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Mater.<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n \u56fe\u4e00\u3001SiOx<\/sub>\/C HS-TA\u3001SiOx<\/sub>\/C HS-GA\u548cSiOx<\/sub>\/C HS-GL\u7684\u5408\u6210\u8def\u7ebf\u793a\u610f\u56fe<\/strong> b-c\uff09SiOx<\/sub>\/C HS-TA\uff1b<\/p>\n d\uff09PHS-GA\uff1b<\/p>\n e-f\uff09SiOx<\/sub>\/C HS-GA\uff1b<\/p>\n g\uff09PHS-GL\uff1b<\/p>\n h-i\uff09SiOx<\/sub>\/C HS-GL\u3002<\/p>\n \u56fe\u4e09\u3001PHSs\u548cSiOx<\/sub>\/C HS\u7684TEM\u56fe\u548c\u5143\u7d20\u5206\u5e03<\/strong> b-c\uff09SiOx<\/sub>\/C HS-TA\uff1b<\/p>\n e\uff09PHS-GA\uff1b<\/p>\n f-g\uff09SiOx<\/sub>\/C HS-GA\uff1b<\/p>\n i\uff09PHS-GL\uff1b<\/p>\n j-k\uff09SiOx<\/sub>\/C HS-GL\uff1b<\/p>\n d\uff09SiOx<\/sub>\/C HS-TA\u7684HAADF-STEM\u548cC\u3001O\u548cSi\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n h\uff09SiOx<\/sub>\/C HS-GA\u7684HAADF-STEM\u548cC\u3001O\u548cSi\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n l\uff09SiOx<\/sub>\/C HS-GL\u7684HAADF-STEM\u548cC\u3001O\u548cSi\u5143\u7d20\u5206\u5e03\u56fe\u3002<\/p>\n \u56fe\u56db\u3001PHSs\u548cSiOx<\/sub>\/C HS\u7684\u7ed3\u6784\u8868\u5f81<\/strong> b\uff09PHS-TA\u548cSiOx<\/sub>\/C HS-TA\u768429<\/sup>Si MAS-NMR\u8c31\uff1b<\/p>\n c-d\uff09SiOx<\/sub>\/C HS-TA\u3001SiOx<\/sub>\/C HS-GA\u548cSiOx\/C HS-GL\u7684Si 2p\u548cC 1s XPS\u8c31\uff1b<\/p>\n e\uff09SiOx<\/sub>\/C HS-TA\u3001SiOx<\/sub>\/C HS-GA\u548cSiOx<\/sub>\/C HS-GL\u7684TGA\u66f2\u7ebf\uff1b<\/p>\n f-g\uff09SiOx<\/sub>\/C HS-TA-HF\u3001SiOx<\/sub>\/C HS-GA-HF\u548cSiOx<\/sub>\/C HS-GL-HF\u7684N2<\/sub>\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\u548c\u5b54\u5f84\u5206\u5e03\u66f2\u7ebf\uff1b<\/p>\n h\uff09SiOx<\/sub>\/C HS-TA-HF\u7684STEM\u56fe\u50cf\u3002<\/p>\n \u56fe\u4e94\u3001SiOx<\/sub>\/C\u8d1f\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong> b-c\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a0.1 A g-1<\/sup>\u65f6\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4f26\u6548\u7387\uff1b<\/p>\n d\uff09\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a1.0 A g-1<\/sup>\u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n e\uff09\u57281000\u6b21\u5faa\u73af\u6d4b\u8bd5\u4e2d\uff0c\u6bcf100\u6b21\u5faa\u73af\u7684GCD\u66f2\u7ebf\u3002<\/p>\n \u56fe\u516d\u3001SiOx<\/sub>\/C\u8d1f\u6781\u7684\u4e0d\u540c\u626b\u63cf\u901f\u7387\u7684\u7535\u5bb9\u548c\u6269\u6563\u63a7\u5236\u8d21\u732e\u7684\u767e\u5206\u6bd4<\/strong> b\uff09\u6b63\u6781\u5cf0\u548c\u8d1f\u6781\u5cf0\u7684Log(i)\u4e0e\u6570Log(V)\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n c\uff09\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7535\u5bb9\u6027\u548c\u6269\u6563\u63a7\u5236\u6027\u8d21\u732e\u7684\u767e\u5206\u6bd4\uff1b<\/p>\n d\uff09\u5728\u626b\u9762\u901f\u7387\u4e3a1.0 mV s-1<\/sup>\u65f6\u7684\u7535\u5bb9\u8d21\u732e;<\/p>\n e\uff09GITT\u5256\u9762\u56fe\uff1b<\/p>\n f\uff09\u6839\u636eGITT\u5256\u9762\u56fe\u8ba1\u7b97\u5f97\u51fa\u7684D<\/em>Li+<\/sub>\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u805a\u5408\u7b56\u7565\uff0c\u53ef\u5408\u6210\u7528\u4e8eSiOx<\/sub>\/C\u4e2d\u7a7a\u9897\u7c92\u7684PHSs\u524d\u9a71\u4f53\u3002\u5229\u7528APTES\u548c\u4e8c\u919b\u5206\u5b50\u4f5c\u4e3a\u7845\u6e90\u548c\u4ea4\u8054\u5242\u7684\u5206\u5b50\u805a\u5408\u7b56\u7565\uff0c\u4f5c\u8005\u6210\u529f\u7684\u5236\u5907\u51fa\u4e86PHSs\uff0c\u800c\u65e0\u9700\u4efb\u4f55\u6a21\u677f\u548c\u6dfb\u52a0\u5242\u3002\u901a\u8fc7\u5728\u805a\u5408\u8fc7\u7a0b\u4e2d\u8c03\u63a7\u4e8c\u919b\u5206\u5b50\uff08TA\u3001GA\u548cGL\uff09\uff0c\u53ef\u8f7b\u6613\u7684\u5236\u5907\u4e00\u7cfb\u5217\u5f62\u6001\u3001\u5c3a\u5bf8\u548c\u78b3\u542b\u91cf\u53ef\u8c03\u8282\u7684PHSs\u3002\u6b64\u5916\uff0c\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e4b\u540e\uff0cPHSs\u4e2d\u7684\u6709\u673a\u7845\u548c\u6709\u673a\u78b3\u88ab\u539f\u4f4d\u8f6c\u5316\u4e3aSiOx<\/sub>\u5355\u5143\u548c\u78b3\u57fa\u8d28\uff0c\u5e76\u7ee7\u627f\u4e86\u4e2d\u7a7a\u7ed3\u6784\uff0c\u4ee5\u53ca\u786e\u4fdd\u4e86SiOx<\/sub>\u7eb3\u7c73\u56e2\u7c07\u5747\u5300\u5206\u6563\u5728\u7684\u78b3\u58f3\u4e2d\u3002\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0cSiOx<\/sub>\/C\u4e2d\u7a7a\u9897\u7c92\u63d0\u4f9b\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u5e93\u4ed1\u6548\u7387\u7b49\u9502\u79bb\u5b50\u5b58\u50a8\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u7684\u5168\u65b0\u53d1\u73b0\u4e3a\u5408\u6210\u57fa\u4e8eSi\u7684\u4e2d\u7a7a\u8d1f\u6781\u63d0\u4f9b\u4e86\u53ef\u6269\u5c55\u4e14\u53ef\u63a7\u5236\u7684\u7b56\u7565\uff0c\u5e76\u4e3a\u5176\u4ed6\u65e0\u6a21\u677f\u4e2d\u7a7a\u6750\u6599\u63d0\u4f9b\u4e86\u542f\u793a\u3002<\/p>\n
\n
\n \u56fe\u4e8c\u3001PHSs\u548cSiOx<\/sub>\/C HSs\u7684SEM\u56fe\u50cf<\/strong>
\n a\uff09PHS-TA\uff1b<\/p>\n
\n a\uff09PHS-TA\uff1b<\/p>\n
\n a\uff09PHS-TA\u768413<\/sup>C MAS-NMR\u8c31\uff1b<\/p>\n
\n a\uff09\u521d\u59cbGCD\u66f2\u7ebf\uff1b<\/p>\n
\n a\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n