a\u622a\u9762\u6c42\u89e3EIS\u6a21\u578b\u7684\u533a\u57df\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aAging in lithium-ion batteries: Model and experimental investigation of harvested LiFePO4 and mesocarbon microbead graphite electrodes<\/p>\n<p>https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0013468613010049<\/p>\n<p><strong>2. J. Electrochem. Soc.<\/strong><strong>\uff1a<\/strong><strong>\u9502\u79bb\u5b50\u7535\u6c60\u5d4c\u5165\u5f0f\u6b63\u6781\u6d4b\u91cf\u963b\u6297\u8c31\u7684\u9610\u91ca<\/strong><\/p>\n<p>\u5728\u6587\u732e\u4e2d\uff0c\u5bf9\u5d4c\u5165\u5f0f\u6b63\u6781\u6750\u6599\u7535\u5316\u5b66\u963b\u6297\u8c31\u7684\u6d4b\u91cf\u89e3\u91ca\u5404\u4e0d\u76f8\u540c\u3002\u5728\u5927\u591a\u6570\u60c5\u51b5\u4e0b\uff0c\u5404\u79cd\u968f\u610f\u9009\u62e9\u7684\u7b49\u6548\u7535\u8def\u88ab\u7528\u4e8e\u9891\u8c31\u5206\u6790\uff0c\u56e0\u6b64\u7ed3\u679c\u7684\u6709\u6548\u6027\u4e3b\u8981\u5728\u4e8e\u62df\u5408\u8d28\u91cf\u3002\u5728\u6b64\uff0c<strong>\u65af\u6d1b\u6587\u5c3c\u4e9a\u56fd\u5bb6\u5316\u5b66\u7814\u7a76\u6240<\/strong><strong>Miran Gaberscek<\/strong><strong>\u56e2\u961f<\/strong>\u629b\u51fa\u4e86\u9ad8\u9891\u534a\u5706\u5f52\u5c5e\u7684\u65b0\u95ee\u9898\uff0c\u8bd5\u56fe\u7528\u7b80\u5316\u7684\u6709\u6548\u7535\u8def\u6765\u89e3\u91ca\u9ad8\u9891\u3001\u4e2d\u9891\u7684\u5706\u5f27\u548c\u4f4e\u9891\u7684\u6269\u6563\u5c3e\u5df4\u7b49\u4e3b\u8981\u7279\u5f81\u3002\u6240\u63d0\u51fa\u7684\u6a21\u578b\u6709\u660e\u786e\u7684\u7269\u7406\u80cc\u666f\uff0c\u4e14\u6240\u9009\u7535\u8def\u53c2\u6570\u7684\u610f\u4e49\u901a\u8fc7\u5728\u78f7\u9178\u94c1\u9502\u548c\u4e8c\u6c27\u5316\u7845\u6750\u6599\u4e0a\u8be6\u7ec6\u7684\u6a21\u62df\u5b9e\u9a8c\u6765\u9a8c\u8bc1\u3002\u7279\u522b\u662f\uff0c\u4f5c\u8005\u8ba8\u8bba\u4e86\u5145\u7535\u72b6\u6001\u3001\u5916\u90e8\u538b\u529b\u3001\u7535\u6781\u8f7d\u91cf\uff08\u539a\u5ea6\uff09\u548c\u7535\u89e3\u8d28\u6d53\u5ea6\u5bf9\u6d4b\u91cf\u548c\u6a21\u62df\u7b49\u6548\u7535\u8def\u7684\u5f71\u54cd\u3002\u6700\u540e\uff0c\u4f5c\u8005\u6df1\u5165\u8ba8\u8bba\u4e86\u6784\u6210\u7535\u6781\u7684\u4e0d\u540c\u76f8\u4e4b\u95f4\u7535\u5b50\u6216\u79bb\u5b50\u63a5\u89e6\u4e0d\u826f\u5f15\u8d77\u7684\u6027\u80fd\u8870\u51cf\u95ee\u9898\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226912\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/2-2.png\" alt=\"\" width=\"600\" height=\"496\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/2-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/2-2-300x248.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2 \u94b4\u9178\u9502\u5bf9\u79f0\u53cc\u7535\u6781\u7535\u6c60\u7684\u4ea4\u6d41\u963b\u6297\u8c31\uff1aLiCoO<sub>2<\/sub>:CB:PTFE = 80:10:10\uff08wt %\uff09; \u7535\u6781\u57285\u5428\u7684\u6db2\u538b\u673a\u4e2d\u9884\u538b0.5\u5206\u949f\u3002\u6bcf\u4e2a\u7535\u6c60\u4f7f\u7528\u4e00\u5bf9\u76f8\u540c\u7684\u7535\u6781\u7ec4\u88c5\uff0c\u7535\u6781\u9884\u5145\u7535\u81f34.25 V\uff0c\u5e76\u5728\u8be5\u7535\u4f4d\u4e0b\u5e73\u886150\u5c0f\u65f6\u3002\u7535\u89e3\u8d28\u6eb6\u5242\u7684\u4f53\u79ef\u6bd4\u59cb\u7ec8\u4e3aEC:DEC=1:1\uff0c\u800cLiPF<sub>6<\/sub>\u76d0\u7684\u6d53\u5ea6\u4e3a1 M\uff08\u56fea\u548cb\uff09\u548c0.01 M\uff08\u56fec\u548cd\uff09\u3002\u5728\u6bcf1.5 cm<sup>2<\/sup>\u7535\u6781\u51e0\u4f55\u8868\u9762\u79ef8 kg\u7684\u6052\u5b9a\u5916\u538b\u4e0b\u6d4b\u91cfEIS\u8c31\uff0c\u6d4b\u91cf\u8c31\u7ebf\u7528\u5706\u5708\u8868\u793a\uff0c\u800c\u4f7f\u7528SCR\u6216SCRF\u6a21\u578b\u62df\u5408\u7684\u66f2\u7ebf\u7528\u5b9e\u7ebf\u8868\u793a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aOn the Interpretation of Measured Impedance Spectra of Insertion Cathodes for Lithium-Ion Batteries<\/p>\n<p>https:\/\/iopscience.iop.org\/article\/10.1149\/1.3489353\/meta<\/p>\n<p><strong>3. Langmuir<\/strong><strong>\uff1a\u77f3\u58a8\u4e0e\u6db2\u4f53\u7535\u89e3\u8d28\u754c\u9762\u4e0a\u7684\u9502\u79bb\u5b50\u8f6c\u79fb\u52a8\u529b\u5b66<\/strong><strong>\u2014<\/strong><strong>\u6eb6\u5242\u548c<\/strong><strong>SEI<\/strong><strong>\u819c\u7684\u5f71\u54cd<\/strong><\/p>\n<p><strong>\u65e5\u672c\u4eac\u90fd\u5927\u5b66<\/strong><strong>Takeshi Abe<\/strong><strong>\u56e2\u961f<\/strong>\u7528\u4ea4\u6d41\u963b\u6297\u8c31\u7814\u7a76\u4e86\u9502\u79bb\u5b50\u5728\u77f3\u58a8\u548c\u6db2\u4f53\u7535\u89e3\u8d28\u754c\u9762\u7684\u8fc1\u79fb\u52a8\u529b\u5b66\u3002\u4ee5\u9ad8\u53d6\u5411\u70ed\u89e3\u77f3\u58a8(HOPG)\u4e3a\u6a21\u578b\u7535\u6781\uff0c\u4ece\u754c\u9762\u4f20\u8f93\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u51fa\u53d1\uff0c\u8ba1\u7b97\u4e86\u754c\u9762\u9502\u79bb\u5b50\u8f6c\u79fb\u7684\u6d3b\u5316\u80fd\u3002\u5f53\u4f7f\u7528\u6eb6\u8d28\u4e3aLiClO<sub>4<\/sub>\uff0c\u6eb6\u5242\u4e3a\u78b3\u9178\u4e59\u70ef\u916f(EC)\u548c\u78b3\u9178\u4e8c\u7532\u916f(DMC)(\u4f53\u79ef\u6bd41\u22361)\u7684\u6df7\u5408\u7269\u7ec4\u6210\u7684\u4e8c\u5143\u7535\u89e3\u8d28\u65f6\uff0c\u754c\u9762\u9502\u79bb\u5b50\u8f6c\u79fb\u7684\u6d3b\u5316\u80fd\u4e3a58kJ mol<sup>-1<\/sup>\uff0c\u800c\u7531\u6eb6\u89e3\u5728DMC\u4e2d\u7684LiClO<sub>4<\/sub>\u7ec4\u6210\u7684\u7535\u89e3\u8d28\uff0c\u7ed9\u51fa\u7684\u6d3b\u5316\u80fd\u4e3a40kJ mol<sup>-1<\/sup>\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cEC\u7684\u6eb6\u5242\u5316\u80fd\u529b\u9ad8\u4e8eDMC\u3002\u56e0\u6b64\uff0c\u53ef\u4ee5\u5f97\u51fa\u7ed3\u8bba\uff0c\u754c\u9762\u9502\u79bb\u5b50\u5728\u77f3\u58a8\u4e0a\u8f6c\u79fb\u7684\u6d3b\u5316\u80fd\uff0c\u53cd\u6620\u4e86\u9502\u79bb\u5b50\u4ece\u6eb6\u5242\u5206\u5b50\u4e2d\u8131\u6eb6\u5242\u5316\u7684\u80fd\u91cf\u3002\u6b64\u5916\uff0c\u5728\u4e0d\u540c\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u819c\u4e0b\uff0c\u754c\u9762\u9502\u79bb\u5b50\u8f6c\u79fb\u7684\u6d3b\u5316\u80fd\u6709\u6240\u4e0d\u540c\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u9502\u79bb\u5b50\u5728\u77f3\u58a8\u754c\u9762\u8f6c\u79fb\u7684\u52a8\u529b\u5b66\u53d7SEI\u819c\u7ec4\u6210\u548c\u9502\u79bb\u5b50\u4ece\u6eb6\u5242\u5206\u5b50\u4e2d\u8131\u6eb6\u5242\u5316\u7684\u5f71\u54cd\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226913\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/3-2.png\" alt=\"\" width=\"455\" height=\"408\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/3-2.png 455w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/3-2-300x269.png 300w\" sizes=\"(max-width: 455px) 100vw, 455px\" \/><\/p>\n<p>\u56fe3 \u4f7f\u7528\u9ad8\u53d6\u5411\u70ed\u89e3\u77f3\u58a8\u7535\u6781\uff0c0.2 V\u65f6\uff0c\u5728LiClO<sub>4<\/sub>\/EC:DMC (\u4f53\u79ef\u6bd41:1\u548c1:9)\u548cLiClO<sub>4<\/sub>\/DMC\u7535\u89e3\u6db2\u4e2d\u754c\u9762\u4f20\u8f93\u6027\u80fd\uff081\/R<sub>ct<\/sub>\uff09\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\u3002SEI\u819c\u662f\u5728\u7531\u4ee5\u4e0b\u7ec4\u6210\u7684\u7535\u89e3\u6db2\u4e2d\u9884\u5148\u5f62\u6210\u7684\uff1a1 mol dm<sup>-3<\/sup> LiClO<sub>4<\/sub>\/EC:DMC (\u4f53\u79ef\u6bd41:1)\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aKinetics of Lithium Ion Transfer at the Interface between Graphite and Liquid Electrolytes: Effects of Solvent and Surface Film<\/p>\n<p>https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/la901829v<\/p>\n<p><strong>4. J. Electrochem. Soc.<\/strong><strong>\uff1a\u5fae\u578b\u53c2\u6bd4\u7535\u6781\u7528\u4e8e\u8f6f\u5305\u9502\u79bb\u5b50\u7535\u6c60\u53cd\u5e94\u7684\u963b\u6297\u5206\u6790<\/strong><\/p>\n<p>\u501f\u52a9\u4e8e\u7b49\u6548\u7535\u8def\uff0c\u7535\u5316\u5b66\u963b\u6297\u8c31\u662f\u8bca\u65ad\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6709\u529b\u5de5\u5177\u3002\u7136\u800c\uff0c\u5728\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5bf9\u9ad8\u529f\u7387\u9700\u6c42\u8d8a\u6765\u8d8a\u8feb\u5207\u3002\u8003\u8651\u5230\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8fd9\u79cd\u9700\u6c42\uff0c\u7535\u6781\u4e2d\u7684\u79bb\u5b50\u7535\u963b\u5f88\u91cd\u8981\uff0c\u5b83\u4f1a\u5728\u9ad8\u529f\u7387\u4e0b\u63d0\u9ad8\u53cd\u5e94\u5206\u5e03\u3002\u56e0\u6b64\uff0c\u8fd9\u610f\u5473\u7740\u4ea4\u6d41\u963b\u6297\u5206\u6790\u5e94\u8be5\u5305\u62ec\u7b49\u6548\u7535\u8def\u4e2d\u7535\u6781\u7684\u79bb\u5b50\u7535\u963b\u3002\u6b64\u5916\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u963b\u6297\u54cd\u5e94\u8fc7\u4e8e\u590d\u6742\uff0c\u65e0\u6cd5\u8be6\u7ec6\u5206\u6790\uff0c\u56e0\u4e3a\u963b\u6297\u54cd\u5e94\u7531\u5316\u5b66\u53cd\u5e94\u548c\u79bb\u5b50\u8fc1\u79fb\u7b49\u91cd\u53e0\u7684\u5355\u5143\u8fc7\u7a0b\u7ec4\u6210\u3002\u56e0\u6b64\uff0c<strong>\u65e5\u672c\u65e9\u7a3b\u7530\u5927\u5b66<\/strong><strong>Tetsuya Osaka<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u963b\u6297\u54cd\u5e94\u5206\u6790\uff0c\u8be5\u963b\u6297\u54cd\u5e94\u7531\u5fae\u53c2\u8003\u7535\u6781\u901a\u8fc7\u4f7f\u7528\u4f20\u8f93\u7ebf\u6a21\u578b(TLM)\u72ec\u7acb\u83b7\u5f97\uff0c\u53ef\u4ee5\u5355\u72ec\u8ba1\u7b97\u7535\u6781\u4e2d\u7684\u79bb\u5b50\u7535\u963b\u3002\u4e0e\u4f20\u7edf\u7684Randles\u7b49\u6548\u7535\u8def\u7c7b\u4f3c\uff0cTLM\u7b49\u6548\u7535\u8def\u53ef\u4ee5\u5c06\u7b49\u6548\u7535\u8def\u6a21\u62df\u7684\u963b\u6297\u54cd\u5e94\u4e0e\u5b9e\u6d4b\u54cd\u5e94\u8fdb\u884c\u62df\u5408\u3002\u672c\u6587\u8ba8\u8bba\u4e86\u5728EIS\u5e94\u7528\u4e2d\uff0c\u7528\u7b49\u6548\u7535\u8def\u4e0eTLM\u8026\u5408\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff0c\u8bca\u65ad\u9502\u79bb\u5b50\u7535\u6c60\u9ad8\u529f\u7387\u6027\u80fd\u65b9\u9762\u7684\u6f5c\u529b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226914\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/4-2.png\" alt=\"\" width=\"503\" height=\"332\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/4-2.png 503w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/4-2-300x198.png 300w\" sizes=\"(max-width: 503px) 100vw, 503px\" \/><\/p>\n<p>\u56fe4 \u5927\u7535\u6d41\u653e\u7535\u8fc7\u7a0b\u4e2d\u653e\u7535\u6df1\u5ea6\u5206\u5e03\u7684\u6b63\u6781\u793a\u610f\u56fe\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aImpedance Analysis with Transmission Line Model for Reaction Distribution in a Pouch Type Lithium-Ion Battery by Using Micro Reference Electrode<\/p>\n<p>https:\/\/iopscience.iop.org\/article\/10.1149\/2.0341603jes\/meta<\/p>\n<p><strong>5. J. Electrochem. Soc.<\/strong><strong>\uff1a\u9502\u79bb\u5b50\u7535\u6781\u76f8\u95f4\u63a5\u89e6\u7684\u91cd\u8981\u6027<\/strong><strong>\u2014<\/strong><strong>\u9ad8\u9891\u963b\u6297\u5706\u5f27\u7684\u542b\u4e49<\/strong><\/p>\n<p>\u9502\u5d4c\u5165\u7535\u6781\u662f\u901a\u8fc7\u5c06\u6d3b\u6027\u6750\u6599\u4e0e\u5bfc\u7535\u5242\u3001\u7c98\u7ed3\u5242\u7684\u6df7\u5408\u7269\u538b\u5728\u91d1\u5c5e\u96c6\u6d41\u4f53\u4e0a\u5236\u6210\u7684\u3002\u5728\u6b64\uff0c<strong>\u65af\u6d1b\u6587\u5c3c\u4e9a\u56fd\u5bb6\u5316\u5b66\u7814\u7a76\u6240<\/strong><strong>Miran Gaberscek<\/strong><strong>\u56e2\u961f<\/strong>\u8bc4\u4f30\u4e86\u5404\u79cd\u76f8\u95f4\u63a5\u89e6\u5982\u4f55\u5f71\u54cd\u7535\u6781\u52a8\u529b\u5b66\u3002\u5728\u4e0d\u540c\u7684\u6b63\u6781\u4e0a\u65bd\u52a0\u53ef\u53d8\u7684\u5916\u90e8\u673a\u68b0\u538b\u529b\uff0c\u5e76\u6d4b\u91cf\u5b83\u4eec\u7684\u963b\u6297\u54cd\u5e94\u3002\u8be5\u5b9e\u9a8c\u5728\u94dd\u7b94\u3001\u94dc\u7b94\u548c\u94f6\u6d46\u7b49\u4e0d\u540c\u96c6\u6d41\u4f53\u4e0a\u5b9e\u9a8c\uff0c\u7ed3\u679c\u663e\u793a\uff0c\u9ad8\u9891\u963b\u6297\u5706\u5f27\u6e90\u4e8e\u91d1\u5c5e\u548c\u7535\u6781\u6750\u6599\u4e4b\u95f4\u7684\u63a5\u89e6\u963b\u6297\uff0c\u8fd9\u4e0e\u4ee5\u524d\u6587\u732e\u4e2d\u7684\u89e3\u91ca\u5b8c\u5168\u4e0d\u540c\u3002\u4f5c\u8005\u5728\u6587\u7ae0\u4e2d\u63d0\u51fa\u4e86\u4e00\u4e2a\u7b49\u6548\u7535\u8def\u6765\u89e3\u91ca\u89c2\u5bdf\u5230\u7684\u73b0\u8c61\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226818\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475.png\" alt=\"\" width=\"686\" height=\"365\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475.png 686w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72475-300x160.png 300w\" sizes=\"(max-width: 686px) 100vw, 686px\" \/><\/p>\n<p>\u56fe5 \u5728\u4e09\u7535\u6781\u7535\u6c60\u4e2d\u6d4b\u91cf\u4e2d\uff0c\uff08a\uff09\u78f7\u9178\u94c1\u9502\u548c\uff08b\uff09\u4e8c\u6c27\u5316\u949b\u7684\u5178\u578b\u963b\u6297\u54cd\u5e94\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aThe Importance of Interphase Contacts in Li Ion Electrodes: The Meaning of the High-Frequency Impedance Arc<\/p>\n<p>https:\/\/iopscience.iop.org\/article\/10.1149\/1.2964220\/meta<\/p>\n<p><strong>\u4e8c<\/strong><strong>. <\/strong><strong>\u50ac\u5316\u8fc7\u7a0b<\/strong><\/p>\n<p><strong>1. J. Electroanal. Chem.<\/strong><strong>\uff1a\u9634\u79bb\u5b50\u5728\u91d1\u5355\u6676\u7535\u6781\u4e0a\u5438\u9644\u7684\u963b\u6297\u7279\u6027<\/strong><\/p>\n<p>\u4e3a\u4e86\u7814\u7a76\u5355\u6676\u7535\u6781\u4e2d\u7535\u5bb9\u5f25\u6563\u7684\u8d77\u56e0\uff0c\u5728\u4e0d\u5b58\u5728\u548c\u5b58\u5728\u7279\u5b9a\u5438\u9644\u9634\u79bb\u5b50(\u4e3b\u8981\u662fBr-)\u7684\u60c5\u51b5\u4e0b\uff0c\u5bf9Au(111)\u548cAu(100)\u8fdb\u884c\u4e86\u4f0f\u5b89\u548c\u963b\u6297\u6d4b\u91cf\u3002\u4ece\u963b\u6297\u8c31\u7ed3\u679c\u4e2d\uff0c\u8bc4\u4f30\u4e86\u8868\u5f81\u5438\u9644\u52a8\u529b\u5b66\u7684\u754c\u9762\u7535\u5bb9\u548c\u901f\u7387\u7cfb\u6570\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u6ca1\u6709\u7279\u5b9a\u5438\u9644\u7684\u60c5\u51b5\u4e0b\uff0c\u53cc\u5c42\u8868\u73b0\u4e3a\u7406\u60f3\u7535\u5bb9\u3002\u5177\u6709\u6052\u5b9a\u76f8\u4f4d\u5143\u7d20\u7684\u8fd1\u4f3c\u4ea7\u751f\u5927\u4e8e0.99\u7684\u6307\u6570\u3002\u5728\u5b58\u5728\u7279\u5b9a\u5438\u9644\u7684\u60c5\u51b5\u4e0b\u89c2\u5bdf\u5230\u7684\u201c\u7535\u5bb9\u5f25\u6563\u201d\u8981\u4e48\u5f52\u56e0\u4e8e\u7f13\u6162\u6269\u6563\u6216\u5438\u9644\u8fc7\u7a0b\uff0c\u8981\u4e48\u5f52\u56e0\u4e8e\u5438\u9644\u5c42\u6216\u886c\u5e95\u8868\u9762\u5185\u7684\u8f6c\u53d8\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226819\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476.png\" alt=\"\" width=\"600\" height=\"417\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72476-300x209.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe6 \u57281 mM HClO<sub>4<\/sub>+0.1 M KClO<sub>4<\/sub>(\u865a\u7ebf)\u548c0.1 M KClO<sub>4<\/sub>(\u5b9e\u7ebf)\u4e2d\u7684\u7535\u5bb9\u7535\u4f4d\u66f2\u7ebf\u548c\u5faa\u73af\u4f0f\u5b89\u56fe\uff1aCA) Au(III)\u548c(B)Au(100)\u3002\u626b\u901f10 mV s-1\uff0c\u8bef\u5dee\u6761\u8868\u793a\u9891\u73870.1 Hz\uff1cf\uff1c5 kHz\u8303\u56f4\u5185\uff0c\u7a33\u6001\u963b\u6297\u6d4b\u8bd5\u4e0b\u7535\u5bb9\u7684\u9891\u6563\u7a0b\u5ea6\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aImpedance aspects of anion adsorption on gold single crystal electrodes<\/p>\n<p>https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/0022072896047006<\/p>\n<p><strong>2. ACS Appl. Mater. Interfaces<\/strong><strong>\uff1a\u78b1\u6027\u4ecb\u8d28\u4e2d\u94c2<\/strong><strong>(111)<\/strong><strong>\u5438\u9644\u6c22\u7684\u6d3b\u5316\u80fd<\/strong><strong>\u2014<\/strong><strong>\u53d8\u6e29\u5ea6\u4e0b\u7684\u963b\u6297\u8c31\u7814\u7a76<\/strong><\/p>\n<p>\u6790\u6c22\u53cd\u5e94\u662f\u7535\u5316\u5b66\u4e2d\u7814\u7a76\u6700\u591a\u7684\u8fc7\u7a0b\u4e4b\u4e00\uff0c\u94c2\u662f\u8fd9\u4e00\u53cd\u5e94\u7684\u6700\u4f73\u50ac\u5316\u5242\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u4f46\u9488\u5bf9\u4e3b\u8981\u53cd\u5e94\u6b65\u9aa4\u7684\u8be6\u7ec6\u3001\u51c6\u786e\u7684\u52a8\u529b\u5b66\u6d4b\u91cf\u4ecd\u7136\u7f3a\u4e4f\uff0c\u4e3b\u8981\u539f\u56e0\u662f\u8be5\u8fc7\u7a0b\u53cd\u5e94\u901f\u5ea6\u5feb\u3002\u5728\u5927\u91cf\u7684\u8ba1\u7b97\u7814\u7a76\u4e2d\uff0c\u6c22\u5728\u94c2(111)\u4e0a\u7684\u5438\u9644\u88ab\u4f5c\u4e3a\u4e00\u4e2a\u57fa\u51c6\u7cfb\u7edf\uff0c\u4f46\u4e0e\u8ba1\u7b97\u7814\u7a76\u76f8\u6bd4\uff0c\u53ef\u9760\u7684\u5b9e\u9a8c\u6570\u636e\u975e\u5e38\u7f3a\u4e4f\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4e86\u89e3\u8fd9\u4e00\u95ee\u9898\uff0c<strong>\u897f\u73ed\u7259\u963f\u5229\u574e\u7279\u5927\u5b66<\/strong><strong>Victor Climent<\/strong><strong>\u56e2\u961f<\/strong>\u8fdb\u884c\u4e86\u6c22\u5438\u9644\u53cd\u5e94\u7684\u6e29\u5ea6\u7814\u7a76\uff0c\u4ee5\u83b7\u5f97\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u94c2(111)\u4e0a\u8be5\u8fc7\u7a0b\u7684\u52a8\u529b\u5b66\u4fe1\u606f\u3002\u901a\u8fc7\u5728278\u2264T\u2264318 K\u7684\u8303\u56f4\u5185\u6d4b\u91cf\u7535\u5316\u5b66\u963b\u6297\u8c31\u548c\u5faa\u73af\u4f0f\u5b89\u56fe\uff0c\u83b7\u5f97\u4e86\u5438\u9644\u7269\u8d28\u7684\u76f8\u5e94\u8868\u9762\u8986\u76d6\u7387\u548c\u6cd5\u62c9\u7b2c\u7535\u8377\u8f6c\u79fb\u7535\u963b\u3002\u4ece\u8fd9\u4e9b\u6570\u636e\u4e2d\uff0c\u6807\u51c6\u901f\u7387\u5e38\u6570\u662f\u901a\u8fc7\u52a8\u529b\u5b66\u6a21\u578b\u83b7\u53d6\u7684\uff0c\u8be5\u6a21\u578b\u5047\u5b9a\u4e86\u4e00\u4e2aFrumkin\u578b\u7b49\u6e29\u7ebf\uff0c\u5f97\u51fa\u7684\u503c\u4e3a2.60\u00d710<sup>-7<\/sup>\u2264k<sup>0<\/sup>\u22641.68\u00d710<sup>-6<\/sup>(s<sup>-1<\/sup>)\u3002\u963f\u96f7\u5c3c\u4e4c\u65af\u56fe\u7ed9\u51fa\u7684\u6d3b\u5316\u80fd\u4e3a32 KJ mol<sup>-1<\/sup>\u3002\u5c06\u8ba1\u7b97\u65b9\u6cd5\u5f97\u5230\u7684\u503c\u4e0e\u603bHER\u7684\u62a5\u544a\u503c\u8fdb\u884c\u6bd4\u8f83\uff0c\u4e3a\u652f\u6301\u6c22\u50ac\u5316\u7684\u672a\u6765\u7814\u7a76\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226820\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477.png\" alt=\"\" width=\"301\" height=\"543\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477.png 301w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72477-166x300.png 166w\" sizes=\"(max-width: 301px) 100vw, 301px\" \/><\/strong><\/p>\n<p>\u56fe7 \u57280.145 V\u65f6\uff0cPt(111)\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684Nyquist\u56fe\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aActivation Energy of Hydrogen Adsorption on Pt(111) in Alkaline Media: An Impedance Spectroscopy Study at Variable Temperatures<\/p>\n<p>https:\/\/pubs.acs.org\/doi\/10.1021\/acsami.0c13158?ref=pdf<\/p>\n<p><strong>\u4e09<\/strong><strong>. <\/strong><strong>\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n<p><strong>1. J. Electrochem. Soc.<\/strong><strong>\uff1a\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u9634\u6781\u7684\u8d28\u5b50\u4f20\u5bfc\u548c\u6c27\u8fd8\u539f\u52a8\u529b\u5b66<\/strong><\/p>\n<p>\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u4e2d\u7684\u7535\u6781\uff08PEM\uff09\u7531\u6d82\u6709\u4e00\u8584\u79bb\u805a\u7269\u5c42\u7684\u78b3\u8f7d\u94c2\u50ac\u5316\u5242\u7ec4\u6210\u3002\u5728\u53d1\u751f\u6c27\u8fd8\u539f\u53cd\u5e94\u7684\u9634\u6781\uff0c\u8d28\u5b50\u901a\u8fc7\u8584\u79bb\u805a\u7269\u5c42\u5230\u8fbe\u50ac\u5316\u5242\u4f4d\u7f6e\u3002\u5728\u6574\u4e2a\u7535\u6781\u539a\u5ea6\u8303\u56f4\u5185\uff0c\u8fd9\u79cd\u8d28\u5b50\u4f20\u5bfc\u7684\u7535\u963b\uff08R<sub>H<\/sub><sup>+<\/sup><sub>,cath<\/sub>\uff09\u4f1a\u5bfc\u81f4\u663e\u8457\u7684\u7535\u538b\u635f\u5931\uff0c\u5c24\u5176\u662f\u5728\u5e72\u71e5\u6761\u4ef6\u4e0b\u3002<strong>\u7f8e\u56fd\u7f57\u5207\u65af\u7279\u5927\u5b66<\/strong><strong>Yuxiu Liu<\/strong>\u53d1\u8868\u7814\u7a76\u6210\u679c\uff0c\u5728H<sub>2<\/sub>\/N<sub>2<\/sub>\u7535\u6c60\u4e2d\uff0c\u5728\u4e0d\u540c\u5de5\u4f5c\u6761\u4ef6\u4e0b\uff0c\u5229\u7528\u4ea4\u6d41\u963b\u6297\u5bf9\u5177\u6709\u4e0d\u540c\u79bb\u805a\u7269\/\u78b3\uff08I\/C\uff09\u6bd4\u7684\u9634\u6781\u4e2d\u7684R<sub>H<\/sub><sup>+<\/sup><sub>,cath<\/sub>\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5728\u5047\u8bbe\u8d28\u5b50\u7535\u963b\u548c\u8d5d\u7535\u5bb9\u5747\u5300\u5206\u5e03\u4e8e\u6574\u4e2a\u7535\u6781\u7684\u60c5\u51b5\u4e0b\uff0c\u901a\u8fc7\u5c06R<sub>H<\/sub><sup>+<\/sup><sub>,cath<\/sub>\u3001\u9634\u6781\u7535\u5bb9\uff08C<sub>cath<\/sub>\uff09\u548c\u9ad8\u9891\u7535\u963b\u62df\u5408\u6210\u7b80\u5316\u7684\u4f20\u8f93\u7ebf\u6a21\u578b\u6765\u5206\u6790\u4ea4\u6d41\u963b\u6297\u6570\u636e\u3002\u5728\u7ed9\u5b9a\u7c7b\u578b\u7684\u7535\u6781\u4e2d\uff0c\u5f53I\/C\u6bd4\u7ea6\u4e3a\uff1c0.6\/1\u6216\u79bb\u805a\u4f53\u4f53\u79ef\u5206\u6570\u4e3a~13%\u65f6\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u5f00\u59cb\u4e0b\u964d\u3002\u4e0eH<sub>2<\/sub>\/O<sub>2<\/sub>\u71c3\u6599\u7535\u6c60\u6027\u80fd\u7684\u6bd4\u8f83\u8868\u660e\uff0c\u8be5\u6280\u672f\u53ef\u4ee5\u91cf\u5316\u7535\u6781\u4e2d\u7684\u6b27\u59c6\u635f\u8017\u3002\u7ecf\u6b27\u59c6\u635f\u8017\u6821\u6b63\u7684\u7535\u6c60\u7535\u538b\u4e0e\u76f8\u5bf9\u6e7f\u5ea6\uff08RH\uff09\u548c\u7535\u6781\u7684I\/C\u6bd4\u65e0\u5173\uff0c\u8fd9\u8868\u660e\u7535\u6781\u8d28\u5b50\u7535\u963b\u7387\u03c1<sub>H<\/sub><sup>+<\/sup><sub>,cath<\/sub>\u786e\u5b9e\u662f\u4e00\u79cd\u4f9d\u8d56\u4e8e\u76f8\u5bf9\u6e7f\u5ea6\u7684\u7535\u6781\u56fa\u6709\u7279\u6027\u3002\u5728\u7814\u7a76\u7684RH\u8303\u56f4\uff08\u226535% RH\uff09\u5185\uff0c\u8fdb\u4e00\u6b65\u88ab\u786e\u8ba4RH\u5bf9ORR\u52a8\u529b\u5b66\u7684\u5f71\u54cd\u4e3a\u76f8\u5f53\u5c0f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226821\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72478.png\" alt=\"\" width=\"600\" height=\"191\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72478.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72478-300x96.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe8 \u819c\u7535\u6781\u7ec4\u4ef6\u4f20\u8f93\u7ebf\u6a21\u578b\u663e\u793a\u4e86\u8d28\u5b50\u819c\u7535\u963b\uff08R<sub>membrane<\/sub>\uff09\u3001\u9012\u589e\u7535\u6781\u8d28\u5b50\u7535\u963b\uff08R<sub>H<\/sub><sup>+<\/sup>,cath,i\uff09\u548c\u7535\u5b50\u7535\u963b\uff08R<sub>electronic<\/sub>\uff09\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aProton Conduction and Oxygen Reduction Kinetics in PEM Fuel Cell Cathodes: Effects of Ionomer-to-Carbon Ratio and Relative Humidity<\/p>\n<p>https:\/\/iopscience.iop.org\/article\/10.1149\/1.3143965\/meta<\/p>\n<p><strong>2. J. Electrochem. Soc.<\/strong><strong>\uff1a\u7535\u5316\u5b66\u963b\u6297\u8c31\u6cd5\u6d4b\u91cf<\/strong><strong>PEFC<\/strong><strong>\u50ac\u5316\u5242\u5c42\u7535\u89e3\u6db2\u7535\u963b<\/strong><\/p>\n<p><strong>\u7f8e\u56fd\u901a\u7528\u6c7d\u8f66\u516c\u53f8<\/strong><strong>Rohit Makharia<\/strong>\u4ecb\u7ecd\u4e86\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\u7528\u4e8e\u89e3\u51b3\u7eaf\u6c22\u71c3\u6599\u805a\u5408\u7269\u7535\u89e3\u8d28\u71c3\u6599\u7535\u6c60\uff08PEFC\uff09\u4e2d\u7684\u5404\u79cd\u6781\u5316\u635f\u5931\u6e90\u3002EIS\u6570\u636e\u62df\u5408\u6210\u71c3\u6599\u7535\u6c60\u6a21\u578b\uff0c\u5176\u4e2d\u50ac\u5316\u5242\u5c42\u7269\u7406\u6027\u8d28\u7531\u4f20\u8f93\u7ebf\u6a21\u578b\u7cbe\u786e\u8868\u793a\u3002\u63d0\u53d6\u7684\u53c2\u6570\u5305\u62ec\u7535\u6c60\u6b27\u59c6\u7535\u963b\u3001\u50ac\u5316\u5242\u5c42\u7535\u89e3\u8d28\u7535\u963b\u548c\u53cc\u5c42\u7535\u5bb9\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e00\u4e2a\u5178\u578b\u7535\u6781\u7684\u50ac\u5316\u5242\u5c42\u7535\u89e3\u6db2\u7535\u963b\uff0c\u572880\u00b0C\u548c\u5b8c\u5168\u52a0\u6e7f\u7684\u6761\u4ef6\u4e0b\u7ea6\u4e3a100 mV cm<sup>2<\/sup>\uff0c\u8fd9\u610f\u5473\u7740\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1 A\/cm2\u65f6\uff0c\u76f4\u6d41\u7535\u538b\u635f\u5931\u7ea6\u4e3a33 mV\u3002\u4e24\u79cd\u5b9e\u9a8c\u65b9\u6cd5\u5f97\u5230\u4e86\u76f8\u4f3c\u7684\u7ed3\u679c\uff0c\u4e00\u79cd\u662f\u4f7f\u7528H<sub>2<\/sub>\uff08\u9633\u6781\uff09\u548cO<sub>2<\/sub>\uff08\u9634\u6781\u6c14\u4f53\u4f9b\u7ed9\uff09\uff0c\u53e6\u4e00\u4e2a\u4e3aH<sub>2<\/sub>\u548cN<sub>2<\/sub>\u4f9b\u7ed9\uff0c\u4e24\u4e2a\u7535\u6c60\u7684\u6709\u6548\u9762\u79ef\u5206\u522b\u4e3a5\u548c50 cm<sup>2<\/sup>\u3002\u6b63\u5982\u9884\u671f\u7684\u90a3\u6837\uff0c\u968f\u7740\u7535\u6781\u4e2d\u79bb\u805a\u7269\u6d53\u5ea6\u7684\u964d\u4f4e\uff0c\u6d4b\u5f97\u7684\u50ac\u5316\u5242\u5c42\u7535\u89e3\u8d28\u7535\u963b\u589e\u52a0\u3002\u5b9e\u9a8c\u8fd8\u89c2\u5bdf\u5230\uff0c\u57281 kHz\u4e0b\u6d4b\u5f97\u7684\u5b9e\u9645\u963b\u6297\uff08\u901a\u5e38\u88ab\u89e3\u91ca\u4e3a\u7535\u6c60\u4e2d\u7684\u6b27\u59c6\u7535\u963b\uff09\uff0c\u5e94\u8be5\u5305\u62ec\u50ac\u5316\u5242\u5c42\u4e2d\u7535\u89e3\u8d28\u7684\u8d21\u732e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226822\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72479.png\" alt=\"\" width=\"600\" height=\"185\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72479.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u72479-300x93.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe9 \u71c3\u6599\u7535\u6c60\u5728H<sub>2<\/sub>\/O<sub>2<\/sub>\u6761\u4ef6\u4e0b\u7684\u7b49\u6548\u7535\u8def\uff0c\u7531\u591a\u5b54\u7535\u6781\u7684\u4f20\u8f93\u7ebf\u6a21\u578b\u8868\u793a\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aMeasurement of Catalyst Layer Electrolyte Resistance in PEFCs Using Electrochemical Impedance Spectroscopy<\/p>\n<p>https:\/\/iopscience.iop.org\/article\/10.1149\/1.1888367\/meta<\/p>\n<p><strong>3. J. Electrochem. Soc.<\/strong><strong>\uff1a\u7528\u963b\u6297\u8c31\u7269\u7406\u6a21\u578b\u8868\u5f81\u805a\u5408\u7269\u7535\u89e3\u8d28\u819c\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n<p>\u6700\u65b0\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u819c\u71c3\u6599\u7535\u6c60\u963b\u6297\u7269\u7406\u6a21\u578b\u7528\u4e8e\u5b9e\u9a8c\u963b\u6297\u8c31\u7684\u6700\u5c0f\u4e8c\u4e58\u62df\u5408\u3002<strong>\u5fb7\u56fd\u4f59\u5229\u5e0c\u7814\u7a76\u4e2d\u5fc3<\/strong><strong>Andrei Kulikovsky<\/strong>\u53d1\u8868\u6700\u65b0\u7814\u7a76\u6210\u679c\uff0c\u5728\u6c27\u6c14\u6d41\u91cf\u7684\u9ad8\u5316\u5b66\u8ba1\u91cf\u6bd4\u4e0b\uff0c\u7535\u6d41\u5bc6\u5ea6100 mA cm<sup>-2<\/sup>\u65f6\u6536\u96c6\u4e86\u4e00\u4e2a\u7535\u6c60\u540c\u4e00\u5b9e\u9a8c\u4e2d\u7684\u5341\u6bb5\u8c31\u7ebf\u3002\u6a21\u578b\u963b\u6297\u62df\u5408\u62df\u5408\u6210\u8c31\u7ebf\uff0c\u5e76\u8ba8\u8bba\u4e86\u7531\u6b64\u4ea7\u751f\u7684\u9634\u6781\u4fa7\u7269\u7406\u53c2\u6570\u3002\u7279\u522b\u4ee4\u4eba\u611f\u5174\u8da3\u7684\u662f\u9634\u6781\u50ac\u5316\u5242\u5c42\u4e2d\u6c27\u6269\u6563\u7cfb\u6570\u503c\u8f83\u4f4e\uff08\u22480.45&#215;10<sup>\u22124 <\/sup>cm<sup>2<\/sup> s<sup>\u22121<\/sup>\uff09\uff0c\u8fd9\u662f\u4e00\u4e2a\u5230\u76ee\u524d\u4e3a\u6b62\u8fd8\u6ca1\u6709\u5b9e\u73b0\u539f\u4f4d\u6d4b\u91cf\u7684\u53c2\u6570\u3002\u8fd9\u4e2a\u4f4e\u503c\uff0c\u4ee5\u53ca\u9634\u6781\u50ac\u5316\u5242\u5c42\uff08CCL\uff09\u8d28\u5b50\u5bfc\u7535\u7387\u03c3<sub>p<\/sub>\uff08\u22480.054 \u03a9<sup>-1<\/sup>\uff09\u7684\u9ad8\u503c\u5f52\u56e0\u4e8e\u6b63\u6781\u50ac\u5316\u5242\u5c42\u4e2d\u542b\u6709\u5927\u91cf\u6db2\u6001\u6c34\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226823\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u724710.png\" alt=\"\" width=\"600\" height=\"354\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u724710.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/\u56fe\u724710-300x177.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe10 \u5206\u6bb5\u5355\u5143\u6d4b\u91cf\u88c5\u7f6e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226915\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-2.png\" alt=\"\" width=\"432\" height=\"148\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-2.png 432w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/09\/5-2-300x103.png 300w\" sizes=\"(max-width: 432px) 100vw, 432px\" \/><\/p>\n<p>\u56fe11 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tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7535\u5316\u5b66\u963b\u6297\u8c31\u662f\u7535\u5316\u5b66\u76f8\u5173\u9886\u57df\u5e94\u7528\u6781\u4e3a\u666e\u904d\u7684\u8868\u5f81\u6280\u672f\u4e4b\u4e00\uff0c\u53ef\u4ee5\u7528\u4e8e\u5206\u6790\u7535\u6781\u8fc7\u7a0b\u52a8\u529b\u5b66\u3001\u53cc\u7535\u5c42\u548c\u6269\u6563\u7b49\uff0c\u63ed\u793a\u7535\u6781\u6750\u6599\u3001\u56fa\u4f53\u7535\u89e3\u8d28\u3001\u5bfc\u7535\u9ad8\u5206\u5b50\u4ee5\u53ca\u8150\u8680\u9632\u62a4\u7b49\u6750\u6599\u7684\u53cd\u5e94&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":226825,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-226812","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226812"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=226812"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226812\/revisions"}],"predecessor-version":[{"id":226918,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226812\/revisions\/226918"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/226825"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=226812"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=226812"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=226812"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}