{"id":221796,"date":"2021-05-12T06:30:44","date_gmt":"2021-05-11T22:30:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=221796"},"modified":"2021-05-11T21:13:06","modified_gmt":"2021-05-11T13:13:06","slug":"%e4%bf%9e%e4%b9%a6%e5%ae%8f%e9%99%a2%e5%a3%abchem-soc-rev-%ef%bc%9a%e5%9f%ba%e4%ba%8e%e4%ba%9a%e7%a8%b3%e6%80%81%e9%87%91%e5%b1%9e%e7%a1%ab%e6%97%8f%e5%8c%96%e5%90%88%e7%89%a9%e7%ba%b3%e7%b1%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=221796","title":{"rendered":"\u4fde\u4e66\u5b8f\u9662\u58ebChem. Soc. Rev.\uff1a\u57fa\u4e8e\u4e9a\u7a33\u6001\u91d1\u5c5e\u786b\u65cf\u5316\u5408\u7269\u7eb3\u7c73\u7ed3\u6784\u7684\u201c\u8f6f\u5316\u5b66\u201d\u8c03\u63a7"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221901\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/1-2.png\" alt=\"\" width=\"600\" height=\"222\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/1-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/1-2-300x111.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u5f15\u8a00 <\/strong><\/p>\n<p>\u7eb3\u7c73\u6750\u6599\u7684\u5408\u7406\u8bbe\u8ba1\u548c\u53ef\u63a7\u5408\u6210\u4fc3\u8fdb\u4e86\u7eb3\u7c73\u5408\u6210\u65b9\u6cd5\u5b66\u7684\u53d1\u5c55\uff0c\u5e76\u4e3a\u8fdb\u4e00\u6b65\u7814\u7a76\u7eb3\u7c73\u6750\u6599\u7ed3\u6784-\u6027\u8d28-\u529f\u80fd\u7684\u5173\u7cfb\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u8fd1\u5341\u51e0\u5e74\u6765\uff0c\u5728\u591a\u7ec4\u5206\u548c\u5f02\u8d28\u7ed3\u6784\u3001\u4e00\u7ef4\u548c\u4e8c\u7ef4\u6750\u6599\u3001\u7a7a\u5fc3\u7ed3\u6784\u3001\u8d85\u7ec6\/\u8d85\u8584\u6676\u4f53\u548c\u7269\u76f8\u53ef\u63a7\u7ed3\u6784\u7b49\u5404\u79cd\u7eb3\u7c73\u6750\u6599\u7684\u5408\u6210\u65b9\u9762\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\u3002\u8fd9\u4e5f\u5438\u5f15\u4e86\u66f4\u591a\u7684\u7814\u7a76\u4eba\u5458\u81f4\u529b\u4e8e\u7eb3\u7c73\u5408\u6210\u7684\u521b\u65b0\uff0c\u901a\u8fc7\u6709\u76ee\u7684\u5730\u201c\u64cd\u7eb5\u201d\u7eb3\u7c73\u5408\u6210\u4e2d\u7684\u201c\u5fae\u5999\u5316\u5b66\u201d\u4ee5\u83b7\u5f97\u66f4\u590d\u6742\u7684\u7ed3\u6784\u548c\u66f4\u7cbe\u51c6\u7684\u529f\u80fd\u3002\u7814\u7a76\u70ed\u70b9\u96c6\u4e2d\u5728\u91c7\u7528\u53ef\u7f16\u7a0b\u7684\u65b9\u5f0f\uff0c\u901a\u8fc7\u8bbe\u8ba1\u5b9a\u5236\u7684\u53cd\u5e94\u6761\u4ef6\uff08\u5982\u5408\u9002\u7684\u524d\u9a71\u7269\u3001\u914d\u4f53\u548c\u6dfb\u52a0\u5242\u7b49\uff09\u6216\u975e\u4f20\u7edf\u7684\u8def\u5f84\uff08\u5982\u56e2\u7c07\u7684\u6210\u6838\u548c\u7ec4\u88c5\u7b49\uff09\u6765\u7cbe\u786e\u5236\u5907\u5177\u6709\u6e05\u6670\u7279\u5f81\uff08\u5982\u7279\u5b9a\u5f62\u72b6\u3001\u7ec4\u5206\u3001\u7269\u76f8\u548c\u754c\u9762\u7b49\uff09\u7684\u7eb3\u7c73\u7ed3\u6784\u3002<\/p>\n<p>\u4e9a\u7a33\u6001\u91d1\u5c5e\u786b\u65cf\u5316\u5408\u7269\u7eb3\u7c73\u6750\u6599\uff08MCNs\uff09\u5177\u6709\u4e30\u5bcc\u7684\u7ec4\u5206\u548c\u6676\u76f8\uff0c\u53ef\u8c03\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u800c\u4e14\u6613\u4e8e\u53d1\u751f\u5404\u79cd\u5316\u5b66\u8f6c\u5316\uff0c\u8fd9\u4e3a\u6211\u4eec\u63a2\u7a76\u548c\u53d1\u5c55\u7eb3\u7c73\u5c3a\u5ea6\u7684\u7269\u7406\u5316\u5b66\u8c03\u63a7\u7b56\u7565\u63d0\u4f9b\u4e86\u5d2d\u65b0\u7684\u89c6\u89d2\u548c\u5e7f\u9614\u7684\u5e73\u53f0\u3002\u201c\u8f6f\u5316\u5b66\u201d\u8c03\u63a7\u6307\u7684\u662f\u5728\u4e0d\u5b8c\u5168\u7834\u574f\u539f\u6709\u7279\u5f81\u7684\u524d\u63d0\u4e0b\uff0c\u5b9e\u73b0\u53ef\u63a7\u7684\u8f6c\u5316\u6216\u57fa\u4e8e\u6b64\u6784\u7b51\u66f4\u9ad8\u7ea7\u7684\u7ed3\u6784\u3002\u201c\u8f6f\u5316\u5b66\u53cd\u5e94\u201d\u901a\u5e38\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u800c\u4e14\u53ef\u4ee5\u8f83\u5bb9\u6613\u5730\u63a7\u5236\u53cd\u5e94\u6b65\u9aa4\uff0c\u56e0\u800c\u6613\u4e8e\u5b9e\u73b0\u5bf9\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u3001\u8def\u5f84\u548c\u673a\u7406\u7684\u63a7\u5236\uff0c\u4ece\u800c\u53ef\u4ee5\u6839\u636e\u9700\u8981\u63a7\u5236\u53cd\u5e94\u53c2\u6570\uff0c\u5bf9\u4ea7\u7269\u7684\u7ec4\u5206\u548c\u7ed3\u6784\u8fdb\u884c\u8bbe\u8ba1\uff0c\u8fdb\u800c\u8fbe\u5230\u201c\u88c1\u526a\u201d\u5176\u7269\u7406\u5316\u5b66\u6027\u8d28\u7684\u76ee\u7684\u3002<\/p>\n<p><strong>\u6210\u679c\u7b80\u4ecb <\/strong><\/p>\n<p>\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c<strong>\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u4fde\u4e66\u5b8f\u9662\u58eb\u8bfe\u9898\u7ec4<\/strong>\u4ecb\u7ecd\u4e86\u57fa\u4e8eMCNs\u7684\u4e9a\u7a33\u7279\u6027\u5bf9\u7eb3\u7c73\u6750\u6599\u7684\u7ed3\u6784\u548c\u529f\u80fd\u8fdb\u884c\u8c03\u63a7\uff0c\u63d0\u51fa\u4e86\u5229\u7528\u8f6f\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u548c\u4fee\u9970\u4e9a\u7a33\u6001MCNs\u7684\u8bbe\u8ba1\u539f\u5219\u548c\u8f6c\u5316\u89c4\u5f8b\u3002\u9996\u5148\uff0c\u4f5c\u8005\u7b80\u8981\u8ba8\u8bba\u4e86MCNs\u4e9a\u7a33\u7279\u6027\u7684\u5177\u4f53\u8868\u73b0\u5f62\u5f0f\uff0c\u5982\u79bb\u5b50\u7684\u8fc1\u79fb\u548c\u7a7a\u4f4d\u3001\u70ed\u4e0d\u7a33\u5b9a\u6027\u548c\u7ed3\u6784\u4e0d\u7a33\u5b9a\u6027\u3001\u5316\u5b66\u53cd\u5e94\u6d3b\u6027\u548c\u6676\u76f8\u8f6c\u53d8\u3002\u7136\u540e\uff0c\u9488\u5bf9MCNs\u4e0d\u540c\u7684\u4e9a\u7a33\u7279\u6027\uff0c\u8bbe\u8ba1\u4e86\u76f8\u5e94\u7684\u8f6f\u5316\u5b66\u53cd\u5e94\u8def\u5f84\uff0c\u5305\u62ec\u79bb\u5b50\u4ea4\u6362\u3001\u50ac\u5316\u751f\u957f\u3001\u5206\u79bb\u6216\u8026\u5408\u3001\u6a21\u677f\u5ac1\u63a5\u6216\u5316\u5b66\u8f6c\u5316\u4ee5\u53ca\u6676\u76f8\u7684\u7a33\u5b9a\u6216\u6784\u5efa\u3002\u968f\u540e\uff0c\u4f5c\u8005\u91cd\u70b9\u4ecb\u7ecd\u4e86\u5229\u7528\u4ee5\u4e0a\u8bbe\u8ba1\u539f\u5219\u548c\u8f6c\u5316\u89c4\u5f8b\u5bf9\u4e9a\u7a33\u6001MCNs\u8fdb\u884c\u5408\u6210\u3001\u4fee\u9970\u548c\u529f\u80fd\u5316\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u6700\u540e,\u5bf9\u57fa\u4e8eMCNs\u8f6f\u5316\u5b66\u8c03\u63a7\u7684\u672a\u6765\u53d1\u5c55\u8fdb\u884c\u4e86\u5c55\u671b\uff0c\u63d0\u4f9b\u4e86\u8fd9\u4e2a\u9886\u57df\u4e3b\u8981\u5b58\u5728\u7684\u6311\u6218\u53ca\u673a\u9047\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>Soft chemistry of metastable metal chalcogenide nanomaterials<\/strong>\u201d\u53d1\u8868\u5728<strong>Chem. Soc. Rev.<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u56fe\u6587\u5bfc\u8bfb <\/strong><\/p>\n<p><strong>\u56fe\u4e00\u3001\u51e0\u79cd\u5178\u578b\u7684\u57fa\u4e8e\u4e9a\u7a33\u6001<\/strong><strong>MCNs<\/strong><strong>\u8f6f\u5316\u5b66\u8c03\u63a7\u7684\u6848\u4f8b<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221797\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72471-4.png\" alt=\"\" width=\"600\" height=\"379\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72471-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72471-4-300x190.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) \u7ea4\u950c\u77ff\u578b\uff08WZ\uff09CdSe\u5230Cu<sub>2<\/sub>Se\u548cWZ-ZnSe\u9633\u79bb\u5b50\u4ea4\u6362\u8fc7\u7a0b\u4e2d\u7684Se\u6676\u683c\u4fdd\u6301\uff0c(b) \u4e94\u786b\u94dc\u77ff\u578bCu<sub>2-x<\/sub>S\u901a\u8fc7\u9633\u79bb\u5b50\u4ea4\u6362\u5411WZ-CoS\u548cMnS\u7684\u76f8\u9009\u62e9\u8f6c\u5316\uff0c(c) \u9ad8\u6e29\u4e0b\u9762\u5fc3\u7acb\u65b9\u03b2-Cu<sub>2<\/sub>Se\u6676\u4f53\u7ed3\u6784\u4e2dCu<sup>+<\/sup>\u79bb\u5b50\u5728[111]\u6676\u9762\u95f4\u7684\u8fc1\u79fb\uff0c(d) \u5ba4\u6e29\u4e0b\u5355\u659c\u03b1-Ag<sub>2<\/sub>S\u6676\u4f53\u7ed3\u6784\u4e2d\u6cbf[001]\u65b9\u5411\u6676\u9762\u95f4\u7684\u79fb\u52a8\uff0c(e) \u5355\u5c42MoS<sub>2<\/sub>\u4ece\u4e09\u65b9\u68f1\u67f1\u534a\u5bfc\u4f53\u76f8\uff082H\uff09\u5411\u516b\u9762\u4f53\u91d1\u5c5e\u76f8\uff081T\uff09\u7684\u6676\u76f8\u8f6c\u53d8\u3002<\/p>\n<p><strong>\u56fe\u4e8c\u3001\u5408\u6210\u548c\u4fee\u9970\u4e9a\u7a33\u6001<\/strong><strong>MCNs<\/strong><strong>\u7684\u8f6f\u5316\u5b66\u53cd\u5e94\u5de5\u5177\u7bb1<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221798\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72472-1.png\" alt=\"\" width=\"600\" height=\"641\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72472-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72472-1-281x300.png 281w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong>\u57fa\u4e8e\u79bb\u5b50\u8fc1\u79fb\u548c\u7a7a\u4f4d\u7684\u8f6f\u5316\u5b66\u8c03\u63a7<\/strong><\/p>\n<p><strong>\u56fe\u4e09\u3001\u6846\u67b6\u8c03\u63a7\uff1a\u5185\u90e8\u201c\u88c1\u526a\u201d\uff08\u7ec4\u5206\u548c\u754c\u9762\u7b49\uff09<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221799\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72473-1.png\" alt=\"\" width=\"600\" height=\"429\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72473-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72473-1-300x215.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) \u7b2c\u4e00\u4ee3Cu<sub>1.8<\/sub>S\u7eb3\u7c73\u9897\u7c92\u5411\u7b2c\u4e8c\u4ee3CdS\/ZnS-Cu<sub>1.8<\/sub>S\u548c\u7b2c\u4e09\u4ee3CdS\/ZnS-CoS\/MnS\/Ni<sub>9<\/sub>S<sub>8<\/sub>\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u8f6c\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u548cSTEM-EDS\u5143\u7d20\u5206\u5e03\u56fe\uff0c(b) \u7b2c\u4e00\u4ee3Cu<sub>1.8<\/sub>S\u7eb3\u7c73\u68d2\u5411\u7b2c\u516d\u4ee3ZnS-CuInS<sub>2<\/sub>-CuGaS<sub>2<\/sub>-CoS-(CdS-Cu<sub>1.8<\/sub>S)\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u8f6c\u5316\u8fc7\u7a0b\u7684STEM-EDS\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n<p><strong>\u56fe\u56db\u3001\u6846\u67b6\u8c03\u63a7\uff1a\u5916\u90e8\u91cd\u6784\uff08\u5c3a\u5bf8\u548c\u5f62\u72b6\u7b49\uff09<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221800\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72474-1.png\" alt=\"\" width=\"600\" height=\"469\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72474-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72474-1-300x235.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) Cu<sub>1.94<\/sub>S\u7eb3\u7c73\u9897\u7c92\u5230\u87ba\u6746\u578b\u3001\u54d1\u94c3\u578b\u548c\u4e09\u660e\u6cbb\u578bCu<sub>1.94<\/sub>S-ZnS\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u8f6c\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff0c(b) Cu<sub>1.94<\/sub>S\u7eb3\u7c73\u9897\u7c92\u5230\u81ea\u8026\u5408\u54d1\u94c3\u72b6Cu<sub>1.94<\/sub>S-CuS\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u8f6c\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe\u4e94\u3001\u50ac\u5316\u751f\u957f\uff1a\u6676\u9762\u4f9d\u8d56\u548c\u201c\u6eb6\u6db2-\u56fa\u6eb6\u4f53-\u56fa\u76f8\u201d\uff08SSS\uff09\u673a\u7406<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221801\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72475-1.png\" alt=\"\" width=\"600\" height=\"446\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72475-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72475-1-300x223.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) Cu<sub>2-x<\/sub>Se\u7eb3\u7c73\u9897\u7c92\u5230\u5177\u6709CdSe\u6838\u548cCdS\u624b\u81c2\u7684\u516b\u8db3\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684\u9633\u79bb\u5b50\u4ea4\u6362\u548c\u6676\u9762\u4f9d\u8d56\u751f\u957f\u8fc7\u7a0b\u793a\u610f\u56fe\u548cHRTEM\u56fe\u50cf\uff0c(b) \u8d85\u79bb\u5b50\u5bfc\u4f53Ag<sub>2<\/sub>Se\u7eb3\u7c73\u9897\u7c92\u50ac\u5316ZnSe\u7eb3\u7c73\u7ebf\u751f\u957f\u8fc7\u7a0b\u7684SSS\u673a\u7406\u793a\u610f\u56fe\u3001HRTEM\u56fe\u50cf\u548cAg<sub>2<\/sub>Se\u7684\u5085\u91cc\u53f6\u8f6c\u6362\uff08FFT\uff09\u82b1\u6837\u3002<\/p>\n<p><strong>\u57fa\u4e8e\u70ed\u4e0d\u7a33\u5b9a\u6027\u548c\u7ed3\u6784\u4e0d\u7a33\u5b9a\u6027\u7684\u8f6f\u5316\u5b66\u8c03\u63a7<\/strong><\/p>\n<p><strong>\u56fe\u516d\u3001\u7c92\u5b50\u5185\u5206\u79bb\uff08\u7ec4\u5206\u548c\u7269\u76f8\u7b49\uff09<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221802\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72476-1.png\" alt=\"\" width=\"600\" height=\"605\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72476-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72476-1-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72476-1-298x300.png 298w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) AgFeS<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\u5230Ag<sub>2<\/sub>S-Fe<sub>7<\/sub>S<sub>8<\/sub>\u4e8c\u805a\u4f53\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u5206\u79bb\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3001TEM\u56fe\u50cf\u548cHAADF-STEM\u56fe\u50cf\uff0c(b) Ag<sub>8<\/sub>GeS<sub>6<\/sub>\u7eb3\u7c73\u9897\u7c92\u5230Ag-Ag<sub>8<\/sub>GeS<sub>6<\/sub>\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684Ag\u5411\u5185\u6269\u6563\u548c\u5411\u5916\u6790\u51fa\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3001TEM\u56fe\u50cf\u53caHAADF-STEM\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe\u4e03\u3001\u7c92\u5b50\u95f4\u8026\u5408<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221803\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72477-1.png\" alt=\"\" width=\"600\" height=\"666\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72477-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72477-1-270x300.png 270w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72478-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u72478-1-300x201.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) \u9009\u62e9\u6027\u4fee\u9970\u7684\u4e8c\u7ef4CuS\u7eb3\u7c73\u7247\u5408\u6210\u7684A\u578b\u3001B\u578b\u548cC\u578b\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff0c(b) \u4e00\u7ef4Cu<sub>2-x<\/sub>S\u7eb3\u7c73\u7ebf\u5408\u6210\u7684MoSe<sub>2<\/sub>-Cu<sub>2-x<\/sub>S\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684HAADF-STEM\u3001HRTEM\u56fe\u50cf\u548c\u539f\u5b50\u7ed3\u6784\u6a21\u578b\uff0c(c) 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724710-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724710-1-300x296.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) Sb<sub>2<\/sub>Te<sub>3<\/sub>\u5230\u591a\u5b54\u7f51\u72b6Te\u7eb3\u7c73\u677f\u7684\u9152\u77f3\u9178\u8f85\u52a9\u6c27\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u548cSEM\u56fe\u50cf\uff0c(b) ZnSe(DETA)<sub>0.5<\/sub>\u5c42\u72b6\u6709\u673a-\u65e0\u673a\u6742\u5316\u7269\u5230\u591a\u5b54Se\u7eb3\u7c73\u7247\u7684\u9178\u5316\u8f85\u52a9\u6c27\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u3001SEM\u548cTEM\u56fe\u50cf\u3002<\/p>\n<p><strong>\u57fa\u4e8e\u6676\u76f8\u5de5\u7a0b\uff08\u76f8\u53d8\u548c\u6784\u7b51\u4e0d\u540c\u6676\u76f8\u5f02\u8d28\u754c\u9762\uff09\u7684\u8f6f\u5316\u5b66\u8c03\u63a7<\/strong><\/p>\n<p><strong>\u56fe\u5341\u4e00\u3001<\/strong><strong>II\u2013VI<\/strong><strong>\u65cf\u534a\u5bfc\u4f53\u786b\u65cf\u5316\u5408\u7269<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221807\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724711-1.png\" alt=\"\" width=\"600\" height=\"685\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724711-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724711-1-263x300.png 263w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) \u52a0\u70ed\u5f15\u53d1Mn<sup>2+<\/sup>\u79bb\u5b50\u63d2\u5165\/\u6790\u51fa\u8bf1\u5bfcZnS\u7eb3\u7c73\u7247\u5728WZ\u548c\u95ea\u950c\u77ff\u578b\uff08ZB\uff09\u95f4\u7684\u53ef\u9006\u76f8\u53d8\u8fc7\u7a0b\u793a\u610f\u56fe\u548cHRTEM\u56fe\u50cf\uff0c(b) OH\u207b\u548c\u4e59\u4e8c\u80fa\u4f5c\u7528\u4e0b\u6c34\u70ed\u5408\u6210\u7684\u4e00\u7ef4\u5b6a\u6676WZ\/ZB-Cd<sub>0.5<\/sub>Zn<sub>0.5<\/sub>S\u540c\u8d28\u7ed3\u76843D\u7ed3\u6784\u3001TEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe\u5341\u4e8c\u3001\u9ec4\u94c1\u77ff\u578b\u8fc7\u6e21\u91d1\u5c5e\u786b\u65cf\u5316\u5408\u7269<\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221808\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724712-1.png\" alt=\"\" width=\"600\" height=\"716\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724712-1.png 600w, 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724713-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/05\/\u56fe\u724713-1-300x273.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>(a) \u94f5\u79bb\u5b50\u63d2\u5165\u5408\u62101T\u2019 WS<sub>2<\/sub>\u7eb3\u7c73\u5e26\u7684SEM\u3001HAADF-STEM\u56fe\u50cf\u548c\u539f\u5b50\u7ed3\u6784\u6a21\u578b\uff0c(b) \u7f13\u6162\u786b\u5316\u5408\u6210\u6df7\u5408\u76f8WO<sub>2.9<\/sub>-(2H\/1T\u2019) WS<sub>2<\/sub>\u5f02\u8d28\u7eb3\u7c73\u7ed3\u6784\u7684HAADF-STEM\u56fe\u50cf\u548cFFT\u82b1\u6837\u3002<\/p>\n<p><strong>\u5c0f\u7ed3 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