{"id":223341,"date":"2021-06-21T12:30:53","date_gmt":"2021-06-21T04:30:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=223341"},"modified":"2021-06-21T11:40:59","modified_gmt":"2021-06-21T03:40:59","slug":"%e5%8d%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e9%ab%98%e5%86%a0%e9%81%93%e5%9b%a2%e9%98%9fnat-commun-%ef%bc%9a%e9%80%9a%e8%bf%87%e6%83%b0%e6%80%a7%e8%81%9a%e5%9b%9b%e6%b0%9f%e4%b9%99%e7%83%af%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=223341","title":{"rendered":"\u5357\u4eac\u5927\u5b66\u9ad8\u51a0\u9053\u56e2\u961fNat. Commun.\uff1a\u901a\u8fc7\u60f0\u6027\u805a\u56db\u6c1f\u4e59\u70ef\u7684\u8d85\u58f0\u6d3b\u5316\u4f7f\u538b\u7535\u50ac\u5316\u4ea7\u751f\u6d3b\u6027\u6c27"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6d3b\u6027\u6c27(ROS)\uff0c\u5982\u7f9f\u57fa\u81ea\u7531\u57fa(\u2022OH)\u3001\u8d85\u6c27\u5316\u7269(\u2022O<sup>2\u2212<\/sup>)\u548c\u5355\u7ebf\u6001\u6c27(<sup>1<\/sup>O<sub>2<\/sub>)\uff0c\u662f\u6700\u5f3a\u7684\u6c34\u6027\u6c27\u5316\u8fd8\u539f\u7269\u79cd\u4e4b\u4e00\u3002\u8fd1\u5e74\u6765\uff0c\u538b\u7535\u50ac\u5316\u5df2\u88ab\u8bc1\u660e\u662f\u4e00\u79cd\u65b0\u578b\u7684\u9ad8\u7ea7\u6c27\u5316\u5de5\u827a\uff0c\u901a\u8fc7\u4f4e\u9891\u632f\u52a8\u6216\u9ad8\u9891\u8d85\u58f0\u6ce2\u5728\u538b\u7535\u50ac\u5316\u5242\u4e0a\u8bf1\u5bfc\u6781\u5316\u5e76\u5efa\u7acb\u5185\u5efa\u7535\u573a\uff0c\u4ece\u800c\u4f7f\u538b\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u5f97\u5230\u6539\u5584\u3002\u5728\u538b\u7535\u50ac\u5316\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u4e2d\uff0c\u7535\u5b50\u548c\u7a7a\u7a74\u53ef\u4ee5\u8fde\u7eed\u5206\u79bb\u5e76\u5438\u5f15\u5230\u76f8\u53cd\u7684\u8868\u9762\u4e0a\u3002\u5728\u6c34\u6eb6\u6db2\u4e2d\uff0c\u8fd9\u4e9b\u8868\u9762\u8f7d\u6d41\u5b50\u53ef\u4ee5\u4e0e\u6c34\u6216\u6eb6\u89e3\u7684\u7269\u8d28\u53d1\u751f\u6c27\u5316\u6216\u8fd8\u539f\u53cd\u5e94\uff0c\u4ea7\u751f\u5747\u76f8ROS\u3002\u538b\u7535\u50ac\u5316ROS\u751f\u6210\u6548\u7387\u672c\u8d28\u4e0a\u53d6\u51b3\u4e8e\u538b\u7535\u7cfb\u6570d<sub>33<\/sub>\uff0c\u901a\u5e38\u538b\u7535\u50ac\u5316\u6d3b\u6027\u968fd<sub>33<\/sub>\u7684\u589e\u52a0\u800c\u589e\u52a0\u3002\u7ecf\u5178\u538b\u7535\u6750\u6599\u5df2\u88ab\u8bc1\u660e\u662f\u538b\u7535\u50ac\u5316\u5242\uff0c\u5305\u62ec\u65e0\u673aBaTiO<sub>3<\/sub>\u3001ZnO\u548cBiFeO<sub>3<\/sub>\u4ee5\u53ca\u6709\u673a\u805a\u504f\u6c1f\u4e59\u70ef(PVDF)\u3002\u7136\u800c\uff0c\u538b\u7535\u7cfb\u6570(d<sub>33<\/sub>\u22483-10<sup>5<\/sup>\u00a0pC\/N)\u592a\u4f4e\uff0c\u4e0d\u80fd\u6709\u6548\u5730\u7528\u4e8e\u538b\u7535\u50ac\u5316\u5e94\u7528\u3002\u9506\u949b\u9178\u94c5(PZT)\u5177\u6709\u5408\u7406\u7684d<sub>33<\/sub>\u00a0(265 pC\/N)\u7528\u4e8e\u538b\u7535\u50ac\u5316\uff0c\u4f46\u94c5\u5b58\u5728\u73af\u5883\u548c\u4eba\u7c7b\u5065\u5eb7\u95ee\u9898\uff0c\u4e14\u5728\u4ea7\u751fROS\u7684\u6761\u4ef6\u4e0b\u4e0d\u7a33\u5b9a\u3002\u975e\u6781\u6027\u805a\u5408\u7269\u9a7b\u6781\u4f53\u6750\u6599\uff0c\u5982\u805a\u56db\u6c1f\u4e59\u70ef\uff08PTFE\uff1bTeflon\uff09\u3001\u805a\u4e19\u70ef\u548c\u805a\u82ef\u4e59\u70ef\uff0c\u662f\u53ef\u4ee5\u51c6\u6c38\u4e45\u5b58\u50a8\u7535\u8377\u6216\u6781\u5316\u7684\u7535\u4ecb\u8d28\u3002\u8fd9\u4e9b\u6709\u673a\u9a7b\u6781\u4f53\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4f20\u611f\u5668\u3001\u7535\u5b50\u7167\u76f8\u3001\u7535\u6d3b\u6027\u7a7a\u6c14\u8fc7\u6ee4\u5668\u548c\u53d1\u7535\u673a\u3002\u540c\u65f6\uff0c\u805a\u5408\u7269\u9a7b\u6781\u4f53\u4e5f\u5177\u6709\u8f83\u5927\u7684\u8868\u89c2\u538b\u7535\u7cfb\u6570\uff0c\u6bd4\u4f20\u7edf\u7684\u538b\u7535\u805a\u5408\u7269(\u5982\u805a\u504f\u6c1f\u4e59\u70ef)\u5927\u4e00\u4e2a\u6570\u91cf\u7ea7\uff0c\u5e76\u63a5\u8fd1\u5df2\u7814\u7a76\u7684\u65e0\u673a\u538b\u7535\u6750\u6599\u7684\u6700\u9ad8\u503c\u3002\u4e00\u822c\u6765\u8bf4\uff0cPTFE\u88ab\u8ba4\u4e3a\u662f\u6781\u5176\u60f0\u6027\u7684\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0cPTFE\u9a7b\u6781\u4f53\u5177\u6709\u4e00\u5b9a\u7684\u5316\u5b66\u6d3b\u6027\uff0c\u56e0\u4e3a\u5b83\u5df2\u7ecf\u4ee5\u5e26\u7535\u6ee4\u819c\u7684\u5f62\u5f0f\u5e94\u7528\u4e8e\u9664\u5c18\u5de5\u4e1a\uff0c\u8be5\u819c\u5229\u7528\u5e26\u7535PTFE\u9a7b\u6781\u4f53\u548c\u5e26\u7535\u7070\u5c18\u9897\u7c92\u4e4b\u95f4\u7684\u9759\u7535\u5438\u5f15\u529b\u3002\u7136\u800c\uff0c\u4f20\u7edf\u7684\u805a\u56db\u6c1f\u4e59\u70ef\u6781\u5316\u65b9\u6cd5\u6bd4\u8f83\u590d\u6742\uff0c\u901a\u5e38\u9700\u8981\u5728200 MV\/m\u8303\u56f4\u5185\u8fdb\u884c\u9ad8\u538b\u7535\u573a\u6781\u5316\u3002\u56e0\u6b64\uff0c\u9700\u8981\u7b80\u5355\u7684\u65b9\u6cd5\u6765\u6fc0\u6d3bPTFE\u9a7b\u6781\u4f53\u9897\u7c92\uff0c\u4ee5\u4fc3\u8fdbPTFE\u9a7b\u6781\u4f53\u538b\u7535\u50ac\u5316\u5242\u7684\u57fa\u7840\u7814\u7a76\u548c\u6f5c\u5728\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5728<strong><b>\u5357\u4eac\u5927\u5b66<\/b><\/strong><strong><b>\u9ad8\u51a0\u9053\u6559\u6388<\/b><\/strong>\u56e2\u961f\u7b49\u4eba\u5e26\u9886\u4e0b\uff0c\u5c55\u793a\u4e86\u4e00\u79cd\u5229\u7528\u6e29\u548c\u7684\u8d85\u58f0\u8fc7\u7a0b\u5c06\u60f0\u6027\u805a\u56db\u6c1f\u4e59\u70ef\uff08PTFE\uff09\u9897\u7c92\uff08&lt;d&gt; ~ 1-5 \u03bcm\uff09\u8bf1\u5bfc\u6781\u5316\u6210\u538b\u7535\u9a7b\u6781\u4f53\u7684\u65b9\u6cd5\u3002\u6301\u7eed\u7684\u8d85\u58f0\u7167\u5c04PTFE\u9a7b\u6781\u4f53\u4ea7\u751fROS\uff0c\u5305\u62ec\u7f9f\u57fa\u81ea\u7531\u57fa(\u2022OH)\u3001\u8d85\u6c27\u5316\u7269(\u2022O<sup>2\u2212<\/sup>)\u548c\u5355\u7ebf\u6001\u6c27(<sup>1<\/sup>O<sub>2<\/sub>)\uff0c\u5176\u901f\u7387\u660e\u663e\u5feb\u4e8e\u5148\u524d\u62a5\u9053\u7684\u538b\u7535\u50ac\u5316\u5242\u3002\u5206\u522b\u5229\u7528\u538b\u7535\u54cd\u5e94\u529b\u663e\u5fae\u955c(PFM)\u548c\u7535\u5b50\u81ea\u65cb\u5171\u632f(ESR)\u7814\u7a76\u4e86\u60f0\u6027PTFE\u7684\u8d85\u58f0\u6d3b\u5316\u548cPTFE\u9a7b\u6781\u4f53\u538b\u7535\u50ac\u5316\u751f\u6210ROS\u7684\u57fa\u672c\u673a\u7406\u3002\u8ba8\u8bba\u4e86\u7a33\u5b9a\u7684PTFE\u538b\u7535\u50ac\u5316\u5242\u5728\u73af\u5883\u548c\u751f\u7269\u533b\u5b66\u65b9\u9762\u7684\u6f5c\u5728\u5e94\u7528\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a<strong><b>\u201cUltrasonic activation of inert poly(tetrafluoroethylene) enables piezocatalytic generation of reactive oxygen species\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86<strong><b>Nat. Commun.<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1 \u8d85\u58f0\u8f90\u7167\u4e0bPTFE\u538b\u7535\u50ac\u5316\u751f\u6210ROS\u7684\u793a\u610f\u56fe<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223342\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1.webp_-7.jpg\" alt=\"\" width=\"600\" height=\"460\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1.webp_-7.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/1.webp_-7-300x230.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5728\u8d85\u58f0\u8f90\u7167\u4e0b\uff0c\u521d\u59cbPTFE\u88ab\u6fc0\u6d3b\u6210\u4e3a\u6c38\u4e45\u6781\u5316\u7684\u538b\u7535PTFE\u9a7b\u6781\u4f53\u3002\u7136\u540e\u5c06\u5468\u56f4\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u8377\u5438\u9644\u5728PTFE\u8868\u9762\u3002\u968f\u540e\uff0c\uff0c\u5438\u9644\u7684\u7535\u8377\u5728\u538b\u7f29\u5e94\u529b\u4e0b\u4f5c\u4e3a\u81ea\u7531\u7535\u8377\u91ca\u653e\u51fa\u6765\uff0c\u4e0e\u6c34\u5206\u5b50\u6216\u6c27\u6c14\u76f8\u4e92\u4f5c\u7528\uff0c\u4ea7\u751f\u5747\u76f8ROS\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2 PTFE\u548cPTFE\u9a7b\u6781\u4f53\u7684\u538b\u7535\u54cd\u5e94\u529b\u663e\u5fae\u955c<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-223343\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/2.webp_-7.jpg\" alt=\"\" width=\"600\" height=\"380\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/2.webp_-7.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/06\/2.webp_-7-300x190.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a,b\uff09\u4e0d\u540c\u5904\u7406\u540e\u7684PTFE\u819c\u7684\uff08a\uff09\u539f\u5b50\u529b\u663e\u5fae\u955c\u56fe\u50cf (AFM) \u548c\uff08b\uff09PFM\u76f8\u56fe\u50cf\u3002\u8d85\u58f0\uff1a\u4e00\u7247PTFE\u819c\u548c50 mL\u53bb\u79bb\u5b50\u6c34\u8d85\u58f0\u7167\u5c041 h\u3002\u62c9\u4f38\uff1a\u7528\u624b\u62c9\u4f38\u4e00\u5757PTFE\u819c\u3002\u538b\u5b9e\uff1a\u5c06PTFE\u819c\u7247\u5728\u538b\u7247\u673a\u4e0a\u538b\u5b9e\uff0c\u538b\u529b\u4e3a25 Mpa\uff0c\u538b\u5b9e5min\u3002\u7535\u573a\uff1a\u5c06PTFE\u819c\u7247\u5728\u5e73\u884c\u7535\u573a(\u7ea6134 kV\/m)\u4e2d\u6781\u53162 h\u3002\u6bd4\u4f8b\u5c3a\uff1a4 \u03bcm\u3002<\/p>\n<p>c\uff09\u5728PTFE\uff08\u989c\u8272\u6761\u8303\u56f4\u4e3a-300\u2013500 pm\uff09\u4e0ePVDF\uff08\u989c\u8272\u6761\u8303\u56f4\u4e3a-15\u201325 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