{"id":220923,"date":"2021-04-24T06:41:15","date_gmt":"2021-04-23T22:41:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=220923"},"modified":"2021-04-23T21:41:31","modified_gmt":"2021-04-23T13:41:31","slug":"nature%e7%b3%bb%e5%88%97%e3%80%81am%e3%80%81jacs%e7%ad%89mof%e3%80%81cof%e6%9c%80%e6%96%b0%e6%88%90%e6%9e%9c%e9%80%9f%e8%a7%88","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=220923","title":{"rendered":"Nature\u7cfb\u5217\u3001AM\u3001JACS\u7b49MOF\u3001COF\u6700\u65b0\u6210\u679c\u901f\u89c8"},"content":{"rendered":"<p>\u672c\u6587\u6c47\u603b\u4e86MOF\u3001COF\u9876\u520a\u4e2d\u53d1\u8868\u7684\u6700\u65b0\u6587\u7ae0\uff0c\u4f9b\u5927\u5bb6\u53c2\u8003\u5b66\u4e60\u3002<\/p>\n<p><strong><b>Nature Mater.\uff1a\u57fa\u4e8e\u4e8c\u7ef4<\/b><\/strong><strong><b>COF<\/b><\/strong><strong><b>\u7684\u5bfc\u70ed\u8d85\u4f4ek\u7535\u4ecb\u8d28\u5c42<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u7531\u4e8e\u5fae\u5904\u7406\u5668\u7684\u7279\u70b9\u662f\u5c0f\u578b\u5316\uff0c\u4f4e\u4ecb\u7535\u5e38\u6570(\u4f4ek)\u6750\u6599\u662f\u5fc5\u8981\u7684\uff0c\u4ee5\u9650\u5236\u7535\u5b50\u4e32\u6270\uff0c\u7535\u8377\u79ef\u7d2f\u548c\u4fe1\u53f7\u4f20\u64ad\u5ef6\u8fdf\u3002\u7136\u800c\uff0c\u6240\u6709\u5df2\u77e5\u7684\u4f4ek\u4ecb\u8d28\u90fd\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u5bfc\u70ed\u6027\uff0c\u8fd9\u4f7f\u5f97\u9ad8\u529f\u7387\u5bc6\u5ea6\u82af\u7247\u7684\u6563\u70ed\u590d\u6742\u5316\u3002\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u914d\u5408\u7269\u6846\u67b6\u6750\u6599\u5177\u6709\u6a21\u5757\u5316\u7ed3\u6784\uff0c\u80fd\u591f\u8fdb\u884c\u5206\u5b50\u7ea7\u522b\u7cbe\u786e\u63a7\u5236\uff0c\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u5b54\u9053\u7ed3\u6784\u548c\u5c42\u72b6\u7247\u72b6\u5f62\u8c8c\u3002\u8fd9\u4e9b\u6027\u8d28\u5bfc\u81f4\u4f20\u7edf\u805a\u5408\u7269\u4e2d\u96be\u4ee5\u5b9e\u73b0\u7684\u7269\u7406\u6027\u8d28\uff0c\u6bd4\u5982\u8f83\u9ad8\u7684\u70ed\u673a\u68b0\u7a33\u5b9a\u6027\u3001\u8f83\u4f4e\u7684\u5bc6\u5ea6\u3002\u5728\u6b64\uff0c\u7f8e\u56fd\u897f\u5317\u5927\u5b66William R. Dichtel\u3001\u5f17\u5409\u5c3c\u4e9a\u5927\u5b66Patrick E. Hopkins\u6559\u6388\u7b49\u62a5\u9053\u4e86\u5236\u5907\u9ad8\u54c1\u8d28COF\u8584\u819c\uff0c\u968f\u540e\u5bf9\u9ad8\u8d28\u91cfCOF\u8584\u819c\u8003\u5bdf\u70ed\u8c03\u5236\u53cd\u5c04\u8c31TR\u3001\u963b\u6297\u6027\u80fd\u3002\u6d4b\u8bd5\u7ed3\u679c\u53d1\u73b0\uff0c2D COF\u8584\u819c\u5c55\u793a\u4e86\u8fbe\u52301 W m<sup>-1<\/sup>\u00a0K<sup>-1<\/sup>\u7684\u5bfc\u70ed\u6027\u80fd\uff0c\u8d85\u4f4e\u7684\u4ecb\u7535\u5e38\u6570k=1.6\u3002\u7531\u4e8eCOF\u7ed3\u6784\u3001\u7ec4\u6210\u53d8\u5316\u591a\u79cd\u591a\u6837\uff0c\u4e3a\u53d1\u5c55\u5404\u79cd\u6027\u80fd\u63d0\u4f9b\u53ef\u80fd\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u5c42\u72b62D COF\u662f\u6709\u5e0c\u671b\u7684\u4e0b\u4e00\u4ee3\u4ecb\u7535\u5c42\uff0c\u8fd9\u79cd\u6548\u679c\u6709\u671b\u5728\u9ad8\u6027\u80fd\u82af\u7247\u4e2d\u5c55\u793a\u5e94\u7528\u524d\u666f\uff0c\u53ef\u80fd\u89e3\u51b3\u6469\u5c14\u5b9a\u5f8b\u8fbe\u5230\u6781\u9650\u7684\u95ee\u9898\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cThermally conductive ultra-low-k\u00a0dielectric layers based on two-dimensional covalent organic frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Mater.\u4e0a\u3002DOI: 10.1038\/s41563-021-00934-3<\/p>\n<p>\u56fe1 COF\u8584\u819c\u7684\u5149\u7535\u7279\u6027<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220934\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-7-4.png\" alt=\"\" width=\"600\" height=\"215\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-7-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-7-4-300x108.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Nature Chem.\uff1aMOF<\/b><\/strong><strong><b>\u5d4c\u5165\u8102\u8d28\u4f53\u4fc3\u8fdb\u6574\u4f53\u5149\u50ac\u5316\u6c34\u5206\u89e3<\/b><\/strong><\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5728\u6790\u6c22\u53cd\u5e94(HER)\u548c\u6c34\u6c27\u5316\u53cd\u5e94(WOR)\u4e2d\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u4f46\u4f7f\u7528MOFs\u8fdb\u884c\u6574\u4f53\u7684\u5149\u50ac\u5316\u6c34\u5206\u89e3\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\uff0c\u4e3b\u8981\u662f\u56e0\u4e3a\u5149\u751f\u6210\u7684\u7535\u5b50\u548c\u7a7a\u7a74\u5feb\u901f\u91cd\u7ec4\u3002\u5728\u8fd9\u91cc\uff0c\u53a6\u95e8\u5927\u5b66\u6c6a\u9a8b\u6559\u6388\u8bfe\u9898\u7ec4\u901a\u8fc7\u5c06HER-MOF\u548cWOR-MOF\u5206\u522b\u7ec4\u88c5\u5728\u8102\u8d28\u4f53\u7684\u758f\u6c34\u548c\u4eb2\u6c34\u533a\u57df\uff0c\u5229\u7528\u6c27\u5316\u8fd8\u539f\u578b\u7684\u7a7f\u68ad\u7269\u8d28Fe<sup>3+<\/sup>\u548c\u56db\u6c2f\u82ef\u918c\u5c06\u4e24\u4e2a\u53cd\u5e94\u4e32\u8054\u8d77\u6765\uff0c\u51cf\u5c11\u5149\u751f\u7535\u8377\u590d\u5408\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u5149\u50ac\u5316\u5168\u5206\u89e3\u6c34\uff0c\u8868\u89c2\u91cf\u5b50\u4ea7\u7387\u8fbe\u5230\u4e861.5\u00b11%\u3002\u672c\u5de5\u4f5c\u901a\u8fc7\u6a21\u4eff\u81ea\u7136\u5149\u5408\u4f5c\u7528\u7cfb\u7edf\uff0c\u5b9e\u73b0\u4e86\u5149\u50ac\u5316\u6c34\u5206\u89e3\uff0c\u4e3a\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u7684\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cMetal\u2013organic frameworks embedded in a liposome facilitate overall photocatalytic water splitting\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Chem.\u4e0a\u3002DOI: 10.1038\/s41557-020-00635-5<\/p>\n<p>\u56fe2 \u7528\u4e8e\u6574\u4f53\u5149\u50ac\u5316\u6c34\u5206\u89e3\u7684LP-MOF\u7684\u7ed3\u6784<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220925\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1-7.png\" alt=\"\" width=\"600\" height=\"506\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1-7-300x253.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Nature Chem.\uff1a\u52a8\u6001\u6676\u4f53\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5076\u6781\u5e8f<\/b><\/strong><\/p>\n<p>\u4e24\u6027\u52a8\u6001\u6676\u4f53(Amphidynamic crystal)\u5177\u6709\u7ed3\u6676\u6027\u548c\u652f\u6301\u52a8\u529b\u5b66\u884c\u4e3a\uff0c\u975e\u5e38\u9002\u5408\u4e8e\u7814\u7a76\u52a8\u6001\u90e8\u5206\u8026\u5408\u6240\u4ea7\u751f\u7684\u6d8c\u73b0\u73b0\u8c61\u3002\u5728\u8fd9\u91cc\uff0c\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821Y.-S. Su, I. Liepuoniute, S. E. Brown, M. A. Garcia-Garibay\u7b49\u5c06\u5076\u6781\u8f6c\u5b50\u5d4c\u5165\u6676\u4f53\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\uff0c\u5f97\u5230\u7531Zn(II)\u8282\u70b9\u3001\u4e24\u79cd\u53cc\u4eb2\u6027\u53cc\u73af[2.2.2]\u8f9b\u70f7\u8fde\u63a5\u4f53\u7ec4\u6210\u3002\u51b7\u5374\u8fc7\u7a0b\u4e2d\uff0c\u8fd9\u4e9b\u8fde\u63a5\u4f53\u7531\u4e8e\u76f8\u5173\u7684\u5076\u6781-\u5076\u6781\u76f8\u4e92\u4f5c\u7528\u800c\u96c6\u4f53\u6392\u5217\u3002\u5f53\u4e00\u4e2a\u5feb\u901f\u65cb\u8f6c\u7684\u3001\u5076\u6781\u65e0\u5e8f\u7684\u526f\u7535\u76f8\u8f6c\u53d8\u4e3a\u6709\u5e8f\u7684\u3001\u53cd\u94c1\u7535\u7684\u76f8\uff0c\u5176\u4e2d\u65cb\u8f6c\u8fde\u63a5\u5668\u7684\u5076\u6781\u77e9\u5f88\u5927\u7a0b\u5ea6\u4e0a\u76f8\u4e92\u62b5\u6d88\u65f6\uff0c\u53ef\u53d8\u6e29\u5ea6\u3001\u9891\u7387\u76f8\u5173\u7684\u4ecb\u7535\u6d4b\u91cf\u63ed\u793a\u4e86\u8f6c\u53d8\u6e29\u5ea6T<sub>c<\/sub>= 100 K\u3002\u5728\u4e8c\u7ef4\u65cb\u8f6c\u6676\u683c\u4e0a\u7684\u8499\u7279\u5361\u7f57\u6a21\u62df\u663e\u793a\u4e86\u5177\u6709\u4f0a\u8f9b\u5bf9\u79f0\u6027\u7684\u57fa\u6001\u4ee5\u53ca\u5076\u6781-\u6676\u683c\u548c\u5076\u6781-\u5076\u6781\u76f8\u4e92\u4f5c\u7528\u7684\u5f71\u54cd\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cDipolar order in an amphidynamic crystalline metal\u2013organic framework through<\/p>\n<p>reorienting linkers\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature Chem.\u4e0a\u3002DOI: 10.1038\/s41557-020-00618-6<\/p>\n<p>\u56fe3 (F<sub>2<\/sub>-BODCA)-MOF\u7684\u590d\u4ecb\u7535\u54cd\u5e94<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220926\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_2-1.png\" alt=\"\" width=\"600\" height=\"881\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_2-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_2-1-204x300.png 204w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>AFM\uff1a\u57fa\u4e8e\u79bb\u5b50\u6db2\u4f53\/MOF\u590d\u5408\u6750\u6599\u7684\u5370\u5237\u7535\u5bb9\u4f20\u611f\u5668\u7528\u4e8eVOC\u68c0\u6d4b<\/b><\/strong><\/p>\n<p>\u897f\u73ed\u7259\u5df4\u65af\u514b\u6750\u6599\u4e2d\u5fc3Eduardo Fernandez,Stefan Wuttke\uff0cRoberto Fern\u00e1ndez de Luis\u7b49\u4eba\u5229\u7528\u4e8c\u7ef4\u6253\u5370\u6280\u672f\u5728\u79bb\u5b50\u6db2\u4f53(IL)\/\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u590d\u5408\u6750\u6599\u5236\u5907\u8584\u819c\u6c14\u4f53\u4f20\u611f\u5668\u3002\u4e3a\u4e86\u5b9e\u73b0\u8fd9\u4e00\u70b9\uff0cMOF\u662f\u7528\u6eb6\u5242\u70ed\u5408\u6210\u7684\uff0c\u5e76\u4e0eIL\u6d78\u6e0d\u3002IL\/MOF\u7684\u7ed3\u6784\u548c\u57fa\u672c\u6027\u8d28\u5229\u7528\u70ed\u3001\u5149\u8c31\u548cx\u5c04\u7ebf\u884d\u5c04\u6280\u672f\u8fdb\u884c\u4e86\u8868\u5f81\uff0c\u5e76\u901a\u8fc7\u963b\u6297\u8c31\u5bf9\u6750\u6599\u7684\u5408\u6210\u4f20\u611f\u80fd\u529b\u8fdb\u884c\u4e86\u8bc4\u4f30\u3002\u7136\u540e\uff0cIL\/MOF\u7cfb\u7edf\u901a\u8fc7\u55b7\u6d82\u96c6\u6210\u52302D\u6253\u5370\u94f6\u7535\u5bb9\u7535\u8def\u4e2d\uff0c\u5e76\u5728\u5b9a\u5236\u7684\u6c14\u4f53\u6d41\u52a8\u88c5\u7f6e\u4e0a\u8fdb\u884c\u6d4b\u8bd5\u3002\u57fa\u4e8eIL\/MOF\u7684\u4f20\u611f\u5668\u66b4\u9732\u4e8e\u6c34\u3001\u4e19\u916e\u548c\u4e59\u9187\u4f1a\u5bfc\u81f4\u7535\u5bb9\u7684\u91cd\u590d\u53d8\u5316(\u4ece0.05\u52307 pF)\u3002\u57fa\u4e8eIL\/MOF\u7684\u4f20\u611f\u5668\u53ef\u4ee5\u5728\u4e0d\u5230\u4e00\u79d2\u7684\u65f6\u95f4\u5185\u68c0\u6d4b\u6d53\u5ea6\u572810k-100k ppm\u8303\u56f4\u5185\u7684\u53d8\u5316\u3002\u8fd9\u9879\u5de5\u4f5c\u7684\u7ed3\u8bba\u662f\u53d1\u5c55\u57fa\u4e8eIL\/MOF\u6750\u6599\u76842D\u6253\u5370\u4f20\u611f\u5668\u7684\u7b2c\u4e00\u6b65\u3002\u5e76\u4e14\u63d0\u4f9b\u4e86\u53ef\u80fd\u6027\u6765\u8c03\u6574\u5b54\u9699\u5ea6\u3001\u5316\u5b66\u3001\u9009\u62e9\u6027\u548c\u7535\u54cd\u5e94\uff0c\u4f7f\u4f20\u611f\u5668\u9002\u5408\u4e8e\u68c0\u6d4b\u6240\u9700\u8981\u7684\u5206\u6790\u7269\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cPrinted Capacitive Sensors Based on Ionic Liquid\/Metal\u00a0Organic Framework Composites for Volatile Organic Compounds Detection\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202010703<\/p>\n<p>\u56fe4 IL\/MOF\u4f20\u611f\u5668\u5408\u6210\u793a\u610f\u56fe\u53ca\u5176\u4f5c\u4e3a\u6c14\u4f53\u68c0\u6d4b\u6253\u5370\u4f20\u611f\u5668\u7684\u5e94\u7528<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220927\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_3.png\" alt=\"\" width=\"600\" height=\"173\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_3-300x87.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>AFM\uff1a\u53ef\u8c03<\/b><\/strong><strong><em><b><i>p<\/i><\/b><\/em><\/strong><strong><b>\u5e26\u53cc\u529f\u80fdCOF\u57fa\u7535\u50ac\u5316\u5242\u7528\u4e8e\u53ef\u5145\u7535\u950c\u7a7a\u6c14\u7535\u6c60<\/b><\/strong><\/p>\n<p>\u7cbe\u7ec6\u63a7\u5236\u78b3\u7535\u50ac\u5316\u5242\u7684\u7269\u7406\u5316\u5b66\u7ed3\u6784\u5bf9\u6539\u5584\u53ef\u5145\u7535\u950c\u7a7a\u6c14\u7535\u6c60\u7f13\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u548c\u6790\u6c27\u53cd\u5e94(OER)\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002COFs\u56e0\u5176\u7ed3\u6784\u53ef\u88ab\u7cbe\u786e\u63a7\u5236\u800c\u88ab\u8ba4\u4e3a\u662f\u8f83\u597d\u7684\u5019\u9009\u78b3\u6750\u6599\u3002\u7136\u800c\uff0c\u5c06ORR\u548cOER\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u6d3b\u6027\u8d4b\u4e88COFs\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u5728\u6b64\uff0c\u97e9\u56fd\u6c49\u9633\u5927\u5b66Sang Uck Lee\uff0cJong-Ho Kim\u7b49\u4eba\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u5236\u5907\u4e86\u5177\u6709\u660e\u786e\u6d3b\u6027\u4f4d\u70b9\u548c\u5b54\u6d1e\u7684\u5421\u5576\u8fde\u63a5\u7684\u4e09\u55ea\u5171\u4ef7\u6709\u673a\u6846\u67b6(PTCOF)\uff0c\u5e76\u901a\u8fc7\u52a0\u5165Co\u7eb3\u7c73\u9897\u7c92(CoNP-PTCOF)\u6765\u8c03\u8282\u5176\u7535\u5b50\u7ed3\u6784\uff0c\u4ee5\u8bf1\u5bfcORR\u548cOER\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u6d3b\u6027\u3002CoNP-PTCOF\u5bf9ORR\u548cOER\u5747\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u8fc7\u7535\u538b\uff0c\u5177\u6709\u51fa\u8272\u7684\u7a33\u5b9a\u6027\u3002\u8ba1\u7b97\u6a21\u62df\u53d1\u73b0\uff0c\u4e0e\u539f\u59cb\u7684PTCOF\u76f8\u6bd4\uff0cCoNP-PTCOF\u7684p\u5e26\u4e2d\u5fc3\u7531\u4e8e\u7535\u8377\u8f6c\u79fb\u800c\u4e0b\u79fb\uff0c\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u66f4\u6709\u5229\u4e8e\u6c27\u4e2d\u95f4\u4f53\u5728\u5421\u5576\u78b3\u6d3b\u6027\u4f4d\u70b9\u4e0a\u7684\u5438\u9644\u548c\u89e3\u5438\u3002\u4e0e\u542b\u6709\u5546\u7528Pt\/C\u548cRuO<sub>2<\/sub>\u7684\u7535\u6c60\u76f8\u6bd4\uff0c\u91c7\u7528\u53cc\u529f\u80fdCoNP-PTCOF\u7684\u950c\u7a7a\u6c14\u7535\u6c60\u5177\u67090.83 V\u7684\u5c0f\u7535\u538b\u95f4\u9699\u548c720\u6b21\u7684\u8010\u4e45\u6027\u3002\u8fd9\u79cd\u8c03\u8282COF\u7535\u50ac\u5316\u6d3b\u6027\u7684\u7b56\u7565\u53ef\u4ee5\u63a8\u5e7f\u5230\u8bbe\u8ba1\u5404\u79cd\u78b3\u7535\u50ac\u5316\u5242\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cBifunctional Covalent Organic Framework-Derived Electrocatalysts with Modulated p-Band Centers for Rechargeable Zn\u2013Air Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AFM\u4e0a\u3002DOI: 10.1002\/adfm.202101727<\/p>\n<p>\u56fe5 \u79bb\u5b50\u578bPTCOF\u7684\u7ed3\u6784\u5206\u6790<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220928\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_4.png\" alt=\"\" width=\"600\" height=\"801\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_4-225x300.png 225w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>AM\uff1a\u7535\u5316\u5b66\u6c34\u5206\u89e3\u7528MOF\u7eb3\u7c73\u7ed3\u6784\u7684\u8bbe\u8ba1<\/b><\/strong><\/p>\n<p>\u7535\u5316\u5b66\u5288\u6c34\u4f5c\u4e3a\u53d1\u5c55\u53ef\u518d\u751f\u80fd\u6e90\u7cfb\u7edf\u7684\u5173\u952e\u9014\u5f84\uff0c\u5df2\u5f15\u8d77\u4eba\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u4eba\u4eec\u8feb\u5207\u5e0c\u671b\u4e3a\u8fd9\u4e9b\u8fc7\u7a0b\u5236\u9020\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5242\uff0c\u4ee5\u964d\u4f4e\u5b83\u4eec\u7684\u8fc7\u7535\u538b\u5e76\u4fc3\u8fdb\u5b9e\u9645\u5e94\u7528\u3002\u8fd1\u5e74\u6765\uff0cMOF\u7eb3\u7c73\u7ed3\u6784\u5177\u6709\u8d85\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u53ef\u8c03\u7684\u7eb3\u7c73\u7ed3\u6784\u548c\u4f18\u5f02\u7684\u5b54\u9699\u7387\uff0c\u6210\u4e3a\u53d1\u5c55\u9ad8\u6d3b\u6027\u7535\u5316\u5b66\u6c34\u5206\u89e3\u50ac\u5316\u5242\u7684\u6709\u524d\u9014\u7684\u6750\u6599\u3002\u5728\u6b64\uff0c\u56db\u5ddd\u5927\u5b66Shuang Li\uff0cYinghan Wang\u53ca Chong Cheng\u7b49\u4eba\u4ecb\u7ecd\u4e86\u8fd1\u5e74\u6765\u5728\u5de5\u7a0bMOF\u7eb3\u7c73\u7ed3\u6784\u7684\u7814\u7a76\u4e2d\u6700\u5173\u952e\u7684\u8fdb\u5c55\uff0c\u6709\u6548\u7684\u7535\u5316\u5b66\u6c34\u5206\u88c2\u3002\u9996\u5148\uff0c\u4ece\u539f\u5b50\u548c\u5206\u5b50\u6c34\u5e73\u4e0a\uff0c\u4ece\u5316\u5b66\u6210\u5206\u4f18\u5316\u548c\u7ed3\u6784\u529f\u80fd\u5316\u4e24\u4e2a\u65b9\u9762\u5bf9MOF\u57fa\/\u884d\u751f\u7535\u50ac\u5316\u5242\u50ac\u5316\u4e2d\u5fc3\u7684\u8bbe\u8ba1\u8fdb\u884c\u4e86\u603b\u7ed3\u548c\u6bd4\u8f83\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u5feb\u901f\u7a81\u7834\u3001\u9ad8\u6d3b\u6027\u4f4d\u70b9\u7684\u8bc6\u522b\u548c\u57fa\u672c\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u63a2\u8ba8\u3002\u6700\u540e\uff0c\u5bf9\u76ee\u524d\u7684\u4e3b\u8981\u6311\u6218\u548c\u672a\u6765\u524d\u666f\u7684\u6c34\u5206\u89e3\u548c\u5546\u4e1a\u5316\u751f\u4ea7\u6c22\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5168\u9762\u7684\u8bc4\u8bba\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u672c\u6587\u5bf9MOF\u7eb3\u7c73\u7ed3\u6784\u7684\u5408\u6210\u539f\u7406\u548c\u7535\u50ac\u5316\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\uff0c\u5e76\u5c06\u5176\u5e94\u7528\u4e8e\u6c34\u5206\u89e3\u7684\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u5176\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cDesigning MOF Nanoarchitectures for Electrochemical Water Splitting\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202006042<\/p>\n<p>\u56fe6 \u7528\u4e8e\u7535\u5316\u5b66\u6c34\u5206\u89e3\u7684MOF\u7eb3\u7c73\u7ed3\u6784\u7684\u8bbe\u8ba1<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220929\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_5.png\" alt=\"\" width=\"600\" height=\"533\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_5-300x267.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>AM\uff1a\u949b\u57faMOFs\u7f3a\u9677\u589e\u5f3a\u58f0\u52a8\u529b\u764c\u75c7\u6cbb\u7597<\/b><\/strong><\/p>\n<p>\u5f00\u53d1\u9ad8\u6548\u3001\u591a\u529f\u80fd\u3001\u751f\u7269\u76f8\u5bb9\u6027\u597d\u7684\u58f0\u654f\u5242\u4ecd\u7136\u662f\u5f53\u524d\u58f0\u52a8\u529b\u6cbb\u7597(SDT)\u7684\u91cd\u70b9\u3002\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240Ziyong Cheng, Jun Lin\u7b49\u4eba\u7b80\u5355\u6784\u5efa\u4e86\u4e00\u79cd\u5177\u6709\u58f0\u654f\u5316\u6548\u679c\u663e\u8457\u6539\u5584\u7684\u5bcc\u7f3a\u9677\u949b\u57faMOF(D-MOF(Ti))\uff0c\u5e76\u5c06\u5176\u7528\u4e8e\u589e\u5f3aSDT\u3002\u4e0e\u5e38\u7528\u7684\u58f0\u654f\u5242TiO<sub>2<\/sub>\u76f8\u6bd4\uff0cD-MOF(Ti)\u7531\u4e8e\u7a84\u5e26\u9699\u7a84\uff0c\u5728\u8d85\u58f0\u7167\u5c04\u4e0b\u4ea7\u751f\u4e86\u8f83\u9ad8\u7684\u6d3b\u6027\u6c27(ROS)\uff0c\u8fd9\u4e3b\u8981\u662f\u6539\u5584\u4e86\u8d85\u58f0\u89e6\u53d1\u7684\u7535\u5b50-\u7a7a\u7a74\u5206\u79bb\u3002\u540c\u65f6\uff0c\u7531\u4e8eTi<sup>3+<\/sup>\u79bb\u5b50\u7684\u5b58\u5728\uff0cD-MOF(Ti)\u4e5f\u8868\u73b0\u51fa\u4e86\u9ad8\u6c34\u5e73\u7684\u82ac\u987f\u6d3b\u6027\uff0c\u53ef\u4ee5\u8fdb\u884c\u5316\u7597\u3002\u7279\u522b\u662f\u8d85\u58f0\u4f5c\u4e3aSDT\u7684\u6fc0\u53d1\u6e90\uff0c\u53ef\u4ee5\u540c\u65f6\u589e\u5f3a\u82ac\u987f\u53cd\u5e94\uff0c\u5b9e\u73b0\u80bf\u7624\u6cbb\u7597\u7684\u663e\u8457\u534f\u540c\u6548\u679c\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0cD-MOF(Ti)\u5728\u5b8c\u6210\u6cbb\u7597\u529f\u80fd\u540e\u53ef\u964d\u89e3\u4ee3\u8c22\u51fa\u4f53\u5916\uff0c\u65e0\u8131\u9776\u6bd2\u6027\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u9879\u5de5\u4f5c\u786e\u5b9a\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u58f0\u654f\u5242\uff0c\u5728\u534f\u540c\u58f0\u52a8\u529b\u548c\u5316\u5b66\u52a8\u529b\u764c\u75c7\u6cbb\u7597\u4e2d\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cConferring Ti-Based MOFs with Defects for Enhanced Sonodynamic Cancer Therapy\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AM\u4e0a\u3002DOI: 10.1002\/adma.202100333<\/p>\n<p>\u56fe7\u00a0D-MOF(Ti)\u7684\u5408\u6210\u53ca\u6297\u80bf\u7624\u6cbb\u7597\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220930\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_6.png\" alt=\"\" width=\"600\" height=\"456\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-1_6-300x228.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>E<\/b><\/strong><strong><b>n<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u567b\u5511\u8fde\u63a5\u7684<\/b><\/strong><strong><b>C<\/b><\/strong><strong><b>OF\u4fc3\u8fdb\u9502\u6709\u673a\u7535\u6c60\u7684\u5feb\u901f\u53cc\u7535\u5b50\u8f6c\u79fb<\/b><\/strong><\/p>\n<p>\u5171\u4ef7\u6709\u673a\u6846\u67b6(COFs)\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u591a\u7528\u9014\u7535\u6781\u7ed3\u6784\uff0c\u5982\u679c\u5b83\u4eec\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u548c\u67d4\u6027\u6765\u7a33\u5b9a\u6c27\u5316\u8fd8\u539f\u529f\u80fd\u3002\u5c3d\u7ba1\u5728\u6982\u5ff5\u4e0a\u662f\u53ef\u884c\u7684\uff0c\u4f46\u8fc4\u4eca\u4e3a\u6b62\uff0c\u57fa\u4e8eCOF\u7684\u7535\u6781\u5f88\u5c11\u6ee1\u8db3\u9ad8\u5bb9\u91cf\u3001\u5faa\u73af\u6027\u548c\u901f\u7387\u80fd\u529b\u3002\u97e9\u56fd\u9ad8\u7b49\u79d1\u5b66\u6280\u672f\u5b66\u9662Woo Youn Kim\uff0cHye Ryung Byon\u7b49\u4eba\u5c06\u567b\u5511\u57fa\u7ed3\u5408\u5230\u6709\u673a\u652f\u67b6\u4e2d\uff0c\u53ef\u4ee5\u5236\u5907\u03c0\u5171\u8f6d\u6676\u4f53\u6709\u673a\u7535\u6781\uff0c\u5e76\u5229\u7528\u5076\u6c2e\u529f\u80fd\u5b9e\u73b0\u53cc\u7535\u5b50\u5feb\u901f\u8f6c\u79fb\u3002\u567b\u5511\u94feCOF\u7535\u6781\u572810\u2103\u4e0b\u5faa\u73af\u4f7f\u7528\u8d85\u8fc75000\u6b21\uff0c\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u9ad8\u7684\u5e73\u9762\u5916\u7535\u5bfc\u7387\uff0c\u83b7\u5f97\u4e86\u22482800 W kg<sup>\u22121<\/sup>\u7684\u9ad8\u529f\u7387\u5bc6\u5ea6\u3002\u7531\u4e8e\u7f3a\u4e4f\u7ed3\u6784\u7a33\u5b9a\u6027\uff0cCOF\u652f\u94fe\u03b2-\u916e\u70ef\u80fa\u548c\u4e9a\u80fa\u7684COF\u8868\u73b0\u4e0d\u4f73\u3002\u5728\u672c\u7814\u7a76\u4e2d\uff0c\u8bc1\u660e\u4e86\u826f\u597d\u914d\u4f53\u7684\u8bbe\u8ba1COFs\u662f\u7a33\u5b9a\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u5173\u952e\uff0c\u5c55\u793a\u4e86\u6784\u5efa\u9ad8\u6027\u80fd\u9502\u6709\u673a\u7535\u6c60COF\u7535\u6781\u7684\u57fa\u672c\u539f\u7406\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cThiazole-Linked Covalent Organic Framework Promoting Fast Two-Electron Transfer for Lithium-Organic Batteries\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728AEnM\u4e0a\u3002DOI: 10.1002\/aenm.202003735<\/p>\n<p>\u56fe8\u00a0\u4e09\u4e2a\u5076\u6c2e\u57faCOF\u7ed3\u6784<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-220931\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-2-7.png\" alt=\"\" width=\"600\" height=\"454\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-2-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/04\/\u56fe\u7247-2-7-300x227.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>J<\/b><\/strong><strong><b>ACS<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>Vis &#8211; 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