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\u4e00\u3001\u80cc\u666f\u4ecb\u7ecd<\/strong><\/p>\n

\u67d4\u6027\u9502\u79bb\u5b50\u7535\u6c60(FLIBs)\u5177\u6709\u4f18\u5f02\u7684\u7535\u5316\u5b66\u50a8\u80fd\u7279\u6027\u548c\u673a\u68b0\u6027\u80fd\u5728\u4f17\u591a\u9886\u57df\u5747\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u4e0e\u4f20\u7edf\u7684\u539a\u5806\u79ef\u7ed3\u6784LIBs\u76f8\u6bd4\uff0cFLIBs\u4e3a\u4e86\u6ee1\u8db3\u67d4\u6027\u7684\u9700\u6c42\uff0c\u901a\u5e38\u66f4\u8584\uff0c\u8fd9\u4f1a\u5bfc\u81f4\u66f4\u4f4e\u7684\u5355\u4f53\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u3002\u800c\u57fa\u4e8e\u8f6c\u5316\u578b\u50a8\u9502\u673a\u5236\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269(TMOs)\u5177\u6709\u8f83\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf(\uff1e700 mAh g-1<\/sup>)\uff0c\u88ab\u8ba4\u4e3a\u662f\u9ad8\u80fd\u91cf\u5bc6\u5ea6FLIBs\u8d1f\u6781\u6750\u6599\u7684\u5019\u9009\u8005\u3002\u4f46\u662f\uff0c\u65e0\u6cd5\u907f\u514d\u7684\u5de8\u5927\u4f53\u79ef\u53d8\u5316\u3001\u5dee\u7684\u7535\u5b50\u7535\u5bfc\u7387\u548c\u539a\u7535\u6781\u7535\u8377\u4f20\u8f93\u80fd\u529b\u5f31\u9020\u6210\u7684\u201c\u6b7b\u8d28\u91cf\u201d\u95ee\u9898\uff0c\u5747\u4e25\u91cd\u5236\u7ea6\u7740TMOs\u4f5c\u4e3aFLIBs\u7535\u6781\u6750\u6599\u7684\u5b9e\u9645\u5e94\u7528\u3002\u7136\u800c\uff0c\u5e38\u89c4\u7684\u5982\u6c34\u70ed\u53cd\u5e94\uff0c\u5316\u5b66\u6c89\u6dc0\uff0c\u79bb\u5b50\u70ed\uff0c\u6eb6\u5242\u70ed\uff0c\u6a21\u677f\u6cd5\u7b49\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u5408\u6210\u51fa\u7684\u4ea7\u7269\u662f\u7c89\u672b\u72b6\uff0c\u82e5\u5236\u4f5c\u6210\u7535\u6781\u5219\u9700\u8981\u989d\u5916\u7684\u7c98\u7ed3\u5242\u548c\u5bfc\u7535\u5242\u8f85\u52a9\uff0c\u8fd9\u53c8\u4e0d\u53ef\u907f\u514d\u5730\u9650\u5236\u4e86\u6d3b\u6027\u8868\u9762\u79ef\uff0c\u589e\u52a0\u4e86\u7535\u6781\u6574\u4f53\u201c\u6b7b \u8d28\u91cf\u201d\u7ec4\u5206\u3002\u5c3d\u7ba1\u6c34\u70ed\u6cd5\u4e5f\u80fd\u539f\u4f4d\u751f\u957f\u6d3b\u6027\u7269\u8d28\uff0c\u4f46\u96be\u4ee5\u901a\u8fc7\u8c03\u63a7\u6c34\u70ed\u6761\u4ef6\u4f7f\u5f97\u6d3b\u6027\u7269\u8d28\u8d1f\u8f7d\u91cf\u8d85\u8fc7 3 mg cm-2<\/sup>\uff0c\u5e76\u4e14\u6d3b\u6027\u7269\u8d28-\u57fa\u5e95\u9644\u7740\u529b\u8f83\u5dee\uff0c\u8fd9\u5c06\u5bfc\u81f4\u5dee\u7684\u9762\u79ef\u6bd4\u5bb9\u91cf\u548c\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u78b3\u5305\u8986\u7b56\u7565\u4f5c\u4e3a\u4e00\u79cd\u6709\u6548\u7684\u624b\u6bb5\u80fd\u589e\u5f3a\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u7535\u8377\u4f20\u8f93\u3002\u5e38\u89c4\u7684\u624b\u6bb5\u662f\u91c7\u7528\u77f3\u58a8\u70ef\u8fdb\u884c\u5305\u8986\uff0c\u4f46\u662f\u7531\u4e8e\u81ea\u652f\u6491\u7535\u6781\u5236\u5907\u7684\u7279\u6027\uff0c\u5f88\u96be\u53bb\u540c\u6b65\u5730\u751f\u957fTMOs\u548c\u77f3\u58a8\u70ef\u5728\u67d4\u6027\u57fa\u5e95\u4e0a\u3002\u6b64\u5916\uff0c\u540e\u5305\u8986\u77f3\u58a8\u70ef\u4e8eTMOs\u7684\u65b9\u5f0f\u65e0\u6cd5\u4fdd\u8bc1\u5b8c\u5168\u5f7b\u5e95\u7684\u5747\u5300\u5305\u8986\u3002\u800c\u82e5\u91c7\u7528\u6709\u673a\u5316\u5408\u7269\u5982(\u8461\u8404\u7cd6\u3001\u591a\u5df4\u80fa\u7b49)\u4f5c\u4e3a\u78b3\u6e90\uff0c\u5728\u9ad8\u6e29\u9000\u706b\u8fc7\u7a0b\u4e2d\uff0c\u5f15\u5165\u7684\u78b3\u5c42\u4f1a\u5c06TMOs\u8fd8\u539f\u6210\u91d1\u5c5e\u5355\u8d28(\u5982\uff1aNiO +C \u2192 Ni + CO)\u3002\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u78b3\u5316(< 500 \u00b0C)\u53ef\u4ee5\u907f\u514dTMOs\u88ab\u8fd8\u539f\u7684\u95ee\u9898\uff0c\u4f46\u4f4e\u6e29\u4e0b\u77f3\u58a8\u5316\u7a0b\u5ea6\u4e0d\u9ad8\u6240\u5f15\u8d77\u7684\u4f4e\u7535\u5bfc\u7387\uff0c\u4ee4\u4eba\u9057\u61be\u5730\u6781\u5927\u51cf\u5f31\u4e86\u7684\u78b3\u5305\u8986\u7684\u529f\u6548\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u5b9e\u73b0\u9ad8\u6027\u80fd\u78b3\u5305\u8986TMOs\u81ea\u652f\u6491\u8d1f\u6781\u7528\u4e8eFLIBs\uff0c\u8feb\u5207\u9700\u8981\u4e00\u79cd\u64cd\u4f5c\u7b80\u4fbf\u3001\u6548\u679c\u4f18\u5f02\u7684\u65b0\u5236\u5907\u7b56\u7565\u3002\u9488\u5bf9\u4e8e\u6b64\uff0c\u6881\u6d4e\u5143\u526f\u6559\u6388\u8bfe\u9898\u7ec4\u57283D\u96c6\u6d41\u4f53\u8bbe\u8ba1\u548c\u81ea\u652f\u6491\u67d4\u6027\u7535\u6781\u7684\u5236\u5907\u65b9\u9762\u5df2\u5f00\u5c55\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\u3002<\/p>\n

\u4e8c\u3001\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6c5f\u6c49\u5927\u5b66\u6881\u6d4e\u5143\u526f\u6559\u6388\u548c\u53f0\u6e7e\u6e05\u534e\u5927\u5b66\u5415\u4e16\u6e90\u6559\u6388<\/strong>\u7b49\u5408\u4f5c\u5728\u56fd\u9645\u77e5\u540d\u671f\u520aAdvanced Functional Materials<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cHigh Performance Flexible Lithium-Ion Battery Electrodes: Ion Exchange Assisted Fabrication of Carbon Coated Nickel Oxide Nanosheet Arrays on Carbon Cloth<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u6c5f\u6c49\u5927\u5b66\u7855\u58eb\u7814\u7a76\u751f\u9648\u76db\u9510\u4e3a\u8be5\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u91c7\u7528\u4e00\u79cd\u65b0\u9896\u7684\u9633\u79bb\u5b50\u4ea4\u6362\u7b56\u7565\u7b80\u6613\u5730\u5408\u6210\u9ad8\u6027\u80fd\u78b3\u5305\u8986NiO\u9635\u5217\u81ea\u652f\u6491\u8d1f\u6781\u3002\u9996\u5148\u5728\u78b3\u5e03(CC)\u4e0a\u7535\u5316\u5b66\u6c89\u79efMg(OH)2<\/sub>\u7eb3\u7c73\u7247\u9635\u5217\u4f5c\u4e3a\u79bb\u5b50\u4ea4\u6362(IE)\u7684\u524d\u9a71\u4f53\uff0c\u63a5\u7740\u4ee5\u8461\u8404\u7cd6\u4e3a\u78b3\u6e90\u8fdb\u884c\u6c34\u70ed\u5305\u8986\uff0c\u5e76\u9ad8\u6e29\u78b3\u5316\u5904\u7406\u3002\u7136\u540e\u4e0eNi2+<\/sup>\u8fdb\u884c\u79bb\u5b50\u4ea4\u6362\u53cd\u5e94\uff0c\u6700\u540e\u7ecf\u4f4e\u6e29\u8131\u6c34\u5904\u7406\uff0c\u6210\u529f\u5730\u5236\u5907\u51fa\u78b3\u5305\u8986NiO-\u78b3\u5e03(C@IENiO-CC)\u81ea\u652f\u6491\u7535\u6781\u3002\u8be5\u7535\u6781\u4e09\u7ef4\u591a\u5b54\u7684\u7eb3\u7c73\u7247\u9635\u5217\u5f62\u8c8c\u589e\u5f3a\u4e86\u4e0e\u7535\u89e3\u6db2\u7684\u6d78\u6da6\u6027\uff0c\u80fd\u591f\u63d0\u4f9b\u66f4\u591a\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\uff1b\u6b64\u5916\uff0c\u4e0e\u5e38\u89c4\u78b3\u5305\u8986\u65b9\u6cd5\u4e0d\u540c\uff0c\u6b64IE\u8f85\u52a9\u78b3\u5305\u8986\u7b56\u7565\u6210\u529f\u5730\u907f\u514d\u4e86\u78b3\u5728\u9ad8\u6e29\u4e0b\u5c06NiO\u8fd8\u539f\u6210\u5355\u8d28Ni\uff0c\u786e\u4fdd\u4e86\u6d3b\u6027\u7269\u8d28NiO\u7684\u7eaf\u5ea6\uff0c\u540c\u65f6\u6709\u6548\u7684\u589e\u5f3a\u4e86NiO\u7eb3\u7c73\u7247\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u7535\u5b50\u7535\u5bfc\u7387\uff1b\u5e76\u4e14\uff0c\u6b8b\u7559\u7684Mg2+<\/sup>\u53ef\u4ee5\u5b9e\u73b0\u539f\u4f4d\u63ba\u6742NiO\uff0c\u589e\u5f3a\u4e86\u6676\u683c\u7ed3\u6784\u7684\u65e0\u5e8f\u5ea6\uff0c\u4ece\u800c\u8d77\u5230\u63d0\u5347NiO\u6676\u7c92\u7684\u7535\u5bfc\u7387\u548cLi+<\/sup>\u6269\u6563\u7387\u7684\u4f5c\u7528\u3002\u5f97\u76ca\u4e8e\u4e0a\u8ff0\u4f18\u52bf\uff0cC@IENiO-CC\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u50a8\u9502\u6027\u80fd\u3002\u57284 mg cm-2<\/sup>\u7684\u9ad8\u8f7d\u91cf\uff0c0.25 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u6761\u4ef6\u4e0b\uff0cC@IENiO-CC\u5177\u67093.08 mAh cm-2<\/sup>\u7684\u9ad8\u9762\u79ef\u6bd4\u5bb9\u91cf\uff1b\u57280.5 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7a33\u5b9a\u5faa\u73af300\u5708\u540e\uff0c\u9762\u5bb9\u91cf\u7ef4\u6301\u57282.5 mAh cm-2<\/sup>\uff1b\u5373\u4f7f\u57288 mA cm-2<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u9762\u5bb9\u91cf\u4ecd\u4fdd\u6301\u57281.78 mAh cm-2<\/sup>\u3002\u6b64\u5916\uff0c\u57fa\u4e8eC@IENiO-CC\u81ea\u652f\u6491\u7535\u6781\u5236\u4f5c\u6210\u7684\u5355\u5c42\u8f6f\u5305\u7535\u6c60\u5728\u4efb\u4f55\u5f2f\u66f2\u6216\u6298\u53e0\u6761\u4ef6\u4e0b\uff0c\u53ef\u4ee5\u7a33\u5b9a\u5730\u8d4b\u4e88\u7535\u5b50\u8bbe\u5907\u80fd\u91cf\uff0c\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u8fd9\u79cd\u7b56\u7565\u6784\u9020\u67d4\u6027\u7535\u6781\u7684\u7684\u5b9e\u7528\u6027\u3002\u56e0\u6b64\uff0c\u8fd9\u79cdIE\u8f85\u52a9\u7684\u78b3\u5305\u8986\u7b56\u7565\u5177\u6709\u5f88\u5f3a\u7684\u5e94\u7528\u524d\u666f\u3001\u53ef\u6269\u5c55\u6027\u548c\u5b9e\u7528\u6027\u3002<\/p>\n

\u4e09\u3001\u56fe\u6587\u5bfc\u8bfb<\/strong><\/p>\n

\u56fe<\/strong>1 C@IENiO-CC<\/strong>\u81ea\u652f\u6491\u7535\u6781\u5408\u6210\u793a\u610f\u56fe\u53ca\u5404\u4e2d\u95f4\u4ea7\u7269<\/strong>SEM<\/strong>\u7167\u7247<\/strong><\/p>\n

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\u56fe<\/strong>2 C@IENiO-CC<\/strong>\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

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\uff08a\uff09I\u2014Mg(OH)2<\/sub>-CC, II,III\u2014C@IENiO-CC\u7684\u6570\u7801\u7167\u7247\uff0c<\/p>\n

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\uff08c\uff09C@IENiO-CC \u653e\u5927\u7684SEM\u56fe\u50cf\uff0c<\/p>\n

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\"\"<\/p>\n

\u56db\u3001\u5c0f\u7ed3<\/strong><\/p>\n

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\u6587\u732e\u8be6\u60c5\uff1a<\/strong><\/p>\n

\u201cHigh Performance Flexible Lithium-Ion Battery Electrodes: Ion Exchange Assisted Fabrication of Carbon Coated Nickel Oxide Nanosheet Arrays on Carbon Cloth\u201d<\/strong>\uff08<\/strong>Adv. Funct. Mater. 2021, 2101199<\/strong>\uff0c<\/strong>DOI<\/strong>\uff1a<\/strong>10.1002\/adfm.202101199<\/strong>\uff09<\/strong><\/p>\n

https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202101199<\/strong><\/a><\/p>\n

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