{"id":22397,"date":"2016-06-27T08:05:51","date_gmt":"2016-06-27T00:05:51","guid":{"rendered":"\/\/m.iemloyee.com\/?p=22397"},"modified":"2016-06-26T23:16:49","modified_gmt":"2016-06-26T15:16:49","slug":"nature-materials%ef%bc%9a%e5%8f%af%e5%ba%94%e7%94%a8%e5%9c%a8%e5%85%89%e7%94%b5%e5%92%8c%e7%94%9f%e7%89%a9%e6%88%90%e5%83%8f%e9%a2%86%e5%9f%9f%e7%9a%84%e9%ab%98%e6%95%88%e8%8d%a7%e5%85%89%e6%9d%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=22397","title":{"rendered":"Nature materials\uff1a\u53ef\u5e94\u7528\u5728\u5149\u7535\u548c\u751f\u7269\u6210\u50cf\u9886\u57df\u7684\u9ad8\u6548\u8367\u5149\u6750\u6599"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-22503\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/Optical-Properties-558.jpg\" alt=\"Optical Properties 558\" width=\"600\" height=\"323\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/Optical-Properties-558.jpg 558w, 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-22398 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72471-26.png\" alt=\"\u56fe\u72471\" width=\"425\" height=\"529\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72471-26.png 425w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72471-26-241x300.png 241w\" sizes=\"(max-width: 425px) 100vw, 425px\" \/><\/p>\n<p><strong><b>a<\/b><\/strong>: \u6797\u5fb7 A\u578b\u6cb8\u77f3\uff08LTA\uff09\u4e0e\u516b\u9762\u6cb8\u77f3\uff08FAU\uff09\u6846\u67b6\u793a\u610f\u56fe\u4ee5\u53ca\u5b83\u4eec\u7684\u6784\u5efa\u6a21\u5757\uff0c\u6a21\u578b\u9876\u70b9\u4e3aT-\u539f\u5b50\uff08Al\u6216\u8005Si\uff09\uff0c\u4e3a\u4e86\u6e05\u695a\u8d77\u89c1\uff0c\u6c27\u539f\u5b50\u4e0e\u53cd\u5411-\u9633\u79bb\u5b50\u6ca1\u6709\u793a\u51fa.<\/p>\n<p><strong><b>b<\/b><\/strong>: 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\u56db\u79cd\u7119\u70e7\u6cb8\u77f3(Agx+Na11\u2212x+)[Al11Si13O48]\uff08<strong><b>FAUX<\/b><\/strong>\uff09\uff0c(Agx+Na6.5\u2212x+)[Al6.5Si17.5O48]\uff08<strong><b>FAUY<\/b><\/strong>\uff09\uff0c (Agx+K12\u2212x+)[Al12Si12O48]\uff08<strong>3A[Agx]<\/strong>\uff09, (Agx+Na12\u2212x+)[Al12Si12O48]\uff08\u00a0<strong>4A[Agx]<\/strong>\uff09\u7684\u79bb\u5b50\u7535\u4f4d\u4e0e\u7531\u7a7a\u6c14\u4e2d\u5149\u7535\u5b50\u80fd\u8c31\u786e\u5b9a\u7684\u94f6\u542b\u91cf\u7684\u5173\u7cfb.<\/p>\n<p><strong><b>b<\/b><\/strong>: 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\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72477-5-768x351.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72477-5-1024x468.png 1024w\" sizes=\"(max-width: 1034px) 100vw, 1034px\" \/><\/p>\n<p><strong><b>a<\/b><\/strong>: 3A\u6cb8\u77f3\u7684\u6fc0\u53d1-\u653e\u5c04\u4e8c\u7ef4\u56fe\u5c55\u793a\u4e50\u968f\u7740\u94f6\u542b\u91cf\u7684\u589e\u52a0\uff0c\u65b0\u5cf0\u7684\u589e\u957f.<\/p>\n<p><strong><b>b<\/b><\/strong>: \u5168\u7f6e\u6362\u548c\u7119\u70e74A\uff0cFAUX\uff0cFAUY\u6cb8\u77f3\u7684\u6fc0\u53d1-\u653e\u5c04\u4e8c\u7ef4\u56fe.<\/p>\n<p><strong><b>c<\/b><\/strong>: \u968fAg\u542b\u91cf\u53d8\u5316FAU\u6cb8\u77f3\u7684\u8367\u5149\u91cf\u5b50\u8f6c\u5316\u7387\uff08\u03bb<sub>exc<\/sub>=305nm\uff09\uff0c\u7ed3\u679c\u663e\u793a\u94f6\u5728\u4f4e\u6d53\u5ea6\u4e0b\uff0cFAUX\uff0cFAUY\u6cb8\u77f3\u95f4\u8bef\u5dee\u663e\u8457. \u8bef\u5dee\u7ebf\u4ee3\u8868\u6807\u51c6\u8bef\u5dee\uff0c\u5b83\u7531\u6bcf\u4e2a\u8bd5\u6837\u4e09\u6b21\u6d4b\u91cf\u7684\u5e73\u5747\u503c\u8ba1\u7b97\u5f97\u5230\uff08\u4e09\u6279\u6837\uff0c\u51719\u6b21\u6d4b\u91cf\uff09.<\/p>\n<p><strong>\u56fe4\u00a0\u94f6\u56e2\u7c07\u7684\u6269\u5c55X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\uff08EXAFS\uff09\u4e0e\u7535\u5b50\u81ea\u65cb\u5171\u632f\uff08ESR\uff09\u7814\u7a76<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-22405 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72478-6.png\" alt=\"\u56fe\u72478\" width=\"535\" height=\"507\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72478-6.png 535w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72478-6-300x284.png 300w\" sizes=\"(max-width: 535px) 100vw, 535px\" \/><\/p>\n<p><strong><b>a,b<\/b><\/strong>: \u56fe<strong><b>a<\/b><\/strong>\u3001\u56fe<strong><b>b<\/b><\/strong>\u5206\u522b\u4ee3\u88683A[Ag<sub>6<\/sub>]\u4e0e3A[Ag<sub>2<\/sub>]\u7684ESR\u7814\u7a76\uff0c\u7ed3\u679c\u663e\u793a\u5bf9\u4e8e\u94f6\u542b\u91cf\u9ad8\u76843A[Ag<sub>6<\/sub>]\u6750\u6599\u67097\u4e2a\u5cf0\u7684ESR\u4fe1\u53f7\uff0c\u800c\u5bf9\u4e8e\u94f6\u542b\u91cf\u4f4e\u76843A[Ag<sub>2<\/sub>]\u6750\u6599\u5219\u6ca1\u6709\u94f6\u56e2\u7c07\u7684ESR\u4fe1\u53f7.<\/p>\n<p><strong><b>c,d<\/b><\/strong>: \u56fe<strong><b>c<\/b><\/strong>\u3001\u56fe<strong><b>d<\/b><\/strong>\u5206\u522b\u4ee3\u8868\u70ed\u5904\u7406\u540eFAUY\uff08Ag<sub>0.5<\/sub>\uff09\u7684k<sup>3<\/sup>-\u91cd\u91cfEXAFS\u4fe1\u53f7\u4ee5\u53ca\u5bf9\u5e94\u7684\u76f8\u4fee\u6b63\u5085\u91cc\u53f6\u8f6c\u6362\uff08FT\uff09.<\/p>\n<p><strong>\u56fe5\u00a0LTA\u6cb8\u77f3\u5728\u8fc7\u91cf\u9634\u79bb\u5b50\u6eb6\u6db2\u4e2d\u7684\u8f6c\u6362<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-22406 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72479-3.png\" alt=\"\u56fe\u72479\" width=\"881\" height=\"362\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72479-3.png 881w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72479-3-300x123.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/\u56fe\u72479-3-768x316.png 768w\" sizes=\"(max-width: 881px) 100vw, 881px\" \/><\/p>\n<p><strong><b>a,b<\/b><\/strong>: \u56fe<strong><b>a<\/b><\/strong>\u3001\u56fe<strong><b>b<\/b><\/strong>\u5206\u522b\u4ee3\u8868 3A[Ag<sub>excess<\/sub>]\u30014A[Ag<sub>excess<\/sub>] \u5168\u7f6e\u6362\u548c\u7119\u70e7\u7684\u6fc0\u53d1-\u653e\u5c04\u4e8c\u7ef4\u56fe\uff0c\u7f6e\u6362\u662f\u5728\u8fc7\u91cf\u6d53\u5ea6\u785d\u9178\u94f6\u6eb6\u6db2\u4e2d\u8fdb\u884c\uff0c\u4ece\u56fe\u4e2d\u53ef\u4ee5\u770b\u5230\uff0c\u5728\u8be5\u6761\u4ef6\u4e0b\uff0c\u6240\u6709\u7684Na<sup>+<\/sup>\u4e0eK<sup>+<\/sup>\u5747\u88ab\u7f6e\u6362\uff0c\u4e24\u8005\u7684\u5149\u8c31\u6bd4\u8f83\u7c7b\u4f3c\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/www.nature.com\/nmat\/journal\/vaop\/ncurrent\/full\/nmat4652.html\" target=\"_blank\">Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5728\u5b9a\u4e49\u660e\u786e\u7684\u4ecb\u7535\u8154\u4e2d\uff0c\u5bf9\u4e8e\u4f9d\u8d56\u5c3a\u5bf8\u548c\u5f62\u72b6\u7684\u5bc6\u95ed\u7a7a\u95f4\u4ee5\u53ca\u4ee5\u91d1\u5c5e\u4e3a\u4e3b\u7684\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u6765\u8bf4\uff0c\u91d1\u5c5e\u539f\u5b50\u548c\u56e2\u7c07\u7684\u96c6\u6210\u662f\u4e00\u4e2a\u975e\u5e38\u5f3a\u6709\u529b\u7684\u7b56\u7565\uff0c\u56e0\u4e3a\u5176\u53ef\u4ee5\u8d4b\u4e88\u5b83\u4eec\u65b0\u7684\u5c5e\u6027\u3002\u4f46\u662f&#8230;<\/p>\n","protected":false},"author":54,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[293,31],"class_list":["post-22397","post","type-post","status-publish","format-standard","hentry","category-keji","tag-nature","tag-dianzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22397"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/54"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=22397"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22397\/revisions"}],"predecessor-version":[{"id":22506,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/22397\/revisions\/22506"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=22397"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=22397"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=22397"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}