{"id":223671,"date":"2021-06-22T12:00:02","date_gmt":"2021-06-22T04:00:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223671"},"modified":"2021-06-22T11:06:14","modified_gmt":"2021-06-22T03:06:14","slug":"%e6%b5%a6%e9%a1%b9%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6wonyong-choi%e9%99%a2%e5%a3%ab%e5%9b%a2%e9%98%9fnat-commun-%ef%bc%9a%e5%88%a9%e7%94%a8%e5%b7%a5%e7%a8%8b%e8%81%9a%e5%90%88%e6%b0%ae%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223671","title":{"rendered":"\u6d66\u9879\u79d1\u6280\u5927\u5b66Wonyong Choi\u9662\u58eb\u56e2\u961fNat. Commun.\uff1a\u5229\u7528\u5de5\u7a0b\u805a\u5408\u6c2e\u5316\u78b3\u63a7\u5236\u592a\u9633\u80fd\u9a71\u52a8H2O2\u5408\u6210\u7684\u591a\u6b65\u9aa4\u673a\u7406\u5206\u6790"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fc7\u6c27\u5316\u6c22\uff08H2<\/sub>O2<\/sub>\uff09\u662f\u4e00\u79cd\u591a\u529f\u80fd\u7684\u5316\u5b66\u54c1\uff0c\u53ef\u4f5c\u4e3a\u7eff\u8272\u6c27\u5316\u5242\u548c\u6e05\u6d01\u6db2\u4f53\u71c3\u6599\u3002\u4e0e\u4f20\u7edf\u7684\u84bd\u918c\u6cd5\u548c\u76f4\u63a5\u5408\u6210\u6cd5\u76f8\u6bd4\uff0c\u592a\u9633\u80fd\u9a71\u52a8H2<\/sub>O2<\/sub>\u5408\u6210\u5177\u6709\u663e\u8457\u7684\u53ef\u6301\u7eed\u6027\u548c\u73af\u5883\u53cb\u597d\u6027\u3002\u7136\u800c\uff0c\u592a\u9633\u80fd\u7684\u6f5c\u529b\u548c\u5b9e\u9645\u5e94\u7528\u4e4b\u95f4\u7684\u5dee\u8ddd\u662f\u6210\u672c\u6548\u76ca\u3002\u6b64\u5916\uff0c\u4e30\u5bcc\u7684\u5149\u50ac\u5316\u5242\u6210\u5206\u548c\u9ad8\u6548\u7387\u7684\u5149\u5b50\u5316\u5b66\u8f6c\u5316\u8fc7\u7a0b\u662f\u6210\u672c\u6548\u76ca\u7684\u4e24\u4e2a\u5173\u952e\u56e0\u7d20\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u4e00\u79cd\u4f4e\u6210\u672c\u7684\u592a\u9633\u80fd\u8f6c\u6362\u6548\u7387\u7684\u5149\u50ac\u5316\u5242\u662f\u5b9e\u73b0\u53ef\u6301\u7eedH2<\/sub>O2<\/sub>\u751f\u4ea7\u76ee\u6807\u7684\u4e3b\u8981\u6311\u6218\u3002\u6548\u7387\u7684\u63d0\u9ad8\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u5bf9\u7eb3\u7c73\u5c3a\u5ea6\u7ed3\u6784\u548c\u6d3b\u6027\u5173\u7cfb\u7684\u5168\u9762\u673a\u7406\u7406\u89e3\u3002\u5f88\u591a\u5149\u50ac\u5316\u5242\u5df2\u7ecf\u88ab\u5f00\u53d1\u7528\u4e8e\u9ad8\u6548\u751f\u4ea7H2<\/sub>O2<\/sub>\u3002\u5728\u5404\u79cd\u5149\u50ac\u5316\u5242\u4e2d\uff0c\u7531\u6709\u673a\u6846\u67b6\u7ec4\u6210\u7684\u805a\u5408\u6c2e\u5316\u78b3\uff08PCN\uff09\u5177\u6709\u6613\u4e8e\u7ed3\u6784\u4f18\u5316\u7684\u4f18\u70b9\uff1b\u5176\u8868\u9762\u60ac\u6302\u5b98\u80fd\u56e2\u548c\u5171\u8f6d\u7535\u5b50\u7ed3\u6784\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u88ab\u6539\u6027\u4ee5\u5b9e\u73b0\u9ad8\u6548\u7684\u50ac\u5316\u53cd\u5e94\u3002\u53ea\u6709\u6e05\u695a\u5730\u4e86\u89e3\u7ed3\u6784-\u5149\u50ac\u5316\u6d3b\u6027\u7684\u5173\u7cfb\uff0c\u5e76\u5728\u8bbe\u8ba1PCN\u7ed3\u6784\u548c\u7ec4\u6210\u65f6\u52a0\u4ee5\u8003\u8651\uff0c\u624d\u80fd\u6700\u5927\u9650\u5ea6\u5730\u53d1\u6325\u8fd9\u4e00\u72ec\u7279\u4f18\u52bf\u3002\u7136\u800c\uff0c\u7406\u89e3\u6574\u4e2a\u5149\u50ac\u5316\u8fc7\u7a0b\u662f\u5177\u6709\u6311\u6218\u6027\u7684\uff0c\u56e0\u4e3a\u5b83\u6d89\u53ca\u591a\u4e2a\u8fde\u7eed\u6b65\u9aa4\uff0c\u5176\u4e2d\u5305\u62ec\u5149\u5b50\u5438\u6536\/\u6fc0\u53d1\u3001\u53d1\u5c04\u8870\u51cf\u3001\u5149\u8bf1\u5bfc\u7535\u8377\u6355\u83b7\/\u5206\u79bb\u3001\u7535\u8377\u4f20\u8f93\u5230\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u3001\u4e0e\u8868\u9762\u5438\u9644\u53cd\u5e94\u7269\u7684\u754c\u9762\u7535\u8377\u8f6c\u79fb\u3001\u4e2d\u95f4\u7269\u8f6c\u5316\u3001\u6700\u7ec8\u4ea7\u7269\u89e3\u5438\u3002\u5728\u8fd9\u4e2a\u590d\u6742\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6bcf\u4e00\u4e2a\u6b65\u9aa4\u90fd\u5bf9\u6574\u4e2a\u592a\u9633\u80fd\u8f6c\u6362\u6548\u7387\u6709\u6240\u8d21\u732e\u3002\u4e8b\u5b9e\u8bc1\u660e\uff0cPCN\u4e0a\u7684\u4fa7\u6c28\u57fa\u80fd\u5f15\u5165\u8f83\u6df1\u7684\u4fd8\u83b7\u4f4d\u70b9\uff0c\u53ef\u80fd\u5bf9\u5149\u50ac\u5316\u6d3b\u6027\u4ea7\u751f\u8d1f\u9762\u5f71\u54cd\u3002\u5df2\u7ecf\u7814\u7a76\u4e86\u5404\u79cd\u6539\u6027PCN\u7ed3\u6784\u548c\u7ec4\u6210\u7684\u65b9\u6cd5\u6765\u63d0\u9ad8\u5176\u5149\u50ac\u5316\u6d3b\u6027\u3002\u7136\u800c\uff0c\u5bf9\u7279\u5b9a\u7684\u7ed3\u6784\u7279\u5f81\u5982\u4f55\u5f71\u54cd\u5149\u50ac\u53162e–<\/sup>\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u4e2d\u6bcf\u4e2a\u6b65\u9aa4\u7684\u5168\u9762\u673a\u7406\u7406\u89e3\u662f\u5177\u6709\u6311\u6218\u6027\u7684\uff0c\u800c\u8fd9\u4e9b\u4fe1\u606f\u5bf9\u4e8e\u5408\u7406\u8bbe\u8ba1\u9ad8\u6548\u592a\u9633\u80fd\u9a71\u52a8\u7684H2<\/sub>O2<\/sub>\u751f\u4ea7\u7cfb\u7edf\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u97e9\u56fd\u79d1\u5b66\u9662\u9662\u58eb<\/b><\/strong>\u3001<\/b><\/strong>\u6d66\u9879\u79d1\u6280\u5927\u5b66Wonyong Choi\u6559\u6388<\/b><\/strong>\u56e2\u961f\u7b49\u4eba\u5e26\u9886\u4e0b\uff0c\u91c7\u7528\u542b\u6c30\u80fa\u94a0\u57fa\u56e2\u7684\u805a\u5408\u6c2e\u5316\u78b3\u9aa8\u67b6\uff0c\u5728\u592a\u9633\u80fd\u9a71\u52a8\u4e0b\u901a\u8fc7\u6c27\u8fd8\u539f\u751f\u4ea7H2<\/sub>O2<\/sub>\uff0c\u5176\u4ea7\u6c22\u901f\u7387\u4e3a18.7 \u03bcmol h\u22121<\/sup>\u00a0mg\u22121<\/sup>\uff0c\u5728380 nm\u5904\u7684\u8868\u89c2\u91cf\u5b50\u4ea7\u7387\u4e3a27.6%\u3002\u7cfb\u7edf\u5730\u5206\u6790\u4e86\u6574\u4e2a\u5149\u50ac\u5316\u8f6c\u5316\u8fc7\u7a0b\uff0c\u5e76\u901a\u8fc7\u5b9e\u9a8c\u548c\u7406\u8bba\u65b9\u6cd5\u8bc1\u5b9e\u4e86\u4e00\u4e9b\u4ee5\u524d\u672a\u77e5\u7684\u7ed3\u6784\u7279\u5f81\u548c\u76f8\u4e92\u4f5c\u7528\u3002\u9aa8\u67b6\u4e2d\u6c30\u80fa\u57fa\u56e2\u548c\u5421\u5576\u6c2e\u914d\u4f4d\u94a0\u7684\u7ed3\u6784\u7279\u5f81\u4fc3\u8fdb\u4e86\u5149\u5b50\u5438\u6536\uff0c\u6539\u53d8\u4e86\u9aa8\u67b6\u7684\u80fd\u91cf\u683c\u5c40\uff0c\u63d0\u9ad8\u4e86\u7535\u8377\u5206\u79bb\u6548\u7387\uff0c\u589e\u5f3a\u4e86\u5bf9\u5206\u5b50\u6c27\u7684\u8868\u9762\u5438\u9644\uff0c\u5e76\u751f\u6210\u9009\u62e9\u6027\u76842e\u2212<\/sup>\u6c27\u8fd8\u539f\u53cd\u5e94\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\u3002\u7279\u522b\u662f\uff0c\u5b9e\u9a8c\u8bc1\u5b9e\u4e86O2<\/sub>\u4e0e\u8868\u9762\u4e4b\u95f4\u7684\u7535\u5b50\u8026\u5408\u4f5c\u7528\uff0c\u63d0\u9ad8\u4e86\u6d3b\u6027\u6d45\u9677\u9631\u7535\u5b50\u7684\u6570\u91cf\u5e76\u5ef6\u957f\u4e86\u5176\u5bff\u547d\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cMechanistic analysis of multiple processes controlling solar-driven H<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0synthesis using engineered polymeric carbon nitride\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86Nat. Commun.<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 \u5149\u50ac\u5316\u5242\u7684\u5408\u6210\u548c\u7ed3\u6784<\/strong>\"\"<\/p>\n

a\uff09\u805a\u5408\u6c2e\u5316\u78b3 (PCN) \u548c\u5177\u6709\u6c30\u80fa\u57fa\u90e8\u5206\u7684\u805a\u5408\u6c2e\u5316\u78b3 (PCN-NaCA-n)\u7684\u5408\u6210\u3002<\/p>\n

b\uff09\u901a\u8fc7DFT\u8ba1\u7b97PCN\u548cPCN-NaCA\u7684\u4f18\u5316\u7ed3\u6784\u3002<\/p>\n

c\uff09PCN\u548cPCN-NaCA-2\u7684N K\u8fb9X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784 (XANES) \u3002\u63d2\u56fe\u663e\u793a\u4e86\u5421\u5576\u6c2e\u548c\u77f3\u58a8\u6c2e\u7684\u653e\u5927\u5cf0\u3002<\/p>\n

\u56fe<\/strong>2 \u592a\u9633\u80fd\u9a71\u52a8\u7684H<\/strong>2<\/sub><\/strong>O<\/strong>2<\/sub><\/strong>\u751f\u4ea7\u6027\u80fd<\/strong>\"\"<\/p>\n

a\uff0945 min\u592a\u9633\u6a21\u62df\u8f90\u7167\u4e0b\u95f4\u6b47\u53cd\u5e94\u5668\u4e2d\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u6bd4\u8f83\uff1aPCN\u3001\u805a\u5408\u6c2e\u5316\u78b3\u3001PCN-400\u3001PCN\u5728400 \u00b0C\u4e0b\u5728N2\u4e2d\u7145\u70e73 h\uff1bPCN-NaCA-1\u2212 PCN-NaCA-3\uff0c\u805a\u5408\u6c2e\u5316\u78b3\uff0c\u5177\u6709\u4e0d\u540c\u91cf\u7684\u6c30\u80fa\u94a0\u57fa\u56e2\uff1bmpg-C3<\/sub>N4<\/sub>\uff0c\u4ecb\u5b54\u6c2e\u5316\u78b3\u3002<\/p>\n

b\uff09PCN-NaCA-2\u751f\u4ea7H2<\/sub>O2<\/sub>\u6027\u80fd\u4e0epH\u7684\u5173\u7cfb\u3002<\/p>\n

c\uff09PCN-NaCA-2\u751f\u4ea7H2<\/sub>O2<\/sub>\u7684\u8868\u89c2\u91cf\u5b50\u4ea7\u7387\uff08\u84dd\u8272\u6761\uff09\u548cUV-Vis\u6f2b\u53cd\u5c04\u5149\u8c31\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u968f\u6ce2\u957f\u7684\u53d8\u5316\u3002<\/p>\n

d\uff09\u5728\u8fde\u7eed\u6d41\u5149\u53cd\u5e94\u5668\u4e2dPCN-NaCA-2\u7684H2<\/sub>O2<\/sub>\u751f\u4ea7\u6027\u80fd\u968f\u5149\u50ac\u5316\u5242\u6d53\u5ea6\u7684\u53d8\u5316\u3002\u8bef\u5dee\u6761\u8868\u793a\u4e0e\u4e09\u6b21\u5b9e\u9a8c\u7684H2<\/sub>O2<\/sub>\u4ea7\u91cf\u5e73\u5747\u503c(a, b)\u548cAQY\u5e73\u5747\u503c(c)\u7684\u6807\u51c6\u5dee\u3002<\/p>\n

\u56fe<\/strong>3 \u5149\u50ac\u5316\u5242\u7684\u6fc0\u53d1\u548c\u731d\u706d\u7279\u6027<\/strong>\"\"<\/p>\n

a\uff09PCN\u805a\u5408\u78b3\u6c2e\u5316\u7269\u3001\u542b\u6709\u4e0d\u540c\u91cf\u7684\u6c30\u80fa\u94a0\u57fa\u56e2PCN-NaCA-1~PCN-NaCA-3\u7684UV-Vis\u6f2b\u53cd\u5c04\u5149\u8c31\u3002<\/p>\n

b\uff09\u8f6c\u6362\u540e\u7684Kubelka-Munk\u51fd\u6570\u4e0e\u5149\u5b50\u80fd\u91cf\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n

c\uff09PCN\uff08\u9ed1\u8272\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\uff09\u7684\u4ef7\u5e26X\u5c04\u7ebf\u5149\u7535\u5b50\u5149\u8c31\u3002<\/p>\n

d\uff09PCN \u548cPCN-NaCA-2\u7684\u80fd\u5e26\u7ed3\u6784\u3002<\/p>\n

e\uff09PCN\uff08\u84dd\u8272\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\uff09\u5728355 nm\u6fc0\u53d1\u4e0b\u7684\u7a33\u6001\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002<\/p>\n

f\uff09PCN\uff08\u84dd\u8272\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\uff09\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149 (TRPL) \u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>4 PCN-NaCA-2\u7684\u98de\u79d2\u77ac\u6001\u5438\u6536\u5149\u8c31(fs-TAS)<\/strong>\"\"<\/p>\n

a, b\uff09\u5728\u771f\u7a7a\u4e0b\u7684\u7518\u6cb9\u6c34\u6eb6\u6db2(3.5 wt%)\u4e2d\uff0c\u7528\u80fd\u91cf\u5bc6\u5ea6\u4e3a79.6 \u03bcJ cm\u22122<\/sup>\u7684365 nm\u6fc0\u5149\u8109\u51b2\u6fc0\u53d1\u540e\uff0cfs-TAS\u5ef6\u8fdf\u65f6\u95f4\u9ad8\u8fbe7 ns\u3002<\/p>\n

c\uff09fs-TAS\u5728640 nm\u6ce2\u957f\u4e0b\uff0c\u5728\u4e00\u7cfb\u5217\u6fc0\u53d1\u80fd\u91cf\u5bc6\u5ea6\u4e0b\u7684\u771f\u7a7a\u4e0b\u7684\u8870\u51cf\u52a8\u529b\u5b66\u8c31\u3002<\/p>\n

d,e\uff09\u57281 atm\u00a0O2<\/sub>\u4e0b\u7684\u7518\u6cb9\u6c34\u6eb6\u6db2(3.5 wt%)\u4e2d\uff0c\u7528\u80fd\u91cf\u5bc6\u5ea6\u4e3a79.6 \u03bcJ cm\u22122<\/sup>\u7684365 nm\u6fc0\u5149\u8109\u51b2\u6fc0\u53d1\u540e\uff0cfs-TAS\u5ef6\u8fdf\u65f6\u95f4\u9ad8\u8fbe7 ns\u3002<\/p>\n

f\uff09fs-TAS\u5728640\u548c660 nm\u6ce2\u957f\u4e0b\uff0c\u5728\u4e00\u7cfb\u5217\u6fc0\u53d1\u80fd\u5bc6\u5ea6\u4e0b\u7684\u7eafO2<\/sub>\u5927\u6c14\u4e2d\u7684\u8870\u51cf\u52a8\u529b\u5b66\u8c31\u3002<\/p>\n

\u56fe<\/strong>5<\/strong>\u00a0\u5149\u81f4\u7535\u5b50\u7684\u8870\u53d8\u52a8\u529b\u5b66<\/strong>\"\"<\/p>\n

\u7eaf\u6c27\uff08\u5b9e\u5fc3\u5706\u548c\u52a0\u4e2d\u5fc3\u5706\uff09\u548c\u771f\u7a7a\uff08\u5b9e\u5fc3\u5706\u548c\u52a0\u4e2d\u5fc3\u5706\uff09\u6761\u4ef6\u4e0b\uff0cPCN-NaCA-2\u5728\u7518\u6cb9\u6c34\u6eb6\u6db2\u4e2d\u7684\u5149\u8bf1\u5bfc\u7535\u5b50\u7684\u521d\u59cb\u632f\u5e45\uff08\u9ed1\u7ebf\uff09\u548c\u8870\u51cf\u534a\u8870\u671f\uff08\u84dd\u7ebf\uff09\u7684\u901a\u91cf\u4f9d\u8d56\u3002<\/p>\n

\u56fe<\/strong>6<\/strong>\u00a0PCN\u548cPCN-NaCA-2\u8868\u9762\u4e0a\u7535\u8377\u548c\u5206\u5b50\u6c27\u7684\u884c\u4e3a<\/strong>\"\"<\/p>\n

a\uff09PCN\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u7684\u8868\u9762\u5149\u7535\u538b(SPV)\u5149\u8c31\u3002<\/p>\n

b\uff09PCN\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u5728100 \u03bcJ 355 nm\u8109\u51b2\u6fc0\u53d1\u4e0b\u7684\u77ac\u6001\u5149\u7535\u538b\u8c31\u3002<\/p>\n

c\uff09PCN\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\u548cPCN-NaCA-2\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u7684\u6c27\u7a0b\u5e8f\u5347\u6e29\u8131\u9644\u66f2\u7ebf(O2<\/sub>-TPD) \u3002<\/p>\n

d, e\uff09PCN-NaCA-2 (d)\u548cPCN (e)\u5728\u65cb\u8f6c\u73af\u76d8\u7535\u6781(RRDE)\u4e0a\u7684\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u56fe(LSV)\u3002Id<\/sub>\u662f\u76d8\u7535\u6d41\u5bc6\u5ea6\uff0cIr<\/sub>\u662f\u73af\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n

\u56fe<\/strong>7<\/strong>\u00a0PCN-NaCA\uff08\u7ea2\u7ebf\uff09\u548cPCN\uff08\u84dd\u7ebf\uff09\u4e0aORR\u6b65\u9aa4\u7684\u81ea\u7531\u80fd\u56fe<\/strong>\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5728\u4f7f\u7528\u751f\u7269\u8d28\u884d\u751f\u7684\u7518\u6cb9\u4f5c\u4e3a\u7535\u5b50\/\u8d28\u5b50\u4f9b\u4f53\u7684\u592a\u9633\u80fd\u9a71\u52a8\u7684\u9009\u62e9\u60272–<\/sup>\u00a0ORR\u4e2d\uff0c\u5e26\u6709\u6c30\u80fa\u94a0\u76d0\u57fa\u56e2\u7684\u6c2e\u5316\u78b3\u6846\u67b6\u5728\u8fde\u7eed\u6d41\u52a8\u7684\u5149\u53cd\u5e94\u4e2d\u5bf9H2<\/sub>O2<\/sub>\u7684\u4ea7\u751f\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u6d3b\u6027\uff0c\u662fPCN\u768424.6\u500d\u3002\u5728PCN\u6846\u67b6\u4e2d\u5f15\u5165\u6c30\u80fa\u94a0\u57fa\u56e2\u6709\u4ee5\u4e0b\u591a\u79cd\u4f5c\u7528\uff1a(1)\u589e\u5f3a\u5149\u5b50\u5438\u6536\uff0c(2)\u6539\u53d8\u6846\u67b6\u7684\u80fd\u91cf\u683c\u5c40\uff0c\u5bfc\u81f4\u5ef6\u7f13\u8f90\u5c04\u7535\u8377\u91cd\u7ec4\uff0c\u6539\u5584\u7535\u5b50\u5728\u8868\u9762\u533a\u57df\u7684\u79ef\u7d2f\uff0c(3)\u6784\u5efa\u5206\u5b50\u6c27\u5438\u9644\u7684\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\uff0c(4)\u6709\u5229\u4e8e\u9009\u62e9\u6027\u76842e–<\/sup>\u00a0ORR\uff0c\u6240\u6709\u8fd9\u4e9b\u90fd\u534f\u540c\u4fc3\u8fdb\u4e86\u592a\u9633\u80fd\u9a71\u52a8\u7684H2<\/sub>O2<\/sub>\u751f\u4ea7\u6027\u80fd\u3002\u7279\u522b\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8868\u9762\u5438\u9644\u5206\u5b50\u6c27\u548cPCN-NaCA-2\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u4e86\u6d45\u5c42\u4fd8\u83b7\u7535\u5b50\u7684\u6570\u91cf\uff0c\u5e76\u5ef6\u957f\u4e86\u5176\u5bff\u547d\u3002\u8fd9\u8868\u660e\uff0c\u5728\u8bbe\u8ba1\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5242\u65f6\uff0c\u5e94\u8003\u8651\u5230\u5149\u5b50\u6fc0\u53d1\u8fc7\u7a0b\u4e2d\u53cd\u5e94\u7269\u4e0e\u8868\u9762\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4ee5\u53ca\u6750\u6599\u7684\u5185\u5728\u6fc0\u53d1\u7279\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aMechanistic analysis of multiple processes controlling solar-driven H<\/u>2<\/sub><\/u>O<\/u>2<\/sub><\/u>\u00a0synthesis using engineered polymeric carbon nitride<\/u><\/a>\uff08Nat. Commun.\uff0c2021\uff0cDOI\uff1a10.1038\/s41467-021-24048-1\uff09<\/p>\n

\u672c\u6587\u7531\u6728\u6587\u97ec<\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/u>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fc7\u6c27\u5316\u6c22\uff08H2O2\uff09\u662f\u4e00\u79cd\u591a\u529f\u80fd\u7684\u5316\u5b66\u54c1\uff0c\u53ef\u4f5c\u4e3a\u7eff\u8272\u6c27\u5316\u5242\u548c\u6e05\u6d01\u6db2\u4f53\u71c3\u6599\u3002\u4e0e\u4f20\u7edf\u7684\u84bd\u918c\u6cd5\u548c\u76f4\u63a5\u5408\u6210\u6cd5\u76f8\u6bd4\uff0c\u592a\u9633\u80fd\u9a71\u52a8H2O2\u5408\u6210\u5177\u6709\u663e\u8457\u7684\u53ef\u6301\u7eed\u6027\u548c\u73af…<\/p>\n","protected":false},"author":2109,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3369,2868,3105,3129],"class_list":["post-223671","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-dft","tag-2868","tag-3105","tag-3129"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223671"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=223671"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223671\/revisions"}],"predecessor-version":[{"id":223681,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223671\/revisions\/223681"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=223671"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=223671"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=223671"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}