{"id":221080,"date":"2021-04-23T08:14:38","date_gmt":"2021-04-23T00:14:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=221080"},"modified":"2021-04-23T08:14:38","modified_gmt":"2021-04-23T00:14:38","slug":"%e4%bb%8a%e6%97%a5%e6%9c%80%e6%96%b0science-%e5%9c%a8%e6%ad%a3%e7%a1%ae%e7%9a%84%e6%97%b6%e6%9c%ba%e5%bc%95%e5%85%a5%e7%94%b2%e5%9f%ba%e5%9f%ba%e5%9b%a2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=221080","title":{"rendered":"\u4eca\u65e5\u6700\u65b0Science: \u5728\u6b63\u786e\u7684\u65f6\u673a\u5f15\u5165\u7532\u57fa\u57fa\u56e2"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u201c\u9b54\u6cd5\u7532\u57fa\uff08magic methyl\uff09\u201d\u6548\u5e94\u662f\u6307\u5f15\u5165\u5355\u7532\u57fa\u57fa\u56e2\u7684\u5019\u9009\u836f\u7269\uff0c\u5176\u5728\u6548\u529b\u3001\u9009\u62e9\u6027\u4ee5\u53ca\u4ee3\u8c22\u7a33\u5b9a\u6027\u65b9\u9762\u53d1\u751f\u4e86\u663e\u8457\u7684\u53d8\u5316\u3002\u76ee\u524d\u5728\u836f\u7269\/\u7c7b\u836f\u7269\u5206\u5b50\u4e2d\uff0c\u5bf9C(sp<sup>3<\/sup>)\u2013H\u8fdb\u884c\u7532\u57fa\u5316\u4e3b\u8981\u5206\u4e3a\u4e24\u6b65\uff0c\u5373\u78b3\u6c22\u952e\u7684\u6c27\u5316\u4ee5\u53ca\u7532\u57fa\u7684\u4eb2\u6838\u52a0\u6210\u3002\u7136\u800c\uff0c\u8fd9\u4e00\u8fc7\u7a0b\u5b58\u5728\u7740\u8bf8\u591a\u7f3a\u70b9\uff0c\u4f8b\u5982\u4e24\u6b65\u5747\u9700\u5728\u4f4e\u6e29\u4e0b\u8fdb\u884c\uff0c\u4ee5\u53ca\u9700\u7528\u6613\u81ea\u71c3\u7684\u4e09\u7532\u57fa\u94dd\u4f5c\u4e3a\u7532\u57fa\u4eb2\u6838\u6765\u6e90\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p><strong>\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u7684<\/strong><strong>Shannon S. Stahl<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u53ef\u5728\u90bb\u8fd1\u6c2e\/\u82b3\u9999\u73af\u7684\u78b3\u4e2d\u5fc3\u8fdb\u884c\u7532\u57fa\u5316\u7684\u591a\u6837\u5316\u7b56\u7565\u3002\u8be5\u7814\u7a76\u663e\u793a\uff0c\u53ef\u89c1\u5149\u542f\u52a8\u7684\u4e09\u7ebf\u6001\u80fd\u91cf\u8f6c\u79fb\u80fd\u591f\u63d0\u9ad8\u6e29\u548c\u6761\u4ef6\u4e0b\u6c27\u6c27\u952e\u5728\u8fc7\u6c27\u5316\u4e8c\u5f02\u4e19\u82ef\u7b49\u4e2d\u5747\u88c2\u4f5c\u7528\uff0c\u4ece\u800c\u4ea7\u751f\u5177\u6709\u6b67\u5316\u53cd\u5e94\u6d3b\u6027\u7684\u70f7\u6c27\u57fa\u81ea\u7531\u57fa\uff0c\u5e76\u5b9e\u73b0\u5e95\u7269\u78b3\u6c22\u952e\u4e2d\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\u6216\u8005\u7532\u57fa\u81ea\u7531\u57fa\u7684\u4ea7\u751f\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u4e9b\u53cd\u5e94\u6b65\u9aa4\u7684\u901f\u7387\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u53cd\u5e94\u6761\u4ef6\u6216\u8005\u8fc7\u6c27\u5316\u7269\u53d6\u4ee3\u7269\u79cd\u7c7b\u6765\u8fdb\u884c\u8c03\u8282\uff0c\u4ece\u800c\u4f18\u5316\u7532\u57fa\u5316\u4ea7\u7269\u7684\u4ea7\u7387\u3002\u57fa\u4e8e\u4ee5\u4e0a\u7684\u7b56\u7565\uff0c\u7814\u7a76\u6210\u529f\u5236\u5907\u4e86\u6c99\u82ac\u9170\u80fa\u3001\u66f2\u7f8e\u82c4\u80fa\u3001\u897f\u90a3\u5361\u585e\u7b49\u7532\u57fa\u5316\u4ea7\u7269\u7efc\u5408\u7814\u7a76\u6210\u679c\uff0c\u56e0\u6b64\u4f5c\u8005\u8ba4\u4e3a\u8be5\u7b56\u7565\u5728\u836f\u7269\u5206\u5b50\u7684\u7532\u57fa\u5316\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u30022021\u5e7404\u670823\u65e5\uff0c\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>C(sp<sup>3<\/sup>)\u2013H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling<\/strong>\u201d\u7684\u6587\u7ae0\u5728\u7ebf\u53d1\u8868\u5728<strong>Science<\/strong>\u4e0a\u3002<\/p>\n<p>\u3010<strong>\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1<\/strong> <strong>\u901a\u8fc7\u5149\u5316\u5b66\u6d3b\u5316\u8fc7\u6c27\u5316\u7269\u5b9e\u73b0<\/strong><strong>C(sp<sup>3<\/sup>)\u2013H<\/strong><strong>\u7532\u57fa\u5316<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221084\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F1.large_-3.jpg\" alt=\"\" width=\"600\" height=\"301\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F1.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F1.large_-3-300x151.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong> <strong>\u5149\u5316\u5b66\u954d\u50ac\u5316\u78b3\u6c22\u7532\u57fa\u5316\u7684\u53cd\u5e94\u673a\u5236<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221083\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F2.large_-3.jpg\" alt=\"\" width=\"600\" height=\"714\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F2.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F2.large_-3-252x300.jpg 252w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3 <\/strong><strong>\u7532\u57fa\u5316\u5e95\u7269<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221082\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F3.large_-3.jpg\" alt=\"\" width=\"600\" height=\"715\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F3.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F3.large_-3-252x300.jpg 252w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe4 \u5229\u7528\u5e03\u5fcd\u53f8\u7279\u9178\u63a7\u5236\u4f4d\u70b9\u9009\u62e9\u6027<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-221081\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F4.large_-2.jpg\" alt=\"\" width=\"600\" height=\"679\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F4.large_-2.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/F4.large_-2-265x300.jpg 265w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/science.sciencemag.org\/content\/372\/6540\/398\" target=\"_blank\" rel=\"noopener\"><strong>C(sp<sup>3<\/sup>)\u2013H methylation enabled by peroxide photosensitization and Ni-mediated radical coupling<\/strong><\/a>\uff08Science, 2021, DOI: 10.1126\/science.abh2623\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4NanoCJ\u4f9b\u7a3f\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u201c\u9b54\u6cd5\u7532\u57fa\uff08magic methyl\uff09\u201d\u6548\u5e94\u662f\u6307\u5f15\u5165\u5355\u7532\u57fa\u57fa\u56e2\u7684\u5019\u9009\u836f\u7269\uff0c\u5176\u5728\u6548\u529b\u3001\u9009\u62e9\u6027\u4ee5\u53ca\u4ee3\u8c22\u7a33\u5b9a\u6027\u65b9\u9762\u53d1\u751f\u4e86\u663e\u8457\u7684\u53d8\u5316\u3002\u76ee\u524d\u5728\u836f\u7269\/\u7c7b\u836f\u7269\u5206\u5b50\u4e2d&#8230;<\/p>\n","protected":false},"author":1076,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-221080","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/221080"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1076"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=221080"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/221080\/revisions"}],"predecessor-version":[{"id":221085,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/221080\/revisions\/221085"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=221080"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=221080"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=221080"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}