{"id":223809,"date":"2021-06-25T06:23:28","date_gmt":"2021-06-24T22:23:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223809"},"modified":"2021-06-24T20:23:39","modified_gmt":"2021-06-24T12:23:39","slug":"%e5%94%90%e6%9c%ac%e5%bf%a0%e9%99%a2%e5%a3%abnsr%ef%bc%9a%e5%88%86%e5%ad%90%e5%86%85%e8%bf%90%e5%8a%a8%e5%8f%97%e9%99%90%ef%bc%88rim%ef%bc%89%e7%9a%84%e6%9c%ba%e7%90%86%e5%86%85%e6%b6%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223809","title":{"rendered":"\u5510\u672c\u5fe0\u9662\u58ebNSR\uff1a\u5206\u5b50\u5185\u8fd0\u52a8\u53d7\u9650\uff08RIM\uff09\u7684\u673a\u7406\u5185\u6db5"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u6240\u5468\u77e5\uff0c\u5206\u5b50\u662f\u5728\u6c38\u4e0d\u505c\u6b47\u7684\u8fd0\u52a8\uff0c\u5e76\u4e14\u4f1a\u5f71\u54cd\u5b83\u4eec\u7684\u6027\u8d28\u3002\u5728\u5149\u7269\u7406\u4e2d\uff0c\u53d1\u5149\u4f53\u7684\u53d1\u5149\u884c\u4e3a\u662f\u7531\u5176\u6fc0\u53d1\u6001\u7684\u7535\u5b50\u548c\u6838\u8fd0\u52a8\u51b3\u5b9a\u7684\u3002\u7075\u6d3b\u7684\u5206\u5b50\u8fd0\u52a8\u901a\u5e38\u6709\u5229\u4e8e\u975e\u8f90\u5c04\u8870\u53d8\uff0c\u4ee5\u53ca\u6fc0\u53d1\u6001\u80fd\u91cf\u8f6c\u5316\u4e3a\u5176\u4ed6\u5f62\u5f0f\u3002\u901a\u5e38\u5229\u7528\u5206\u5b50\u5185\u8fd0\u52a8\u53d7\u9650\uff08restriction 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emission, AIE\uff09\u6750\u6599\u662f\u4e00\u7c7b\u5728\u5355\u5206\u5b50\u81ea\u7531\u72b6\u6001\u53d1\u5149\u8f83\u5f31\u800c\u5728\u805a\u96c6\u6001\u53d1\u5149\u663e\u8457\u589e\u5f3a\u7684\u65b0\u578b\u53d1\u5149\u6750\u6599\u3002\u5176\u4e2d\uff0c\u79d1\u5b66\u5bb6\u4eec\u5e7f\u6cdb\u63a5\u53d7\u7684AIE\u673a\u7406\u662fRIM\uff0c\u6839\u636e\u8fd0\u52a8\u6a21\u5f0f\u7684\u4e0d\u540c\u8fd8\u53ef\u4ee5\u7ec6\u5206\u6210\u5206\u5b50\u5185\u8f6c\u52a8\u53d7\u9650\uff08RIR\uff09\u548c\u5206\u5b50\u5185\u632f\u52a8\u53d7\u9650\uff08RIV\uff09\u3002\u56e0\u6b64\uff0c\u79d1\u5b66\u5bb6\u4eec\u8bd5\u56fe\u901a\u8fc7\u9650\u5236\u5206\u5b50\u5185\u65cb\u8f6c\/\u632f\u52a8\uff08RIR\/RIV\uff09\u6765\u8bbe\u8ba1\u5e26\u6709\u8f6c\u5b50\/\u632f\u52a8\u5668\u7684AIE\u53d1\u5149\u539f\uff08AIEgens\uff09\uff0c\u4ece\u800c\u5b9e\u73b0\u5728\u6eb6\u6db2\u72b6\u6001\u4e0b\u4e0d\u53d1\u5149\uff0c\u800c\u5728\u805a\u96c6\u72b6\u6001\u4e0b\u9ad8\u53d1\u5149\u3002\u4f46\u662f\u5e76\u975e\u6240\u6709\u8fd0\u52a8\u90fd\u4f1a\u5bfc\u81f4\u53d1\u5149\u731d\u706d\u3002\u8fd1\u5e74\u6765\uff0c\u901a\u8fc7\u5927\u91cf\u7684\u7814\u7a76\u8868\u660e\u5bfc\u81f4\u975e\u8f90\u5c04\u8dc3\u8fc1\u7684\u5173\u952e\u5206\u5b50\u8fd0\u52a8\uff0c\u5e76\u4ece\u91cf\u5b50\u5316\u5b66\u89d2\u5ea6\u9610\u660eAIEgens\u7684\u6fc0\u53d1\u6001\u5931\u6d3b\u9014\u5f84\u3002\u540c\u65f6\uff0c\u5df2\u5efa\u7acb\u4e86\u4e0d\u540c\u7684\u6a21\u578b\u6765\u63ed\u793aRIM\u673a\u7406\u7684\u5185\u6db5\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u5728\u300a\u56fd\u5bb6\u79d1\u5b66\u8bc4\u8bba\u300b\uff08National 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intramolecular motions (RIM)\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong>National Science Review<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u4e0d\u540c\u975e\u8f90\u5c04\u8dc3\u8fc1\u9014\u5f84\u7684\u591a\u79cd\u6a21\u578b\u6df1\u5316RIM\u673a\u7406\u7684\u5185\u6db5<\/strong><br \/>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223810\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1-1.jpeg\" alt=\"\" width=\"800\" height=\"625\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1-1.jpeg 800w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1-1-300x234.jpeg 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1-1-768x600.jpeg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" 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\/>\uff08A\uff09S<sub>1<\/sub>-S<sub>0<\/sub>\u632f\u52a8\u8026\u5408\u53d7\u9650\uff1b<\/p>\n<p>\uff08B\uff09\u9525\u5f62\u4ea4\u53c9\u901a\u9053\u53d7\u9650\uff1b<\/p>\n<p>\uff08C\uff09\u6697\u6001\u901a\u9053\u53d7\u9650\uff1b<\/p>\n<p>\uff08D\uff09\u6291\u5236\u5149\u5316\u5b66\u53cd\u5e94\u3002<\/p>\n<p>\u5176\u4e2d\uff0cCI=\u9525\u5f62\u4ea4\u53c9\uff0cPET=\u5149\u81f4\u7535\u5b50\u8f6c\u79fb\uff0cTICT=\u626d\u66f2\u7684\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\uff0cISC=\u7cfb\u7edf\u95f4\u4ea4\u53c9\u3002<\/p>\n<p><strong>\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4ece\u7b80\u660e\u627c\u8981\u7684\u89d2\u5ea6\uff0c\u4f5c\u8005\u603b\u7ed3\u4e86\u56db\u79cd\u4e0e\u4e0d\u540c\u7684\u975e\u8f90\u5c04\u9014\u5f84\u76f8\u5173\u7684\u673a\u7406\u6a21\u578b\uff0c\u5e76\u7ed9\u51fa\u4e86\u793a\u610f\u56fe\u548c\u7b80\u5355\u7684\u4f8b\u5b50\uff0c\u63ed\u793a\u4e86RIM\u673a\u7406\u7684\u5185\u6db5\u3002\u672a\u6765\u7684\u7814\u7a76\u4e2d\uff0c\u9664\u4e86\u63ed\u793a\u5931\u6d3b\u9014\u5f84\u548c\u786e\u5b9a\u5bfc\u81f4\u53d1\u5149\u731d\u706d\u7684\u786e\u5207\u5206\u5b50\u8fd0\u52a8\u5916\uff0c\u5176\u4ed6\u4e0e\u5206\u5b50\u8fd0\u52a8\u6709\u5173\u7684\u673a\u7406\u8bfe\u9898\u4e5f\u503c\u5f97\u63a2\u7d22\uff0c\u5305\u62ec\u56fa\u6001\u5206\u5b50\u8fd0\u52a8\u3001\u5206\u5b50\u95f4\u5e73\u79fb\u8fd0\u52a8\u3001\u5206\u5b50\u8fd0\u52a8\u7684\u9891\u7387\u548c\u632f\u5e45\u7b49\u3002\u6b64\u5916\uff0c\u8fd8\u9700\u8981\u5bf9\u5177\u6709\u805a\u96c6\u7c7b\u8bf1\u5bfc\u53d1\u5149\u3001\u5ba4\u6e29\u78f7\u5149\u7b49AIE\u7cfb\u7edf\u8fdb\u884c\u66f4\u6e05\u6670\u3001\u66f4\u5168\u9762\u7684\u673a\u7406\u89e3\u91ca\u3002\u603b\u4e4b\uff0c\u4f5c\u8005\u5e0c\u671b\u901a\u8fc7\u9010\u6b65\u5b8c\u5584AIE\u7684\u673a\u7406\u56fe\uff0c\u4ee5\u4fbf\u66f4\u597d\u5730\u7406\u89e3\u4ecb\u89c2\u805a\u96c6\u7684\u79d1\u5b66\uff0c\u4ece\u800c\u5b9e\u73b0\u65b0\u9896\u4e14\u591a\u6837\u7684AIE\u6750\u6599\u7684\u6709\u8da3\u5e94\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/academic.oup.com\/nsr\/article\/8\/6\/nwaa260\/5928587\" target=\"_blank\" rel=\"noopener\">Mechanistic connotations of restriction of intramolecular motions (RIM)<\/a><\/strong>. <em>National Science Review<\/em>, <strong>2021<\/strong>, DOI: 10.1093\/nsr\/nwaa260.<\/p>\n<p>\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 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