{"id":225710,"date":"2021-08-09T12:00:00","date_gmt":"2021-08-09T04:00:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=225710"},"modified":"2021-08-09T10:23:04","modified_gmt":"2021-08-09T02:23:04","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e6%9c%80%e6%96%b0nature-mater-%e6%b0%b4%e9%92%a0%e9%94%b0%e7%9f%bf%e7%94%b5%e5%ae%b9%e8%a1%8c%e4%b8%ba%e6%9c%ba%e7%90%86%e7%9a%84%e6%b7%b1%e5%b1%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=225710","title":{"rendered":"\u6700\u65b0Nature Mater.:\u6c34\u94a0\u9530\u77ff\u7535\u5bb9\u884c\u4e3a\u673a\u7406\u7684\u6df1\u5c42\u6b21\u89e3\u91ca"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u7535\u89e3\u8d28\u79bb\u5b50\u5728\u56fa\u6db2\u7535\u5316\u5b66\u754c\u9762\u7684\u5438\u9644\u662f\u4e00\u79cd\u666e\u904d\u5b58\u5728\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\uff0c\u76f4\u63a5\u5e94\u7528\u4e8e\u80fd\u91cf\u5b58\u50a8\u3001\u7535\u5bb9\u53bb\u79bb\u5b50\u548c\u5143\u7d20\u56de\u6536\u3002\u7535\u5316\u5b66\u754c\u9762\u79bb\u5b50\u7684\u7ec4\u7ec7\u548c\u52a8\u529b\u5b66\u5bf9\u4e8e\u7406\u89e3\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u7535\u8377\u8f6c\u79fb\u4e5f\u5f88\u91cd\u8981\u3002\u79bb\u5b50\u4e0e\u7535\u6781\u8868\u9762\u7684\u76f8\u4e92\u4f5c\u7528\u7a0b\u5ea6\u53ef\u4ee5\u7528\u4e24\u4e2a\u5438\u9644\u6781\u7aef\u6765\u63cf\u8ff0\uff1a\uff081\uff09\u5b8c\u5168\u6eb6\u5242\u5316\u79bb\u5b50\u7684\u5438\u9644\uff0c\u4e3b\u8981\u662f\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff1b\uff082\uff09\u53bb\u6eb6\u5242\u5316\u6216\u90e8\u5206\u6eb6\u5242\u5316\u7684\u7279\u5b9a\u5438\u9644\u79bb\u5b50\uff0c\u6d89\u53ca\u5316\u5b66\u952e\uff0c\u8fd9\u5bfc\u81f4\u5728\u7535\u5316\u5b66\u754c\u9762\u5b9a\u4e49\u4e24\u79cd\u7c7b\u578b\u7684\u7535\u5bb9\uff1a\u4e0e\u9759\u7535\u5438\u9644\u76f8\u5173\u7684\u975e\u6cd5\u62c9\u7b2c\u53cc\u7535\u5c42 (EDL) \uff08\uff08\u4ec5\u6d89\u53ca\u9759\u7535\u76f8\u4e92\u4f5c\u7528\uff09\uff09\u7535\u5bb9\u548c\u4e0e\u7279\u5b9a\u5438\u9644\u76f8\u5173\u7684\u6cd5\u62c9\u7b2c\u8d5d\u7535\u5bb9\uff08\uff08\u6d89\u53ca\u6c27\u5316\u8fd8\u539f\uff09\uff09\u3002\u7eb3\u7c73\u7ed3\u6784\u7684\u6c34\u94a0\u9530\u77ff\u5728\u6c34\u7cfb\u7535\u89e3\u8d28\u4e2d\u8868\u73b0\u51fa\u9ad8\u6bd4\u7535\u5bb9\u548c\u8fd1\u4e4e\u7406\u60f3\u7684\u7535\u5bb9\u884c\u4e3a\uff0c\u4f7f\u5176\u6210\u4e3a\u4f4e\u6210\u672c\u3001\u9ad8\u529f\u7387\u50a8\u80fd\u8bbe\u5907\u7684\u91cd\u8981\u7535\u6781\u6750\u6599\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u6c34\u94a0\u9530\u77ff\u4e5f\u8868\u73b0\u51fa\u4e0e\u8d5d\u7535\u5bb9\u76f8\u5173\u8054\u7684\u7279\u5f81\uff0c\u4f8b\u5982\u5728\u7ed3\u6784\uff0c\u5c40\u90e8\u952e\u5408\u548cMn\u7684\u6c27\u5316\u6001\u7684\u53d8\u5316\u3002\u4ee5\u4e0d\u540c\u65b9\u5f0f\u89e3\u91ca\u76f8\u540c\u7684\u7535\u5316\u5b66\u54cd\u5e94\u8868\u660e\u76ee\u524d\u5bf9\u5305\u542b\u7eb3\u7c73\u9650\u5236\u7684\u7eb3\u7c73\u7ed3\u6784\u6750\u6599\u4e2d\u7684\u7535\u5316\u5b66\u7535\u5bb9\u7684\u7406\u89e3\u4e0d\u591f\u5145\u5206\u3002\u6b64\u5916\uff0c\u9633\u79bb\u5b50\u5d4c\u5165\u6c34\u94a0\u9530\u77ff\u5bfc\u81f4\u4e86\u4e00\u4e2a\u95ee\u9898\uff0c\u5373\u4e3a\u4ec0\u4e48\u5b83\u4f1a\u51fa\u73b0\u7535\u5bb9\u6027\uff0c\u800c\u5927\u591a\u6570\u5176\u4ed6\u79bb\u5b50\u5d4c\u5165\uff08\u4f8b\u5982\u9502\u79bb\u5b50\u7535\u6c60\uff09\u5219\u6ca1\u6709\u3002\u6c34\u94a0\u9530\u77ff\u5185\u7684\u6c34\u5408\u4f5c\u7528\u548c\u9650\u5236\u7684\u7ed3\u5408\u6a21\u7cca\u4e86\u4f20\u7edf\u7535\u5bb9EDL\u548c\u6cd5\u62c9\u7b2c\u5d4c\u5165\u4e4b\u95f4\u7684\u533a\u522b\u3002<\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd<\/strong>\u5317\u5361\u7f57\u83b1\u7eb3\u5dde\u7acb\u5927\u5b66<\/strong>Veronica Augustyn\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u4e3a\u4e86\u9610\u660e\u6c34\u94a0\u9530\u77ff\u4e2d\u76f8\u5173\u7684\u7535\u5bb9\u673a\u5236\uff0c\u4f7f\u7528\u975e\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\u3001\u7535\u5316\u5b66\u77f3\u82f1\u6676\u4f53\u5fae\u5929\u5e73\u3001\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u548c\u539f\u4f4d\u539f\u5b50\u529b\u663e\u5fae\u955c\u81a8\u80c0\u4eea\u8868\u5f81\u4e86\u6c34\u94a0\u9530\u77ff\u5bf9\u5916\u52a0\u7535\u4f4d\u7684\u54cd\u5e94\uff0c\u4ee5\u63d0\u4f9b\u5bf9\u5176\u7ed3\u6784\u3001\u91cd\u91cf\u548c\u529b\u5b66\u7b49\u591a\u4e2a\u89d2\u5ea6\u5168\u9762\u7684\u7406\u89e3\u3002\u540c\u65f6\uff0c\u8fd9\u4e9b\u89c2\u5bdf\u7ed3\u679c\u5f97\u5230\u4e86\u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u7684\u6c34\u94a0\u9530\u77ff\u9633\u79bb\u5b50\u63d2\u5c42\u7ed3\u6784\u7684\u539f\u5b50\u5c3a\u5ea6\u6a21\u62df\uff0c\u57fa\u4e8eReaxFF\u53cd\u5e94\u529b\u573a\u7684\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u57fa\u4e8eReaxFF\u7684\u6c34\u7cfb\u7535\u89e3\u8d28\u754c\u9762\u52a8\u529b\u5b66\u7684\u8499\u7279\u5361\u7f57\u7b49\u76f8\u5173\u7406\u8bba\u6a21\u62df\u7684\u652f\u6301\u3002\u6b64\u5916\uff0c\u9610\u660e\u4e86\u7684\u5c40\u90e8\u548c\u7535\u5b50\u7ed3\u6784\uff0c\u786e\u5b9a\u4e86\u6700\u53ef\u80fd\u7684\u5d4c\u5165\u7269\u8d28\u5e76\u4e86\u89e3\u79bb\u5b50\u5d4c\u5165\u7684\u52a8\u529b\u5b66\u3002\u7814\u7a76\u8868\u660e\uff0c\u6c34\u94a0\u9530\u77ff\u4e2d\u7684\u7535\u5bb9\u7535\u8377\u5b58\u50a8\u662f\u7531\u5c42\u95f4\u9633\u79bb\u5b50\u5d4c\u5165\u63a7\u5236<\/strong>\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u7eb3\u7c73\u9650\u5236\u5c42\u95f4\u7ed3\u6784\u6c34\u7684\u5b58\u5728\uff0c\u589e\u52a0\u4e86\u5d4c\u5165\u9633\u79bb\u5b50\u548c\u91d1\u5c5e\u6c27\u5316\u7269\u4e4b\u95f4\u7684\u8ddd\u79bb\uff0c\u5bfc\u81f4\u76f8\u4e92\u4f5c\u7528\u964d\u4f4e\uff0c\u8868\u73b0\u51fa\u7535\u5bb9\u6027\u8d28\uff0c\u5b83\u4ecb\u5bfc\u4e86\u63d2\u5c42\u9633\u79bb\u5b50\u4e0e\u6c34\u94a0\u9530\u77ff\u4e3b\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5e76\u5bfc\u81f4\u4e86\u6700\u5c0f\u7684\u7ed3\u6784\u53d8\u5316\u3002\u603b\u4e4b\uff0c\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\u5c06\u6c34\u94a0\u9530\u77ff\u7684\u7535\u5bb9\u54cd\u5e94\u5206\u4e3aEDL\u6216\u8d5d\u7535\u5bb9\u7684\u7ed3\u679c\u5e76\u4e0d\u80fd\u5b8c\u5168\u4ee3\u8868\u8be5\u673a\u5236\uff0c\u7c7b\u4f3c\u4e8e\u79bb\u5b50\u952e\u548c\u5171\u4ef7\u952e\u4e4b\u95f4\u7684\u533a\u522b\u3002\u672c\u6587\u8fd8\u5047\u8bbe\u7eb3\u7c73\u7ed3\u6784\u6c34\u4ecb\u5bfc\u4e86\u5d4c\u5165\u9633\u79bb\u5b50\u4e0eMnO2<\/sub>\u5c42\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5bfc\u81f4\u79bb\u5b50\u5d4c\u5165\u51e0\u4e4e\u6ca1\u6709\u6f5c\u5728\u7684\u4f9d\u8d56\u6027\u548c\u7ed3\u6784\u53d8\u5316\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cEffects of interlayer confinement and hydration on capacitive charge storage in birnessite<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Materials<\/i><\/em><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>\u4e00<\/b><\/strong>\u3001\u7535\u5316\u5b66\u754c\u9762\u548c\u7535\u6781\u6750\u6599\u7684\u7eb3\u7c73\u9650\u5236\u5c42\u4e2d\u9633\u79bb\u5b50\u5438\u9644\u7684\u6982\u5ff5<\/b><\/strong>\u5bf9\u6bd4<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

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\uff08b\uff09\u5728\u5c42\u95f4\u7eb3\u7c73\u9650\u5236\u4e0b, \u5c42\u95f4\u8ddd\u79bb\uff08d\uff09\u548c\u9633\u79bb\u5b50\u6eb6\u5242\u5316\u7a0b\u5ea6\u51b3\u5b9a\u4e86\u7535\u6781\u6750\u6599\u4e0e\u9633\u79bb\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u7a0b\u5ea6\u3002\u672c\u6587\u5047\u8bbe\u8fd9\u4f1a\u5bfc\u81f4\u7c7b\u4f3c\u4e8e\u5e73\u9762\u754c\u9762\u7684\u9633\u79bb\u5b50\u5438\u9644\u884c\u4e3a\uff0c\u9759\u7535\u5438\u9644\u662f\u7531\u4e8e\u6eb6\u5242\u5316\u9633\u79bb\u5b50\u7684\u5d4c\u5165\u548c\u53bb\u6eb6\u5242\u5316\u9633\u79bb\u5b50\u5d4c\u5165\u65f6\u7684\u7535\u8377\u8f6c\u79fb\u3002<\/p>\n

\u56fe<\/b><\/strong>\u4e8c\u3001\u7535\u6c89\u79ef\u6c34\u94a0\u9530\u77ff\u8584\u819c\u7684\u7ed3\u6784\u548c\u5f62\u6001<\/b><\/strong>\"\"<\/b><\/strong>\uff08a\uff09\u6c34\u94a0\u9530\u77ff\u6676\u4f53\u7ed3\u6784\u6a21\u578b\uff1b<\/p>\n

\uff08b\uff09XRD\u56fe\u8c31\u4ee5\u663e\u793a\u5c42\u95f4\u8ddd\uff1b<\/p>\n

\uff08c\uff09\u663e\u793a\u6c34\u94a0\u9530\u77ff\u7684Mn-O\u62c9\u4f38\u6a21\u5f0f\u7684\u62c9\u66fc\u5149\u8c31\uff1a<\/p>\n

\uff08d\uff09\u5728\u8fdc\u79bb\u7535\u63a5\u89e6\u7684\u7535\u6781\u5e95\u90e8\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09\u6c34\u94a0\u9530\u77ff\u7eb3\u7c73\u7247\u7684\u653e\u5927SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09\u57280.5 M K2<\/sub>SO4<\/sub>\u7535\u89e3\u8d28\u4e2d\u7684AFM\u6db2\u4f53\u6572\u51fb\u6a21\u5f0f\u9ad8\u5ea6\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/b><\/strong>\u4e09<\/b><\/strong>\u3001\u6c34\u94a0\u9530\u77ff\u5728<\/b><\/strong>0.5 M K<\/b><\/strong>2<\/b><\/sub><\/strong>SO<\/b><\/strong>4<\/b><\/sub><\/strong>\u4e2d\u7684\u7535\u5316\u5b66<\/b><\/strong>\u884c\u4e3a<\/b><\/strong>\u548c\u7ed3\u6784<\/b><\/strong>\u6f14\u53d8<\/b><\/strong>\"\"<\/b><\/strong><\/p>\n

\uff08a\uff09\u4ee510 mV s-1<\/sup>\u7684\u626b\u901f\u7684CV\u663e\u793a\u51fa\u8fd1\u4e4e\u7406\u60f3\u7684\u7535\u5bb9\u884c\u4e3a\uff1b<\/p>\n

\uff08b\uff09\u975e\u539f\u4f4dXRD\u7684\u5f52\u4e00\u5316\uff08001\uff09\u5cf0\uff0c\u8868\u660e\u5939\u5c42\u4e3b\u8981\u5728\u7535\u4f4d\u8303\u56f4\u7684\u4e2d\u95f4\u81a8\u80c0\uff1b<\/p>\n

\uff08c\uff0cd\uff09K+<\/sup>\u8131\u5d4c\u548c\u5d4c\u5165\u524d\u540e\u7684DFT\u7ed3\u6784\uff0c\u8868\u660e\u5c42\u95f4\u8ddd\u968f\u7740\u9633\u79bb\u5b50\u8131\u5d4c\u800c\u589e\u52a0\u3002<\/p>\n

\u56fe<\/b><\/strong>\u56db<\/b><\/strong>\u3001\u6c34\u94a0\u9530\u77ff\u4e2d\u4ee5\u9633\u79bb\u5b50\u4e3a\u4e3b\u7684\u7535\u5bb9\u6027\u7535\u8377\u5b58\u50a8<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09K2<\/sub>SO4<\/sub>\u4e2d\u6c34\u94a0\u9530\u77ff\u7684\u8d28\u91cf\u53d8\u5316\u4e0e\u7535\u4f4d\uff1b<\/p>\n

\uff08b\uff09\u4ee510 mV s-1<\/sup>\u7684\u626b\u901f\u6d4b\u8bd5\u7684CV\u8868\u660e\u7535\u6d41\u4e0e\u8d28\u91cf\u53d8\u5316\u76f4\u63a5\u76f8\u5173\uff1b<\/p>\n

\uff08c\uff09K+<\/sup>\u548cH2<\/sub>O\u5d4c\u5165\u6c34\u94a0\u9530\u77ff\u4e2d\u7684ReaxFF GCMC\u6a21\u62df\u5feb\u7167\u3002<\/p>\n

\u56fe<\/b><\/strong>\u4e94<\/b><\/strong>\u3001<\/b><\/strong>K<\/b><\/strong>+<\/b><\/sup><\/strong>\u548cH<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>\uff08\u8131\uff09\u5d4c\u5165\u8fc7\u7a0b\u4e2d\u6c34\u94a0\u9530\u77ff\u5c40\u90e8\u548c\u7535\u5b50\u7ed3\u6784\u7684\u53d8\u5316<\/b><\/strong><\/p>\n

\"\"\uff08a\uff09\u6c34\u94a0\u9530\u77ff\u5728K2<\/sub>SO4<\/sub>\u4e2d\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u7684\u7d2f\u79ef\u62df\u5408\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u6765\u81ea\u539f\u4f4d\u62c9\u66fc\u7684\u03bd1<\/sub>\u4e2d\u5fc3\u7684\u51e0\u4e4e\u8fde\u7eed\u7684\u53d8\u5316\u4e0e\u6765\u81eaXRD\u7684\u5c42\u95f4\u95f4\u8ddd\u7684\u53d8\u5316\u76f8\u5173\u6027\uff1b<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>Effects of interlayer confinement and hydration on capacitive charge storage in birnessite<\/u><\/strong><\/a>\u201d(<\/strong>Nature Materials<\/i><\/em><\/strong>\uff0c<\/b><\/strong>202<\/strong>1<\/strong>\uff0c<\/strong>10.1038\/s41563-021-01066-4<\/strong>)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4ebaCYM\u7f16\u8bd1\u4f9b\u7a3f\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

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 <\/p>\n","protected":false},"excerpt":{"rendered":"

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