{"id":225997,"date":"2021-08-14T06:30:41","date_gmt":"2021-08-13T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=225997"},"modified":"2021-08-13T14:26:55","modified_gmt":"2021-08-13T06:26:55","slug":"%e9%83%91%e5%b7%9e%e5%a4%a7%e5%ad%a6%e5%a7%ac%e6%b5%b7%e9%b9%8f%e5%9b%a2%e9%98%9finorg-chem%ef%bc%9a%e5%ae%a4%e6%b8%a9%e5%88%b6%e5%a4%87batif6mn4%e5%a4%a7%e5%8d%95%e6%99%b6%e7%ba%a2%e5%85%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=225997","title":{"rendered":"\u90d1\u5dde\u5927\u5b66\u59ec\u6d77\u9e4f\u56e2\u961fInorg\u00a0Chem\uff1a\u5ba4\u6e29\u5236\u5907BaTiF6:Mn4+\u5927\u5355\u6676\u7ea2\u5149\u8367\u5149\u4f53"},"content":{"rendered":"
Mn4+<\/sup>\u6fc0\u6d3b\u6c1f\u5316\u7269\u8367\u5149\u7c89\u5177\u6709\u5bbd\u5e26\u84dd\u5149\u5438\u6536\u3001\u7a84\u5e26\u7ea2\u5149\u53d1\u5c04\u53ca\u91cf\u5b50\u6548\u7387\u9ad8\u3001\u70ed\u731d\u706d\u6e29\u5ea6\u9ad8\u7b49\u7279\u70b9\uff0c\u81ea\u7f8e\u56fd\u901a\u7528\u7535\u6c14\u516c\u53f8\u5c06K2<\/sub>SiF6<\/sub>:Mn4<\/sup>+<\/sup>\u7ea2\u5149\u8367\u5149\u7c89\u5546\u4e1a\u5316\u540e\uff0c\u65b0\u578bMn4+<\/sup>\u6fc0\u6d3b\u7ea2\u5149\u8367\u5149\u7c89\u7684\u7814\u53d1\u53ca\u5176\u5728\u767d\u5149\u534a\u5bfc\u4f53\u53d1\u5149\u4e8c\u6781\u7ba1\u4e2d\u7684\u5e94\u7528\u5f15\u8d77\u4e86\u6781\u5927\u5174\u8da3\u3002\u4f46Mn4+<\/sup>\u6fc0\u6d3b\u6c1f\u5316\u7269\u8367\u5149\u7c89\u5728\u6f6e\u6e7f\u73af\u5883\u4e0b\u6613\u53d1\u751f\u6f6e\u89e3\u52a3\u5316\uff0c\u6240\u542b[MnF6<\/sub>]2<\/sup>–<\/sup>\u6f6e\u89e3\u4e3aK2<\/sub>MnF5<\/sub>\/MnOOH\/MnO\u7b49\u800c\u4e25\u91cd\u964d\u4f4e\u8367\u5149\u7c89\u7684\u91cf\u5b50\u6548\u7387\u3002\u4e3a\u4e86\u963b\u6b62[MnF6<\/sub>]2<\/sup>–<\/sup>\u57fa\u56e2\u7684\u6f6e\u89e3\uff0c\u76ee\u524d\u6587\u732e\u62a5\u9053\u4e866\u79cd\u7b56\u7565\uff1a\u6709\u673a\u5305\u8986\u3001\u65e0\u673a\u5305\u8986\u3001\u81ea\u8eab\u5305\u8986\u3001\u8868\u9762\u51cfMn\u949d\u5316\u5904\u7406\u3001\u6c34\u70ed\u518d\u7ed3\u6676\u3001\u5236\u5907\u5355\u6676\u8367\u5149\u4f53\u3002\u5176\u4e2d\uff0c\u5236\u5907\u5355\u6676\u8367\u5149\u4f53\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u964d\u4f4e[MnF6<\/sub>]2<\/sup>–<\/sup>\u57fa\u56e2\u6f6e\u89e3\u52a3\u5316\u901f\u7387\uff0c\u8fd8\u53ef\u4ee5\u51cf\u5c11\u7f3a\u9677\u3001\u63d0\u9ad8\u70ed\u4f20\u5bfc\u3001\u91c7\u7528\u975e\u6811\u8102\u5c01\u88c5\u7b49\u7279\u70b9\u3002\u5bf9\u4e8e\u6c1f\u7845\u9178\u76d0\u3001\u6c1f\u949b\u9178\u76d0\u7b49\u6eb6\u89e3\u5ea6\u76f8\u5bf9\u8f83\u4f4e\u7684\u57fa\u8d28\uff0c\u5982\u4f55\u5236\u5907\u5927\u5355\u6676\u8367\u5149\u4f53\u76ee\u524d\u5c1a\u672a\u89c1\u62a5\u9053\u3002\u6bd4\u5982\u5bf9\u4e8eBaTiF6<\/sub>:Mn4+<\/sup>\uff0c\u56e0\u4e3aBaF2<\/sub>\u539f\u6599\u5728\u5e38\u6e29\u4e0b\u96be\u6eb6\u4e8e\u6c34\u6587\u732e\u62a5\u9053\u591a\u91c7\u7528\u6c34\u70ed\u53cd\u5e94\u5236\u5907\uff0c\u4f46\u6c34\u70ed\u6761\u4ef6\u4e0b\u9530\u6e90\uff08\u5982K2<\/sub>MnF6<\/sub>\uff09\u7684\u4ef7\u6001\u96be\u4ee5\u63a7\u5236\u5728+4\u4ef7\u3002\u5982\u4f55\u5728\u5ba4\u6e29\u6216\u66f4\u4f4e\u6e29\u6761\u4ef6\u4e0b\u5236\u5907\u6eb6\u89e3\u5ea6\u8f83\u4f4e\u7684\u5927\u5355\u6676\u8367\u5149\u4f53\uff0c\u662f\u6709\u5f85\u7814\u7a76\u7684\u95ee\u9898\u3002<\/p>\n \u57fa\u4e8e\u6b64\uff0c\u90d1\u5dde\u5927\u5b66\u59ec\u6d77\u9e4f\u535a\u58eb\u62a5\u9053\u4e86\u4e00\u79cd\u5236\u5907BaTiF6<\/sub>:Mn4+<\/sup>\u5355\u6676\u8367\u5149\u4f53\u7684\u5ba4\u6e29\u6eb6\u6db2\u5408\u6210\u65b9\u6cd5\uff0c\u5373\u76f8\u8f6c\u53d8\u6cd5\u3002\u8be5\u65b9\u6cd5\u5229\u7528BaTiOF4<\/sub>\u4e3a\u524d\u9a71\u4f53\uff0c\u5728K2<\/sub>MnF6<\/sub>\/HF\u6eb6\u6db2\u4e2d\u901a\u8fc7\u6eb6\u89e3\/\u6c1f\u5316\u8f6c\u53d8\u4e3aBaTiF6<\/sub>\uff0c\u540c\u65f6Mn4<\/sup>+<\/sup>\u5143\u7d20\u539f\u4f4d\u63ba\u6742\u8fdb\u5165\u8be5\u57fa\u8d28\u4e2d\u800c\u5f97\u5230BaTiF6<\/sub>:Mn4+<\/sup>\u7ea2\u5149\u8367\u5149\u7c89\u3002\u901a\u8fc7\u63a7\u5236BaTiOF4<\/sub>\u524d\u9a71\u4f53\u7684\u7ed3\u6676\u5ea6\u3001\u6709\u6548\u63a7\u5236\u4e86\u5176\u76f8\u8f6c\u53d8\u901f\u7387\u548c\u76ee\u6807\u4ea7\u7269\u6676\u4f53\u5f62\u6838\u4e0e\u751f\u957f\u901f\u7387\uff0c\u4ece\u800c\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\u5f97\u5230\u4e86\u7834\u7eaa\u5f55\u7684\u3001\u957f\u5ea6\u9ad8\u8fbe200\u2212300 \u03bcm\u7684BaTiF6<\/sub>:Mn4+<\/sup>\u67f1\u72b6\u5355\u6676\u8367\u5149\u4f53\u3002\u901a\u8fc7\u8367\u5149\u5149\u8c31\u548c\u6f2b\u53cd\u5c04\u5149\u8c31\u624b\u6bb5\uff0c\u8868\u5f81\u4e86\u6240\u5236\u5907\u5355\u6676\u8367\u5149\u6750\u6599\u6d78\u6ce1\u5728\u6c34\u4e2d\u7684\u6c34\u89e3\u8001\u5316\u884c\u4e3a\uff0c\u53d1\u73b0\u5176\u8868\u73b0\u51fa\u6bd4\u5546\u4e1aK2<\/sub>SiF6<\/sub>:Mn4+<\/sup>\u8367\u5149\u7c89\u66f4\u597d\u7684\u8010\u6c34\u89e3\u8001\u5316\u6027\u80fd\u3002\u672c\u7814\u7a76\u4e3a\u5ba4\u6e29\u5236\u5907\u5176\u4ed6\u5177\u6709\u5f3a\u8010\u6c34\u89e3\u8001\u5316\u6027\u80fd\u7684\u6c1f\u949b\u9178\u76d0\u6216\u6c1f\u7845\u9178\u76d0\u8367\u5149\u7c89\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n \u56fe1. (a) \u5171\u6c89\u6dc0\u6cd5\u548c\u6c34\u70ed\u6cd5\u6240\u5408\u6210BaTiOF4<\/sub>\u7684XRD\u56fe\u8c31\uff1b(b) \u5c06\u6240\u5408\u6210\u7684BaTiOF4<\/sub>\u524d\u9a71\u4f53\u6d78\u5165K2<\/sub>MnF6<\/sub>\/HF\u6eb6\u6db2\u4e2d\u4e0d\u540c\u65f6\u95f4\u6240\u5f97\u4ea7\u7269\u7684SEM\u56fe\u50cf\u3002<\/p>\n \u5728\u672c\u7814\u7a76\u4e2d\uff0c\u5206\u522b\u91c7\u7528\u5171\u6c89\u6dc0\u6cd5\u548c\u6c34\u70ed\u6cd5\u5408\u6210\u5177\u6709\u4e0d\u540c\u7ed3\u6676\u5ea6\u7684BaTiOF4<\/sub>\u524d\u9a71\u4f53\u3002\u5c06\u5176\u6d78\u5165K2<\/sub>MnF6<\/sub>\/HF\u6eb6\u6db2\u4e2d\u901a\u8fc7\u76f8\u8f6c\u53d8\u65b9\u6cd5\u83b7\u5f97BaTiF6<\/sub>:Mn4+<\/sup>\u8367\u5149\u6750\u6599\u65f6\uff0c\u5206\u522b\u8868\u73b0\u51fa\u660e\u663e\u4e0d\u540c\u7684\u76f8\u8f6c\u53d8\u901f\u7387\u3002<\/p>\n \u56fe2. \u4ee5\u91c7\u7528\u4e0d\u540c\u65b9\u6cd5\u5236\u5907\u7684BaTiOF4<\/sub>\u4e3a\u524d\u9a71\u4f53\u6240\u5236\u5907\u7684BaTiF6<\/sub>:Mn4+<\/sup>\u8367\u5149\u6750\u6599\u7684\u6fc0\u53d1\u5149\u8c31(a, c)\u548c\u53d1\u5c04\u5149\u8c31(c, d)<\/p>\n \u6240\u5236\u5907\u7684\u5355\u6676BaTiF6<\/sub>:Mn4+<\/sup>\u8367\u5149\u6750\u6599\u8868\u73b0\u51fa\u76f8\u4f3c\u7684\u8367\u5149\u6027\u8d28\uff0c\u6fc0\u53d1\u5149\u8c31\u4e3b\u5cf0\u4f4d\u4e8e464 nm\u3001\u53d1\u5149\u5149\u8c31\u4e3b\u5cf0\u4f4d\u4e8e633 nm\u3002\u96f6\u58f0\u5b50\u7ebf\u53d1\u5149\u8f83\u5f31\uff0c\u8bf4\u660eMn4<\/sup>+<\/sup>\u5728BaTiF6<\/sub>\u57fa\u8d28\u6676\u683c\u4e2d\u6240\u5f62\u6210\u7684\u5fae\u89c2\u516b\u9762\u4f53\u76f8\u5bf9\u89c4\u6574\uff1b\u65af\u6258\u514b\u65af\u548c\u53cd\u65af\u6258\u514b\u65af\u03bd6<\/sub>\u53d1\u5149\u5cf0\u51fa\u73b0\u4e86\u5288\u88c2\uff0c\u4e0eBaTiF6<\/sub>\u7684\u7a7a\u95f4\u7fa4\uff08R<\/i><\/em>-3m<\/i><\/em>\uff09\u4f4e\u4e8e\u7acb\u65b9\u6676\u7cfb\u76f8\u543b\u5408\u3002<\/p>\n \u56fe3. \u4ee5\u6c34\u70ed\u6cd5\u6240\u5f97BaTiOF4<\/sub>\u4e3a\u524d\u9a71\u4f53\u6240\u5236\u5907\u7684BaTiF6<\/sub>:Mn4+<\/sup>\u8367\u5149\u6750\u6599\u7684\u5149\u5b66\u7167\u7247(a, b)\u548cSEM\u56fe\u50cf(c, d)<\/p>\n \u5c06\u6c34\u70ed\u6cd5\u6240\u5f97BaTiOF4<\/sub>\u524d\u9a71\u4f53\u4e0eK2<\/sub>MnF6<\/sub>\/HF\u6eb6\u6db2\u6df7\u5408\u540e\uff0c\u4ee5\u9002\u5f53\u9891\u7387\u9010\u6ef4\u52a0\u5165\u5230\u57f9\u517b\u76bf\u4e2d\uff0c\u6700\u7ec8\u5f97\u5230\u4e86\u76ee\u524d\u6587\u732e\u6240\u89c1\u5c3a\u5bf8\u6700\u5927\u7684BaTiF6<\/sub>:Mn4+<\/sup>\u5355\u6676\u8367\u5149\u6750\u6599\uff08200-300 \u03bcm\uff09\u3002<\/p>\n \u56fe4. BaTiF6<\/sub>:Mn4+<\/sup>\u5355\u6676\u8367\u5149\u6750\u6599\u4e0e\u5546\u4e1aK2<\/sub>SiF6<\/sub>:Mn4+<\/sup>\u6d78\u6c34\u52a3\u5316\u5bf9\u6bd4(a),\u00a0\u8367\u5149\u5f3a\u5ea6\u53d8\u5316(b)\u548c\u6d78\u6ce124 h\u540e\u7684\u6f2b\u53cd\u5c04\u5149\u8c31(c)<\/p>\n \u91c7\u7528\u8367\u5149\u5149\u8c31\u548c\u6f2b\u53cd\u5c04\u5149\u8c31\u8bc4\u4ef7\u5c06\u6240\u5236\u5907BaTiF6<\/sub>:Mn4+<\/sup>\u5355\u6676\u8367\u5149\u6750\u6599\u4e0e\u5546\u4e1aK2<\/sub>SiF6<\/sub>:Mn4<\/sup>+<\/sup>\u8367\u5149\u7c89\u6d78\u5165\u6c34\u4e2d\u5bf9\u6bd4\u6c34\u89e3\u52a3\u5316\u884c\u4e3a\u3002\u53ef\u89c1\u57283\u00a0h\u540e\uff0c\u5546\u4e1aK2<\/sub>SiF6<\/sub>:Mn4<\/sup>+<\/sup>\u8367\u5149\u7c89\u5df2\u5b8c\u5168\u53d8\u68d5\u8272\uff0c\u800cBaTiF6<\/sub>:Mn4+<\/sup>\u5355\u6676\u8367\u5149\u6750\u6599\u5c1a\u4fdd\u6301\u8f83\u5f3a\u8367\u5149\u5f3a\u5ea6\uff1b\u6f2b\u53cd\u5c04\u5149\u8c31\u4e5f\u8bc1\u660e\u53d8\u68d5\u662f\u6837\u54c1\u4e2d\u7684Mn4<\/sup>+<\/sup>\u8f6c\u53d8\u4e3a\u5176\u4ed6\u6742\u8d28\u4ef7\u6001\uff08\u5982Mn3<\/sup>+<\/sup>\uff09\u3002<\/p>\n \u8bba\u6587\u4fe1\u606f<\/p>\n BaTiF<\/b><\/strong>6<\/b><\/sub><\/strong>:Mn<\/b><\/strong>4+<\/b><\/sup><\/strong>\u00a0Red Phosphor: Synthesis of Single Crystals at Room Temperature and the High Hydrolysis-Resistant Property<\/b><\/strong><\/p>\n Zhaowu Wang, Xiuyuan Wang, Haipeng Ji,* Jian Xu, Zongtao Zhang, and Deliang Chen*<\/p>\n Inorganic<\/i><\/em>\u00a0<\/i><\/em>Chemistry<\/i><\/em>, 2021, online.<\/p>\n \u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acs.inorgchem.1c01601<\/p>\n","protected":false},"excerpt":{"rendered":" Mn4+\u6fc0\u6d3b\u6c1f\u5316\u7269\u8367\u5149\u7c89\u5177\u6709\u5bbd\u5e26\u84dd\u5149\u5438\u6536\u3001\u7a84\u5e26\u7ea2\u5149\u53d1\u5c04\u53ca\u91cf\u5b50\u6548\u7387\u9ad8\u3001\u70ed\u731d\u706d\u6e29\u5ea6\u9ad8\u7b49\u7279\u70b9\uff0c\u81ea\u7f8e\u56fd\u901a\u7528\u7535\u6c14\u516c\u53f8\u5c06K2SiF6:Mn4+\u7ea2\u5149\u8367\u5149\u7c89\u5546\u4e1a\u5316\u540e\uff0c\u65b0\u578bMn4…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-225997","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225997"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=225997"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225997\/revisions"}],"predecessor-version":[{"id":226002,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225997\/revisions\/226002"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=225997"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=225997"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=225997"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n