{"id":224941,"date":"2021-07-30T06:35:02","date_gmt":"2021-07-29T22:35:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=224941"},"modified":"2021-07-29T18:35:17","modified_gmt":"2021-07-29T10:35:17","slug":"%e4%b8%9c%e4%ba%ac%e5%a4%a7%e5%ad%a6nature-catalysis%ef%bc%9a%e9%93%81%e5%82%ac%e5%8c%96%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7%e5%99%bb%e5%90%a9c-h-c-h%e5%81%b6%e8%81%94%e5%92%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=224941","title":{"rendered":"\u4e1c\u4eac\u5927\u5b66Nature Catalysis\uff1a\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u5076\u8054\u548c\u7f29\u805a\u7528\u4e8e\u6709\u673a\u5c0f\u5206\u5b50\u548c\u805a\u5408\u7269\u534a\u5bfc\u4f53\u5236\u9020"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aTakahiro Doba\u200a<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aRui Shang\uff0cEiichi 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224944\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25.png\" alt=\"\" width=\"439\" height=\"839\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25.png 439w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-2-25-157x300.png 157w\" sizes=\"(max-width: 439px) 100vw, 439px\" 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224945\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25.png\" alt=\"\" width=\"569\" height=\"863\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25.png 569w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-3-25-198x300.png 198w\" sizes=\"(max-width: 569px) 100vw, 569px\" 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-224946\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24.png\" alt=\"\" width=\"600\" height=\"610\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-4-24-295x300.png 295w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20.png\" alt=\"\" width=\"600\" height=\"751\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/07\/\u56fe\u7247-5-20-240x300.png 240w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe5|\u94c1\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027\u567b\u5429C-H\/C-H\u7f29\u805a\u7684\u8303\u56f4\u3002<\/p>\n<p><strong>\u7ed3\u8bed<\/strong><\/p>\n<p>\u4e0a\u8ff0\u5de5\u4f5c\u5f3a\u8c03\u4e86\u5408\u4f5c\u4f7f\u7528\u4e24\u79cd\u5bcc\u542b\u7a00\u571f\u7684\u91d1\u5c5e(\u5373\u94c1\u548c\u94dd)\u6765\u5408\u6210\u6709\u673a\u7535\u5b50\u5668\u4ef6\u5e94\u7528\u4e2d\u91cd\u8981\u7684\u03c0\u5171\u8f6d\u5c0f\u5206\u5b50\u548c\u5927\u5206\u5b50\u7684\u597d\u5904\u3002\u672c\u6587\u8ba4\u4e3a\uff0cTP\u914d\u4f53\u548cDEO\/Al(III)\u7ec4\u5408\u4e2d\u7684\u7ed3\u6784\u548c\u7535\u5b50\u5143\u7d20\u5728\u63a7\u5236\u6709\u673a\u94c1\u4e2d\u95f4\u4f53\u7684\u4ef7\u6001\u548c\u81ea\u65cb\u6001\u65b9\u9762\u53d6\u5f97\u4e86\u5f88\u597d\u7684\u5e73\u8861\u3002C-H\/C-H\u7f29\u805a\u662f\u5bf9\u805a\u5408\u7269\u5408\u6210\u4e2d\u6709\u9650\u7684\u6709\u673a\u94c1\u50ac\u5316\u4f53\u7cfb\u7684\u8865\u5145\uff0c\u5c06\u6210\u4e3a\u8fdb\u4e00\u6b65\u5f00\u53d1\u5b9e\u7528\u94c1\u50ac\u5316\u7684\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u56e2\u961f\u4ecb\u7ecd<\/strong><\/p>\n<p>\u6771\u4eac\u5927\u5b66\u9769\u65b0\u5206\u5b50\u6280\u672f\u8bb2\u5ea7\u4e2d\u6751\u7814\u7a76\u5ba4<\/p>\n<p>\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u6c47\u603b\u4ee5\u53ca\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\uff1a<\/p>\n<p>1. Iron-Catalyzed Tandem Cyclization of Diarylacetylene to a Strained 1,4-Dihydropentalene Framework for Narrow-Band-Gap Materials<\/p>\n<p>Chen, M.; Sato, W.; Shang, R.*;\u00a0Nakamura,\u00a0E.* <em><i>J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>20<\/b><\/strong><strong><b>21<\/b><\/strong>,\u00a0<em><i>1<\/i><\/em><em><i>43, <\/i><\/em>6823\u20136828.<\/p>\n<p>2. Chromium(III)-catalyzed C(sp<sup>2<\/sup>)-H Alkynylation and Allylation of Secondary Amides with Trimethylaluminum as Base<b><\/b><\/p>\n<p>Chen, M.; Doba, T.; Sato, T.;\u00a0Ilies, L.;\u00a0Shang, R.*;\u00a0Nakamura,\u00a0E.*\u00a0<em><i>J. Am. Chem. Soc.<\/i><\/em><strong><b>\u00a0<\/b><\/strong><strong><b>20<\/b><\/strong><strong><b>20<\/b><\/strong>, <em><i>142, <\/i><\/em>4883\u20134891<em><i>.<\/i><\/em><\/p>\n<p>3. Homocoupling-free Iron-catalyzed Twofold C\u2013H Activation\/cross-couplingsof Aromatics via Transient Connection of Reactants<\/p>\n<p>Doba, T.;\u00a0Matsubara, T.;\u00a0Ilies, L.;\u00a0Shang, R.*;\u00a0Nakamura,\u00a0E.*\u00a0<em><i>Nat. Catal. <\/i><\/em><strong><b>2019<\/b><\/strong>, <em><i>2, <\/i><\/em>400\u2013406.<\/p>\n<p>4. Iron-Catalyzed C\u2013H Bond Activation<\/p>\n<p>Shang, R.; Ilies, L.*;\u00a0Nakamura, E.*\u00a0<em><i>Chem. Rev.<\/i><\/em>\u00a0<strong><b>2017<\/b><\/strong><em><i>, 117, <\/i><\/em>9086\u20139139<em><i>.<\/i><\/em><\/p>\n<p>5. Iron-catalyzed ortho C\u2013H Methylationof Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand<\/p>\n<p>Shang, R.; Ilies, L.*;\u00a0Nakamura, E.*\u00a0<em><i>J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>6<\/b><\/strong>, <em><i>138, <\/i><\/em>10132\u201310135<em><i>.<\/i><\/em><\/p>\n<p>6. Iron-catalyzed Directed C(sp<sup>2<\/sup>)\u2013H and C(sp<sup>3<\/sup>)\u2013H Functionalization with Trimethylaluminium<\/p>\n<p>Shang, R.; Ilies, L.*; Nakamura, E.*<em><i>\u00a0J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>5<\/b><\/strong>, <em><i>137, <\/i><\/em>7660\u20137663<em><i>.<\/i><\/em><\/p>\n<p>7. Iron-catalyzed C (sp<sup>2<\/sup>)\u2013H Bond Functionalization with Organoboron Compounds<\/p>\n<p>Shang, R.; Ilies, L.*; Sobi, A.; Nakamura, E.*<em><i>\u00a0J. Am. <\/i><\/em><em><i>Chem. Soc. <\/i><\/em><strong><b>201<\/b><\/strong><strong><b>4<\/b><\/strong>, <em><i>136, <\/i><\/em>14349\u201314352<em><i>.<\/i><\/em><\/p>\n<p>8. \u03b2-Arylation of carboxamides via iron-catalyzed C (sp<sup>3<\/sup>)\u2013H bond activation<\/p>\n<p>Shang, R.; Ilies, L.; Matsumoto, A.; Nakamura, E.*; <em><i>J. Am. Chem. Soc. <\/i><\/em><strong><b>2013<\/b><\/strong>, <em><i>135<\/i><\/em>, 6030\u20136032<em><i>.<\/i><\/em><\/p>\n<p>\u672c\u6587\u7531SSC\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aTakahiro Doba\u200a \u901a\u8baf\u4f5c\u8005\uff1aRui Shang\uff0cEiichi Nakamura \u901a\u8baf\u5355\u4f4d\uff1a\u4e1c\u4eac\u5927\u5b66 DOI\uff1ahttps:\/\/doi.org&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-224941","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/224941"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=224941"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/224941\/revisions"}],"predecessor-version":[{"id":225235,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/224941\/revisions\/225235"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=224941"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=224941"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=224941"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}