{"id":223420,"date":"2021-06-15T18:11:40","date_gmt":"2021-06-15T10:11:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223420"},"modified":"2021-06-18T15:04:10","modified_gmt":"2021-06-18T07:04:10","slug":"mof%e5%a4%a7%e7%89%9b%ef%bc%9a%e9%82%93%e9%b9%a4%e7%a5%a5%e3%80%81%e7%8e%8b%e5%8d%9a%e3%80%81%e5%8d%9c%e6%98%be%e5%92%8c%e3%80%81%e6%b1%9f%e6%b5%b7%e9%be%99%e3%80%81%e6%9e%97%e6%96%87%e6%96%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223420","title":{"rendered":"MOF\u5927\u725b\uff1a\u9093\u9e64\u7fd4\u3001\u738b\u535a\u3001\u6c6a\u9a8b\u3001\u6c5f\u6d77\u9f99\u3001\u6797\u6587\u658c\u3001\u5468\u5b8f\u624d\u3001Yaghi\u7b49\u8fd1\u671f\u6210\u679c\u901f\u89c8\u00a0"},"content":{"rendered":"<p><strong><b>N<\/b><\/strong><strong><b>ature\uff1a<\/b><\/strong><strong><b>MOF<\/b><\/strong><strong><b>\u5b54\u9699\u586b\u5145TiO<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>\u590d\u5408\u6750\u6599\u5b9e\u73b0\u9ad8\u6548\u4e8c\u6c27\u5316\u78b3\u5149\u8fd8\u539f<\/b><\/strong><\/p>\n<p>MOF\u4e0e\u6c14\u4f53\u5206\u5b50\u4e4b\u95f4\u5177\u6709\u7279\u5f02\u6027\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u518d\u52a0\u4e0aMOF\u5177\u6709\u4e30\u5bcc\u6709\u5e8f\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u4f7f\u5f97MOF\u6210\u4e3a\u80fd\u591f\u5b9e\u73b0\u6c14\u4f53\u5206\u5b50\u5149\u50ac\u5316\u8f6c\u5316\u7684\u7406\u60f3\u6750\u6599\u3002\u7136\u800c\uff0c\u4e0e\u7ecf\u5178\u7684\u56fa\u6001\u6216\u8005\u5206\u5b50\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u76ee\u524d\u7684MOF\u57fa\u6750\u6599\u8fd8\u672a\u80fd\u5b9e\u73b0\u9ad8\u6548\u7684\u4e8c\u6c27\u5316\u78b3\u8f6c\u6362\u6548\u7387\u3002\u6b66\u6c49\u5927\u5b66\u7684\u9093\u9e64\u7fd4\u3001Ling Zan\u4ee5\u53ca\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7684Osamu Terasaki\u6559\u6388\u7b49\u4eba\u521b\u9020\u4e86\u4e00\u79cd\u65b0\u578b\u7684MOF\u5185\u201c\u5206\u5b50\u9694\u95f4\uff08molecular compartments\uff09\u201d\u6750\u6599\u3002\u5728MIL-101\u53ca\u5176\u884d\u751f\u7269\u7684\u5b54\u7ed3\u6784\u5185\u751f\u957f\u4e8c\u6c27\u5316\u949b\uff0c\u4ece\u800c\u6784\u5efa\u5177\u6709\u4e86\u5206\u5b50\u9694\u95f4\u7684MOF\u57fa\u590d\u5408\u6750\u6599\u3002\u7814\u7a76\u663e\u793a\uff0c\u8fd9\u4e00\u9694\u95f4\u80fd\u591f\u4fc3\u8fdb\u5149\u5438\u6536\/\u7535\u5b50\u751f\u6210\u7684\u4e8c\u6c27\u5316\u949b\u5355\u5143\u4e0e\u5177\u6709\u50ac\u5316\u6027\u80fd\u7684MOF\u91d1\u5c5e\u7c07\u4ea7\u751f\u534f\u540c\u4f5c\u7528\uff0c\u4ece\u800c\u5b9e\u73b0\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u8fc7\u7a0b\u4ee5\u4ea7\u751f\u6c27\u6c14\u3002\u5728\u8fd9\u4e00\u590d\u5408\u6750\u6599\u4e2d\uff0c\u4e8c\u6c27\u5316\u78b3\u5149\u8fd8\u539f\u7684\u91cf\u5b50\u6548\u7387\u751a\u81f3\u53ef\u4ee5\u9ad8\u8fbe11.3%\uff08350nm\u5149\u6e90\u5904\uff09\uff0c\u8868\u660e\u4e8c\u6c27\u5316\u949b\u5728MOF\u4f53\u7cfb\u4e2d\u7684\u7cbe\u786e\u5b9a\u4f4d\u80fd\u591f\u6709\u6548\u63d0\u5347\u4e8c\u6c27\u5316\u949b\u7684\u6d3b\u6027\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFilling metal\u2013organic framework mesopores with TiO<sub>2<\/sub>\u00a0for CO<sub>2<\/sub>\u00a0photoreduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u4e0a\u3002<\/p>\n<p>DOI: 10.1038\/s41586-020-2738-2<\/p>\n<p>\u56fe1 \u63a7\u5236MOF\u590d\u5408\u6750\u6599\u4e2dTiO<sub>2<\/sub>\u5355\u5143\u7684\u6570\u91cf\u548c\u4f4d\u7f6e<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223423\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-12.png\" alt=\"\" width=\"406\" height=\"608\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-12.png 406w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-12-200x300.png 200w\" sizes=\"(max-width: 406px) 100vw, 406px\" \/><\/p>\n<p><strong><b>Na<\/b><\/strong><strong><b>ture Chem<\/b><\/strong><strong><b>.\uff1a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e0e\u8102\u8d28\u4f53\u7ed3\u5408\u5b9e\u73b0\u5149\u50ac\u5316\u5168\u6c34\u5206\u89e3<\/b><\/strong><\/p>\n<p>MOF\u548cMOL\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u6c34\u6c27\u5316\u53cd\u5e94\uff08WOR\uff09\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u5feb\u901f\u590d\u5408\uff0c\u5229\u7528MOF\/MOL\u5b9e\u73b0\u5149\u50ac\u5316\u6c34\u5206\u89e3\u4ecd\u7136\u5177\u6709\u6781\u5927\u7684\u6311\u6218\u6027\u3002\u81ea\u7136\u5149\u5408\u4f5c\u7528\u5229\u7528\u7c7b\u56ca\u4f53\u819c\u5728\u7a7a\u95f4\u4e0a\u5206\u79bb\u5149\u751f\u7535\u8377\u5bf9\uff0c\u786e\u4fdd\u9ad8\u7684\u5149\u80fd\u8f6c\u5316\u6548\u7387\u3002\u53d7\u6b64\u542f\u53d1\uff0c\u53a6\u95e8\u5927\u5b66\u6c6a\u9a8b\u6559\u6388\u8bfe\u9898\u7ec4\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u7ec4\u88c5\u7b56\u7565\uff0c\u901a\u8fc7\u5c06HER-MOL\u548cWOR-MOF\u5206\u522b\u7ec4\u88c5\u5728\u8102\u8d28\u4f53\u7684\u758f\u6c34\u548c\u4eb2\u6c34\u533a\u57df\uff0c\u5229\u7528\u6c27\u5316\u8fd8\u539f\u578b\u7684\u7a7f\u68ad\u7269\u8d28Fe<sup>3+<\/sup>\u548c\u56db\u6c2f\u82ef\u918c\u5c06\u4e24\u4e2a\u534a\u53cd\u5e94\u4e32\u8054\u8d77\u6765\uff0c\u51cf\u5c11\u5149\u751f\u7535\u8377\u590d\u5408\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5168\u5206\u89e3\u6c34\uff0c\u8868\u89c2\u91cf\u5b50\u4ea7\u7387\u8fbe\u5230\u4e861.5\u00b11%\u3002\u672c\u5de5\u4f5c\u901a\u8fc7\u6a21\u4eff\u81ea\u7136\u5149\u5408\u4f5c\u7528\u7cfb\u7edf\uff0c\u5b9e\u73b0\u4e86\u5149\u50ac\u5316\u6c34\u5206\u89e3\uff0c\u4e3a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetal\u2013organic frameworks embedded in a liposome\u00a0facilitate overall photocatalytic water splitting\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Chem.\u4e0a\u3002DOI:\u00a010.1038\/s41557-020-00635-5<\/p>\n<p>\u56fe2\u00a0HER-MOF\u548cWOR-MOF\u7684\u77ac\u6001\u5438\u6536\u5149\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223422\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-1-12.png\" alt=\"\" width=\"600\" height=\"715\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-1-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-1-12-252x300.png 252w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Matter\uff1a\u673a\u5668\u5b66\u4e60<\/b><\/strong><strong><b>\u8c03\u63a7MOFs\u7eb3\u7c73\u6676\u5f62\u8c8c<\/b><\/strong><\/p>\n<p>\u7531\u4e8e\u7ed3\u6676\u52a8\u529b\u5b66\u7684\u590d\u6742\u6027\u53ca\u5408\u6210\u53d8\u91cf\u7a7a\u95f4\u7684\u9ad8\u7ef4\u6027\uff0c\u7eb3\u7c73\u6676\u4f53\u53ef\u63a7\u7684\u5f62\u8c8c\u8bbe\u8ba1\u4ecd\u5145\u6ee1\u6311\u6218\u3002\u673a\u5668\u5b66\u4e60\u53ef\u4ee5\u8fdb\u884c\u9ad8\u7ef4\u53d8\u91cf\u7a7a\u95f4\u7684\u6570\u636e\u6316\u6398\uff0c\u4e3a\u89e3\u51b3\u8fd9\u4e00\u6311\u6218\u5e26\u6765\u4e86\u65b0\u7684\u673a\u9047\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u53a6\u95e8\u5927\u5b66\u6c6a\u9a8b\u3001\u5468\u8fbe\u7b49\u4eba\u5229\u7528\u673a\u5668\u5b66\u4e60\u6765\u6307\u5bfc\u7eb3\u7c73\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7eb3\u7c73\u6750\u6599(nMOFs)\u7684\u5f62\u8c8c\u8c03\u63a7\u3002\u9996\u5148\uff0c\u5229\u7528\u201c\u51b3\u7b56\u6811\u201d\u7b97\u6cd5\u5206\u6790\u4e86\u4e0d\u540c\u5408\u6210\u6761\u4ef6\u4e0b\u7684\u7269\u76f8\u548c\u5f62\u8c8c\uff0c\u5728\u4f17\u591a\u5408\u6210\u53c2\u6570\u4e2d\u63d0\u53d6\u51fa\u6c34\u548c\u7532\u9178\u7684\u6d53\u5ea6\u4e24\u4e2a\u53d8\u91cf\uff0c\u518d\u7528\u201c\u968f\u673a\u68ee\u6797\u201d\u65b9\u6cd5\u786e\u5b9a\u4e86nMOFs\u5f62\u8c8c\u548c\u8bd5\u9a8c\u6761\u4ef6\u7684\u5bf9\u5e94\u5173\u7cfb\u2014\u2014\u201c\u76f8\u533a\u201d\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u66f4\u5feb\u5730\u5bf9\u7eb3\u7c73\u8584\u7247\u8fdb\u884c\u6d4b\u91cf\u3001\u603b\u7ed3\u5236\u5907\u89c4\u5f8b\uff0c\u8fd8\u5229\u7528\u56fe\u50cf\u8bc6\u522b\u4e2d\u7684Mask-RCNN\u7b97\u6cd5\u5bf9\u00a0&gt;1500\u5f20\u626b\u63cf\u7535\u955c\u56fe\u50cf\u8fdb\u884c\u5206\u6790\uff0c\u81ea\u52a8\u6d4b\u91cf\u4e86\u5176\u539a\u5ea6\u4e0e\u957f\u5ea6\u7684\u5206\u5e03\uff0c\u4ece\u800c\u627e\u5230\u5408\u6210\u201c\u91d1\u5c5e\u6709\u673a\u5355\u5c42\u201d(MOL)\u7684\u6761\u4ef6\u3002\u539f\u4f4d\u6db2\u4f53\u7535\u955c\u548c\u8d28\u8c31\u5206\u6790\u663e\u793a\uff0c\u5408\u6210\u6eb6\u6db2\u4e2d\u4e24\u79cd\u5b64\u7acb\u91d1\u5c5e\u6c27\u7c07\u8282\u70b9\u95f4\u7684\u5e73\u8861\u4e0e\u6240\u751f\u6210MOF\u7684\u7269\u76f8\u548c\u5f62\u8c8c\u9ad8\u5ea6\u76f8\u5173\u3002\u57fa\u4e8e\u5bf9\u201c\u76f8\u533a\u201d\u7684\u8ba4\u8bc6\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u51fa\u4e0d\u540c\u7684\u5206\u6b65\u5408\u6210\u5e8f\u5217\u6210\u529f\u83b7\u5f97\u4e86\u66f4\u591a\u79cd\u5f62\u8c8c\u7684MOF\u6750\u6599\uff08\u5982\u516d\u8fb9\u5f62\u7eb3\u7c73\u7247\u3001\u516b\u9762\u4f53\u3001\u51f9\u516b\u9762\u4f53\u3001\u4e2d\u7a7a\u516b\u9762\u4f53\u53ca\u622a\u89d2\u516b\u9762\u4f53\u7b49\uff09\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u70ef\u70c3\u52a0\u6c22\u7684\u50ac\u5316\u53cd\u5e94\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMachine-Learning-Guided Morphology Engineering of Nanoscale Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Matter\u4e0a\u3002DOI: 10.1016\/j.matt.2020.04.021<\/p>\n<p>\u56fe3\u00a0\u7528\u673a\u5668\u5b66\u4e60\u7b97\u6cd5\u786e\u5b9a\u5408\u6210\u76f8\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223424\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-11.png\" alt=\"\" width=\"600\" height=\"669\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-3-11-269x300.png 269w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>CS C<\/b><\/strong><strong><b>a<\/b><\/strong><strong><b>talysis<\/b><\/strong><strong><b>\uff1a\u8d85\u5171\u8f6dC<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u5149\u50ac\u5316\u6c27\u5316\u80fa\u5076\u8054\u548c\u786b\u9170\u80fa\u73af\u5316<\/b><\/strong><\/p>\n<p>\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u7531\u4e8e\u5176\u5b54\u9699\u7387\u548c\u53ef\u8c03\u5149\u5438\u6536\u7279\u6027\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684\u591a\u76f8\u5149\u50ac\u5316\u5242\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u5149\u7a33\u5b9a\u6027\u548c\u7535\u8377\u5206\u79bb\u5bf9\u63d0\u9ad8\u5149\u50ac\u5316\u8f6c\u5316\u6548\u7387\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5317\u4eac\u7406\u5de5\u5927\u5b66\u738b\u535a\u7b49\u4eba\u5229\u7528\u82ef\u5e76\u567b\u5429\u4e8c\u5511\u5355\u5143\u6784\u5efa\u4e86\u4e00\u79cd\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u548c\u589e\u5f3a\u7535\u8377\u5206\u79bb\u80fd\u529b\u7684\u5168\u5171\u8f6d\u7ed9\u4f53-\u53d7\u4f53COF\u3002\u6240\u5236\u5907\u7684COF\u80fd\u5728\u7a7a\u6c14\u548c\u53ef\u89c1\u5149\u4e0b\u6709\u6548\u751f\u6210\u8d85\u6c27\u81ea\u7531\u57fa\u9634\u79bb\u5b50\uff0c\u4ecb\u5bfc\u786b\u9170\u80fa\u5149\u50ac\u5316\u6c27\u5316\u80fa\u5076\u8054\u73af\u5316\u4e3a1,2,4-\u567b\u4e8c\u5511\uff0c\u4e2d\u9ad8\u6536\u7387\u548c\u9ad8\u53ef\u5faa\u73af\u6027\u3002\u672c\u7814\u7a76\u8bc1\u660e\u4e86\u5177\u6709D-A\u7ed3\u6784\u7684\u5b8c\u5168\u5171\u8f6dCOFs\u5728\u5149\u9a71\u52a8\u6709\u673a\u5408\u6210\u4e2d\u7684\u5de8\u5927\u80fd\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cFully Conjugated Donor-Acceptor Covalent Organic Frameworks for Photocatalytic Oxidative Amine Coupling and Thioamide Cyclization\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Catalysis\u4e0a\u3002DOI: 10.1021\/acscatal.0c01242<\/p>\n<p>\u56fe4\u00a0a) Py-BSZ-COF\u7684\u5408\u6210\u3002b) Py-BSZ-COF\u7ed3\u6784\u6a21\u578b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223425\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-11.png\" alt=\"\" width=\"600\" height=\"227\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-4-11-300x114.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>C<\/b><\/strong><strong><b>hem\uff1aPd\u7eb3\u7c73\u9897\u7c92\u4e0eMOF\u4e2d\u5de5\u7a0b\u5b54\u58c1\u7684\u7ed3\u5408\u589e\u5f3a\u50ac\u5316\u4f5c\u7528<\/b><\/strong><\/p>\n<p>\u521b\u9020\u81ea\u7531\u83b7\u53d6\u7684\u6d3b\u6027\u4f4d\u70b9\u5e76\u8c03\u8282\u5b83\u4eec\u4e0e\u5e95\u7269\u7684\u76f8\u4e92\u4f5c\u7528\u662f\u6709\u6548\u50ac\u5316\u7684\u5173\u952e\uff0c\u4f46\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u4e2d\u79d1\u5927\u7684\u6c5f\u6d77\u9f99\u6559\u6388\u7b49\u4eba\u5c06\u8868\u9762\u88f8\u9732\u7684\u91d1\u5c5eNP\u5c01\u88c5\u5230MOF\u4e2d\uff0c\u901a\u8fc7\u8bbe\u8ba1MOF\u5b54\u58c1\u5fae\u73af\u5883\u6765\u5b9e\u73b0\u4e0e\u57fa\u5e95\u7684\u53ef\u8c03\u76f8\u4e92\u4f5c\u7528\uff0c\u5c06\u88f8\u9732\u7684Pd\u7eb3\u7c73\u9897\u7c92\uff08NPs\uff09\u5df2\u5c01\u88c5\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09MIL-101-NH<sub>2<\/sub>\u4e2d\uff0c\u5f97\u5230Pd@MIL-101-NH<sub>2<\/sub>\u3002\u758f\u6c34\u6027\u5168\u6c1f\u70f7\u57fa\u7ecf\u8fc7\u5408\u6210\u540e\u4fee\u9970\u5230-NH<sub>2<\/sub>\u57fa\u4e0a\uff0c\u5f97\u5230Pd@MIL-101-F<sub>x<\/sub>\uff08x = 3\u30015\u30017\u300111\u300115\uff09\uff0c\u8be5\u5206\u5b50\u53ef\u5de5\u7a0b\u5316MOF\u5b54\u58c1\u4ee5\u8c03\u8282Pd\u5468\u56f4\u7684\u5fae\u73af\u5883\u4ee5\u53ca\u4e0e\u5e95\u7269\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u65e0\u8bba\u662f\u6709\u673a\u7845\u70f7\u7684\u8131\u6c22\u5076\u8054\uff0c\u8fd8\u662f\u5364\u4ee3\u785d\u57fa\u82ef\u7684\u52a0\u6c22\uff0c\u758f\u6c34\u4fee\u9970\u540e\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u90fd\u5f97\u5230\u4e86\u6781\u5927\u7684\u63d0\u9ad8\uff0c\u8fd9\u662f\u7531\u4e8ePd\u4e0e\u6539\u6027MOF\u5bbf\u4e3b\u4e4b\u95f4\u826f\u597d\u7684\u5e95\u7269\u5bcc\u96c6\u548c\u8c03\u8282\u76f8\u4e92\u4f5c\u7528\u3002\u8fdc\u8fdc\u8d85\u8fc7\u4e86\u4f20\u7edf\u7684\u652f\u6301\u578b\u6216\u8868\u9762\u6d3b\u6027\u5242\u4fdd\u62a4\u578bPd NPs\u3002\u91d1\u5c5eNPs@MOF\u590d\u5408\u6750\u6599\u5c06\u662f\u4e00\u4e2a\u7406\u60f3\u7684\u5e73\u53f0\uff0c\u901a\u8fc7\u6613\u4e8e\u8c03\u8c10\u7684MOFs\uff0c\u5c06\u6613\u63a5\u8fd1\u7684\u91d1\u5c5e\u4f4d\u70b9\u7684\u56fa\u6709\u6d3b\u6027\u4e0e\u5de5\u7a0b\u5fae\u73af\u5883\u96c6\u6210\u5728\u4e00\u8d77\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cIntegration of Pd nanoparticles\u00a0with engineered pore walls in MOFs\u00a0for enhanced catalysis\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem\u4e0a\u3002DOI:\u00a010.1016\/j.chempr.2020.11.023<\/p>\n<p>\u56fe5\u00a0\u7ec4\u88c5\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223426\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-10.png\" alt=\"\" width=\"600\" height=\"314\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-10-300x157.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>ngew.<\/b><\/strong><strong><b>\uff1aM<\/b><\/strong><strong><b>OF\u5408\u7406\u5236\u5907\u4f4e\u914d\u4f4d\u5355\u539f\u5b50\u954d<\/b><\/strong><strong><b>\u7535\u50ac\u5316\u5242<\/b><\/strong><strong><b>\u7528\u4e8e\u9ad8\u9009\u62e9\u6027\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f<\/b><\/strong><\/p>\n<p>\u5355\u539f\u5b50\u50ac\u5316\u5242(SACs)\u4ee5\u5176\u8d85\u9ad8\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5982\u4f55\u5408\u7406\u63a7\u5236SACs\u7684\u534f\u8c03\u5fae\u73af\u5883\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u5728\u6b64\uff0c\u4e2d\u79d1\u5927\u7684\u6c5f\u6d77\u9f99\u6559\u6388\u7b49\u4eba\u5f00\u53d1\u4e86\u4e00\u79cd\u540e\u5408\u6210\u91d1\u5c5e\u53d6\u4ee3(PSMS)\u7b56\u7565\uff0c\u5728\u9884\u5148\u8bbe\u8ba1\u7684\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u7684\u6c2e\u63ba\u6742\u78b3\u4e0a\u5236\u5907\u4e86\u4e0d\u540cN\u914d\u4f4d\u6570\u7684\u5355\u539f\u5b50\u954d\u50ac\u5316\u5242(\u8868\u793aNi-N<sub>x<\/sub>-C)\u3002Ni-N<sub>3<\/sub>-C\u50ac\u5316\u5242\u7528\u4e8eCO<sub>2<\/sub>\u7535\u8fd8\u539f\u65f6\uff0cCO \u6cd5\u62c9\u7b2c\u7535\u6d41\u6548\u7387\u6548\u7387(FE)\u9ad8\u8fbe95.6%\uff0c\u660e\u663e\u4f18\u4e8eNi-N<sub>4<\/sub>-C\u50ac\u5316\u5242\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0cNi-N<sub>3<\/sub>\u00a0-C\u4e2d\u8f83\u4f4e\u7684Ni\u914d\u4f4d\u6570\u53ef\u4ee5\u663e\u8457\u4fc3\u8fdbCOOH*\u7684\u751f\u6210\uff0c\u4ece\u800c\u52a0\u901fCO<sub>2<\/sub>\u7684\u8fd8\u539f\u3002\u6b64\u5916\uff0cNi-N<sub>3<\/sub>-C\u5728Zn -CO<sub>2<\/sub>\u7535\u6c60\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\uff0c\u8d85\u9ad8CO FE\u548c\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u3002\u672c\u7814\u7a76\u4e3aSACs\u534f\u540c\u5fae\u73af\u5883\u8c03\u8282CO<sub>2<\/sub>\u5229\u7528\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u666e\u904d\u9014\u5f84\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cRational Fabrication of Low-Coordinate Single-Atom Ni Electrocatalysts by MOFs for Highly Selective CO<sub>2<\/sub>\u00a0Reduction\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/ange.202016219<\/p>\n<p>\u56fe6\u00a0Ni-N<sub>3<\/sub>-C\u4f5c\u4e3aZn-CO<sub>2<\/sub>\u7535\u6c60\u9634\u6781\u50ac\u5316\u5c42<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223427\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-8.png\" alt=\"\" width=\"600\" height=\"444\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-6-8-300x222.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>ACS C<\/b><\/strong><strong><b>ataly<\/b><\/strong><strong><b>sis<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>MOF\u96c6\u6210\u9ad8\u5730\u58f3\u4e30\u5ea6\u7684<\/b><\/strong><strong><b>\u5149\u654f\u5242<\/b><\/strong><strong><b>\u548c\u50ac\u5316\u5242\u7528\u4e8e\u5149\u50ac\u5316\u6c27\u5316<\/b><\/strong><\/p>\n<p>\u00a0\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e24\u79cd\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs) Zr<sub>6<\/sub>-Cu\/Fe-1\u548cZr<sub>6<\/sub>-Cu\/Fe-2\uff0c\u96c6\u6210\u4e86\u9ad8\u5730\u58f3\u4e30\u5ea6\u7684\u94dc\u57fa\u5149\u654f\u5355\u5143\uff08Cu-PSs\uff09\u548c\u5ec9\u4ef7\u94c1\u57fa\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\uff0c\u5e94\u7528\u4e8e\u5149\u50ac\u5316\u9700\u6c27\u6c27\u5316\u53cd\u5e94\u3002\u5229\u7528MOF\u7684\u7ed3\u6784\u4f18\u52bf\uff0c MOF\u7ed3\u6784\u7684\u4f4d\u70b9\u9694\u79bb\u4f18\u52bf\u589e\u5f3a\u4e86\u5ec9\u4ef7\u91d1\u5c5e\u5149\u654f\u4e2d\u5fc3\u548c\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u7a33\u5b9a\u6027\uff0c\u4e24\u79cdMOF\u50ac\u5316\u5242\u5728\u6c27\u6c14\u53c2\u4e0e\u7684\u5149\u50ac\u5316\u6c27\u5316\u9187\u7c7b\u6216\u82c4\u57fa\u5316\u5408\u7269\u751f\u6210\u542b\u7fb0\u57fa\u5316\u5408\u7269\u7684\u8fc7\u7a0b\u4e2d\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u4ea7\u7269\u9009\u62e9\u6027\u3002\u5728\u5e38\u6e29\u5e38\u538b\u00a0O<sub>2\u00a0<\/sub>\u6c1b\u56f4\u4e0b\uff0c\u5149\u50ac\u5316\u53cd\u5e94\u4e2d\u00a0Zr<sub>6<\/sub>-Cu\/Fe-1<strong><b>\u00a0<\/b><\/strong>\u76f8\u5bf9\u4e8e\u5747\u76f8\u4f53\u7cfb\u63d0\u9ad8\u4e86\u8fd110\u500d\u50ac\u5316\u6d3b\u6027\uff0c\u540c\u65f6\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5e95\u7269\u9002\u5e94\u6027\uff0c\u9002\u7528\u4e8e\u4e00\u7cfb\u5217\u542b\u6709\u4e0d\u540c\u5b98\u80fd\u56e2\u7684\u5e95\u7269\u4f53\u7cfb\u3002\u63a7\u5236\u5b9e\u9a8c\u3001\u5149\u8c31\u8bc1\u636e\u548c\u8ba1\u7b97\u7814\u7a76\u63ed\u793a\u4e86\u5149\u6c27\u5316\u673a\u7406:[Cu-PS]*\u88abO<sub>2<\/sub>\u6c27\u5316\u731d\u706d\u540e\u4ea7\u751f[Cu<sup>II<\/sup>-PS]\uff0c\u4ece\u800c\u6709\u6548\u5730\u6c27\u5316Fe<sup>III<\/sup>\u2212OH\u751f\u6210\u7f9f\u57fa\u81ea\u7531\u57fa\u7528\u4e8e\u5e95\u7269\u6c27\u5316\u3002\u8fd9\u9879\u5de5\u4f5c\u7a81\u51fa\u4e86MOFs\u5728\u4fc3\u8fdb\u4e30\u5bcc\u7684\u91d1\u5c5e\u57fa\u5149\u50ac\u5316\u65b9\u9762\u7684\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cIntegration of Earth-Abundant Photosensitizers and Catalysts in\u00a0Metal\u2212Organic Frameworks Enhances Photocatalytic Aerobic\u00a0Oxidation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Catalysis\u4e0a\u3002DOI: 10.1021\/acscatal.0c05053<\/p>\n<p>\u56fe7\u00a0MOFs\u50ac\u5316\u5242\u7528\u4e8e\u5149\u50ac\u5316\u6709\u6c27\u6c27\u5316<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223428\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-6.png\" alt=\"\" width=\"600\" height=\"769\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-6-234x300.png 234w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>JACS<\/b><\/strong><strong><b>\uff1aMOFs\u4e2d<\/b><\/strong><strong><b>\u4eba\u5de5\u53cc\u6838\u94dc\u5355\u6c27\u9176\u7684\u5408\u7406\u6784\u9020<\/b><\/strong><\/p>\n<p>\u4eba\u5de5\u9176\u7cfb\u7edf\u88ab\u5e7f\u6cdb\u7814\u7a76\uff0c\u4ee5\u6a21\u62df\u5176\u81ea\u7136\u5bf9\u7b49\u7269\u7684\u7ed3\u6784\u548c\u529f\u80fd\u3002\u7136\u800c\uff0c\u5728\u8fd9\u4e9b\u4eba\u5de5\u7cfb\u7edf\u4e2d\uff0c\u7ed3\u6784\u5efa\u6a21\u548c\u50ac\u5316\u6d3b\u6027\u4e4b\u95f4\u4ecd\u7136\u5b58\u5728\u7740\u663e\u8457\u7684\u5dee\u8ddd\u3002\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u4ece\u949b\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u5f00\u59cb\u6784\u5efa\u4eba\u5de5\u53cc\u6838\u94dc\u5355\u52a0\u6c27\u9176\u7684\u65b0\u7b56\u7565\u3002\u5c06MIL-125\uff08Ti\uff09\u4e8c\u7ea7\u6784\u7b51\u5355\u5143\uff08SBUs\uff09\u4e0a\u7684\u6c22\u6c27\u57fa\u56e2\u53bb\u8d28\u5b50\u5316\uff0c\u4f7f\u5f97SBUs\u4e0e\u5bc6\u96c6\u7684Cu<sup>I<\/sup>\u5bf9\u53d1\u751f\u91d1\u5c5e\u5316\uff0c\u5e76\u8fdb\u4e00\u6b65\u88ab\u5206\u5b50O<sub>2<\/sub>\u6c27\u5316\uff0c\u751f\u6210Cu<sup>II<\/sup><sub>2<\/sub>\uff08\u03bc<sub>2<\/sub>-OH\uff09<sub>2<\/sub>\uff08Ti<sub>8<\/sub>-Cu<sub>2<\/sub>\uff09\u3002\u4e3a\u4e86\u8fdb\u884c\u6bd4\u8f83\uff0c\u4f5c\u8005\u8fd8\u5408\u6210\u4e86\u4eba\u5de5\u5355\u6838Cu\u5355\u52a0\u6c27\u9176Ti<sub>8<\/sub>-Cu<sub>1<\/sub>\u3002\u7814\u7a76\u901a\u8fc7\u70ed\u91cd\u5206\u6790\uff0c\u7535\u611f\u8026\u5408\u7b49\u79bb\u5b50\u4f53\u8d28\u8c31\uff0cX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\uff0c\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31\u548c\u7d2b\u5916\u53ef\u89c1\u5149\u8c31\u7b49\u5bf9\u5408\u6210\u7684MOFs\u57fa\u5355\u52a0\u6c27\u9176\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u5728\u5b58\u5728\u5171\u6cb8\u7269\u7684\u60c5\u51b5\u4e0b\uff0cTi<sub>8<\/sub>-Cu<sub>2<\/sub>\u5bf9\u5e7f\u6cdb\u7684\u5355\u52a0\u6c27\u8fc7\u7a0b\u8868\u73b0\u51fa\u51fa\u8272\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5305\u62ec\u73af\u6c27\u5316\uff0c\u7f9f\u57fa\u5316\uff0cBaeyer-Villiger\u6c27\u5316\u548c\u78fa\u5316\u6c27\u5316\uff0cTON\u9ad8\u8fbe3450\u3002\u6bd4Ti<sub>8<\/sub>-Cu<sub>1<\/sub>\u9ad8\u81f3\u5c1117\u500d\u3002\u8ba1\u7b97\u7ed3\u679c\u8fdb\u4e00\u6b65\u8868\u660e\uff0cTi<sub>8<\/sub>-Cu<sub>2<\/sub>\u4e2d\u7684Cu<sub>2<\/sub>\u4f4d\u534f\u540c\u7a33\u5b9a\u4e86O-O\u952e\u88c2\u89e3\u7684Cu-O<sub>2<\/sub>\u52a0\u5408\u7269\uff0c\u5176\u81ea\u7531\u80fd\u6bd4Ti<sub>8<\/sub>-Cu<sub>1<\/sub>\u4e2d\u7684\u5355\u6838Cu\u4f4d\u589e\u52a0\u4e866.6 kcal\/mol\uff0c\u8bf4\u660eTi<sub>8<\/sub>-Cu<sub>2<\/sub>\u7684\u50ac\u5316\u6d3b\u6027\u660e\u663e\u9ad8\u4e8eTi<sub>8<\/sub>-Cu<sub>1<\/sub>\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cRational Construction of an Artificial Binuclear Copper\u00a0Monooxygenase in a Metal\u2212Organic Framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728JACS\u4e0a\u3002DOI: 10.1021\/jacs.0c11920<\/p>\n<p>\u56fe8\u00a0Cu<sub>2<\/sub>\u4e0eO<sub>2<\/sub>\u7ed3\u5408\u7684\u6d3b\u6027\u4f4d\u70b9<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223429\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-5.png\" alt=\"\" width=\"600\" height=\"632\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-5-285x300.png 285w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>An<\/b><\/strong><strong><b>gew.<\/b><\/strong><strong><b>\uff1a\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2dCu(I)\u548cAg(I)\u7684\u5bf9\u63a5\u7528\u4e8e\u5438\u9644\u548c\u5206\u79bb\u6c19\u6c14<\/b><\/strong><\/p>\n<p>\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\uff0c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7ae0\u8dc3\u6807\u7b49\u4eba \u63d0\u51fa\u4e86\u4e00\u79cd\u91d1\u5c5e\u5bf9\u63a5\u7b56\u7565\uff0c\u5229\u7528\u6709\u673a\u652f\u67f1\u7684\u7cbe\u786e\u7a7a\u95f4\u6392\u5217\u4f5c\u4e3a\u91d1\u5c5e\u5728MOF\u4e2d\u7684\u87af\u5408\u70b9\u3002\u5229\u7528\u5206\u5e03\u5728MOF-303\u4e2d\u6cbf\u68d2\u72b6Al-O\u4e8c\u7ea7\u7ed3\u6784\u5355\u5143\u5206\u5e03\u7684\u76f8\u90bb\u5421\u5511\u4e8c\u9178\u76d0\u952e\u4e0a\u7684\u975e\u914d\u4f4d\u6c2e\u539f\u5b50[Al(OH)(C<sub>5<\/sub>H<sub>2<\/sub>O<sub>4<\/sub>N<sub>2<\/sub>)]\uff0c\u4ee5\u539f\u5b50\u7cbe\u5ea6\u87af\u5408Cu(I)\u548cAg(I)\uff0c\u5f97\u5230\u4e86\u91d1\u5c5e\u5316\u7684Cu-\u548cAg-MOF-303\u5316\u5408\u7269[(CuCl)<sub>0.50<\/sub>Al(OH)(C<sub>5<\/sub>H<sub>2<\/sub>O<sub>4<\/sub>N<sub>2<\/sub>)\u548c(AgNO<sub>3<\/sub>)<sub>0.49<\/sub>-Al(OH)(C<sub>5<\/sub>H<sub>2<\/sub>O<sub>4<\/sub>N<sub>2<\/sub>)]\u3002\u5229\u7528\u4e09\u7ef4\u7535\u5b50\u884d\u5c04\u548c\u6269\u5c55X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5149\u8c31\u6280\u672f\u7814\u7a76\u4e86Cu(I)\u548cAg(I)\u7684\u914d\u4f4d\u51e0\u4f55\u7ed3\u6784\u3002\u5f97\u5230\u7684\u91d1\u5c5e\u5316MOF\u7684\u5b54\u5f84\u5927\u5c0f\u4e0eXe\u7684\u5927\u5c0f\u76f8\u5339\u914d\uff0c\u56e0\u6b64\u53ef\u4ee5\u9ad8\u5bb9\u91cf\u548c\u9009\u62e9\u6027\u5730\u7ed3\u5408Xe\/Kr\u6df7\u5408\u7269\u4e2d\u7684Xe\u3002Ag-MOF-303\u5728298 K\u548c0.2 bar\u7684\u6e29\u5ea6\u4e0b\u8868\u73b0\u51fa59 cm<sup>3<\/sup>\u00a0cm<sup>-3<\/sup>\u7684Xe\u5438\u6536\uff0c\u9009\u62e9\u6027\u4e3a10.4\uff0c\u662f\u6027\u80fd\u6700\u597d\u7684MOF\u4e4b\u4e00\u3002\u4e0e\u539f\u88c5MOF-303\u76f8\u6bd4\uff0c\u52a8\u6001\u5206\u79bb\u6027\u80fd\u63d0\u9ad8\u4e86100%\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cDocking of Cu(I) and Ag(I) in Metal-Organic Frameworks for\u00a0Adsorption and Separation of Xenon\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/anie.202015262<\/p>\n<p>\u56fe9\u00a0\u5de5\u7a0b\u5316MOF\u4ee5\u5b9e\u73b0\u9ad8\u6027\u80fd\u6c14\u4f53\u5206\u79bb<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223430\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-5.png\" alt=\"\" width=\"600\" height=\"356\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-9-5-300x178.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>An<\/b><\/strong><strong><b>gew.<\/b><\/strong><strong><b>\uff1a\u4e00\u7cfb\u5217\u4ecb\u5b54\u7a00\u571f\u91d1\u5c5e<\/b><\/strong><strong><b>\u6709\u673a\u9aa8\u67b6\u6750\u6599<\/b><\/strong><strong><b>\u6784\u9020\u901a\u8fc7\u6709\u673a\u4e8c\u7ea7\u5355\u5143<\/b><\/strong><\/p>\n<p>\u4ece\u4e3b\u8981\u6216\u6b21\u8981\u7ed3\u6784\u5355\u5143(SBUs)\u7ec4\u88c5\u590d\u6742\u8fde\u63a5\u62d3\u6251\u7684\u80fd\u529b\u4e3a\u6269\u5c55\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5e93\u63d0\u4f9b\u4e86\u5f88\u597d\u7684\u524d\u666f\u3002MOFs\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u9700\u8981\u5728\u6846\u67b6\u5185\u5efa\u7acb\u5c42\u6b21\u4e92\u52a8\u3002\u4ece\u4e3b\u8981\u6216\u6b21\u8981\u7ed3\u6784\u5355\u5143(SBUs)\u7ec4\u88c5\u590d\u6742\u8fde\u63a5\u62d3\u6251\u7684\u80fd\u529b\u4e3a\u6269\u5c55\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u5e93\u63d0\u4f9b\u4e86\u5f88\u597d\u7684\u524d\u666f\u3002\u5fb7\u5dde\u519c\u5de5\u5927\u5b66\u5468\u5b8f\u624d\u7b49\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4ecb\u5b54\u7ed3\u6784\u7684RE-MOFs\uff0cPCN-2020(RE, RE = Eu, Y, Yb, Tb, Ce)\uff0c\u5b83\u662f\u7531\u65b0\u578b\u7684\u5341\u4e8c\u8fde\u63a5\u7684\u03c0-\u5806\u79ef\u8298\u8d85\u5206\u5b50\u6784\u7b51\u57fa\u5143\u548c\u7ecf\u5178\u7684\u5341\u4e8c\u8fde\u63a5RE<sub>6<\/sub>\u91d1\u5c5e\u7c07\u6784\u7b51\u800c\u6210\u3002\u7814\u7a76\u7ed3\u679c\u663e\u793a\u5341\u4e8c\u8fde\u63a5\u7684\u65e0\u673a\u7acb\u65b9\u516b\u9762\u4f53SBUs\u548c\u5341\u4e8c\u8fde\u63a5\u7684\u6709\u673a\u65e0\u5e8f\u516d\u89d2\u68f1\u67f1\u4f53SBUs\u7ec4\u88c5\u53ef\u6784\u7b51\u5f62\u6210\u4e00\u79cd\u4ece\u672a\u62a5\u9053\u8fc7\u7684\u7ed3\u6784\uff0c\u6700\u7ec8\u53ef\u4ee5\u7b80\u5316\u6210\u7531\u5e73\u9762\u6b63\u65b9\u5f62\u548c\u56db\u9762\u4f53\u8fde\u63a5\u800c\u6210\u76844,4-\u8fde\u63a5\u7684pts\u7f51\u72b6\u7ed3\u6784\u3002PCN-2020(RE)\u4e0d\u4ec5\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u4fdd\u6301\u7a33\u5b9a\uff0c\u540c\u65f6\u5728\u8f83\u5bbdpH\u7684\u6c34\u6eb6\u6db2\uff08pH = 1\u20139\uff09\u4e2d\u4e5f\u4fdd\u6301\u7740\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e3a\u7a00\u571fMOFs\u5728\u542b\u6c34\u73af\u5883\u4e2d\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u6587\u7ae0\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u90e8\u5206PCN-2020(RE)\u5728CO<sub>2<\/sub>\u4e0e\u73af\u6c27\u5316\u5408\u7269\u73af\u52a0\u6210\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8bc1\u5b9e\u5176\u662f\u4e00\u7c7b\u9ad8\u6548\u7684CO<sub>2<\/sub>\u8f6c\u5316\u50ac\u5316\u5242\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cA Series of Mesoporous Rare-Earth Metal-Organic Frameworks\u00a0Constructed from Organic Secondary Building Units\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002DOI: 10.1002\/ange.202011653<\/p>\n<p>\u56fe10 PCN-2020\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223431\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-10-3.png\" alt=\"\" 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