{"id":223354,"date":"2021-06-18T12:00:15","date_gmt":"2021-06-18T04:00:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223354"},"modified":"2021-06-18T09:57:36","modified_gmt":"2021-06-18T01:57:36","slug":"nature-communications%ef%bc%9a%e5%85%b3%e4%ba%8e%e7%94%b5%e5%82%ac%e5%8c%96%e6%9e%90%e6%b0%a2%e4%b8%ad%e6%b0%a2%e6%ba%a2%e5%87%ba%e7%8e%b0%e8%b1%a1%e7%9a%84%e5%9f%ba%e6%9c%ac%e8%a7%82%e7%82%b9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223354","title":{"rendered":"Nature Communications\uff1a\u5173\u4e8e\u7535\u50ac\u5316\u6790\u6c22\u4e2d\u6c22\u6ea2\u51fa\u73b0\u8c61\u7684\u57fa\u672c\u89c2\u70b9"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1aJiayuan Li<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1aJun Hu\uff08\u80e1\u519b\uff09\uff0cYongquan Qu\uff08\u77bf\u6c38\u6cc9\uff09\uff0cYuanyuan 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size-full wp-image-223356\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-9.png\" alt=\"\" width=\"529\" height=\"528\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-9.png 529w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-9-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-2-9-300x300.png 300w\" sizes=\"(max-width: 529px) 100vw, 529px\" \/><\/p>\n<p>\u56fe2|\u50ac\u5316\u5242\u8bbe\u8ba1\u3002<\/p>\n<p><strong><b>PTM\/COP\u578b\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1<\/b><\/strong><\/p>\n<p>\u4ee5Pt\/CoP\u4e3a\u6a21\u578b\u50ac\u5316\u5242\uff0cPt(\u0394\u03a6<sub>Pt<\/sub>=5.37 eV)\u548cCoP(\u0394\u03a6<sub>CoP<\/sub>=5.56 eV)\u4e4b\u95f4\u7684~0.19 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H<sub>2<\/sub>SO<sub>4<\/sub>\u4e2d\uff0c\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u4e3a1.0wt%\u7684PTM\/COP\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u8bc4\u4ef7\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223359\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-8.png\" alt=\"\" width=\"600\" height=\"485\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-5-8-300x243.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-4.png\" alt=\"\" width=\"600\" height=\"412\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-7-4-300x206.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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eV(\u4f4d1)\u3001\u22120.06 eV(\u4f4d2)\u548c\u22120.36 eV(\u4f4d3)\uff0c\u8fd9\u8868\u660e\u5728Pt\u548cCoP(\u4f4d3)\u754c\u9762\u6709\u660e\u663e\u7684\u8d28\u5b50\u6355\u83b7\u3002\u53cd\u4e4b\uff0c\u6700\u7a33\u5b9a\u7684Co\u4f4d(4\u4f4d)\u7684\u0394G<sub>H<\/sub>\u4e3a0.04 eV\uff0c\u8868\u660eCoP\u7684Co\u4f4d\u66f4\u6709\u5229\u4e8e\u901a\u8fc7\u7834\u574fCo-H\u952e\u751f\u6210\u6c22\u5206\u5b50\u3002\u5982\u679cH\u80fd\u8de8\u8fc7Pt\u56e2\u7c07\u7684\u8fb9\u7f18\u8f6c\u79fb\u5230CoP\u8868\u9762\uff0c\u5219\u65e0\u8bba\u662f\u8d28\u5b50\u7684\u521d\u59cb\u5438\u9644\u8fd8\u662fH<sub>2<\/sub>\u7684\u6700\u7ec8\u8131\u9644\uff0cHER\u90fd\u5f88\u5bb9\u6613\u8fdb\u884c\u3002\u7136\u800c\uff0c\u7531\u4e8e\u57283\u53f7\u4f4d(\u0394G<sub>H<\/sub>=\u22120.36 eV)\u5904\u6709\u5f88\u5f3a\u7684\u6c22\u6355\u83b7\uff0c\u8fd9\u6837\u7684\u6ea2\u51fa\u8fc7\u7a0b\u5728\u754c\u9762\u4e0a\u53d7\u5230\u4e86\u963b\u788d\u3002\u56e0\u6b64\uff0c\u6574\u4e2aHER\u8fc7\u7a0b\u53d7\u6d3b\u6027\u6c22\u7269\u79cd\u4ece3\u4f4d\u52304\u4f4d\u754c\u9762\u6269\u6563\u7684\u9650\u5236\uff0c\u5b58\u5728\u663e\u8457\u7684\u70ed\u529b\u5b66(0.40 eV)\u548c\u52a8\u529b\u5b66\u52bf\u5792(0.79 eV)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223362\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-3.png\" alt=\"\" width=\"600\" height=\"343\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/\u56fe\u7247-8-3-300x172.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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