{"id":221508,"date":"2021-05-08T06:49:32","date_gmt":"2021-05-07T22:49:32","guid":{"rendered":"\/\/m.iemloyee.com\/?p=221508"},"modified":"2021-05-07T20:49:45","modified_gmt":"2021-05-07T12:49:45","slug":"%e9%a6%99%e6%b8%af%e5%9f%8e%e5%b8%82%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%8d%8echem-rev-%e7%94%b1%e5%a4%9a%e5%b0%ba%e5%ba%a6%e5%9f%ba%e5%85%83%e6%9e%84%e5%bb%ba%e7%9a%84%e9%9d%9e%e5%b8%b8%e8%a7%84%e7%9b%b8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=221508","title":{"rendered":"\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5f20\u534eChem. Rev.:\u7531\u591a\u5c3a\u5ea6\u57fa\u5143\u6784\u5efa\u7684\u975e\u5e38\u89c4\u76f8\u6676\u4f53\u6750\u6599"},"content":{"rendered":"
\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n \u6676\u76f8\u662f\u6307\u6676\u4f53\u6750\u6599\u4e2d\u539f\u5b50\uff0c\u79bb\u5b50\u6216\u5206\u5b50\u7684\u5468\u671f\u6027\u6392\u5217\u3002\u5177\u6709\u76f8\u540c\u5316\u5b66\u7ec4\u6210\u4f46\u4e0d\u540c\u6676\u76f8\u7684\u6750\u6599\u53ef\u80fd\u8868\u73b0\u51fa\u660e\u663e\u4e0d\u540c\u7684\u7406\u5316\u7279\u6027\uff0c\u4f8b\u5982\u786c\u91d1\u521a\u77f3\u4e0e\u8f6f\u77f3\u58a8\uff0c\u534a\u5bfc\u75352H-MoS2<\/sub>\u4e0e\u534a\u91d1\u5c5e1T’-MoS2<\/sub>\u3002\u5728\u6700\u8fd1\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u7eb3\u7c73\u79d1\u5b66\u548c\u7eb3\u7c73\u6280\u672f\u7684\u5feb\u901f\u53d1\u5c55\u4fc3\u8fdb\u4e86\u7eb3\u7c73\u7ea7\u591a\u6676\u76f8\u6750\u6599\u7684\u5408\u6210\u548c\u6027\u8d28\u7814\u7a76\u3002\u5f97\u76ca\u4e8e\u7eb3\u7c73\u6750\u6599\u7684\u8d85\u5c0f\u5c3a\u5bf8\u548c\u9ad8\u8868\u9762\u80fd\uff0c\u5177\u6709\u4e0d\u540c\u6676\u76f8\u7684\u7eb3\u7c73\u6750\u6599\u53ef\u901a\u8fc7\u7b80\u4fbf\u7684\u65b9\u6cd5\u5408\u6210\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5728\u7eb3\u7c73\u6750\u6599\u4e2d\u53ef\u4ee5\u5b58\u5728\u4e0d\u540c\u4e8e\u5176\u70ed\u529b\u5b66\u7a33\u5b9a\u7684\u5757\u72b6\u5bf9\u5e94\u7269\u7684\u201c\u975e\u5e38\u89c4\u76f8\u201d\u3002\u4e0e\u5177\u6709\u5e38\u89c4\u76f8\u7684\u7eb3\u7c73\u6750\u6599\u76f8\u6bd4\uff0c\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u7eb3\u7c73\u6750\u6599\u663e\u793a\u51fa\u975e\u5e38\u6709\u8da3\u7684\u50ac\u5316\uff0c\u5149\u5b66\uff0c\u7535\u548c\u78c1\u6027\u80fd\uff0c\u8fd9\u8868\u660e\u7eb3\u7c73\u6750\u6599\u76f8\u5de5\u7a0b\uff08PEN\uff09\u5df2\u6210\u4e3a\u4e00\u79cd\u53ef\u8c03\u8282\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u7684\u7406\u5316\u6027\u8d28\u548c\u5e94\u7528\u7684\u6709\u524d\u9014\u7684\u624b\u6bb5\u3002<\/p>\n \u6b64\u5916\uff0c\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u53ef\u88ab\u770b\u4f5c\u662f\u7531\u539f\u5b50\u4e3a\u57fa\u5143\u6784\u5efa\u7684\u957f\u7a0b\u6709\u5e8f\u7684\u7ec4\u88c5\u7ed3\u6784\u3002\u9664\u4e86\u539f\u5b50\uff0c\u5177\u6709\u66f4\u5927\u5c3a\u5ea6\u7684\u5b9e\u4f53\uff08\u5305\u62ec\u7eb3\u7c73\u56e2\u7c07\uff0c\u7403\u5f62\u7eb3\u7c73\u7c92\u5b50\uff0c\u5404\u5411\u5f02\u6027\u7eb3\u7c73\u7c92\u5b50\u548c\u5fae\u7c92\uff09\u4e5f\u53ef\u88ab\u7528\u4f5c\u57fa\u5143\uff0c\u901a\u8fc7\u81ea\u7ec4\u88c5\u6784\u5efa\u8d85\u6676\u6750\u6599\u3002\u4e0d\u540c\u4e8e\u7eb3\u7c73\u6676\u4f53\u6750\u6599\uff0c\u5728\u6784\u5efa\u8d85\u6676\u6750\u6599\u65f6\uff0c\u57fa\u5143\u7684\u5c3a\u5bf8\u3001\u5f62\u72b6\u3001\u8868\u9762\u7279\u6027\uff0c\u4ee5\u53ca\u57fa\u5143\u4e0e\u57fa\u5143\u3001\u57fa\u5143\u4e0e\u6eb6\u5242\u3001\u57fa\u5143\u4e0e\u57fa\u5e95\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u529b\u7b49\u90fd\u662f\u53ef\u8c03\u63a7\u7684\u3002\u7531\u4e8e\u7ec4\u88c5\u8fc7\u7a0b\u7684\u53ef\u63a7\u6027\u4e0e\u590d\u6742\u6027\uff0c\u8d85\u6676\u6750\u6599\u7684\u7ed3\u6784\u66f4\u52a0\u4e30\u5bcc\u3002\u9664\u4e86\u5bc6\u5806\u79ef\u7ed3\u6784\uff0c\u975e\u5bc6\u5806\u79ef\u7ed3\u6784\u3001\u5bf9\u79f0\u6027\u8f83\u4f4e\u7684\u6676\u4f53\u7ed3\u6784\u3001\u4ee5\u53ca\u5728\u539f\u5b50\u548c\u5206\u5b50\u6676\u4f53\u4e2d\u6ca1\u6709\u7c7b\u4f3c\u7269\u7684\u7ed3\u6784\u90fd\u53ef\u80fd\u5b58\u5728\u4e8e\u8d85\u6676\u6750\u6599\u4e2d\u3002\u8fd9\u4e9b\u5177\u6709\u76f8\u540c\u7ec4\u5206\u4f46\u4e0d\u540c\u6676\u76f8\u7684\u8d85\u6676\u6750\u6599\u4e5f\u53ef\u80fd\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u7406\u5316\u7279\u6027\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n \u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u5f20\u534e\u8bfe\u9898\u7ec4<\/b><\/strong>\u4ecb\u7ecd\u4e86\u4ece\u591a\u5c3a\u5ea6\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u548c\u8d85\u6676\u6750\u6599\u7684\u8fc7\u7a0b\uff0c\u8fd9\u4e9b\u57fa\u5143\u5305\u62ec\u539f\u5b50\uff0c\u7eb3\u7c73\u56e2\u7c07\uff0c\u7403\u5f62\u7eb3\u7c73\u9897\u7c92\uff0c\u5404\u5411\u5f02\u6027\u7eb3\u7c73\u9897\u7c92\u548c\u5fae\u7c92\u3002\u9996\u5148\uff0c\u4f5c\u8005\u7b80\u8981\u8ba8\u8bba\u4e86\u4e0e\u591a\u5c3a\u5ea6\u81ea\u7ec4\u88c5\u76f8\u5173\u7684\u4e00\u4e9b\u57fa\u7840\u77e5\u8bc6\u3002\u7136\u540e\uff0c\u9488\u5bf9\u4e0d\u540c\u5c3a\u5ea6\u7684\u57fa\u5143\uff0c\u8be6\u7ec6\u603b\u7ed3\u4e86\u5177\u6709\u91cc\u7a0b\u7891\u610f\u4e49\u7684\u53d1\u73b0\uff0c\u91cd\u70b9\u4ecb\u7ecd\u4e86\u5b9e\u73b0\u53ef\u63a7\u7ec4\u88c5\u7684\u7b56\u7565\u4ee5\u53ca\u7528\u4e8e\u83b7\u5f97\u975e\u5e38\u89c4\u76f8\u7684\u91cd\u8981\u53c2\u6570\u3002\u968f\u540e\uff0c\u9488\u5bf9\u4e0d\u540c\u5c3a\u5ea6\u7684\u57fa\u5143\uff0c\u4f5c\u8005\u603b\u7ed3\u4e86\u7eb3\u7c73\u6676\u4f53\u6750\u6599\u548c\u8d85\u6676\u6750\u6599\u7684\u7406\u5316\u6027\u8d28\u548c\u5e94\u7528\u7684\u6676\u76f8\u4f9d\u8d56\u6027\u3002\u6700\u540e\uff0c\u63d0\u4f9b\u4e86\u8fd9\u4e2a\u9886\u57df\u5b58\u5728\u7684\u4e3b\u8981\u6311\u6218\u53ca\u673a\u9047\uff0c\u4ee5\u53ca\u5bf9\u672a\u6765\u7814\u7a76\u65b9\u5411\u7684\u4e2a\u4eba\u89c1\u89e3\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<\/strong>Unconventional-Phase Crystalline Materials Constructed from Multiscale Building Blocks<\/strong>\u201d<\/strong>\u53d1\u8868\u5728Chem. Rev.<\/b><\/strong>\u4e0a<\/strong>\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n Fig<\/b><\/strong>u<\/strong>re 1.<\/b><\/strong>\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u7eb3\u7c73\u6676\u548c\u8d85\u6676\u6750\u6599\u7684\u5178\u578b\u793a\u4f8b\uff0c\u5b83\u4eec\u662f\u7531\u591a\u5c3a\u5ea6<\/b><\/strong>\u57fa\u5143<\/b><\/strong>\u7ec4\u88c5\u800c\u6210\u7684\uff0c<\/b><\/strong>\u8fd9\u4e9b\u57fa\u5143<\/b><\/strong>\u5305\u62ec\u539f\u5b50\uff0c\u7eb3\u7c73\u56e2\u7c07\uff0c\u7403\u5f62\u7eb3\u7c73\u9897\u7c92\uff0c\u5404\u5411\u5f02\u6027\u7eb3\u7c73\u9897\u7c92\u548c\u5fae\u7c92<\/b><\/strong><\/p>\n \u591a\u5c3a\u5ea6\u81ea\u7ec4\u88c5\u76f8\u5173\u7684\u57fa\u7840\u77e5\u8bc6\uff1a<\/p>\n Figure 2.<\/b><\/strong>\u7c92\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528<\/b><\/strong>\u529b\uff08\u5438\u5f15\u529b\u548c\u6392\u65a5\u529b\uff09<\/b><\/strong>\u7684\u793a\u610f\u56fe<\/b><\/strong><\/p>\n \u4ee5\u539f\u5b50\u4e3a\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u7eb3\u7c73\u6676\uff1a<\/p>\n Figure 3.<\/b><\/strong>\u91d1\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684hcp\u76f8<\/b><\/strong><\/p>\n \uff08a-b\uff09\u8d85\u85842H\u76f8\u91d1\u7247\u7684TEM\u548cHRTEM\u56fe\u50cf \uff08c-d\uff09\u8d85\u85844H\u76f8\u91d1\u5e26\u7684TEM\u548cHRTEM\u56fe\u50cf \uff08e-f\uff09\u5178\u578b\u7684\u9510\u89d24H\u76f8\u5b6a\u6676\u91d1\u7eb3\u7c73\u98ce\u7b5d\u7684TEM\u548cHRTEM\u56fe\u50cf \uff08g-h\uff09\u5178\u578b\u7684\u949d\u89d24H\u76f8\u5b6a\u6676\u91d1\u7eb3\u7c73\u98ce\u7b5d\u7684TEM\u548cHRTEM\u56fe\u50cf<\/p>\n Figure 4.<\/b><\/strong>\u91d1\u57fa\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684hcp\u76f8\u548c\u76f8\u53d8<\/b><\/strong><\/p>\n \uff08a\uff09\u793a\u610f\u56fe\u663e\u793aRu\u7eb3\u7c73\u68d2\u57284H\/fcc Au\u7eb3\u7c73\u7ebf\u76844H\u76f8\u548cfcc\u5b6a\u6676\u754c\u4e0a\u7684\u9009\u62e9\u6027\u751f\u957f\uff08\u5de6\u56fe\uff09\u548c\u5178\u578bAu-Ru\u7eb3\u7c73\u7ebf\u7684\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08STEM\uff09\u56fe\u50cf\uff08\u53f3\u56fe\uff09<\/p>\n \uff08b\uff09\u793a\u610f\u56fe\u663e\u793a\u4e86Rh\u7eb3\u7c73\u68d2\u5728Au-Ru\u7eb3\u7c73\u7ebf\u4e0a\u7684\u9009\u62e9\u6027\u751f\u957f\uff08\u5de6\u56fe\uff09\u548c\u5178\u578b\u7684Au-Ru-Rh\u7eb3\u7c73\u7ebf\u7684STEM\u56fe\u50cf\uff08\u53f3\u56fe\uff09<\/p>\n \uff08c-d\uff09TEM\u56fe\u663e\u793a\u4e86\u5355\u6676fcc Au\u7eb3\u7c73\u9897\u7c92\u54114H\u76f8\u7684\u76f8\u53d8<\/p>\n \uff08e-f\uff09TEM\u56fe\u50cf\u663e\u793a\u4e864H\u76f8\u7eb3\u7c73\u57df\u5230fcc\u76f8\u7684\u90e8\u5206\u76f8\u53d8<\/p>\n Figure 5.Rh\u548cPd\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684hcp\u76f8<\/b><\/strong><\/p>\n \uff08a-b\uff09\u901a\u8fc7\u7535\u5b50\u675f\u8bf1\u5bfc\u7684Rh\u5355\u5c42\u5206\u89e3\u548c\u6eb6\u5242\u70ed\u5408\u6210\u5236\u5907\u7684hcp Rh\u7eb3\u7c73\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff08c\uff09\u4ece\u65e0\u5b9a\u5f62\u7684Pd\u7eb3\u7c73\u7c92\u5b50\u4e2d\u9009\u62e9\u6027\u5408\u6210\u5177\u67092H\u6216fcc\u76f8\u7684Pd\u7eb3\u7c73\u7c92\u5b50\uff0c\u4ee5\u53ca\u57282H-Pd\u7eb3\u7c73\u7c92\u5b50\u4e0a\u8fdb\u884cAu\uff0cAg\u548cPt\u7684\u76f8\u9009\u62e9\u6027\u5916\u5ef6\u751f\u957f\u7684\u793a\u610f\u56fe\uff08d\uff09fcc-2H-fcc\u5f02\u76f8Pd@Au\u6838-\u58f3\u7eb3\u7c73\u68d2\u7684\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08HAADF-STEM\uff09\u56fe\u50cf<\/p>\n Figure 6.\u8d35\u91d1\u5c5e\u57fa\u5408\u91d1\u7eb3\u7c73\u6750\u6599\u4e2d\u7684hcp\u76f8<\/b><\/strong><\/p>\n \uff08a-b\uff09\u5178\u578b\u83b2\u84ec\u5f62hcp\/fcc\u5f02\u76f8Pt-Ni\u5408\u91d1\u8d85\u7ed3\u6784\u7684STEM\u548c\u539f\u5b50\u5206\u8fa8\u7387HAADF-STEM\u56fe\u50cf\uff08c-d\uff09\u5178\u578b\u7684fcc AuRu3<\/sub>\u7eb3\u7c73\u7ed3\u6784\u7684STEM\u548c\u539f\u5b50\u5206\u8fa8\u7387HAADF-STEM\u56fe\u50cf\uff08e-f\uff09\u5178\u578b\u7684hcp AuRu3<\/sub>\u7eb3\u7c73\u7ed3\u6784\u7684STEM\u548c\u539f\u5b50\u5206\u8fa8\u7387HAADF-STEM\u56fe\u50cf<\/p>\n Figure 7.Ru\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684fcc\u76f8<\/b><\/strong><\/p>\n \uff08a-b\uff09\u901a\u8fc7\u591a\u5143\u9187\u6cd5\u5408\u6210\u7684\u5177\u6709fcc\u76f8\u548chcp\u76f8\u7684Ru\u7eb3\u7c73\u9897\u7c92\u7684HRTEM\u56fe\u50cf\uff08c\uff09fcc Ru\u7eb3\u7c73\u6846\u67b6\u7684TEM\u56fe\u50cf\uff08d\uff09fcc Ru\u7acb\u65b9\u7eb3\u7c73\u7b3c\u7684TEM\u56fe\u50cf\uff08e\uff09\u793a\u610f\u56fe\u5206\u522b\u663e\u793a\u4e86fcc\u548chcp Ru\u58f3\u5728Pd-Cu\u5408\u91d1\u6a21\u677f\u4e0a\u7684\u5916\u5ef6\u751f\u957f\u548c\u975e\u5916\u5ef6\u751f\u957f\uff08f-g\uff09\u5728Pd-Cu\u5408\u91d1\u6a21\u677f\u4e0a\u5916\u5ef6\u751f\u957f\u7684fcc Ru\u58f3\u7684TEM\u548cHRTEM\u56fe\u50cf<\/p>\n Figure 8.\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684bct\/bco\u76f8<\/b><\/strong><\/p>\n \uff08a\uff09\u5177\u6709bct\u76f8\u7684\u4e94\u6b21\u5b6a\u6676\u7684Ag\u7eb3\u7c73\u7ebf\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u56fe\u50cf \uff08b\uff09\u5177\u6709\u4e94\u6b21\u5b6a\u6676\u7684Ag\u7eb3\u7c73\u7ebf\u7684\u793a\u610f\u56fe\uff08c\uff09\u94f6\u7eb3\u7c73\u7ebf\u7684XRD\u56fe\u6848\uff08d-e\uff09\u5177\u6709fcc\uff0cbct\u548cbco\u76f8\u5171\u5b58\u7684\u4e94\u6b21\u5b6a\u6676\u7684\u53cc\u9525\u4f53Au\u5fae\u6676\u7684SEM\u56fe\u50cf\uff08f\uff09\u5728\u4e0d\u540c\u7684\u70ed\u89e3\u6e29\u5ea6\u4e0b\u5236\u5907\u7684\u91d1\u5fae\u6676\u7684XRD\u56fe\u8c31<\/p>\n \u4ee5\u7eb3\u7c73\u56e2\u7c07\u4e3a\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u8d85\u6676\u6750\u6599\uff1a<\/p>\n Figure 9.\u914d\u4f53\u5bf9\u7eb3\u7c73\u7c07\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \uff08a\uff09Au60<\/sub>S6<\/sub>\u548cAu60<\/sub>S7<\/sub>\u7eb3\u7c73\u56e2\u7c07\u7684\u7ed3\u6784\uff08b\uff09\u5206\u522b\u7531Au60<\/sub>S6<\/sub>\u548cAu60<\/sub>S7<\/sub>\u7eb3\u7c73\u7c07\u7ec4\u88c5\u7684\u5177\u67096H\uff08\u5de6\u56fe\uff09\u548c\u4e09\u659c\u6676\uff08\u53f3\u56fe\uff09\u76f8\u7684\u8d85\u6676\u683c\uff08c\uff09\u7531Au92<\/sub>(TBBT)44<\/sub>\u7eb3\u7c73\u7c07\u7ec4\u88c5\u800c\u6210\u76844H\u76f8\u8d85\u6676\u683c<\/p>\n Figure 10.\u914d\u4f53\u5bf9\u7eb3\u7c73\u7c07\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \uff08a\uff09\u5206\u522b\u4ecez\uff08\u5de6\u56fe\uff09\uff0cy\uff08\u4e2d\u56fe\uff09\u548cx\uff08\u53f3\u56fe\uff09\u65b9\u5411\u89c2\u5bdf\u7684\u5355\u659c\u8d85\u6676\u683c\u4e2dAu246<\/sub>(p-MBT)80<\/sub>\u7eb3\u7c73\u7c07\u7684\u6676\u4f53\u6392\u5217 \uff08b\uff09\u7eb3\u7c73\u7c07\u4e4b\u95f4\u8868\u9762\u914d\u4f53\u7684\u76f8\u5e94\u6392\u5217 \uff08c\uff09Au\u6838\u6781\u70b9\u5904\u914d\u4f53\u7684\u65cb\u8f6c\u5806\u79ef\u7ed3\u6784\u53caAu\u6838\u8170\u90e8\u7684\u5e73\u884c\u5806\u79ef\u7ed3\u6784\u00a0\uff08d\uff09\u901a\u8fc7Au103<\/sub>S2<\/sub>(S-Nap)41<\/sub>\u7eb3\u7c73\u56e2\u7c07\u7684\u5206\u5c42\u7ec4\u88c5\u6784\u9020\u7684\u5177\u6709\u4e4b\u5b57\u5f62\u56fe\u6848\u7684\u8d85\u6676\u683c<\/p>\n Figure 11. \u914d\u4f53\u5bf9\u4e8c\u5143\u7eb3\u7c73\u7c07\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \uff08a-c\uff09\u5728PtB\u578b\u516d\u65b9\u8d85\u6676\u683c\u4e2d\u663e\u793a\u4e00\u4e2a(AuAg)45<\/sub>(SR)27<\/sub>(PPh3<\/sub>)6<\/sub>\u7eb3\u7c73\u56e2\u7c07\u4e0e\u516d\u4e2a(AuAg)267<\/sub>(SR)80<\/sub>\u7eb3\u7c73\u56e2\u7c07\u7684\u8868\u9762\u914d\u4f53\u7684\u6392\u5217\uff08d\uff09(AuAg)45<\/sub>\u7684\u81a6\u914d\u4f53\uff08\u4ee5\u7eff\u8272\u8868\u793a\uff09\u4e0e(AuAg)267<\/sub>\u7684\u5def\u57fa\u914d\u4f53\uff08\u4ee5\u7c89\u7ea2\u8272\u8868\u793a\uff09\u4e4b\u95f4\u7684\u7c07\u95f4C-H\u00b7\u00b7\u03c0\u76f8\u4e92\u4f5c\u7528<\/p>\n Figur<\/b><\/strong>e 1<\/strong>2.\u6297\u8861\u79bb\u5b50\u5bf9\u7eb3\u7c73\u7c07\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \uff08a\uff09\u5177\u6709\u4e09\u659c\u6676\u76f8\uff08\u5de6\u56fe\uff09\u548c\u5355\u659c\u6676\u76f8\uff08\u53f3\u56fe\uff09\u7684\u8d85\u6676\u683c\uff0c\u5206\u522b\u7531\u5177\u6709[AgCl2<\/sub>]–<\/sup>\u548c[Cl]–<\/sup>\u6297\u8861\u9634\u79bb\u5b50\u7684[Au21<\/sub>(SR)12<\/sub>(PCP)2<\/sub>]+<\/sup>\u7eb3\u7c73\u56e2\u7c07\u7ec4\u88c5\u800c\u6210\uff08b\uff09\u7531Au1<\/sub>Ag22<\/sub>\u7eb3\u7c73\u7c07\u7ec4\u88c5\u6210\u7684SCIF-1\uff0cSCIF-2-Left\u548cSCIF-2-Right\u8d85\u6676\u683c\uff08c\uff09\u76f8\u5e94\u7684CPL\u5149\u8c31 \uff08d\uff09\u7531[Ag26<\/sub>Au(2-EBT)18<\/sub>(PPh3<\/sub>)6<\/sub>]+<\/sup>\u548c[Ag24<\/sub>Au(2-EBT)18<\/sub>]–<\/sup>\u5171\u540c\u7ec4\u88c5\u800c\u5f62\u6210\u7684\u5177\u6709\u9010\u5c42\u5806\u53e0\u7ed3\u6784\u7684\u4e09\u659c\u8d85\u6676\u683c\uff08e\uff09\u7531[Ag24<\/sub>Au(2-EBT)18<\/sub>]–<\/sup>\u7eb3\u7c73\u56e2\u7c07\u548c[PPh4<\/sub>]+<\/sup>\u6297\u8861\u9633\u79bb\u5b50\u5171\u540c\u7ec4\u88c5\u6784\u6210\u7684\u7acb\u65b9\u8d85\u6676\u683c<\/p>\n Figu<\/b><\/strong>re 1<\/strong>3.\u6838\u5bf9\u79f0\u6027\u5bf9\u7eb3\u7c73\u7c07\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \u4ee5\u7403\u5f62\u7eb3\u7c73\u9897\u7c92\u4e3a\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u8d85\u6676\u6750\u6599\uff1a<\/p>\n Figure 14.\u914d\u4f53\u5bf9\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7ed3\u6784\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n \uff08a\uff09bcc\uff08\u9876\u90e8\uff09\u548cfcc\uff08\u5e95\u90e8\uff09\u6676\u683c\u7684\u6676\u80de\u548cW-S\u6676\u80de \uff08b\uff09\u901a\u8fc7\u7ec4\u88c5\u5df1\u786b\u9187\u4fee\u9970\u76842 nm Au\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684\u5177\u6709Frank-Kasper\u76f8\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf\uff08\u5de6\u56fe\uff09\u548c\u7ed3\u6784\u6a21\u578b\uff08\u53f3\u56fe\uff09 \uff08c\uff09\u5206\u522b\u7531\u5177\u6709\u5bc6\u96c6\u548c\u7a00\u758f\u914d\u4f53\u4fee\u9970\u7684PbS\u7eb3\u7c73\u6676\u4f53\u6784\u9020\u7684fcc\u548cbcc\u8d85\u6676\u683c\u7684\u7ed3\u6784\u6a21\u578b\u548c\u63a0\u5165\u5c04\u5e7f\u89d2X\u5c04\u7ebf\u6563\u5c04\u56fe\uff08GIWAXS\uff09<\/p>\n Figure 15.\u901a\u8fc7\u57fa\u4e8eDNA\u7684\u65b9\u6cd5\u6784\u5efa\u7684\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a-b\uff09\u901a\u8fc7\u7ec4\u88c5DNA\u4fee\u9970\u7684Au\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684bcc\u548chcp\u8d85\u6676\u683c \uff08c\uff09\u901a\u8fc7\u5206\u522b\u7ec4\u88c5DNA\u529f\u4fee\u9970\u7684Au\u7eb3\u7c73\u9897\u7c92\u548c\u7a7a\u5fc3DNA\u6846\u67b6\u5e76\u7ec4\u88c5DNA\u4fee\u9970\u7684Au\u7eb3\u7c73\u9897\u7c92\u800c\u6784\u5efa\u7684\u7b80\u5355\u7acb\u65b9\uff08\u5de6\u56fe\uff09\u548cbcc\uff08\u53f3\u56fe\uff09\u8d85\u6676\u683c\u7684\u6676\u80de\u548cSAXS\u56fe<\/p>\n Figure 16.\u5177\u6709\u53d6\u5411\u6027\u7684\u7eb3\u7c73\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a-b\uff09\u7531\u5177\u6709C4h\u548cC2h\u5bf9\u79f0\u6027\u7684PbS\u7eb3\u7c73\u6676\u4f53\u7ec4\u88c5\u800c\u6210\u7684fcc\u8d85\u6676\u683c\uff08c-d\uff09\u7531PbSe\u7eb3\u7c73\u6676\u4f53\u5b9a\u5411\u805a\u96c6\u5f62\u6210\u7684\u4e8c\u7ef4\u8702\u7a9d\u72b6\u548c\u6b63\u65b9\u5f62\u8d85\u6676\u683c<\/p>\n Fig<\/b><\/strong>u<\/strong>re 17.\u7eb3\u7c73\u7c92\u5b50\u7684\u6a21\u677f\u5bfc\u5411\u7ec4\u88c5<\/b><\/strong> \uff08a\uff09\u663e\u793a\u5728Au\u7eb3\u7c73\u7c92\u5b50\u5b58\u5728\u4e0b\u7194\u878d\u6db2\u6676\u5316\u5408\u7269\u5411\u87ba\u65cb\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u8f6c\u53d8\u7684\u793a\u610f\u56fe\uff08\u5de6\u56fe\uff09\uff0c\u4ee5\u53caAu\u87ba\u65cb\u8d85\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff08\u53f3\u56fe\uff09 \uff08b\uff09\u5177\u6709\u516d\u8fb9\u5f62\u8702\u7a9d\u7ed3\u6784\u7684Au\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08c\uff09\u5177\u6709\u5468\u671f\u6027\u7eb3\u7c73\u73af\u7ed3\u6784\u7684Au\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7684STEM\u56fe\u50cf<\/p>\n Figure 18.\u4f7f\u7528DNA\u6a21\u677f\u5b9a\u5411\u7ec4\u88c5\u7403\u5f62\u7eb3\u7c73\u9897\u7c92<\/b><\/strong><\/p>\n \uff08a\uff09\u4f7f\u7528\u5206\u522b\u5177\u6709\u516b\u9762\u4f53\uff0c\u7ec6\u957f\u65b9\u5f62\u53cc\u9525\u4f53\uff0c\u7acb\u65b9\u548c\u68f1\u67f1\u5f62\u76843D DNA\u6298\u7eb8\u6846\u67b6\u6784\u9020\u7684\u5177\u6709fcc\uff0cbct\uff0c\u7b80\u5355\u7acb\u65b9\u548c\u7b80\u5355\u516d\u65b9\u76f8\u7684\u8d85\u6676\u683c\u7684\u6676\u80de \uff08b\uff09\u793a\u610f\u56fe\u663e\u793a\u4e86\u4f7f\u75283D DNA\u56db\u9762\u4f53\u6846\u67b6\u548c\u4e24\u79cd\u7c7b\u578b\u7684DNA\u4fee\u9970\u7684\u7eb3\u7c73\u9897\u7c92\u6784\u9020\u7acb\u65b9\u91d1\u521a\u77f3\u8d85\u6676\u683c \uff08c\uff09\u9876\u90e8\u663e\u793a\u4e86\u56db\u79cd\u7c7b\u578b\u7684DNA\u3002\u5e95\u90e8\u663e\u793a\u5305\u542b\u56db\u79cd\u7c7b\u578b\u7684Au\u8d85\u7ed3\u6784\u7684TEM\u56fe\u50cf\u53ca\u5176\u76f8\u5e94\u7684\u7ed3\u6784\u6a21\u578b<\/p>\n Figure 19.\u4ee5\u70df\u8349\u82b1\u53f6\u75c5\u6bd2\u5916\u58f3\u86cb\u767d\u4e3a\u6a21\u677f\u7ec4\u88c5\u91d1\u7eb3\u7c73\u9897\u7c92<\/b><\/strong><\/p>\n \uff08a\uff09\u793a\u610f\u56fe\u663e\u793a\u901a\u8fc7Cu2<\/sup>+<\/sup>-\u7ec4\u6c28\u9178\u87af\u5408\u65b9\u6cd5\u5c06TMV\u76d8\u7ec4\u88c5\u6210\u5177\u6709\u8702\u7a9d\u7ed3\u6784\u7684\u4e8c\u7ef4\u5355\u5c42\u819c\u5e76\u5f62\u6210\u4e09\u79cd\u7c7b\u578b\u7684\u951a\u5b9a\u4f4d\u70b9\uff08b-d\uff09\u5177\u6709\uff08b\uff09\u8702\u7a9d\u7ed3\u6784\uff0c\uff08c\uff09\u73af\u72b6\u7ed3\u6784\u548c\uff08d\uff09\u4e24\u8005\u7ed3\u5408\u76842D Au\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf\u548c\u7ed3\u6784\u6a21\u578b<\/p>\n Figure 20.\u901a\u8fc7\u7ec4\u88c5\u540e\u8680\u523b\u5904\u7406\u6784\u9020\u7684\u975e\u5bc6\u5806\u79ef\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u5b9e\u9a8c\u7a0b\u5e8f\u793a\u610f\u56fe \uff08b\uff09\u901a\u8fc7\u4ece\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u548c\u6bd4\u4f8b\u7684Au-Fe3<\/sub>O4<\/sub>\u00a0\u4e8c\u5143\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u4e2d\u9009\u62e9\u6027\u523b\u8680Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684\u56db\u79cd\u7c7b\u578b\u7684\u975e\u5bc6\u6392Au\u7eb3\u7c73\u9897\u7c92\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf<\/p>\n Figure 21.\u5177\u6709\u4e0d\u540c\u6676\u76f8\u7684\u4e8c\u5143\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u901a\u8fc7\u7ec4\u88c5\u5c3a\u5bf8\u6bd4\u4e3a0.67\u7684CdSe\u548cPbSe\u7eb3\u7c73\u7c92\u5b50\u6784\u6210\u7684\u5177\u6709\u72ec\u7279A6<\/sub>B19<\/sub>\u7ed3\u6784\u7684\u4e8c\u5143\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf\uff0c\uff08b\uff09\u901a\u8fc7\u7ec4\u88c510.2 nm Fe2<\/sub>O3<\/sub>-C9\u548c4.1 nm Au-C18\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684Li3<\/sub>Bi\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08c\uff09\u901a\u8fc7\u7ec4\u88c510.2 nm Fe2<\/sub>O3<\/sub>-C18\u548c4.1 nm Au-C9\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684bcc-AB6<\/sub>\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08d\uff09\u901a\u8fc7\u7ec4\u88c56.2 nm PbSe\u548c3.0 nm Pd\u7eb3\u7c73\u9897\u7c92\u6784\u6210\u7684Fe4<\/sub>C\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08e\uff09\u901a\u8fc7\u7ec4\u88c57.6 nm PbSe\u548c5.0 nm Au\u7eb3\u7c73\u9897\u7c92\u6784\u6210\u7684CuAu\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08f\uff09\u901a\u8fc7\u7ec4\u88c57.2 nm PbSe\u548c5.0 nm Au\u7eb3\u7c73\u9897\u7c92\u6784\u6210\u7684CaCu5<\/sub>\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08g-h\uff09\u901a\u8fc7\u7ec4\u88c56.2 nm PbSe\u548c3.0 nm Pd\u7eb3\u7c73\u9897\u7c92\u6784\u5efa\u7684\u4e24\u79cd\u8d85\u6676\u683c\u7684\uff08TEM\u56fe\u50cf \uff08i\uff09\u901a\u8fc7\u7ec4\u88c5\u5927\u5c0f\u76f8\u7b49\uff0c\u5e26\u76f8\u53cd\u7535\u8377\u7684Au\u548cAg\u7eb3\u7c73\u9897\u7c92\u6784\u6210\u7684\u7c7b\u91d1\u521a\u77f3\u8d85\u6676\u4f53\u7684SEM\u56fe\u50cf<\/p>\n Figure 22.\u7531\u4e8c\u5143\u7eb3\u7c73\u9897\u7c92\u7ec4\u88c5\u7684\u51c6\u6676\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u753113.4 nm Fe2<\/sub>O3<\/sub>\u548c5 nm Au\u7eb3\u7c73\u7c92\u5b50\u81ea\u7ec4\u88c5\u7684\u5341\u4e8c\u6b21\u5bf9\u79f0\u51c6\u6676\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08b\uff09\u75316.2 nm FePt\u548c11.5 nm Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u7c92\u5b50\u81ea\u7ec4\u88c5\u7684\u5341\u4e8c\u6b21\u5bf9\u79f0\u51c6\u6676\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08c\uff09\u663e\u793a\u5341\u4e8c\u6b21\u5bf9\u79f0\u51c6\u6676\u548cCaB6<\/sub>\u578b\u8d85\u6676\u683c\u5171\u5b58\u7684TEM\u56fe\u50cf \uff08d\uff09\u663e\u793a\u5341\u4e8c\u6b21\u5bf9\u79f0\u51c6\u6676\u548c\u03c3\u76f8\u8d85\u6676\u683c\u5171\u5b58\u7684TEM\u56fe\u50cf<\/p>\n Figure 23.\u4e09\u5143\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u7531CdSe\u548c\u4e24\u79cd\u4e0d\u540c\u5c3a\u5bf8\u7684PbSe\u7eb3\u7c73\u7c92\u5b50\u5171\u540c\u7ec4\u88c5\u800c\u6210\u7684ABC4<\/sub>\u578b\u4e09\u5143\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf\uff08b-c\uff09\u7531FePt\u548c\u4e24\u79cd\u4e0d\u540c\u5c3a\u5bf8\u7684Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u7c92\u5b50\u5171\u540c\u7ec4\u88c5\u7684ABC2<\/sub>\u578b\u4e09\u5143\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684\u7ed3\u6784\u6a21\u578b\uff08d\uff09\u53ef\u9006DNA\u62d3\u6251\u5d4c\u63d2\u65b9\u6cd5\u7684\u793a\u610f\u56fe \uff08e-g\uff09\u901a\u8fc7\u53ef\u9006DNA\u62d3\u6251\u5d4c\u63d2\u65b9\u6cd5\u6784\u5efa\u7684ABC12<\/sub>\u578b\uff0cA2<\/sub>B3<\/sub>\u578b\u548cAB4<\/sub>\u578b\u4e09\u5143\u7eb3\u7c73\u7c92\u5b50\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf\u53ca\u76f8\u5e94\u7ed3\u6784\u6a21\u578b<\/p>\n \u4ee5\u5404\u5411\u5f02\u6027\u7eb3\u7c73\u9897\u7c92\u4e3a\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u8d85\u6676\u6750\u6599\uff1a<\/p>\n Figure 24.\u7531\u4e00\u7ef4\u7eb3\u7c73\u68d2\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u7531\u4e00\u7ef4ZnO\u7eb3\u7c73\u68d2\u5e76\u6392\u6392\u5217\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08b-c\uff09\u7531\u4e00\u7ef4\u91d1\u7eb3\u7c73\u68d2\u7ec4\u88c5\u7684\u5411\u5217\u578b\u548c\u5c42\u5217\u578b\u7684\u6db2\u6676\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf \uff08d\uff09\u7531\u4e24\u5c42\u5782\u76f4\u53d6\u5411\u7684CdS\u7eb3\u7c73\u68d2\u8d85\u6676\u683c\u91cd\u53e0\u800c\u5f62\u6210\u7684\u7c7b\u5341\u4e8c\u6b21\u5bf9\u79f0\u51c6\u6676\u83ab\u5c14\u8d85\u6676\u683c\u7684STEM\u56fe\u50cf\uff0c\u5176\u9519\u4f4d\u89d2\u7ea6\u4e3a29\u00b0\uff08e-h\uff09\u7531CdSe@CdS\u534a\u5bfc\u4f53\u7eb3\u7c73\u68d2\u7ec4\u88c5\u800c\u6210\u7684\u53cc\u5706\u9876\u5706\u67f1\u72b6\u8d85\u6676\u4f53\u548c\u7ec6\u957f\u9488\u72b6\u8d85\u6676\u4f53\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf<\/p>\n Figure 25.\u75312D\u7eb3\u7c73\u7247\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u75312D Eu2<\/sub>O3<\/sub>\u7eb3\u7c73\u76d8\u9762\u5bf9\u9762\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08b-c\uff09\u7531GdF3<\/sub>\u692d\u5706\u5f62\u7eb3\u7c73\u7247\u7ec4\u88c5\u800c\u6210\u7684\u67f1\u72b6\u548c\u5c42\u72b6\u6db2\u6676\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08d\uff09\u7531\u83f1\u5f62\u7eb3\u7c73\u7247\u7ec4\u88c5\u7684\u5177\u6709cmm\u5bf9\u79f0\u6027\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08e-f\uff09\u7531\u4e0d\u89c4\u5219\u516d\u8fb9\u5f62\u7eb3\u7c73\u7247\u7ec4\u88c5\u800c\u6210\u7684\u5e73\u884c\u6392\u5217\u548c\u4ea4\u66ff\u6392\u5217\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08g\uff09\u7531Cu2<\/sub>S\u7eb3\u7c73\u76d8\u7ec4\u88c5\u800c\u6210\u7684\u591a\u97623D\u8d85\u6676\u7684SEM\u56fe\u50cf \uff08h\uff09\u7531\u516d\u8fb9\u5f62Ag\u7eb3\u7c73\u68f1\u955c\u7ec4\u88c5\u800c\u6210\u7684\u87ba\u65cb3D\u8d85\u6676\u7684SEM\u56fe\u50cf<\/p>\n Figure 26.\u7531\u591a\u9762\u4f53\u7eb3\u7c73\u6676\u4f53\u7ec4\u88c5\u7684\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u7531CdTe\u622a\u89d2\u56db\u9762\u4f53\u7ec4\u88c5\u800c\u6210\u7684\u87ba\u65cb1D\u8d85\u6676\u7684SEM\u56fe\u50cf\uff08\u5de6\u56fe\uff09\u548c\u7ed3\u6784\u6a21\u578b\uff08\u53f3\u56fe\uff09 \uff08b\uff09\u7531PVP\u805a\u5408\u7269\u4fee\u9970\u7684Ag\u516b\u9762\u4f53\u7eb3\u7c73\u6676\u4f53\u7ec4\u88c5\u800c\u6210\u7684\u975e\u5bc6\u6392\u87ba\u65cb\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf\uff08c\uff09\u7531PVP\u4fee\u9970\u7684Ag\u516b\u9762\u4f53\u7ec4\u88c5\u800c\u6210\u76842D hcp\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf \uff08d\uff09\u75311-\u4e19\u786b\u9187\u4fee\u9970\u7684Ag\u516b\u9762\u4f53\u7ec4\u88c5\u800c\u6210\u7684\u4e8c\u7ef4\u975e\u5bc6\u6392\u516d\u65b9\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf \uff08e\uff09\u75311-\u5341\u516d\u70f7\u786b\u9187\u4fee\u9970\u7684Ag\u516b\u9762\u4f53\u7ec4\u88c5\u800c\u6210\u76842D\u6b63\u65b9\u5f62\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf<\/p>\n Figure 27.\u7531\u591a\u9762\u4f53\u7eb3\u7c73\u6676\u4f53\u7ec4\u88c5\u7684\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u622a\u89d2\u56db\u9762\u4f53\u91cf\u5b50\u70b9\u7684\u5404\u5411\u5f02\u6027\u914d\u4f53\u8986\u76d6\u793a\u610f\u56fe 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30.\u7531\u4e0d\u540c\u5f62\u72b6\u7684\u5404\u5411\u5f02\u6027\u7eb3\u7c73\u6676\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c<\/b><\/strong><\/p>\n \uff08a\uff09\u7531Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u7403\u548cNaYF4<\/sub>\u7eb3\u7c73\u68d2\u7ec4\u88c5\u800c\u6210\u7684AB2<\/sub>\u578b\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08b-c\uff09\u7531CdSe\/CdS\u7eb3\u7c73\u68d2\u548cLaF3<\/sub>\u7eb3\u7c73\u76d8\u7ec4\u88c5\u800c\u6210\u7684AB\u578b\u548cAB6<\/sub>\u578b\u4e8c\u5143\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08d\uff09\u4ece\u4e24\u79cd\u5c3a\u5bf8\u7684LaF3<\/sub>\u7eb3\u7c73\u76d8\u548cCdSe\/CdS\u7eb3\u7c73\u68d2\u7ec4\u88c5\u800c\u6210\u7684ABC\u578b\u4e09\u5143\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08e-f\uff09\u5728\u6c27\u5316\u7845\u886c\u5e95\u548c\u975e\u6676\u78b3\u886c\u5e95\u4e0a\u7531LaF3<\/sub>\u4e09\u89d2\u5f62\u7eb3\u7c73\u7247\u548cAu\u7eb3\u7c73\u9897\u7c92\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08g\uff09\u7531\u516b\u811a\u72b6CdSe-CdS\u548cFe3<\/sub>O4<\/sub>\u7eb3\u7c73\u7c92\u5b50\u7ec4\u88c5\u800c\u6210\u7684\u5177\u6709\u201c\u4e95\u5b57\u68cb\u201d\u7ed3\u6784\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08h\uff09\u7531\u5177\u6709\u4e92\u8865\u5f62\u72b6\u7684\u83f1\u5f62GdF3<\/sub>\u548c\u4e09\u811a\u72b6Gd2<\/sub>O3<\/sub>\u7eb3\u7c73\u7247\u7ec4\u88c5\u800c\u6210\u7684\u8d85\u6676\u683c\u7684TEM\u56fe\u50cf \uff08i-j\uff09\u7531DNA\u4fee\u9970\u7684Au\u7eb3\u7c73\u9897\u7c92\u548c\u7eb3\u7c73\u7acb\u65b9\u4f53\u7ec4\u88c5\u800c\u6210\u7684NaCl\u578b\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf\u548c\u7ed3\u6784\u6a21\u578b \uff08k-l\uff09\u7531DNA\u4fee\u9970\u7684Au\u7eb3\u7c73\u9897\u7c92\u548c\u7eb3\u7c73\u516b\u9762\u4f53\u7ec4\u88c5\u800c\u6210\u7684CsCl\u578b\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf\u548c\u7ed3\u6784\u6a21\u578b<\/p>\n \u4ee5\u5fae\u7c92\u4e3a\u57fa\u5143\u6784\u5efa\u5177\u6709\u975e\u5e38\u89c4\u76f8\u7684\u8d85\u6676\u6750\u6599\uff1a<\/p>\n Figure 31.\u4e00\u5143\u5fae\u7c92\u8d85\u6676\u683c\u7684\u6784\u5efa<\/b><\/strong><\/p>\n \uff08a\uff09\u7531\u692d\u7403\u7ec4\u88c5\u800c\u6210\u7684\u4e09\u89d2\u5f62\u7f51\u7edc\u7684\u663e\u5fae\u7167\u7247 \uff08b\uff09\u7531\u03b8\u5f62SiO2<\/sub>\u68d2\u7ec4\u88c5\u800c\u6210\u7684\u5177\u6709\u201cprone\u201d\u76f8\u7684\u5b6a\u6676\u8d85\u6676\u7684\u5149\u5b66\u663e\u5fae\u7167\u7247 \uff08c\uff09\u7531\u4e09\u89d2\u5f62\u5fae\u7c92\u7ec4\u88c5\u800c\u6210\u7684\u4e09\u91cd\u6db2\u6676\u7684\u5149\u5b66\u663e\u5fae\u7167\u7247 \uff08d-e\uff09\u7531PS-TPM-PS\u5fae\u7c92\u7ec4\u88c5\u800c\u6210\u76841D\u503e\u659c\u68af\u94fe\u72b6\u548c2D\u6b63\u65b9\u5f62\u8d85\u6676\u683c\u7684\u5149\u5b66\u56fe\u50cf \uff08f\uff09\u7531\u201c\u4e09\u5d4c\u6bb5Janus\u201d\u5fae\u7c92\u7ec4\u88c5\u800c\u6210\u7684kagome\u8d85\u6676\u683c\u7684\u8367\u5149\u5149\u5b66\u56fe\u50cf<\/p>\n Figure 32.\u7531\u6a21\u677f\uff0c\u7ea6\u675f\u548c\u5916\u90e8\u573a\u5f15\u5bfc\u7684\u4e00\u5143\u5fae\u7c92\u8d85\u6676\u683c\u7684\u6784\u9020<\/b><\/strong><\/p>\n \uff08a-b\uff09\u901a\u8fc7\u5728\u5149\u523b\u6a21\u677f\u8868\u9762\u4e0a\u6c89\u79efPS\u7403\u800c\u6784\u5efa\u7684\u7acb\u65b9\u548c\u7ebf\u6027\u94fe\u72b6\u5fae\u7c92\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf \uff08c\uff09\u901a\u8fc7\u6a21\u677f\u8bf1\u5bfc\u7ec4\u88c5\u6cd5\u6784\u5efa\u7684bcc\u8d85\u6676\u683c\u7684SEM\u56fe\u50cf \uff08d\uff09\u901a\u8fc7\u7ea6\u675f\u8bf1\u5bfc\u7ec4\u88c5\u6784\u5efa\u7684\u5177\u6709\u7eaf\u5de6\u624b\uff0c\u5de6\u624b\u548c\u53f3\u624b\u6df7\u5408\u4ee5\u53ca\u7eaf\u53f3\u624b\u624b\u6027\u7684\u87ba\u65cb\u94fe\u7684\u793a\u610f\u56fe\u548cSEM\u56fe\u50cf \uff08e-g\uff09\u5728\u5916\u90e8\u7535\u573a\u4e0b\u83b7\u5f97\u7684\uff08e\uff09bco\uff0c\uff08f\uff09bct\u548c\uff08g\uff09sft\u8d85\u6676\u683c\u7684\u5171\u805a\u7126\u663e\u5fae\u7167\u7247<\/p>\n Figure 33.\u7531\u5916\u90e8\u78c1\u573a\u5f15\u5bfc\u7684\u4e8c\u5143\u5fae\u7c92\u8d85\u6676\u683c\u7684\u6784\u9020<\/b><\/strong><\/p>\n \uff08a\uff09\u5728\u5916\u90e8\u78c1\u573a\u4e0b\uff0c\u4ee5\u78c1\u6d41\u4f53\u4e2d\u7684\u5177\u6709\u987a\u78c1\u6027\u548c\u53cd\u78c1\u6027\u7684\u7403\u5f62\u5fae\u7c92\u4f5c\u4e3a\u57fa\u5143\u6784\u9020\u7684\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u4e8c\u5143\u8d85\u6676\u683c\u7684\u7ed3\u6784\u6a21\u578b\u548c\u8367\u5149\u663e\u5fae\u7167\u7247 \uff08b\uff09\u5728\u5916\u90e8\u78c1\u573a\u4e0b\uff0c\u4ee5Ni\/PDMS\u4e3a\u6a21\u677f\uff0c\u4ee5\u5177\u6709\u987a\u78c1\u6027\u548c\u53cd\u78c1\u6027\u7684\u7403\u5f62\u5fae\u7c92\u4e3a\u57fa\u5143\u6784\u9020\u7684\u4e8c\u5143AB\u578b\uff0c\u4e8c\u5143AB2<\/sub>\u578b\u548c\u4e00\u79cd\u4e09\u5143\u8d85\u6676\u683c<\/p>\n Figure 34.\u7531\u5e26\u6709\u76f8\u53cd\u7535\u8377\u7684\u4e8c\u5143\u5fae\u7c92\u6784\u5efa\u7684\u79bb\u5b50\u578b\u8d85\u6676<\/b><\/strong><\/p>\n \uff08a\uff09CsCl\u578b\uff0c\uff08b\uff09LS6<\/sub>\u578b\uff0c\uff08c\uff09NaCl\u578b\uff0c\uff08d\uff09NiAs\u578b\u79bb\u5b50\u578b\u8d85\u6676\u683c\u7684\u663e\u5fae\u7167\u7247\uff08e-f\uff09LS8<\/sub>hcp<\/sup>\u548c\uff08g-h\uff09LS8<\/sub>fcc<\/sup>\u578b\u79bb\u5b50\u578b\u8d85\u6676\u683c\u7684\u663e\u5fae\u7167\u7247\u53ca\u5176\u7406\u8bba\u6a21\u578b<\/p>\n 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\uff08b\uff09Au60<\/sub>S6<\/sub>\u00a06H\u8d85\u6676\u683c\u548c\u975e\u6676\u6001\u805a\u96c6\u4f53\u7684\u56fa\u6001\u5149\u81f4\u53d1\u5149\u5149\u8c31\uff08c-d\uff09\u6df7\u5408\u6709\u4e0d\u540c\u4f53\u79ef\u5206\u6570\u6b63\u5df1\u70f7\u7684\u4e8c\u6c2f\u7532\u70f7\u4e2dAu<\/p>\n
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