{"id":220683,"date":"2021-04-17T06:58:29","date_gmt":"2021-04-16T22:58:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=220683"},"modified":"2021-04-16T19:58:39","modified_gmt":"2021-04-16T11:58:39","slug":"%e5%8c%97%e8%88%aanat-commun-%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bd%e9%92%be%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%94%a8%e6%97%a0%e7%bc%ba%e9%99%b7%e9%93%81%e6%b0%b0%e5%8c%96%e9%94%b0%e9%92%be","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=220683","title":{"rendered":"\u5317\u822aNat. Commun.\uff1a\u9ad8\u6027\u80fd\u94be\u79bb\u5b50\u7535\u6c60\u7528\u65e0\u7f3a\u9677\u94c1\u6c30\u5316\u9530\u94be\u6b63\u6781\u6750\u6599"},"content":{"rendered":"
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Commun.<\/b><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe1 <\/strong>K<\/b><\/strong>2<\/b><\/sub><\/strong>Mn[Fe(CN)<\/b><\/strong>6<\/b><\/sub><\/strong>]<\/b><\/strong>\u7684\u5408\u6210\u9014\u5f84<\/strong> \u65e0\u87af\u5408\u5242\uff08a\uff09\u548c\u4f7f\u7528EDTA\u87af\u5408\u5242\uff08b\uff09\u7684\u5171\u6c89\u6dc0\u6cd5\u5408\u6210\u94c1\u6c30\u5316\u9530\u94be\uff08K2<\/sub>Mn[Fe(CN)6<\/sub>]\u7684\u793a\u610f\u56fe\u53ca\u5f97\u5230\u7684\u6750\u6599\u7684SEM\u56fe\u7247\u3002<\/p>\n \u56fe2 KMF-EDTA\u7684\u8868\u5f81<\/strong> a, b\uff09\u00a0KMF-EDTA\u6837\u54c1\u7684Rietveld\u7cbe\u4feeXRD\u56fe\u8c31\uff08a\uff09\u548c\u6676\u4f53\u7ed3\u6784\u56fe\uff08b\uff09\u3002<\/p>\n c\uff09KMF-EDTA\u6837\u54c1\u5728N2<\/sub>\u4e2d\u6d4b\u8bd5\u7684TGA\u66f2\u7ebf\u3002<\/p>\n 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d\uff0ce\uff09KMF-EDTA||Cyc-\u77f3\u58a8\u5168\u7535\u6c60\u5728\u6052\u5b9a\u7684\u5145\u7535\u6bd4\u7535\u6d41\uff080.03 A g-1<\/sup>\uff09\u548c\u4e0d\u540c\u7684\u653e\u7535\u6bd4\u7535\u6d41\uff080.03~1.0 A g-1<\/sup>\uff09\u4e0b\u7684\u989d\u5b9a\u5bb9\u91cf\uff08d\uff09\u548c\u7535\u538b\u66f2\u7ebf\uff08e\uff09<\/p>\n f\uff0cg\uff09KMF-EDTA||Cyc-\u77f3\u58a8\u5168\u7535\u6c60\u572830 mA g-1<\/sup>\u4e0b\u7684\u957f\u671f\u5faa\u73af\u7a33\u5b9a\u6027\uff08f\uff09\u548c\u7535\u538b\u66f2\u7ebf\uff08g\uff09\u3002\u6839\u636eKMF-EDTA\u5728\u5168\u7535\u6c60\u4e2d\u7684\u8d28\u91cf\u8ba1\u7b97\u51fa\uff08b-g\uff09\u4e2d\u7684\u6bd4\u7535\u6d41\u548c\u6bd4\u5bb9\u91cf\u3002<\/p>\n h\uff09\u4e00\u4e9b\u62a5\u9053\u7684K\u79bb\u5b50\u5168\u7535\u6c60\u7684\u5e73\u5747\u653e\u7535\u7535\u538b\u548c\u6bd4\u80fd\u91cf\u4e0e\u5bb9\u91cf\u7684\u5173\u7cfb\u3002\u6ce8\u610f\uff1ah\u7684\u5bb9\u91cf\u548c\u6bd4\u80fd\u91cf\u5747\u662f\u6839\u636e\u76f8\u5e94\u5168\u7535\u6c60\u4e2d\u6b63\u6781\u548c\u8d1f\u6781\u6750\u6599\u7684\u603b\u8d28\u91cf\u8ba1\u7b97\u7684\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u56e2\u961f\u501f\u52a9EDTA\u5408\u6210\u4e86\u4e00\u79cd\u7f3a\u9677\u548c\u6b8b\u4f59\u6c34\u542b\u91cf\u8d85\u4f4e\u7684\u94c1\u6c30\u5316\u9530\u94be\uff0c\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\u5b83\u662f\u4e00\u79cd\u5f88\u6709\u524d\u9014\u7684KIBs\u6b63\u6781\u6750\u6599\u3002\u5236\u5907\u7684KMF-EDTA\u6837\u54c1\u8868\u73b0\u51fa154.7 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\u3001\u9ad8\u5e73\u5747\u653e\u7535\u7535\u538b\uff083.941 V vs. K+<\/sup>\/K\uff09\u548c609.7 Wh kg-1<\/sup>\u7684\u9ad8\u6bd4\u80fd\u91cf\u3002\u5728\u4e0d\u540c\u7684\u6bd4\u7535\u6d41\u4e0b\u8868\u73b0\u51fa\u8d85\u5f3a\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c7800\u6b21\u5faa\u73af\u540e\u5b9e\u73b0\u4e8680%\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u5b9e\u9a8c\u7814\u7a76\u548c\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u6837\u54c1\u4f18\u826f\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u5f52\u56e0\u4e8e\u5176\u65e0\u7f3a\u9677\u7684\u7ed3\u6784\u548c\u53ef\u5ffd\u7565\u7684\u542b\u6c34\u91cf\uff0c\u6709\u6548\u5730\u7f13\u89e3\u4e86\u9530\u79bb\u5b50\u7684\u6eb6\u89e3\u548c\u4e0e\u6c34\u76f8\u5173\u7684\u526f\u53cd\u5e94\u7b49\u95ee\u9898\u3002\u7ec4\u88c5\u7684KMF-EDTA ||\u77f3\u58a8\u5168\u7535\u6c60\u53ef\u4ee5\u63d0\u4f9b331.5 Wh kg-1<\/sup>\u7684\u9ad8\u6bd4\u80fd\u91cf\uff0c92.8%\u7684\u9ad8\u80fd\u91cf\u6548\u7387\u5e76\u5728300\u6b21\u5faa\u73af\u540e\u672a\u51fa\u73b0\u5bb9\u91cf\u8870\u51cf\uff0c\u8fd9\u8868\u660e\u4f4e\u6210\u672c\u548c\u9ad8\u6027\u80fd\u7684KIBs\u5728\u5bf9\u80fd\u91cf\u5bc6\u5ea6\u8981\u6c42\u4e0d\u9ad8\u7684\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u6709\u5f88\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n \u4e0a\u8ff0\u5de5\u4f5c\u5f97\u5230\u4e2d\u7ec4\u90e8\u9ad8\u5c42\u6b21\u4eba\u624d\u9752\u5e74\u9879\u76ee\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u79d1\u5b66\u57fa\u91d1\u7684\u8d44\u52a9\u3002<\/p>\n<\/p>\n
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