{"id":225538,"date":"2021-08-12T06:17:25","date_gmt":"2021-08-11T22:17:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=225538"},"modified":"2021-08-11T21:17:52","modified_gmt":"2021-08-11T13:17:52","slug":"nat-mater-%ef%bc%9a%e8%b6%85%e6%b5%93%e7%94%b5%e8%a7%a3%e8%b4%a8%e5%8f%af%e5%8a%a9%e5%8a%9b%e5%ae%9e%e7%8e%b0%e5%b1%82%e7%8a%b6%e5%8d%a4%e5%8c%96%e7%89%a9%e7%9a%84%e6%8f%92%e5%b1%82%e7%94%b5%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=225538","title":{"rendered":"Nat. Mater.\uff1a\u8d85\u6d53\u7535\u89e3\u8d28\u53ef\u52a9\u529b\u5b9e\u73b0\u5c42\u72b6\u5364\u5316\u7269\u7684\u63d2\u5c42\u7535\u5316\u5b66"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u7eb5\u89c2\u7535\u5316\u5b66\u5668\u4ef6\u7684\u5386\u53f2\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\u53f2\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4e5f\u662f\u63d2\u5c42\u5316\u5408\u7269\u7684\u53d1\u5c55\u53f2\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u6709\u4e9b\u5316\u5408\u7269\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7ed3\u6784\u975e\u5e38\u76f8\u4f3c\uff0c\u4f46\u5176\u4ece\u6765\u672a\u88ab\u89c6\u4f5c\u6f5c\u5728\u7684\u4e3b\u4f53\u6750\u6599\u3002\u4f8b\u5982\uff0c\u5f53\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u548c\u786b\u5316\u7269\u88ab\u5e7f\u6cdb\u7814\u7a76\u65f6\uff0c\u4e09\u5364\u5316\u9492\uff08VX<sub>3<\/sub>\uff09\u5bb6\u65cf\u5c3d\u7ba1\u4e0e\u79bb\u5b50\u6027\u9502\u79bb\u5b50\u6b63\u6781\u5c42\u72b6\u6750\u6599\u786b\u5316\u949b\u7b49\u7ed3\u6784\u76f8\u4f3c\uff0c\u4f46\u5176\u672a\u88ab\u89c6\u4f5c\u7535\u6c60\u63d2\u5c42\u6210\u5206\u8fdb\u884c\u7814\u7a76\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u6eb6\u89e3\u6027\u95ee\u9898\u7684\u5b58\u5728\u3002\u5364\u5316\u7269\u81f3\u4eca\u4e5f\u5f88\u96be\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u7684\u6f5c\u5728\u5bf9\u8c61\u3002\u800c\u5728\u53e6\u4e00\u65b9\u9762\uff0c\u7535\u89e3\u8d28\u6784\u5efa\u8bbe\u8ba1\u4e5f\u88ab\u8ba4\u4e3a\u53ef\u4ee5\u89e3\u51b3\u9502\u79bb\u5b50\u7535\u6c60\u63d2\u5c42\u7684\u7a33\u5b9a\u6027\u95ee\u9898\u3002\u4f8b\u5982\uff0c\u8d85\u6d53\uff08superconcentrated\uff09\u7535\u89e3\u8d28\u88ab\u8ba4\u4e3a\u6709\u671b\u89e3\u51b3\u78b3\u9178\u76d0\u7535\u89e3\u8d28\u4e2d\u7ecf\u5e38\u51fa\u73b0\u7684\u95ee\u9898\uff0c\u6bd4\u5982\u4e0e\u9502\u91d1\u5c5e\u7684\u4e0d\u76f8\u5bb9\u6027\u3001\u9ad8\u538b\u4e0b\u7684\u4e0d\u7a33\u5b9a\u6027\u4ee5\u53ca\u6613\u71c3\u6027\u7b49\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><strong>\u6cd5\u5170\u897f\u5b66\u9662\u7684<\/strong><strong>Jean-Marie Tarascon<\/strong><strong>\u548c<\/strong><strong>Alexis Grimaud<\/strong><strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u53d1\u8868\u6587\u7ae0\u5c55\u793a\u4e86\u901a\u8fc7\u4f7f\u7528\u8d85\u6d53\u7535\u89e3\u8d28\uff085 M LiFSI\u7684\u78b3\u9178\u4e8c\u7532\u916f\u6eb6\u6db2\uff09\u4fc3\u4f7f\u9502\u79bb\u5b50\u4ee5\u7535\u5316\u5b66\u7684\u65b9\u5f0f\u53ef\u9006\u63d2\u5165VX<sub>3<\/sub>\u5316\u5408\u7269\u7684\u53ef\u884c\u6027\u3002\u901a\u8fc7\u7ed3\u5408\u7535\u5316\u5b66\u6d4b\u91cf\u548c\u7ed3\u6784\u5206\u6790\u65b9\u6cd5\uff0c\u7814\u7a76\u9610\u91ca\u4e86\u4e00\u4e2a\u9502\u79bb\u5b50\/\u5316\u5b66\u5f0f\u5355\u5143\u80fd\u591f\u53ef\u9006\u5730\u63d2\u5c42\u5230\u8fd9\u4e9b\u5364\u5316\u7269\u4e2d\u3002\u4e0d\u4ec5\u5982\u6b64\uff0c\u5229\u7528\u7535\u89e3\u8d28\u6784\u5efa\u65b9\u6cd5\uff0c\u4f5c\u8005\u8fd8\u8bc1\u660e\u4e86\u8d85\u6d53\u7535\u89e3\u8d28\u5bf9\u65e0\u673a\u6210\u5206\u7684\u6eb6\u89e3\u6027\u4e0e\u70ed\u529b\u5b66\u6548\u5e94\u6709\u5173\u800c\u975e\u52a8\u529b\u5b66\u6548\u5e94\u3002\u8fd9\u4e9b\u7814\u7a76\u7ed3\u679c\u4e0d\u4ec5\u52a0\u6df1\u4e86\u5bf9\u8d85\u6d53\u7535\u89e3\u8d28\u7684\u7406\u89e3\uff0c\u4e5f\u4e3a\u8bbe\u8ba1\u65b0\u578b\u63d2\u5165\u5316\u5408\u7269\u63d0\u4f9b\u4e86\u5173\u952e\u601d\u8def\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a<strong>\u201cExtending insertion electrochemistry to soluble layered halides with superconcentrated electrolytes\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong>Nature Materials<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u7535\u89e3\u8d28\u6784\u5efa\u89e3\u9501\u9502\u79bb\u5b50\u5728<\/strong><strong>VX<sub>3<\/sub><\/strong><strong>\u5316\u5408\u7269\u4e2d\u7684\u53ef\u9006\u63d2\u5c42<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225539\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/1.jpg\" alt=\"\" width=\"600\" height=\"273\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/1-300x137.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/2.jpg\" alt=\"\" width=\"600\" height=\"271\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/2-300x136.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09VI<sub>3<\/sub>\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u73b0\u573a\u539f\u4f4d\u540c\u6b65\u52a0\u901f\u5668X\u5c04\u7ebf\u884d\u5c04\u663e\u793a\u4e86\u4f34\u968f\u6709\u4e2d\u95f4\u4f53\u751f\u957f\u7684\u53ef\u9006\u76f8\u53d8\uff1b<\/p>\n<p>\uff08b\uff09\u539f\u59cb\u3001\u4e2d\u95f4\u4f53\u548c\u653e\u7535\u622a\u6b62\u9636\u6bb5\u7684VCl<sub>3<\/sub>\u3001VBr<sub>3<\/sub> \u3001VI<sub>3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\uff08\u4ece\u5de6\u5230\u53f3\uff09\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56fe\u4e09\u3001\u7535\u8377\u8865\u507f\u673a\u5236\u7684\u6d4b\u5b9a<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-225541\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/3.jpg\" alt=\"\" width=\"600\" height=\"473\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/3-300x237.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u5229\u7528\u95f4\u6b47\u6052\u7535\u6d41\u7535\u4f4d\u6ef4\u5b9a\u6cd5\u5bf9VCl<sub>3<\/sub>\u3001VBr<sub>3<\/sub> 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/4.jpg\" alt=\"\" width=\"600\" height=\"337\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/4.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/08\/4-300x169.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p>\uff08a\uff09\u5229\u7528ICP-MS\u6d4b\u91cfLiFSI\/DMC\u7535\u89e3\u8d28\u4e2dVCl<sub>3<\/sub>\u7684\u6eb6\u89e3\u6027\u4e0eLiFSI\u6d53\u5ea6\u7684\u51fd\u6570\u5173\u7cfb\uff1b<\/p>\n<p>\uff08b\uff091M LiFSI\/DMC\u7535\u89e3\u8d28\u5206\u522b\u4ee5VCl<sub>3<\/sub>\u3001VBr<sub>3<\/sub> \u3001VI<sub>3<\/sub>\u8fdb\u884c\u9971\u548c\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\uff1b<\/p>\n<p>\uff08c\uff09\u5229\u7528ICP-MS\u6d4b\u91cfLiFSI\/DMC\u7535\u89e3\u8d28\u4e2dVCl<sub>3<\/sub>\u3001VBr<sub>3<\/sub> 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href=\"https:\/\/www.nature.com\/articles\/s41563-021-01060-w?utm_source=xmol&amp;utm_medium=affiliate&amp;utm_content=meta&amp;utm_campaign=DDCN_1_GL01_metadata\" target=\"_blank\" rel=\"noopener\">Extending insertion electrochemistry to soluble layered halides with superconcentrated electrolytes<\/a>, <em>Nature Materials<\/em>, <strong>2021<\/strong>, DOI: 10.1038\/s41563-021-01060-w.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 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