{"id":223550,"date":"2021-06-18T06:30:00","date_gmt":"2021-06-17T22:30:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223550"},"modified":"2021-06-17T10:25:31","modified_gmt":"2021-06-17T02:25:31","slug":"%e6%b5%99%e7%90%86%e5%b7%a5%e8%83%a1%e6%af%85-%e7%89%b9%e6%8b%89%e5%8d%8e%e4%bb%98%e5%a0%83nano-letters%ef%bc%9a%e7%9f%b3%e6%a6%b4%e7%9f%b3-%e9%ab%98%e5%88%86%e5%ad%90%e7%ba%b3%e7%b1%b3%e7%ba%a4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223550","title":{"rendered":"\u6d59\u7406\u5de5\u80e1\u6bc5\/\u7279\u62c9\u534e\u4ed8\u5803Nano\u00a0Letters\uff1a\u77f3\u69b4\u77f3\/\u9ad8\u5206\u5b50\u7eb3\u7c73\u7ea4\u7ef4\u6784\u7b51\u7ed3\u5b9e\u7684\u56fa\u6001\u7535\u89e3\u8d28\u819c"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5f20\u840c\u840c<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u80e1\u6bc5\uff0c\u4ed8\u5803<\/p>\n<p>DOI\uff1a10.1021\/acs.nanolett.1c01704<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1021\/acs.nanolett.1c01704\"><u>https:\/\/doi.org\/10.1021\/acs.nanolett.1c01704<\/u><\/a><\/p>\n<p><strong><b>\u7814\u7a76\u80cc\u666f\uff1a<\/b><\/strong><\/p>\n<p>\u65e0\u673a\u7eb3\u7c73\u6750\u6599\uff08\u5982 SiO<sub>2<\/sub>\u3001ZrO<sub>2<\/sub>\u3001TiO<sub>2<\/sub>\u548c\u5176\u4ed6\u975eLi<sup>+<\/sup>\u5bfc\u7535\u7eb3\u7c73\u9897\u7c92\u6216 Li<sub>7<\/sub>La<sub>3<\/sub>Zr<sub>2<\/sub>O<sub>12<\/sub>\u3001Li<sub>0.33<\/sub>La<sub>0.557<\/sub>TiO<sub>3<\/sub>\u548c\u5176\u4ed6Li<sup>+<\/sup>\u5bfc\u7535\u7eb3\u7c73\u9897\u7c92\uff09\u5206\u6563\u5728\u805a\u5408\u7269\u79bb\u5b50\u5bfc\u4f53\u4e2d\u636e\u62a5\u9053\u53ef\u4ee5\u589e\u5f3a\u79bb\u5b50\u4f20\u5230\u548c\u673a\u68b0\u6027\u80fd\u3002\u9897\u7c92\u88ab\u63ba\u5165\u805a\u5408\u7269\u57fa\u4f53\u4e2d\u4ee5\u5f71\u54cd\u805a\u5408\u7269\u94fe\u7684\u518d\u7ed3\u6676\u52a8\u529b\u5b66\uff0c\u4ece\u800c\u4fc3\u8fdb\u5c40\u90e8\u65e0\u5b9a\u5f62\u533a\u57df\u5e76\u63d0\u9ad8\u9502\u76d0\u805a\u5408\u7269\u4f53\u7cfb\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u7531\u4e8e\u975e\u6676\u533a\u9762\u79ef\u7684\u589e\u52a0\u4ee5\u53ca\u586b\u6599\u4e0e\u805a\u5408\u7269\u754c\u9762\u7684\u6539\u5584\uff0c\u7eb3\u7c73\u7ed3\u6784\u586b\u6599\u7684\u5f00\u53d1\u5df2\u88ab\u8bc1\u660e\u662f\u63d0\u9ad8\u805a\u5408\u7269\u590d\u5408\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n<p>2016 \u5e74\uff0c\u4ed8\u5803\u8fd8\u5728\u9a6c\u91cc\u5170\u5927\u5b66\u80e1\u826f\u5175\u6559\u6388\u8bfe\u9898\u7ec4\u505a\u535a\u540e\u7684\u65f6\u5019\uff0c\u9996\u6b21\u5408\u6210\u4e86LLZO\u7eb3\u7c73\u7ea4\u7ef4\uff0c\u5e76\u62a5\u9053\u4e86\u4e00\u79cd\u4f7f\u75283D LLZO\u7eb3\u7c73\u7ea4\u7ef4\u7f51\u7edc\u5bf9\u9502\u7535\u6c60\u5e94\u7528\u8fdb\u884c\u673a\u68b0\u548c\u7535\u5316\u5b66\u589e\u5f3a\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u56fa\u4f53\u590d\u5408\u7535\u89e3\u8d28\u819c\uff08PNAS June 28, 2016 113 (26) 7094-7099\uff09\u3002\u8fd9\u9879\u5de5\u4f5c\u5f00\u62d3\u4e86\u8fde\u7eed\u79bb\u5b50\u5bfc\u4f53\u5728\u6709\u673a\u9ad8\u5206\u5b50\u673a\u4f53\u4e2d\u7684\u601d\u8def\uff0c\u6210\u4e3a\u968f\u540e\u51e0\u5e74\u6709\u673a\u65e0\u673a\u590d\u5408\u7535\u89e3\u8d28\u819c\u7814\u53d1\u7684\u4e00\u4e2a\u91cd\u8981\u65b9\u5411\u3002\u7136\u800c\uff0c\u4f7f\u7528\u8106\u6027\u9676\u74f7\u5bfc\u4f53\u7eb3\u7c73\u7ea4\u7ef4\u7684 3D 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-1-15.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-1-15-300x153.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>2<\/b><\/strong><strong><b>\uff1aL<\/b><\/strong><strong><b>LZO<\/b><\/strong><strong><b>\u8d1f\u8f7d<\/b><\/strong><strong><b>\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u7f51\u7edc\u5236\u5907\u56fa\u4f53\u7535\u89e3\u8d28\u819c\u3002<\/b><\/strong>a\uff0cLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u7535\u89e3\u8d28\u7684\u5236\u5907\u793a\u610f\u56fe\u3002b\uff0cLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u819c\u7684\u6570\u7801\u7167\u7247\u3002c\uff0cLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u819c\u6324\u538b\u6210\u56e2\u524d\u540e\u7684\u6570\u7801\u7167\u7247\u3002d\uff0c\u5177\u6709LLZO\/h-polymer\uff08PVDF-PEO with LiTFSI\uff09\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u53ca\u5176\u60ac\u6302\u624b\u673a\u7684\u6570\u7801\u7167\u7247\u3002e\uff0c\u5177\u6709LLZO\/h-polymer\uff08PVDF-PEO with LiTFSI\uff09\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u5728150\u00b0C\u52a0\u70ed30\u5206\u949f\u524d\u540e\u7684\u6570\u7801\u7167\u7247\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223556\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-7.png\" alt=\"\" width=\"600\" height=\"585\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-7-300x293.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>3D \u5bfc\u79bb\u5b50\u7eb3\u7c73\u7ea4\u7ef4\u7f51\u7edc\u7684\u5f62\u6001\u548c\u7ed3\u6784\u8868\u5f81\u3002<\/b><\/strong>a\uff0cLLZO\u9897\u7c92\u5728\u6df7\u5408\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u4e0a\u7684\u5206\u5e03\u793a\u610f\u56fe\u3002 LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u5728 b\uff0c\u4f4e\u548c c\uff0c\u9ad8\u653e\u5927\u500d\u6570\u4e0b\u7684 SEM \u56fe\u50cf\u3002d\uff0cLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684TEM\u56fe\u50cf\u3002e\uff0cLLZO \u7c89\u672b\u3001\u7eaf PVDF \u7eb3\u7c73\u7ea4\u7ef4\u548c LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684XRD\u56fe\u3002 f\uff0c\u6df7\u5408\u805a\u5408\u7269\uff08PVDF-PEO with LiTFSI\uff09\u7eb3\u7c73\u7ea4\u7ef4\u548cLLZO\/h-polymer\uff08PVDF-PEO with LiTFSI\uff09\u7eb3\u7c73\u7ea4\u7ef4\u7684TGA\u3002G\uff0c\u5206\u522b\u5177\u6709\u6df7\u5408\u805a\u5408\u7269\uff08PVDF-PEO with LiTFSI\uff09\u7eb3\u7c73\u7ea4\u7ef4\u548c LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u4f5c\u4e3a 3D \u7f51\u7edc\u589e\u5f3a\u7684 PEO \u57fa\u590d\u5408\u7535\u89e3\u8d28\u819c\u7684\u5e94\u529b\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223557\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-6.png\" alt=\"\" width=\"600\" height=\"506\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-6-300x253.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>LLZO\/h-<\/b><\/strong><strong><b>polymer<\/b><\/strong><strong><b>\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u8868\u5f81\u3002<\/b><\/strong>a\uff0c\u5177\u6709h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u548c\u5177\u6709\u4e0d\u540cLLZO\u542b\u91cf\u7684LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684Arrhenius\u66f2\u7ebf\u3002b\uff0cLi | LLZO\/h-polymer\u00a0| Li\u5bf9\u79f0\u7535\u6c60\u7684\u8ba1\u65f6\u7535\u6d41\u5206\u6790\u66f2\u7ebf\uff0c\u63d2\u56fe\uff1a\u7535\u6c60\u6781\u5316\u524d\u540e\u7684\u5948\u594e\u65af\u7279\u963b\u6297\u8c31\u3002c\uff0c\u542bh-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u548c\u542bLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684LSV\u66f2\u7ebf\u3002d\uff0c\u00a0Li | h-polymer\u00a0| Li\u548cLi | LLZO\/h-polymer | Li\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u524d\u540e\u7684\u7535\u5316\u5b66\u963b\u6297\u3002e\uff0c\u542bh-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u548c\u542bLLZO\/h-\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684Li\/Li\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002f\uff0ce) \u4e2d\u5faa\u73af\u9636\u6bb5 I\u3001II \u548c III \u7684\u653e\u5927\u89c6\u56fe\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223558\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-11-5.png\" alt=\"\" width=\"600\" height=\"431\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-11-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-11-5-300x216.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>\uff1a\u5177\u6709<\/b><\/strong><strong><b>\u00a0LLZO\/h-<\/b><\/strong><strong><b>polymer<\/b><\/strong><strong><b>\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684 LiFePO<\/b><\/strong><strong><sub><b>4<\/b><\/sub><\/strong><strong><b>\/Li \u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u8868\u5f81\u548c\u5177\u6709 LLZO\/h-<\/b><\/strong><strong><b>polymer<\/b><\/strong><strong><b>\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684\u67d4\u6027\u8868\u5f81\u3002<\/b><\/strong>a\uff0c\u5177\u6709LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u7535\u89e3\u8d28\u7684LiFePO<sub>4<\/sub>\/Li\u96c6\u6210\u7535\u6c60\u793a\u610f\u56fe\u3002b\uff0c\u5177\u6709LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684LiFePO<sub>4<\/sub>\/Li\u7535\u6c60\u7684\u500d\u7387\u5bb9\u91cf\uff080.2-2C\uff09\u3002c\uff0cLiFePO<sub>4 <\/sub>| LLZO\/h-polymer\u00a0| Li\u7535\u6c60\u572850\u00b0C\u30010.2 C\u4e0b\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u7684\u5145\u653e\u7535\u66f2\u7ebf\u3002d\uff0c\u542bh-polymer\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u7535\u89e3\u8d28\u548c\u542bLLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u590d\u5408\u7535\u89e3\u8d28\u7684LiFePO4\/Li\u7535\u6c60\u57280.2 C\u300150\u2103\u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u3002e\uff0c\u5177\u6709LLZO\/h-polymer\u7eb3\u7c73\u7ea4\u7ef4\u7684\u590d\u5408\u7535\u89e3\u8d28\u7684\u888b\u5f0fLiFePO<sub>4<\/sub>\/Li\u7535\u6c60\u7684\u539f\u59cb\u3001\u5f2f\u66f2\u3001\u6298\u53e0\u548c\u6062\u590d\u6d4b\u8bd5\u7684\u5149\u5b66\u56fe\u50cf\u3002\u7ea2\u8272\u5706\u5708\u5185\u4e3aLED\u706f\u5e26\u3002<\/p>\n<p><strong><b>\u5c0f\u7ed3\uff1a<\/b><\/strong><\/p>\n<p>\u8be5\u7814\u7a76\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u7684\u5bfc\u7535\u6c27\u5316\u7269\u589e\u5f3a\u7684\u00a03D \u79bb\u5b50\u4f20\u5bfc\u7f51\u7edc\uff0c\u5177\u6709\u9ad8\u673a\u68b0\u5f3a\u5ea6\u3001\u67d4\u6027\u548c\u5bfc\u79bb\u5b50\u7279\u6027\u4ee5\u53ca\u66f4\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u7531\u4e92\u8fde\u7684\u5bfc\u7535\u6c27\u5316\u7269\u7eb3\u7c73\u9897\u7c92\uff08\u4f8b\u5982\uff0cLLZO\uff09\u548c\u5bfc\u7535\u805a\u5408\u7269\u4f5c\u4e3a\u8bb8\u591a\u7528\u4e8e\u56fa\u6001\u9502\u7535\u6c60\u7684\u8106\u6027\u5bfc\u7535\u9676\u74f7\u6750\u6599\u7684\u673a\u68b0\u575a\u56fa\u7684\u66ff\u4ee3\u54c1\u3002LLZO \u7eb3\u7c73\u9897\u7c92\u4e0e\u6df7\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\uff08\u5e26\u6709 LiTFSI \u7684 PVDF-PEO\uff09\u5171\u9759\u7535\u7eba\u4e1d\u4ee5\u5f62\u6210 3D \u7f51\u7edc\uff0c\u5e76\u5bc6\u96c6\u586b\u5145\u5728\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u4e2d\u3002\u8fd9\u79cd\u7ed3\u6784\u4e0d\u4ec5\u589e\u5f3a\u4e86\u590d\u5408\u7535\u89e3\u8d28\u7684\u673a\u68b0\u5f3a\u5ea6\uff0c\u800c\u4e14\u8fdb\u4e00\u6b65\u4f18\u5316\u4e86\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u8def\u5f84\u3002\u5728 50 \u00b0C \u65f6\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u4e3a 5.02 V\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a 1.05 \u00d7 10<sup>\u22124<\/sup>\u00a0S cm<sup>\u22121<\/sup>\u3002\u6b64\u5916\uff0cLi\/Li \u5bf9\u79f0\u7535\u6c60\u5728 0.1 mA cm<sup>-2<\/sup>\u00a0\u4e0b 1000 \u5c0f\u65f6\u5185\u4fdd\u6301\u7a33\u5b9a\u5faa\u73af\u3002\u5168\u56fa\u6001\u7535\u6c60\u7684\u653e\u7535\u6bd4\u5bb9\u91cf\u4e3a 147.6 mAh g<sup>-1<\/sup>\uff0c\u5728 0.2 C \u4e0b180 \u6b21\u5faa\u73af\u540e\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a 99.2%\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u805a\u5408\u7269\/\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u819c\u548c\u56fa\u4f53\u9502\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u8fdb\u5c55\u3002<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5f20\u840c\u840c \u901a\u8baf\u4f5c\u8005\uff1a\u80e1\u6bc5\uff0c\u4ed8\u5803 DOI\uff1a10.1021\/acs.nanolett.1c01704 https:\/\/doi.org\/10.1021\/acs&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-223550","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223550"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=223550"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223550\/revisions"}],"predecessor-version":[{"id":223559,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/223550\/revisions\/223559"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=223550"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=223550"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=223550"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}