{"id":225564,"date":"2021-08-09T06:39:55","date_gmt":"2021-08-08T22:39:55","guid":{"rendered":"\/\/m.iemloyee.com\/?p=225564"},"modified":"2021-08-08T20:40:11","modified_gmt":"2021-08-08T12:40:11","slug":"%e9%9f%a9%e5%b8%83%e5%85%b4%e9%99%a2%e5%a3%abnature-communications%ef%bc%9a%e4%bb%8e%e6%9c%a8%e8%b4%a8%e7%b4%a0%e4%b8%ad%e7%94%9f%e4%ba%a7%e8%8b%af","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=225564","title":{"rendered":"\u97e9\u5e03\u5174\u9662\u58ebNature Communications\uff1a\u4ece\u6728\u8d28\u7d20\u4e2d\u751f\u4ea7\u82ef"},"content":{"rendered":"<p><strong><b>\u80cc\u666f\u4ecb\u7ecd<\/b><\/strong><\/p>\n<p>\u5982\u4eca\uff0c\u82ef\u662f\u5316\u5de5\u884c\u4e1a\u4e0d\u53ef\u6216\u7f3a\u7684\u5927\u5b97\u5546\u54c1\uff0c2019\u5e74\u5168\u7403\u82ef\u4ea7\u91cf\u8d85\u8fc76100\u4e07\u5428\u3002\u672a\u6765\u5341\u5e74\uff0c\u5168\u7403\u82ef\u9700\u6c42\u9884\u8ba1\u5c06\u4ee5\u6bcf\u5e742.9\u00a0%\u7684\u901f\u5ea6\u589e\u957f\u3002\u7279\u522b\u662f\u5728\u5236\u9020\u4e1a\uff0c\u82ef\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u8bb8\u591a\u90e8\u95e8\uff0c\u5728\u90a3\u91cc\u5b83\u4e0e\u5176\u4ed6\u57fa\u672c\u5316\u5b66\u54c1(\u5982\u4e59\u70ef\u548c\u4e19\u70ef)\u7ed3\u5408\u548c\u52a0\u5de5\uff0c\u4ee5\u751f\u4ea7\u6709\u4ef7\u503c\u7684\u6d88\u8d39\u54c1\uff0c\u5982\u670d\u88c5\u3001\u5305\u88c5\u3001\u6c7d\u8f66\u90e8\u4ef6\u3001\u5efa\u7b51\u6750\u6599\u3001\u836f\u54c1\u3001\u5316\u5986\u54c1\u3001\u963b\u71c3\u5242\u3001\u5149\u76d8\u3001\u773c\u955c\u955c\u7247\u3001\u5730\u6bef\uff0c\u533b\u7528\u690d\u5165\u7269\uff0c\u6ce1\u6cab\u7edd\u7f18\uff0c\u7c98\u5408\u5242\uff0c\u978b\u7c7b\uff0c\u9690\u5f62\u773c\u955c\uff0c\u67d3\u6599\uff0c\u519c\u836f\u3002\u76ee\u524d\uff0c\u82ef\u4e3b\u8981\u901a\u8fc7\u50ac\u5316\u91cd\u6574\u3001\u84b8\u6c7d\u88c2\u89e3\u3001\u7532\u82ef\u6b67\u5316\u548c\u7164\u70ad\u52a0\u5de5\u7b49\u65b9\u5f0f\u4ece\u77f3\u6cb9\u548c\u7164\u70ad\u4e2d\u751f\u4ea7\u3002\u6b64\u5916\uff0c\u8fd8\u5728\u8fdb\u884c\u5c06\u7532\u70f7\u8f6c\u5316\u4e3a\u82ef\u7684\u7814\u7a76\u3002\u4f46\u4e0a\u8ff0\u9014\u5f84\u5747\u4f9d\u8d56\u5316\u77f3\u8d44\u6e90\uff0c\u4e14\u5b58\u5728\u6761\u4ef6\u590d\u6742\u4e25\u5cfb\u3001\u80fd\u8017\u9ad8\u3001\u73af\u5883\u6c61\u67d3\u4e25\u91cd\u7b49\u7f3a\u70b9\u3002\u56e0\u6b64\uff0c\u8feb\u5207\u9700\u8981\u91c7\u53d6\u66f4\u52a0\u826f\u6027\u548c\u53ef\u6301\u7eed\u7684\u6218\u7565\uff0c\u4f8b\u5982\u5229\u7528\u53ef\u518d\u751f\u8d44\u6e90\u4f5c\u4e3a\u539f\u6599\uff0c\u7ecf\u6d4e\u5730\u751f\u4ea7\u82ef\uff0c\u4ece\u800c\u4f7f\u6211\u4eec\u6446\u8131\u5bf9\u5316\u77f3\u8d44\u6e90\u7684\u4f9d\u8d56\uff0c\u5177\u6709\u91cd\u5927\u7684\u5de5\u4e1a\u548c\u793e\u4f1a\u610f\u4e49\u3002\u8fd9\u79cd\u6709\u5438\u5f15\u529b\u7684\u3001\u5ec9\u4ef7\u7684\u3001\u4e0d\u53ef\u98df\u7528\u7684\u6750\u6599\u5c31\u662f\u6728\u8d28\u7ea4\u7ef4\u7d20\u751f\u7269\u8d28\uff0c\u5b83\u662f\u7531\u5168\u4e16\u754c\u7684\u6797\u4e1a\u548c\u519c\u4e1a\u6d3b\u52a8\u4ea7\u751f\u7684\u3002\u6728\u8d28\u7d20\u662f\u6728\u8d28\u7ea4\u7ef4\u7d20\u7684\u4e3b\u8981\u6210\u5206\uff0c\u662f\u81ea\u7136\u754c\u4e2d\u6700\u4e30\u5bcc\u7684\u82b3\u9999\u65cf\u5efa\u7b51\u6784\u4ef6\u7684\u53ef\u518d\u751f\u8d44\u6e90\uff0c\u5e74\u4ea7\u91cf\u7ea6500\u4ebf\u516c\u5428\u3002\u5728\u5206\u5b50\u7ed3\u6784\u4e0a\uff0c\u6728\u8d28\u7d20\u7684\u82b3\u9999\u7279\u6027\u6e90\u4e8e\u82ef\u73af\u7ed3\u6784\uff0c\u4f7f\u5176\u6210\u4e3a\u53ef\u6301\u7eed\u548c\u7406\u60f3\u7684\u82ef\u751f\u4ea7\u539f\u6599\u3002\u8fd1\u5e74\u6765\uff0c\u4ee5\u6728\u8d28\u7d20\u4e3a\u539f\u6599\u4f7f\u5176\u7a33\u5b9a\u4e3a\u5316\u77f3\u57fa\u5316\u5b66\u54c1\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\uff0c\u5e76\u83b7\u5f97\u4e86\u5404\u79cd\u6709\u4ef7\u503c\u7684\u7528\u4e8e\u8fd0\u8f93\u71c3\u6599\u548c\u5de5\u4e1a\u751f\u4ea7\u7684\u5316\u5b66\u54c1\u3002\u6728\u8d28\u7d20\u9ad8\u6548\u5236\u82ef\u9700\u8981C<sub>sp2<\/sub>-C<sub>sp3<\/sub>\/C<sub>sp2<\/sub>-O\u5168\u90e8\u8f6c\u5316\u4e3aC-H\u952e\uff0c\u800c\u4e0d\u9700\u8981\u4fa7\u52a0\u6c22\u5316\uff0c\u8fd9\u4e00\u70b9\u975e\u5e38\u91cd\u8981\uff0c\u4f46\u76ee\u524d\u5c1a\u672a\u6709\u4eba\u5b9e\u73b0\u3002<\/p>\n<p>\u4e3a\u53d1\u5c55\u7406\u60f3\u7684\u6728\u8d28\u7d20-\u82ef\u5408\u6210\u8def\u7ebf\uff0c\u8fd1\u65e5\uff0c<strong><b>\u4e2d\u79d1\u9662\u5316\u5b66\u7814\u7a76\u6240\u97e9\u5e03\u5174\u9662\u58eb\uff0c<\/b><\/strong><strong><b>\u5b5f\u5e86\u78ca<\/b><\/strong><strong><b>\u7b49\u4eba<\/b><\/strong>\u5728Nature Communications\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201cSustainable production of benzene from lignin\u201d\u3002\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u4ee5RuW\/HY<sub>30<\/sub>\u4e3a\u591a\u529f\u80fd\u50ac\u5316\u5242\uff0c\u4ee5\u6c34\u4e3a\u53cd\u5e94\u4ecb\u8d28\uff0c\u91c7\u7528\u539f\u4f4d\u7cbe\u5236\u7b56\u7565\u8f6c\u5316C<sub>sp2<\/sub>-C<sub>sp3<\/sub>\u548cC<sub>sp2<\/sub>-O\u952e\uff0c\u53ef\u6301\u7eed\u5730\u4ece\u6728\u8d28\u7d20\u751f\u4ea7\u82ef\u7684\u65b9\u6cd5\u3002\u7ed3\u5408\u63a7\u5236\u5b9e\u9a8c\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u8be6\u7ec6\u9610\u8ff0\u4e86\u53cd\u5e94\u673a\u7406\u3002\u8be5\u9ad8\u6548\u65b9\u6848\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u6269\u5927\u89c4\u6a21\uff0c\u4ece50.0 g\u6728\u8d28\u7d20\u4e2d\u53ef\u751f\u4ea78.5 g\u82ef\u4ea7\u54c1\uff0c\u6ca1\u6709\u4efb\u4f55\u9971\u548c\u526f\u4ea7\u7269\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u6728\u8d28\u7d20\u4f5c\u4e3a\u539f\u6599\u9ad8\u6548\u751f\u4ea7\u82ef\u5f00\u8f9f\u4e86\u9053\u8def\u3002<\/p>\n<p><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225569\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-10-1.png\" alt=\"\" width=\"600\" height=\"539\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-10-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-10-1-300x270.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe1. \u82ef\u751f\u4ea7\u7684\u7b56\u7565\u3002<\/p>\n<p>a. \u751f\u4ea7\u82ef\u7684\u4f20\u7edf\u5de5\u4e1a\u8def\u7ebf\u3002b. \u82ef\u751f\u4ea7\u5929\u7136\u6c14\u8def\u7ebf\u3002c. Lignin-to-benzene\u8def\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225568\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-9-1.png\" alt=\"\" width=\"600\" height=\"731\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-9-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-9-1-246x300.png 246w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2. PtSA\/Cs<sub>2<\/sub>SnI<sub>6<\/sub>\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n<p>a, b. XRD;<\/p>\n<p>c,d. EXAFS\u00a0\u8c31<\/p>\n<p>e, f. XPS<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225567\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-8-1.png\" alt=\"\" width=\"600\" height=\"275\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-8-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-8-1-300x138.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe3. C<sub>sp2<\/sub>\u2013C<sub>sp3<\/sub>\u952e\u7684\u8f6c\u6362\u673a\u7406\u7814\u7a76\u3002<\/p>\n<p>a. C<sub>sp2<\/sub>-C<sub>sp3<\/sub>\u952e\u8f6c\u6362\u7684\u80fd\u91cf\u5206\u5e03\u56fe\u3002<\/p>\n<p>b. a\u4e2dBronsted\u9178\u4e2d\u5fc3\u548c\u4e2d\u95f4\u7ed3\u6784(\u7ed3\u6784II\u548cIII)\u7684\u7a7a\u95f4\u586b\u5145\u6a21\u578b\u3002<\/p>\n<p>c. \u7ed3\u6784III\u7684\u6838\u952e\u6307\u6807\u548c1a\u53cd\u5e94\u4e2dC &#8211; C\u952e\u6f14\u5316\u7684<sup>13<\/sup>C NMR\u5206\u6790\u3002<\/p>\n<p>d. <sup>27<\/sup>Al MQMAS\u5728\u7a7a\u767d\u5b9e\u9a8c\u4e2d\u5bf9\u716e\u6cb8\u7684RuW\/HY30\u50ac\u5316\u5242\u8fdb\u884c\u5206\u6790\u3002<\/p>\n<p>e. <sup>27<\/sup>Al MQMAS\u5206\u6790RuW\/HY30\u50ac\u5316\u5242\u57281a\u53cd\u5e94\u4e2d\u7684\u53cd\u5e94\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225566\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-7-1.png\" alt=\"\" width=\"600\" height=\"619\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-7-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-7-1-291x300.png 291w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4. \u539f\u4f4d\u7cbe\u70bc\u7b56\u7565:C<sub>sp2<\/sub>-C<sub>sp3<\/sub>\u548cC<sub>sp2<\/sub>-O\u952e\u7684\u7ec4\u5408\u3002<\/p>\n<p>\u4e00\u822c\u7684\u53cd\u5e94\u56fe\u5728\u4e0a\u9762\u3002\u7528\u7ea2\u8272\u6807\u8bb0\u7684\u5316\u5b66\u952e\u88ab\u8f6c\u5316\uff0c\u7528\u7eff\u8272\u6807\u8bb0\u7684\u82ef\u73af\u662f\u5c31\u5730\u7cbe\u5236\u7b56\u7565\u7684\u7406\u60f3\u4ea7\u7269\u3002\u6240\u63d0\u4f9b\u7684\u82ef\u4ea7\u54c1\u7684\u4ea7\u91cf\u662f\u5728\u5e95\u7269\u7684\u5b8c\u5168\u8f6c\u6362\uff0c\u4f5c\u4e3a\u4e09\u4e2a\u5e73\u884c\u5b9e\u9a8c\u7684\u5e73\u5747\u503c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225565\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-6-1.png\" alt=\"\" width=\"600\" height=\"455\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-6-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/\u56fe\u7247-6-1-300x228.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe5.\u00a0\u6728\u8d28\u7d20\u7684\u539f\u4f4d\u7cbe\u5236\u3002<\/p>\n<p>\u7528\u4e09\u7ef4\u56fe\u6bd4\u8f83\u6240\u91c7\u7528\u6728\u8d28\u7d20\u7684\u82ef\u6536\u7387\u3001\u82ef\u4e19\u9187\u7ed3\u6784\u542b\u91cf\u3001\u7532\u6c27\u57fa\/\u82ef\u73af\u6bd4\u4f8b\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3<\/b><\/strong><\/p>\n<p>\u4ee5RuW\/HY<sub>30<\/sub>\u4e3a\u591a\u529f\u80fd\u50ac\u5316\u5242\uff0c\u4ee5\u6c34\u4e3a\u53cd\u5e94\u4ecb\u8d28\uff0c\u91c7\u7528\u539f\u4f4d\u7cbe\u5236\u7b56\u7565\u8f6c\u5316C<sub>sp2<\/sub>-C<sub>sp3<\/sub>\u548cC<sub>sp2<\/sub>-O\u952e\uff0c\u53ef\u6301\u7eed\u5730\u4ece\u6728\u8d28\u7d20\u751f\u4ea7\u82ef\uff0c\u8fd9\u8fdb\u4e00\u6b65\u5f15\u8d77\u4e86\u4eba\u4eec\u5bf9\u751f\u7269\u8d28\u5b9a\u4ef7\u65b9\u6cd5\u7684\u5173\u6ce8\u3002\u89c4\u6a21\u5316\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c50.0 g\u6728\u8d28\u7d20\u53ef\u4ee5\u751f\u4ea78.5 g\u82ef\uff0c\u6ca1\u6709\u4efb\u4f55\u9971\u548c\u526f\u4ea7\u7269\u3002\u8fd9\u79cd\u6728\u8d28\u7d20\u539f\u4f4d\u7cbe\u5236\u7b56\u7565\u5c06\u88ab\u6355\u83b7\u7684\u82ef\u73af\u4ece\u6728\u8d28\u7d20\u7684\u5206\u5b50\u7ed3\u6784\u4e2d\u89e3\u6784\u51fa\u6765\uff0c\u4e3a\u4ee5\u6728\u8d28\u7d20\u4e3a\u539f\u6599\u5b9e\u73b0\u82ef\u7684\u53ef\u6301\u7eed\u751f\u4ea7\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\uff0c\u5177\u6709\u6781\u5927\u7684\u5b9e\u9645\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"#citeas\"><u>Sustainable production of benzene from lignin. Nat Communications, 2021, 12, 4534. DOI\uff1a<\/u><\/a><a href=\"https:\/\/doi.org\/10.1038\/s41467-021-24780-8\"><u>10.1038\/s41467-021-24780-8<\/u><\/a><u>.<\/u><\/p>\n<p>\u672c\u6587\u7531\u7eb3\u7c73\u5c0f\u767d\u4f9b\u7a3f\u3002\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u80cc\u666f\u4ecb\u7ecd \u5982\u4eca\uff0c\u82ef\u662f\u5316\u5de5\u884c\u4e1a\u4e0d\u53ef\u6216\u7f3a\u7684\u5927\u5b97\u5546\u54c1\uff0c2019\u5e74\u5168\u7403\u82ef\u4ea7\u91cf\u8d85\u8fc76100\u4e07\u5428\u3002\u672a\u6765\u5341\u5e74\uff0c\u5168\u7403\u82ef\u9700\u6c42\u9884\u8ba1\u5c06\u4ee5\u6bcf\u5e742.9\u00a0%\u7684\u901f\u5ea6\u589e\u957f\u3002\u7279\u522b\u662f\u5728\u5236\u9020\u4e1a\uff0c\u82ef\u88ab&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-225564","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225564"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=225564"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225564\/revisions"}],"predecessor-version":[{"id":225719,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/225564\/revisions\/225719"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=225564"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=225564"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=225564"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}