{"id":224646,"date":"2021-07-19T06:32:04","date_gmt":"2021-07-18T22:32:04","guid":{"rendered":"\/\/m.iemloyee.com\/?p=224646"},"modified":"2021-07-18T21:32:20","modified_gmt":"2021-07-18T13:32:20","slug":"%e9%a1%b6%e5%88%8a%e9%80%9f%e8%a7%88%ef%bc%9a%e5%be%90%e5%bc%ba%e9%99%a2%e5%a3%abam%e3%80%81%e6%a5%bc%e9%9b%84%e6%96%87sci-adv-%e3%80%81%e6%9e%97%e6%96%87%e6%96%8cjacs%e3%80%81%e9%83%91%e5%8d%97","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=224646","title":{"rendered":"\u9876\u520a\u901f\u89c8\uff1a\u5f90\u5f3a\u9662\u58ebAM\u3001\u697c\u96c4\u6587Sci. Adv.\u3001\u6797\u6587\u658cJACS\u3001\u90d1\u5357\u5cf0JACS\u7b498\u7bc7\u6700\u65b0MOF\u8fdb\u5c55"},"content":{"rendered":"

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N<\/b><\/strong>ature Commun.<\/b><\/strong>\uff1a<\/b><\/strong>\u5177\u6709\u5355\u539f\u5b50\u4e2d\u5fc3\u7684<\/b><\/strong>M<\/b><\/strong>OF\u819c\u7528\u4e8e\u5149\u50ac\u5316<\/b><\/strong>\u4e8c\u6c27\u5316\u78b3\u548c\u6c27\u6c14\u8fd8\u539f<\/b><\/strong><\/p>\n

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A<\/b><\/strong>M<\/b><\/strong>\uff1a\u6eb6\u6db2\u53ef\u52a0\u5de5\u7684<\/b><\/strong>\u5177\u6709\u53ef\u53d8\u529f\u80fd<\/b><\/strong>\u7684M<\/b><\/strong>OF\u7eb3\u7c73\u7247<\/b><\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u672c\u8d28\u4e0a\u7f3a\u4e4f\u6d41\u52a8\u6027\uff0c\u56e0\u6b64\u5177\u6709\u6eb6\u89e3\u52a0\u5de5\u6027\u3002\u76f4\u63a5\u5408\u6210\u5177\u6709\u7c7b\u4f3c\u805a\u5408\u7269\u7684\u6eb6\u6db2\u53ef\u52a0\u5de5\u6027\u7684MOFs\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\uff0c\u4f46\u5728\u8bb8\u591a\u5e94\u7528\u4e2d\u90fd\u975e\u5e38\u53d7\u6b22\u8fce\u3002\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u8d75\u4e39\u6559\u6388\u8054\u5408\u5e7f\u5dde\u5927\u5b66\u4e54\u667a\u5a01\u6559\u6388\u7b49\u4eba\u5f00\u53d1\u4e86\u5177\u6709\u53ef\u53d8\u529f\u80fd\u7684\u591a\u5b54MOF\u7eb3\u7c73\u7247\uff0c\u53ef\u5e7f\u6cdb\u7528\u4e8e\u7535\u5b50\u5668\u4ef6\u4e2d\u3002\u7814\u7a76\u4e2d\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u5ea6\u7a33\u5b9a\u7684MOF\u60ac\u6d6e\u6db2\uff0c\u8be5\u60ac\u6d6e\u6db2\u7531\u8d85\u5927\u7684(\u5e73\u5747\u9762\u79ef>15000\u00a0um2<\/sup>) \u4e14\u529f\u80fd\u53ef\u53d8\u7684NUS-8\u7eb3\u7c73\u7247\u7ec4\u6210\u3002\u8fd9\u662f\u901a\u8fc7\u5728\u5408\u6210\u8fc7\u7a0b\u4e2d\u6dfb\u52a0\u76d6\u5c42\u5206\u5b50\uff0c\u901a\u8fc7\u660e\u667a\u5730\u63a7\u5236\u524d\u9a71\u4f53\u6d53\u5ea6\u548cMOF\u7eb3\u7c73\u7247-\u6eb6\u5242\u76f8\u4e92\u4f5c\u7528\u6765\u5b9e\u73b0\u7684\u3002\u7531\u6b64\u4ea7\u751f\u7684\u4e8c\u7ef4\u5177\u6709\u53ef\u53d8\u529f\u80fd\u7684NUS-8\u7eb3\u7c73\u7247\u5177\u6709\u51fa\u8272\u7684\u6eb6\u6db2\u52a0\u5de5\u6027\u80fd\uff0c\u53ef\u5bb9\u6613\u5236\u9020MOF\u6574\u6599\u3001\u6c14\u51dd\u80f6\u3001\u5e72\u51dd\u80f6\u4ee5\u53ca\u539a\u5ea6\u548c\u529f\u80fd\u53ef\u8c03\u7684\u540c\u8d28\u8584\u819c\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5b9e\u9a8c\u548c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u8bc1\u660e\u4e86\u4e0e\u4e0d\u540c\u7ec8\u7aef\u7ec4\u529f\u80fd\u5316\u7684NUS-8\u819c\u96c6\u6210\u7684\u7535\u5bb9\u4f20\u611f\u5668\u7531\u4e8e\u5176\u4e0d\u540c\u7684\u4e3b-\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\uff0c\u5bf9\u4e19\u916e\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u4f20\u611f\u884c\u4e3a\u3002\u9884\u8ba1\u8fd9\u79cd\u7b80\u5355\u7684\u65b9\u6cd5\u5c06\u6781\u5927\u5730\u4fc3\u8fdbMOFs\u5728\u5fae\u578b\u5316\u7535\u5b50\u5668\u4ef6\u4e2d\u7684\u96c6\u6210\uff0c\u5e76\u6709\u5229\u4e8e\u5176\u5927\u89c4\u6a21\u751f\u4ea7\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSolution-Processable Metal\u2013Organic Framework Nanosheets with Variable Functionalities\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202101257<\/p>\n

\u56fe4\u7528\u4e8e\u76f4\u63a5\u548c\u53ef\u6269\u5c55\u5408\u6210\u5747\u5300\u548c\u7a33\u5b9a\u7684\u60ac\u6d6e\u6db2\u7684\u793a\u610f\u56fe\uff0c\u7531\u5177\u6709\u4f18\u5f02\u6eb6\u6db2\u52a0\u5de5\u80fd\u529b\u7684\u8d85\u5927\u91d1\u5c5e-\u6709\u673a\u7eb3\u7c73\u7247(MONs)\u7ec4\u6210\u3002<\/p>\n

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A<\/b><\/strong>M<\/b><\/strong>\uff1a\u6c14\u84b8MOF\u5408\u6210\u7b56\u7565<\/b><\/strong>\u5236\u5907p\u63ba\u6742<\/b><\/strong>\u58c1\u7aef\u5f00\u53e3\u7684\u78b3\u7b3c\u6750\u6599<\/b><\/strong>\u5177\u6709\u589e\u5f3a\u7684\u950c\u79bb\u5b50\u50a8\u80fd\u80fd\u529b<\/b><\/strong>\u548c<\/b><\/strong>\u8d85\u7a33\u5b9a\u6027<\/b><\/strong><\/p>\n

\u78b3\u5fae\/\u7eb3\u7c73\u7b3c\u5728\u7535\u5316\u5b66\u50a8\u80fd\u7cfb\u7edf\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u5728\u6b64\uff0c\u4f5c\u4e3a\u4e00\u79cd\u6982\u5ff5\u9a8c\u8bc1\uff0c\u5357\u79d1\u5927\u5f90\u5f3a\u9662\u58eb\u7b49\u4eba\u8bbe\u8ba1\u4e86\u4e00\u79cd\u56fa\u6001\u6c14\u84b8\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u65b9\u6cd5\u6765\u5236\u9020\u78b3\u7b3c\uff0c\u5728\u58c1\u4e0a\u63a7\u5236\u5f00\u53e3\uff0c\u5e76\u6dfb\u52a0N, P\u63ba\u6742\u5242\u3002\u5229\u7528\u5236\u5907\u7684\u58c1\u4e0a\u6709\u5927\u5f00\u53e3\u7684\u78b3\u7b3c\u589e\u5f3a\u4e86\u8d28\u91cf\u4f20\u9012\u52a8\u529b\u5b66\uff0c\u6c2e\u3001\u78f7\u63ba\u6742\u5242\u6709\u5229\u4e8e\u950c\u79bb\u5b50\u7684\u5316\u5b66\u5438\u9644\u3002\u8fd9\u79cd\u5f00\u653e\u5f0f\u78b3\u7b3c(OCCs)\u7528\u4f5c\u9ad8\u7ea7\u6c34\u76f8\u950c\u79bb\u5b50\u6df7\u5408\u8d85\u7ea7\u7535\u5bb9\u5668(ZHSCs)\u7684\u78b3\u9634\u6781\u65f6\uff0c\u5176\u5de5\u4f5c\u7535\u538b\u53ef\u8fbe2.0 V\uff0c\u57280.1 A g\u22121<\/sup>\u65f6\u7684\u5bb9\u91cf\u53ef\u63d0\u9ad8\u5230225 mAh g\u22121<\/sup>\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u7684\u5faa\u73af\u5bff\u547d\u53ef\u8fbe30\u4e07\u6b21\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a96.5%\u3002\u7279\u522b\u662f\uff0c\u4ee5OCCs\u4e3a\u7535\u6781\u6750\u6599\u7684ZHSC\u5668\u4ef6\uff0c\u5177\u670997 Wh kg\u22121<\/sup>\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u6781\u9ad8\u7684\u529f\u7387\u5bc6\u5ea66.5\u00a0kW kg-1<\/sup>\u3002\u6b64\u5916\uff0c\u8be5\u8bbe\u5907\u53ef\u4ee5\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u5de5\u4f5c\u221225 ~ + 40\u00b0C\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Gas-Steamed MOF Route to P-Doped Open Carbon Cages with Enhanced Zn-Ion Energy Storage Capability and Ultrastability\u201d\u4e3a\u9898\u76ee\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202101698<\/p>\n

\u56fe5\u00a0\u6c14\u84b8MOF\u6cd5\u5408\u6210N, P\u63ba\u6742\u5f00\u653e\u78b3\u7b3c(OCCs)\u7684\u5de5\u827a\u793a\u610f\u56fe<\/p>\n

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A<\/b><\/strong>FM<\/b><\/strong>\uff1a\u591a\u91d1\u5c5e<\/b><\/strong>MOF\u884d\u751f\u7684\u7a7a\u5fc3\u591a\u5b54\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7528\u4e8e\u4e09\u6a21\u6001\u6210\u50cf\u5f15\u5bfc\u6d3b\u6027\u6c27\u589e\u5f3a\u534f\u540c\u6cbb\u7597<\/b><\/strong><\/p>\n

\u5357\u5f00\u5927\u5b66Xue-Bo Yin\u6559\u6388\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u4e09\u8054\u6001\u6210\u50cf\u5f15\u5bfc\u534f\u540c\u5149\u70ed\u6cbb\u7597(PTT)\/\u5149\u52a8\u529b\u6cbb\u7597(PDT)\/\u5316\u5b66\u52a8\u529b\u6cbb\u7597(CDT)\u3002\u4e3a\u6b64\uff0c\u9996\u5148\u5728\u5ba4\u6e29\u4e0b\u5728\u7eb3\u7c73\u5c3a\u5ea6\u4e0a\u7ec4\u88c5\u4e86\u6df7\u5408\u91d1\u5c5e\u94dc\/\u950c\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u3002\u6709\u8da3\u7684\u662f\uff0c\u52a0\u70edMOF\u53ef\u4ee5\u5f97\u5230Cu+\/2+<\/sup>\u5171\u5b58\u7684\u7a7a\u5fc3\u591a\u5b54\u7ed3\u6784\u3002\u5728\u4e59\u9170\u4e19\u916e\u9530(II)\u5b58\u5728\u4e0b\uff0c\u540e\u7eed\u7684\u70ed\u5904\u7406\u5c06Mn2+<\/sup>\u548cMnO2<\/sub>\u6574\u5408\u3002\u8be5\u7a7a\u5fc3\u590d\u5408\u6750\u6599\u5b9e\u73b0\u4e86\u5149\u654f\u5242\u5432\u54da\u83c1\u7eff(ICG)\u7684\u6709\u6548\u8d1f\u8f7d\uff0c\u5728\u6fc0\u5149\u7167\u5c04\u4e0b\uff0c\u805a\u5408ICG\u5b9e\u73b0\u4e86\u5149\u70ed\u6210\u50cf\u548cPTT\u3002ICG\u4e00\u65e6\u5728\u80bf\u7624\u90e8\u4f4d\u91ca\u653e\uff0c\u5c31\u4f1a\u663e\u793a\u8367\u5149\u6210\u50cf\u548cPDT\u80fd\u529b\u3002Cu+<\/sup>\/Mn2+<\/sup>\u79bb\u5b50\u4e0eH2<\/sub>O2<\/sub>\u53d1\u751f\u7c7bFenton\u53cd\u5e94\u4ea7\u751f\u7ec6\u80de\u6bd2\u6027\u2022OH\u7528\u4e8e\u589e\u5f3aCDT\u3002Cu2+<\/sup>\/MnO2<\/sub>\u6e05\u9664\u8c37\u80f1\u7518\u80bd\uff0c\u6539\u5584\u6d3b\u6027\u6c27\u81ea\u7531\u57fa\u6cbb\u7597\uff0c\u800c\u5f62\u6210\u7684Mn2+<\/sup>\u79bb\u5b50\u4fc3\u8fdb\u78c1\u5171\u632f\u6210\u50cf\u3002\u660e\u663e\u7684\u662f\uff0cO2<\/sub>\u662f\u7531\u5185\u6e90H2<\/sub>O2<\/sub>\u50ac\u5316\u5206\u89e3\u4ea7\u751f\u7684\uff0c\u4ee5\u6539\u5584ICG\u4ecb\u5bfc\u7684PDT\u3002\u6b64\u5916\uff0c\u5149\u70ed\u8bf1\u5bfc\u7684\u5c40\u90e8\u70ed\u7597\u52a0\u901f\u2022OH\u7684\u751f\u6210\u4ee5\u589e\u5f3aCDT\u3002\u8fd9\u79cd\u534f\u540c\u65e0\u836f\u6297\u80bf\u7624\u7b56\u7565\u5b9e\u73b0\u4e86\u5bf9\u6b63\u5e38\u7ec4\u7ec7\u7684\u9ad8\u7597\u6548\u548c\u4f4e\u526f\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u8be5\u6df7\u5408\u91d1\u5c5eMOF\u662f\u5b9e\u73b0\u4e2d\u7a7a\u7ed3\u6784\u591a\u529f\u80fd\u6574\u5408\uff0c\u63d0\u9ad8\u6cbb\u7597\u80fd\u529b\u7684\u6709\u6548\u7b56\u7565\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMixed-Metal MOF-Derived Hollow Porous Nanocomposite\u00a0for Trimodality Imaging Guided Reactive Oxygen Species Augmented Synergistic Therapy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202104378<\/p>\n

\u56fe6\u00a0a)ICG@Mn\/Cu\/Zn-MOF@MnO2<\/sub>\u539f\u7406\u56fe\u3002b) \u4e09\u6a21\u6001\u6210\u50cf\u5f15\u5bfc\u6d3b\u6027\u6c27\u589e\u5f3a\u534f\u540c\u6cbb\u7597\u673a\u5236\u65b9\u6848<\/p>\n

\"\"<\/p>\n

J<\/b><\/strong>ACS<\/b><\/strong>\uff1a<\/b><\/strong>\u624b\u6027\u56e2\u7c07<\/b><\/strong>M<\/b><\/strong>OF\u7684\u7ec4\u88c5\u53ca\u5176\u62c6\u5378\u8fc7\u7a0b\u4e2d\u7684\u624b\u6027\u8bb0\u5fc6\u6548\u5e94<\/b><\/strong><\/p>\n

\u8bb8\u591a\u91d1\u5c5e\u7c07\u5408\u7269\u672c\u8d28\u4e0a\u662f\u624b\u6027\u7684\uff0c\u4f46\u901a\u5e38\u5408\u6210\u4e3a\u5916\u6d88\u65cb\u6df7\u5408\u7269\u3002\u91c7\u7528\u624b\u6027Ag14<\/sub>(SPh-(CF3<\/sub>)2<\/sub>)12<\/sub>(PPh3<\/sub>)4<\/sub>(DMF)4<\/sub>\u00a0(Ag14<\/sub>)\u56e2\u7c07\u4e0e\u4f53\u79ef\u8f83\u5927\u7684\u786b\u9178\u76d0\u914d\u4f53\u4e3a\u4f8b\uff0c\u53a6\u95e8\u5927\u5b66Boon K. Teo\u3001\u90d1\u5357\u5cf0\u6559\u6388\u7b49\u4eba\u5c55\u793a\u4e86\u4e00\u79cd\u5f88\u6709\u610f\u4e49\u7684\u7ec4\u88c5-\u62c6\u5378(ASDS)\u7b56\u7565\uff0c\u4ee5\u83b7\u5f97\u76f8\u5e94\u7684\u540c\u624b\u6027\u5bf9\u6620\u4f53R-Ag14m<\/sub>\u548cS-Ag14m<\/sub>\u7684\u5149\u5b66\u7eaf\u6676\u4f53\u3002ASDS\u7b56\u7565\u5229\u7528\u4e86\u4e24\u4e2a\u5177\u6709\u4e0d\u540c\u624b\u6027\u6784\u578b\u7684\u53cc\u9f7f\u8fde\u63a5\u4f53\uff08LR\u3001LS\uff09\uff0c\u4e3a\u4e86\u6bd4\u8f83\uff0c\u8fd8\u4f7f\u7528\u4e86LR\u548cLS\u7b49\u6469\u5c14\u7684\u5916\u6d88\u65cb\u6df7\u5408\u7269(LRS)\u3002\u91c7\u7528X\u5c04\u7ebf\u6676\u4f53\u5b66\u65b9\u6cd5\u5bf93\u79cd\u4e09\u7ef4(3D) Ag14<\/sub>\u57fa\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u8fdb\u884c\u4e86\u8868\u5f81,\u5982\u9884\u671f\u7684\u90a3\u6837\uff0cAg14<\/sub>-LR\u548cAg14<\/sub>-LS\u4e2d\u7684\u6784\u5efa\u5757\u5206\u522b\u662f\u540c\u624b\u6027\u7684R-Ag14\u548cS-Ag14\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cAg14<\/sub>-LRS\u662f\u975e\u624b\u6027\u7684\uff0c\u5177\u6709\u7c7b\u91d1\u521a\u77f3\u7ed3\u6784\uff0c\u542b\u6709\u4ea4\u66ff\u7684R-Ag14<\/sub>\u548cS-Ag14<\/sub>\u56e2\u7c07\u3002\u5728\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\uff0c\u5916\u6d88\u65cb\u7684Ag14<\/sub>\u7c07\u88ab\u8f6c\u5316\u4e3a\u540c\u624b\u6027\u7684\u6784\u5efa\u5757\uff0c\u5373R-Ag14<\/sub>\u4e3aAg14<\/sub>-LR, S-Ag14<\/sub>\u4e3aAg14<\/sub>-LS\u3002\u968f\u540e\uff0c\u901a\u8fc7\u6c34\u6c34\u89e3\u4eceAg14<\/sub>-LR\u548cAg14<\/sub>-LS\u6676\u4f53\u4e2d\u53bb\u9664\u4e86\u624b\u6027\u8fde\u63a5\u7269\uff0c\u5e76\u4ece\u5206\u79bb\u7684\u56fa\u4f53\u6750\u6599Ag14<\/sub>-DR\u548cAg14<\/sub>-DS\u4e2d\u5f97\u5230\u5149\u5b66\u7eaf\u5bf9\u6620\u4f53R-Ag14m<\/sub>\u548cS-Ag14m<\/sub>\u3002\u5e0c\u671b\u8fd9\u79cd\u7b80\u5355\u7684\u7ec4\u88c5\u7b56\u7565\u53ef\u4ee5\u7528\u4e8e\u6784\u5efa\u57fa\u4e8e\u56e2\u7c07\u7684\u624b\u6027\u7ec4\u88c5\u6750\u6599\uff0c\u540e\u7eed\u7684\u62c6\u5378\u65b9\u6848\u53ef\u4ee5\u7528\u4e8e\u4ece\u5df2\u5236\u5907\u7684\u5916\u6d88\u65cb\u6df7\u5408\u7269\u4e2d\u83b7\u5f97\u5149\u5b66\u7eaf\u624b\u6027\u56e2\u7c07\u5206\u5b50\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAssembly of Chiral Cluster-Based Metal\u2212Organic Frameworks and\u00a0the Chirality Memory Effect during their Disassembly\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI:\u00a010.1021\/jacs.1c03251<\/p>\n

\u56fe7\u00a0\u00a0S-Ag14m<\/sub>\u548cR-Ag14m<\/sub>\u7684\u7ed3\u6784<\/p>\n

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\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n

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