{"id":219933,"date":"2021-03-31T06:30:23","date_gmt":"2021-03-30T22:30:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=219933"},"modified":"2021-03-30T11:34:35","modified_gmt":"2021-03-30T03:34:35","slug":"%e8%a5%bf%e5%8d%97%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6%e6%9d%a8%e7%bb%b4%e6%b8%85nano-energy%e9%80%9a%e8%bf%87%e9%85%b8%e6%80%a7%e5%88%86%e5%ad%90%e5%89%aa%e5%88%80%e8%a3%81%e5%89%aati3cntx-mxen-2","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=219933","title":{"rendered":"\u897f\u5357\u4ea4\u901a\u5927\u5b66\u6768\u7ef4\u6e05Nano Energy:\u901a\u8fc7\u9178\u6027\u5206\u5b50\u526a\u5200\u88c1\u526aTi3CNTx\u00a0MXene"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/p>\n

MXenes\u7531\u4e8e\u5176\u826f\u597d\u7684\u7535\u5bfc\u7387\uff0c\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548c\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u800c\u8d8a\u6765\u8d8a\u53d7\u5230\u79d1\u5b66\u754c\u7684\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u5bf9MXenes\u8fdb\u884c\u4fee\u9970\u7684\u65b9\u6cd5\u8d8a\u6765\u8d8a\u591a\uff0c\u7f3a\u9677\u5de5\u7a0b\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u63a7\u5236\u4e8c\u7ef4\u6750\u6599\u7684\u7535\u3001\u78c1\u3001\u7535\u5316\u5b66\u548c\u5149\u7535\u6027\u80fd\u3002\u7136\u800c\uff0c\u7531\u4e8eMXene\u7684\u72ec\u7279\u7ed3\u6784\uff0c\u5728MXene\u7eb3\u7c73\u7247\u4e0a\u7cbe\u51c6\u5730\u5f15\u5165\u7f3a\u9677\u6216\u7a7a\u4f4d\u662f\u4e00\u9879\u5177\u6709\u6311\u6218\u6027\u7684\u5de5\u4f5c\u3002<\/p>\n

\u6210\u679c\u4ecb\u7ecd<\/b><\/strong><\/p>\n

\u8fd1\u65e5\u897f\u5357\u4ea4\u901a\u5927\u5b66\u6768\u7ef4\u6e05\u6559\u6388\u56e2\u961f\u63d0\u51fa\u4e00\u79cd\u201c\u5206\u5b50\u526a\u5200\u201d\u7684\u65b9\u6cd5\u5bf9Ti3<\/sub>CNTx<\/sub>\u00a0MXenes\u8fdb\u884c\u7cbe\u51c6\u5730\u88c1\u526a\u5f97\u5230\u591a\u7f3a\u9677\u7684MXene\uff0c\u5e76\u4e14\u5c06\u5176\u5e94\u7528\u5728\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u4e0a\uff0c\u8868\u73b0\u51fa\u53ef\u89c2\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u53e6\u5916\uff0c\u5728\u6b64\u57fa\u7840\u4e0a\u6211\u4eec\u89e3\u91ca\u4e86\u5176\u673a\u7406\uff0c\u8fd9\u4e9b\u7f3a\u9677\u4f4d\u70b9\u662f\u8d28\u5b50\u5316\u53cd\u5e94\u7684\u7406\u60f3\u5e73\u53f0\uff0c\u4f7f\u8d5d\u7535\u5bb9\u53cd\u5e94\u4e2d\u7684\u8d28\u5b50\u5177\u6709\u66f4\u5f3a\u7684\u6269\u6563\u548c\u4f20\u8f93\u80fd\u529b\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cTailoring Ti3<\/sub>CNTx<\/sub>\u00a0MXene\u00a0via<\/i><\/em>\u00a0an acid molecular scissor\u201d\u53d1\u8868\u4e8eNano Energy\u671f\u520a\u4e0a\uff0c\u535a\u58eb\u7814\u7a76\u751f\u9648\u5b81\u4fca\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u897f\u5357\u4ea4\u901a\u5927\u5b66\u5f20\u6d77\u6d9b\u6559\u6388\u548c\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u9648\u4fca\u6559\u6388\u4e3a\u672c\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\u56fe1. \u9178\u6027\u5206\u5b50\u526a\u5200\u7684\u4f5c\u7528\u673a\u7406\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u00a0(a)\u591a\u6d3b\u6027\u4f4d\u70b9\u7684Ti3<\/sub>CNTx<\/sub>MXene\u7684\u8d5d\u7535\u5bb9\u53cd\u5e94\u7684\u8fc7\u7a0b\u3002(b, c) \u9178\u6027\u5206\u5b50\u526a\u5200\u4f5c\u7528\u4e0b\u5f62\u6210\u4e09\u79cd\u6d3b\u6027\u6c2e\u3002(d) Pyridinic-N\u6d3b\u6027\u4f4d\u70b9\u3002(e) N-O\u6d3b\u6027\u4f4d\u70b9\u3002(f) Pyrrolic-N\u6d3b\u6027\u4f4d\u70b9\u3002(g) Ti3<\/sub>AlCN\u7684N1s XPS\u8c31\u3002(h) Ti3<\/sub>CNTx<\/sub>\u7684N1s XPS\u8c31\u8868\u660e\u88c1\u526a\u540e\u7684Ti3<\/sub>CNTx<\/sub>\u00a0MXenes\u5177\u6709\u591a\u79cd\u6c2e\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

\u56fe2. \u88c1\u526a\u540e\u7684Ti<\/b><\/strong>3<\/b><\/sub><\/strong>CNT<\/b><\/strong>x<\/b><\/sub><\/strong>\u7684\u5f62\u8c8c\u3002<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u00a0(a) \u8f83\u5c11\u7a7a\u4f4d\u7f3a\u9677\u7684Ti3<\/sub>CNTx<\/sub>-12h\u7684HRTEM\u56fe\u50cf\u3002(b) \u591a\u6d3b\u6027\u4f4d\u70b9\u7684Ti3<\/sub>CNTx<\/sub>-24h\u7684HRTEM\u56fe\u50cf\u3002(c) Ti3<\/sub>CNTx<\/sub>-48h HRTEM\u56fe\u50cf\uff0c\u5927\u91cf\u7684\u5b54\u6d1e\u5bfc\u81f4\u7684MXene\u6676\u683c\u7578\u53d8\u7684\u3002\u6bd4\u4f8b\u5c3a\u5747\u4e3a1 nm\u3002(d) \u968f\u7740\u88c1\u526a\u7a0b\u5ea6\u7684\u589e\u52a0\uff0c\u7f3a\u9677\u5bc6\u5ea6\u589e\u52a0\u3002(e) \u4e0d\u540c\u6837\u54c1\u7684\u5c3a\u5bf8\u5206\u5e03\u3002(f) Ti3<\/sub>CNTx<\/sub>-12h\u548cTi3<\/sub>CNTx<\/sub>-24h\u7684AFM\u56fe\u50cf\u548c\u539a\u5ea6\u8f6e\u5ed3\u8868\u660e\u76f8\u8f83\u4e8e\u672a\u88c1\u526a\u7684Ti3<\/sub>CNTx<\/sub>\u00a0MXene, \u9ad8\u6d3b\u6027\u7684MXene\u7eb3\u7c73\u7247\u539a\u5ea6\u6ca1\u6709\u53d8\u5316\u3002<\/b><\/p>\n

\u56fe3. \u00a0Ti<\/b><\/strong>3<\/b><\/sub><\/strong>CNT<\/b><\/strong>x<\/b><\/sub><\/strong>\u819c\u5728H<\/b><\/strong>2<\/b><\/sub><\/strong>SO<\/b><\/strong>4<\/b><\/sub><\/strong>\u00a0(1 M)\u7535\u89e3\u8d28\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u00a0(a)Ti3<\/sub>CNTx<\/sub>-24h\u7535\u6781\u7684CV\u66f2\u7ebf\u8868\u73b0\u51fa\u5176\u5177\u6709\u66f4\u9ad8\u7684\u8d5d\u7535\u5bb9\u5bb9\u91cf\u3002(b) Ti3<\/sub>CNTx<\/sub>-12h\u7535\u6781\u7684CV\u66f2\u7ebf\u3002(c)\u7531CV\u66f2\u7ebf\u5f97\u5230\u7684\u6240\u6709\u6837\u54c1\u7684\u6bd4\u7535\u5bb9\u3002(d) Ti3<\/sub>CNTx<\/sub>-24h\u7684GCD\u66f2\u7ebf\u3002(e) Ti3<\/sub>CNTx<\/sub>-12h\u7684GCD\u66f2\u7ebf\u3002(f)\u7531GCD\u66f2\u7ebf\u5f97\u5230\u7684\u6bd4\u7535\u5bb9\u3002(g) \u6240\u6709Ti3<\/sub>CNTx<\/sub>\u7535\u6781\u7684\u5948\u594e\u65af\u7279\u56fe\u3002(h) Ti3<\/sub>CNTx<\/sub>-12h\u548cTi3<\/sub>CNTx<\/sub>-24h\u5bf9\u5e94\u7684\u672c\u5f81\u9762\u79ef\u7535\u5bb9\u3001\u5b9e\u6d4b\u9762\u79ef\u7535\u5bb9\u548c\u65f6\u95f4\u5e38\u6570\u3002(i) \u968f\u7740\u88c1\u526a\u65f6\u95f4\u7684\u589e\u52a0\uff0c\u6c2e\u542b\u91cf\u548c\u6bd4\u7535\u5bb9\u7684\u53d8\u5316\u8d8b\u52bf\u4e00\u81f4\u3002<\/p>\n

\u56fe4. Ti<\/b><\/strong>3<\/b><\/sub><\/strong>CNT<\/b><\/strong>x<\/b><\/sub><\/strong>\u5fae\u578b\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u5236\u5907\u5de5\u827a\u793a\u610f\u56fe\u53ca\u5176\u7535\u5316\u5b66\u6027\u80fd\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a-c) \u5236\u5907\u5de5\u827a\u6d41\u7a0b\u56fe\u3002(d) \u4e0d\u540c\u6307\u5bbd\u7684\u7535\u5bb9\u5668\u7684CV\u66f2\u7ebf\u3002(e) \u4e0d\u540c\u6307\u5bbd\u7535\u5bb9\u5668\u7684\u5948\u594e\u65af\u7279\u56fe\u3002(f) \u4e0d\u540c\u6307\u5bbd\u7535\u5bb9\u5668\u7684GCD\u66f2\u7ebf\u3002(g) \u7528Ti3<\/sub>CNTx<\/sub>-12h\u548cTi3<\/sub>CNTx<\/sub>-24h\u7ec4\u88c5\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u7684Ragone\u56fe\u3002\u9ad8\u6d3b\u6027\u7684Ti3<\/sub>CNTx<\/sub>\u00a0MXene\u62e5\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002<\/p>\n

\u56fe5. \u96c6\u6210\u5316Ti<\/b><\/strong>3<\/b><\/sub><\/strong>CNT<\/b><\/strong>x<\/b><\/sub><\/strong>\u57fa\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a-c) \u4e32\u8054\u5668\u4ef6\u7684CV\u66f2\u7ebf, GCD\u66f2\u7ebf\u548c\u5948\u594e\u65af\u7279\u56fe\u3002(d-f) \u5e76\u8054\u5668\u4ef6\u7684CV\u66f2\u7ebf\uff0cGCD\u66f2\u7ebf\u548c\u5948\u594e\u65af\u7279\u56fe\u3002<\/p>\n

\u5c0f\u7ed3<\/b><\/strong><\/p>\n

\u4f5c\u8005\u4eec\u901a\u8fc7\u9178\u6027\u5206\u5b50\u526a\u5200\u7b56\u7565\u6765\u7cbe\u786e\u5730\u88c1\u526aTi3<\/sub>CNTx<\/sub>\u00a0MXenes\uff0c\u5b9e\u73b0\u4e86\u5177\u6709\u8bbe\u8ba1\u7684\u5f62\u6001\u548c\u9002\u5f53\u7684\u7f3a\u9677\u5bc6\u5ea6\u7684Ti3<\/sub>CNTx<\/sub>\u00a0MXenes\u7684\u5236\u5907\u3002\u8bbe\u8ba1\u7684\u7f3a\u9677\u4f4d\u70b9\u662f\u8d28\u5b50\u5316\u53cd\u5e94\u7684\u7406\u60f3\u5e73\u53f0\uff0c\u4f7f\u8d5d\u7535\u5bb9\u53cd\u5e94\u4e2d\u7684\u8d28\u5b50\u5177\u6709\u66f4\u5f3a\u7684\u6269\u6563\u548c\u4f20\u8f93\u80fd\u529b\u3002\u6b64\u5916\uff0c\u6211\u4eec\u8fdb\u4e00\u6b65\u5c01\u88c5\u4e86\u9ad8\u6027\u80fd\u7684Ti3<\/sub>CNTx<\/sub>\u57fa\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u5176\u4f53\u79ef\u7535\u5bb9\u8fbe\u5230250 F cm-3<\/sup>,\u00a0\u57280.43 W cm-3<\/sup>\u7684\u529f\u7387\u5bc6\u5ea6\u4e0b\u4ecd\u4fdd\u630112.46 mWh cm-3<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u672c\u6587\u62a5\u9053\u7684\u9178\u5206\u5b50\u526a\u5200\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u63a7\u548c\u5efa\u8bbe\u6027\u7684\u65b9\u6cd5\u6765\u88c1\u526aMXene\uff0c\u5b83\u53ef\u4ee5\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u91cd\u5851MXene\u7eb3\u7c73\u6750\u6599\uff0c\u56e0\u6b64\u8be5\u7b56\u7565\u6253\u5f00\u4e86\u4e00\u7cfb\u5217MXene\u5728\u80fd\u6e90\u3001\u4f20\u611f\u548c\u533b\u7597\u65b9\u9762\u7684\u5e94\u7528\u7684\u6f5c\u529b\u3002<\/p>\n

\u8bba\u6587\u94fe\u63a5<\/b><\/strong><\/p>\n

Tailoring Ti3<\/sub>CNTx<\/sub>\u00a0MXene via an Acid Molecular Scissor, Nano Energy<\/b><\/strong>, 2021\uff0c85:106007.<\/p>\n

https:\/\/doi.org\/10.1016\/j.nanoen.2021.106007<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 MXenes\u7531\u4e8e\u5176\u826f\u597d\u7684\u7535\u5bfc\u7387\uff0c\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u548c\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u800c\u8d8a\u6765\u8d8a\u53d7\u5230\u79d1\u5b66\u754c\u7684\u5173\u6ce8\u3002\u76ee\u524d\uff0c\u5bf9MXenes\u8fdb\u884c\u4fee\u9970\u7684\u65b9\u6cd5\u8d8a\u6765\u8d8a\u591a\uff0c\u7f3a\u9677\u5de5\u7a0b\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u63a7\u5236…<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-219933","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219933"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=219933"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219933\/revisions"}],"predecessor-version":[{"id":219935,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219933\/revisions\/219935"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=219933"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=219933"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=219933"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}