{"id":226468,"date":"2021-08-25T06:30:21","date_gmt":"2021-08-24T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=226468"},"modified":"2021-08-24T16:34:30","modified_gmt":"2021-08-24T08:34:30","slug":"%e9%be%99%e5%b2%a9%e5%ad%a6%e9%99%a2%e5%91%a8%e6%b1%9f%e8%81%aa%e5%90%b4%e6%b3%89%e7%94%9f%e5%8d%9a%e5%a3%ab%e5%9b%a2%e9%98%9fcej%ef%bc%9a%e9%82%bb%e4%bd%8d%e9%98%b3%e7%a6%bb%e5%ad%90%e5%b0%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=226468","title":{"rendered":"\u9f99\u5ca9\u5b66\u9662\u5468\u6c5f\u806a&#038;\u5434\u6cc9\u751f\u535a\u58eb\u56e2\u961fCEJ\uff1a\u90bb\u4f4d\u9633\u79bb\u5b50\u5c3a\u5bf8\u8c03\u63a7Sr8CaX(PO4)7: Eu2+\u53d1\u5149\u6027\u80fd\u5e76\u83b7\u5f97\u9ad8\u663e\u8272\u56fa\u6001\u7167\u660e\u5149\u6e90"},"content":{"rendered":"<p>\u5982\u4f55\u8c03\u63a7\u6fc0\u6d3b\u79bb\u5b50\u5728\u4e0d\u540c\u6676\u683c\u4f4d\u70b9\u7684\u53d1\u5149\u884c\u4e3a\u5bf9\u53d1\u5c55\u4e0b\u4e00\u4ee3\u9ad8\u8d28\u91cf\u7167\u660e\u5149\u6e90\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002\u5f53\u524d\uff0c\u64cd\u7eb5\u6fc0\u6d3b\u79bb\u5b50\u5728\u4e0d\u540c\u6676\u683c\u683c\u70b9\u7684\u5206\u5e03\u4f9d\u65e7\u662f\u4e00\u9879\u91cd\u8981\u7684\u79d1\u6280\u6311\u6218\u3002\u767d\u78f7\u9499\u77ff\u6784\u578b<em><i>\u03b2<\/i><\/em>-Ca<sub>3<\/sub>(PO<sub>4<\/sub>)<sub>2<\/sub>\u57fa\u8d28\u4e00\u65b9\u9762\u80fd\u591f\u63d0\u4f9b\u4e94\u79cd\u4e0d\u540c\u7684\u9633\u79bb\u5b50\u683c\u4f4d\u7528\u4e8e\u7b49\u4ef7\u6216\u5f02\u4ef7\u9633\u79bb\u5b50\u66ff\u6362\u6765\u5f62\u6210\u65b0\u7684\u8367\u5149\u57fa\u8d28\u6750\u6599\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u6fc0\u6d3b\u79bb\u5b50\u5360\u636e\u5728\u4e0d\u540c\u7684\u6676\u683c\u683c\u70b9\u5c06\u4ea7\u751f\u4e30\u5bcc\u591a\u5f69\u7684\u53d1\u5149\u6027\u80fd\u3002\u57fa\u4e8e\u6b64\uff0c\u9f99\u5ca9\u5b66\u9662\u5316\u5b66\u4e0e\u6750\u6599\u5b66\u9662\u5468\u6c5f\u806a&amp;\u5434\u6cc9\u751f\u535a\u58eb\u7ec4\u5efa\u7684\u7a00\u571f\u5149\u7535\u65b0\u6750\u6599\u56e2\u961f\u901a\u8fc7\u4f20\u7edf\u7684\u9ad8\u6e29\u56fa\u76f8\u70e7\u7ed3\u6280\u672f\u6210\u529f\u5236\u5907\u4e86\u8fd1\u7d2b\u5916\u6fc0\u53d1\u9ec4\u5149\u53d1\u5c04\u7684Sr<sub>8<\/sub>CaX(PO<sub>4<\/sub>)<sub>7<\/sub>: Eu<sup>2+<\/sup>\u00a0(X = Al, Ga)\u8367\u5149\u7c89\uff0c\u63d0\u51fa\u4e86\u201c\u90bb\u4f4d\u9633\u79bb\u5b50\u5c3a\u5bf8\u6548\u5e94\u201d\u7b56\u7565\u6765\u5b9e\u73b0\u53d1\u5149\u6027\u80fd\u7684\u8c03\u63a7\uff0c\u4e3a\u591a\u9633\u79bb\u5b50\u683c\u70b9\u578b\u8367\u5149\u7c89\u7684\u53d1\u5149\u6027\u80fd\u8c03\u63a7\u63d0\u4f9b\u4e86\u501f\u9274\u610f\u4e49\u3002\u76f8\u5173\u7ed3\u679c\u53d1\u8868\u5728Chemical Engineering Journal\u00a0(DOI: 10.1016\/j.cej.2021.131869)\u3002<\/p>\n<p>Sr<sub>8<\/sub>CaX(PO<sub>4<\/sub>)<sub>7<\/sub>: Eu<sup>2+<\/sup>\u00a0(X = Al, Ga)\u57fa\u8d28\u5177\u6709\u4e5d\u914d\u4f4d\u7684Sr(1, 3, 5)O<sub>9<\/sub>\uff0c\u516b\u914d\u4f4d\u7684Sr(2)O<sub>8<\/sub>\uff0c\u548c\u4e00\u4e2a\u7279\u6b8a\u7a7a\u4f4d\u7684Sr(4)O<sub>6<\/sub>\uff1b\u540c\u65f6\uff0cEu<sup>2+<\/sup>\u79bb\u5b50\u5728\u8fd9\u4e9b\u6676\u683c\u4f4d\u70b9\u7684\u53d1\u5149\u5206\u522b\u5750\u843d\u5728\u53d1\u5149\u5149\u8c31\u4e2d\u7684\u84dd\u7eff\u5149\u6ce2\u6bb5\uff0c\u7eff\u5149\u6ce2\u6bb5\u548c\u7ea2\u5149\u6ce2\u6bb5\u3002\u5728Sr<sub>8<\/sub>CaX(PO<sub>4<\/sub>)<sub>7<\/sub>\u6676\u4f53\u7ed3\u6784\u4e2d\uff0cXO<sub>6<\/sub>\u516b\u9762\u4f53\u901a\u8fc7\u78f7\u6c27\u56db\u9762\u4f53PO<sub>4<\/sub>\u201c\u624b\u62c9\u624b\u201d\u8fde\u63a5\u5230Sr(4)\u7684\u6676\u683c\u683c\u70b9\u3002\u5f53X = Al\u65f6\uff0c\u76f8\u8fde\u63a5\u7684Sr(4)-O\u952e\u957f\u5206\u522b\u662f2.5872 \u00c5\u4e0e2.4767 \u00c5\uff1b\u5f53X = Ga\u65f6\uff0c\u7531\u4e8er (Ga<sup>3+<\/sup>)\uff1er (Al<sup>3+<\/sup>)\uff0c\u901a\u8fc7\u201c\u624b\u62c9\u624b\u201d\u8fde\u63a5\u7684Sr(4)\u7a7a\u95f4\u4f1a\u53d7\u5230\u4e00\u5b9a\u7a0b\u5ea6\u7684\u6324\u538b\uff0c\u5176\u5177\u4f53\u8868\u73b0\u5728\u76f8\u8fde\u63a5\u7684Sr(4)-O\u952e\u957f\u53d8\u77ed\uff082.5849 \u00c5\u548c2.4740 \u00c5\uff09\u3002\u800c\u8fd9\u79cd\u5fae\u5c0f\u7684\u7a7a\u95f4\u6536\u7f29\u4f1a\u51cf\u5c11\u53d1\u5149\u4e2d\u5fc3Eu<sup>2+<\/sup>\u79bb\u5b50\u8fdb\u5165Sr(4)\u683c\u4f4d\u7684\u542b\u91cf\uff0c\u8fdb\u800c\u5f71\u54cd\u53d1\u5c04\u5149\u8c31\u4e2d\u7ea2\u5149\u6ce2\u6bb5\u7684\u5f3a\u5ea6\uff0c\u4ece\u800c\u5b9e\u73b0\u5149\u8c31\u8c03\u63a7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-226470\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-3-15.png\" alt=\"\" width=\"600\" height=\"249\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-3-15.png 600w, 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Eu<sup>2+<\/sup>\uff0c\u5176\u4e2dSc<sup>3+<\/sup>\uff0cLu<sup>3+<\/sup>\uff0cY<sup>3+<\/sup>\u79bb\u5b50\u534a\u5f84\u76f8\u5bf9\u8f83\u5927\uff0c\u4f1a\u66f4\u5927\u7a0b\u5ea6\u7684\u538b\u7f29Sr(4)\u4f4d\u70b9\u7684\u7a7a\u95f4\u5927\u5c0f\uff0c\u4ece\u800c\u51cf\u5f31\u8367\u5149\u7c89\u7684\u7ea2\u5149\u53d1\u5c04\uff0c\u5448\u73b0\u51fa\u9ec4\u7eff\u6216\u8005\u7eff\u5149\u53d1\u5c04\u3002\u6700\u540e\uff0c\u6240\u5236\u5907SCXP\u8367\u5149\u7c89\u4e0e\u5546\u7528\u84dd\u7c89\u548c400 nm\u7684\u82af\u7247\u5c01\u88c5\u7684\u767d\u5149LED\u5668\u4ef6\u5448\u73b0\u51fa\u8f83\u9ad8\u663e\u8272\u6307\u6570\uff0c\u8fd9\u5bf9\u4e8e\u53d1\u5c55\u4e0b\u4e00\u4ee3\u9ad8\u8d28\u91cf\u7167\u660e\u5149\u6e90\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<\/p>\n<p>https:\/\/doi.org\/10.1016\/j.cej.2021.131869<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5982\u4f55\u8c03\u63a7\u6fc0\u6d3b\u79bb\u5b50\u5728\u4e0d\u540c\u6676\u683c\u4f4d\u70b9\u7684\u53d1\u5149\u884c\u4e3a\u5bf9\u53d1\u5c55\u4e0b\u4e00\u4ee3\u9ad8\u8d28\u91cf\u7167\u660e\u5149\u6e90\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u610f\u4e49\u3002\u5f53\u524d\uff0c\u64cd\u7eb5\u6fc0\u6d3b\u79bb\u5b50\u5728\u4e0d\u540c\u6676\u683c\u683c\u70b9\u7684\u5206\u5e03\u4f9d\u65e7\u662f\u4e00\u9879\u91cd\u8981\u7684\u79d1\u6280\u6311\u6218\u3002\u767d\u78f7\u9499\u77ff\u6784&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-226468","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226468"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=226468"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226468\/revisions"}],"predecessor-version":[{"id":226473,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/226468\/revisions\/226473"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=226468"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=226468"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=226468"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}