{"id":219160,"date":"2021-03-13T06:13:05","date_gmt":"2021-03-12T22:13:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=219160"},"modified":"2021-03-12T22:13:14","modified_gmt":"2021-03-12T14:13:14","slug":"%e6%9d%a5%e5%90%a7%ef%bc%8c%e5%b1%95%e7%a4%ba%e8%bf%99%e7%a7%8d15%e5%b2%81%e6%9d%90%e6%96%99%e7%9a%84%e6%96%b0%e8%bf%9b%e5%b1%95%ef%bc%81","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=219160","title":{"rendered":"\u6765\u5427\uff0c\u5c55\u793a\u8fd9\u79cd15\u5c81\u6750\u6599\u7684\u65b0\u8fdb\u5c55\uff01"},"content":{"rendered":"

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2005<\/b><\/strong>\u5e74\u672b\uff0c<\/b><\/strong>\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08C<\/b><\/strong>ovalent <\/b><\/strong>O<\/b><\/strong>rganic <\/b><\/strong>F<\/b><\/strong>rameworks<\/b><\/strong>\uff0cCOFs\uff09<\/b><\/strong>\u6a2a\u7a7a\u51fa\u4e16\uff0c\u4f5c\u4e3a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u2014MOFs\u7684\u6700\u4f73\u62cd\u6863\uff0c\u5b83\u7684\u8bde\u751f\u4e3a\u65b0\u578b\u6846\u67b6\u5316\u5b66\u4f53\u7cfb\u7684\u5efa\u6784\u3001\u65b0\u578b\u529f\u80fd\u6750\u6599\u7684\u62d3\u5c55\uff0c\u4ee5\u53ca\u591a\u91cd\u5316\u5b66\u548c\u7269\u7406\u884c\u4e3a\u7b49\u65b9\u9762\u7684\u7814\u7a76\u548c\u5e94\u7528\u5e26\u6765\u65b0\u7684\u673a\u9047\u3002\u6700\u8fd1\uff0c\u53c8\u6709\u54ea\u4e9bCOFs\u7684\u65b0\u8fdb\u5c55?<\/p>\n

\u6709\u8ba1\u7b97+\u5b9e\u9a8c\uff0c\u6709\u80fd\u6e90\u50ac\u5316\uff0c\u6709\u65b0\u7ed3\u6784\uff0c\u6709\u65b0\u601d\u7ef4\uff0c\u8fd8\u6709\u66f4\u91cd\u8981\u7684\u7a33\u5b9a\u6027\u7b49\u3002<\/u><\/p>\n

\u6765\u5427\uff0c\u5c55\u793a\uff01<\/b><\/strong><\/p>\n

\u4e8c\u3001COFs\u6700\u65b0\u8fdb\u5c55<\/b><\/strong><\/p>\n

\u00a0<\/b><\/strong>\u8ba1\u7b97\uff01<\/b><\/strong><\/p>\n

1. J. Phys. Chem. C<\/i><\/b><\/em><\/strong>: <\/b><\/strong>MOF@COF\u8fde\u63a5\u4f53\u7684\u8ba1\u7b97\u8bc6\u522b<\/b><\/strong><\/p>\n

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2. J.Am.Chem.Soc.<\/i><\/b><\/em><\/strong>\uff1a\u9a6f\u670d\u676f[4]\u82b3\u70c3\u57fa\u4e8c\u7ef4COFs\u7684\u62d3\u6251\u7ed3\u6784:<\/b><\/strong>\u4e92\u7a7f\u4e0e\u975e\u4e92\u7a7f\u6846\u67b6\u53ca\u5176\u5bf9\u9633\u79bb\u5b50\u67d3\u6599\u7684\u9009\u62e9\u6027\u53bb\u9664<\/b><\/strong><\/p>\n

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3. ACS Catal.<\/i><\/b><\/em><\/strong>:\u589e\u5f3a\u53ef\u89c1\u5149\u9a71\u52a8\u5236\u6c22\u7684\u7a33\u5065\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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4. Chem.Mater.<\/i><\/b><\/em><\/strong>:<\/b><\/strong>\u805a\u9170\u4e9a\u80fa\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u5408\u6210\u53ca\u5728CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u6355\u83b7\u548c\u6c34\u7cfb\u94a0\u79bb\u5b50\u7535\u6c60\u5e94\u7528\u4e2d\u7684\u7ed3\u6784-\u6027\u80fd\u5173\u7cfb<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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5. J.Am.Chem.Soc.<\/i><\/b><\/em><\/strong>\uff1a\u5177\u6709\u67d4\u6027\u7ed3\u6784\u5355\u5143\u7684\u7ed3\u6676\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u4e09\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6(3D COFs)\u7684\u6784\u5efa\u662f\u975e\u5e38\u56f0\u96be\u7684\uff0c\u56e0\u4e3a\u5b83\u4eec\u7684\u5408\u6210\u9a71\u52a8\u529b\u4e3b\u8981\u6765\u81ea\u5171\u4ef7\u952e\u7684\u5f62\u6210\u3002\u4e3a\u4e86\u4fbf\u4e8e\u5408\u6210\uff0c\u521a\u6027\u7ed3\u6784\u5355\u5143\u59cb\u7ec8\u662f\u8bbe\u8ba13D COFs\u7684\u9996\u9009\u3002\u539f\u5219\u4e0a\uff0c\u7528\u67d4\u6027\u7684\u5355\u5143\u6784\u5efa3D COFs\u5e94\u8be5\u5f88\u6709\u5438\u5f15\u529b\uff0c\u4f46\u662f\u6b64\u7c7b\u7cfb\u7edf\u7684\u53d1\u5c55\u9047\u5230\u4e86\u74f6\u9888\uff0c\u5c24\u5176\u662f\u5728\u8bbe\u8ba1\u5408\u6210\u548c\u7ed3\u6784\u786e\u5b9a\u65b9\u9762\u3002\u8fd9\u9879\u6210\u679c\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u9ad8\u5ea6\u7ed3\u6676\u76843D COF (FCOF-5)\uff0c\u5728\u7ed3\u6784\u57fa\u5143\u4e3b\u94fe\u4e2d\u5177\u6709\u67d4\u6027\u7684C\u2013O\u5355\u952e\u3002\u6709\u8da3\u7684\u662f\uff0cFCOF-5<\/b><\/strong>\u662f\u67d4\u6027\u7684<\/b><\/strong>\uff0c\u5728\u84b8\u6c7d\u5438\u9644\/\u89e3\u5438\u65f6\u53d1\u751f\u53ef\u9006\u7684\u81a8\u80c0\/\u6536\u7f29\uff0c\u8868\u660e\u5b58\u5728\u547c\u5438\u8fd0\u52a8\u3002<\/b><\/strong>\u8fdb\u4e00\u6b65\u5236\u5907\u4e86\u4e00\u79cd\u5177\u6709FCOF-5\u7ed3\u6784\u7684\u667a\u80fd\u8f6f\u805a\u5408\u7269\u590d\u5408\u819c\uff0c\u8be5\u590d\u5408\u819c\u5177\u6709\u53ef\u9006\u7684\u84b8\u6c7d\u89e6\u53d1\u76f8\u53d8\u3002<\/b><\/strong>\u56e0\u6b64\uff0c\u7531\u67d4\u6027\u5355\u5143\u6784\u5efa\u76843D COFs\u53ef\u4ee5\u8868\u73b0\u51fa\u6709\u8da3\u7684\u547c\u5438\u884c\u4e3a\uff0c\u8fd9\u79cd\u67d4\u6027\u591a\u5b54\u6676\u4f53\u5c06\u5177\u6709\u591a\u79cd\u6709\u8da3\u7279\u6027\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u7406\u8bba+\u5b9e\u9a8c\uff01<\/b><\/strong><\/p>\n

6.\u00a0<\/i><\/b><\/em><\/strong>ACS Appl. Mater. Interfaces.<\/i><\/b><\/em><\/strong>: <\/b><\/strong>\u8d85\u9ad8\u7898\u6355\u83b7\u80fd\u529b\u7684\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u7406\u8bba\u7b5b\u9009\u548c\u5b9e\u9a8c\u5408\u6210<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\"\"<\/b><\/strong><\/p>\n

\u6700\u8d5e\u70ed\u7a33\u5b9a\uff01<\/b><\/strong><\/p>\n

7. Faraday Discuss.<\/i><\/b><\/em><\/strong>: <\/b><\/strong>\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7684\u70ed\u7a33\u5b9a\u6027\u8d8b\u52bf<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u4e8c\u7ef4\u5171\u4ef7\u6709\u673a\u6846\u67b6(2D COFs)\u662f\u5408\u6210\u7684\u591a\u6837\u5316\u7684\u5c42\u72b6\u5927\u5206\u5b50\u3002\u5b83\u4eec\u7684\u5171\u4ef7\u6676\u683c\u88ab\u8ba4\u4e3a\u8d4b\u4e88\u4e86\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u901a\u5e38\u901a\u8fc7\u70ed\u91cd\u5206\u6790(TGA)\u6765\u8bc4\u4f30\u3002\u7136\u800c\uff0cTGA\u6d4b\u91cf\u7684\u662f\u6325\u53d1\u6027\u964d\u89e3\u4ea7\u7269\u5f62\u6210\u7684\u6e29\u5ea6\uff0c\u5bf9COF\u7684\u5468\u671f\u6027\u7ed3\u6784\u7684\u53d8\u5316\u4e0d\u654f\u611f\u3002\u901a\u8fc7\u4f7f\u7528\u53d8\u6e29XRD\u3001TGA\u3001\u6f2b\u53cd\u5c04\u7ea2\u5916\u5149\u8c31\u548cDFT\u8ba1\u7b97\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\u7814\u7a76\u4e8610\u79cd2D COFs\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u53d1\u73b02D <\/b><\/strong>COFs<\/b><\/strong>\u7ecf\u5386\u4e86\u4e00\u4e2a<\/b><\/strong>\u666e\u9002\u6027<\/b><\/strong>\u7684\u4e24\u6b65\u70ed\u964d\u89e3\u8fc7\u7a0b\u3002<\/b><\/strong>\u5728\u7b2c\u4e00\u964d\u89e3\u6e29\u5ea6\u4e0b\uff0c2D COFs\u5931\u53bb\u7ed3\u6676\u5ea6\u800c\u4e0d\u53d1\u751f\u5316\u5b66\u964d\u89e3\u3002\u7136\u540e\uff0c\u5728\u66f4\u9ad8\u7684\u6e29\u5ea6\u4e0b\uff0c\u5b83\u4eec\u4f1a\u5316\u5b66\u964d\u89e3\u4e3a\u6325\u53d1\u6027\u7684\u526f\u4ea7\u7269\u3002\u5bf92D\u00a0COFs\u7a33\u5b9a\u6027\u7684\u63a2\u7d22\u5f97\u5230\u4e86\u4e00\u4e9b\u6709\u8d8b\u52bf\u6027\u7684\u7ed3\u8bba\uff1a\u787c\u9178\u916f\u8fde\u63a5\u7684<\/b><\/strong>COFs<\/b><\/strong>\u901a\u5e38\u6bd4\u7c7b\u4f3c\u7684\u4e9a\u80fa\u8fde\u63a5\u7684<\/b><\/strong>COFs<\/b><\/strong>\u66f4\u70ed\u7a33\u5b9a\u3002<\/b><\/strong>\u8f83\u5c0f\u7684\u6676\u683c\u6bd4\u5316\u5b66\u6027\u8d28\u76f8\u4f3c\u7684\u8f83\u5927\u6676\u683c\u66f4\u80fd\u62b5\u6297\u70ed\u964d\u89e3\u3002\u6b64\u5916\uff0c\u5b54\u529f\u80fd\u5316\u7684COFs\u6bd4\u5176\u672a\u529f\u80fd\u5316\u7684\u7c7b\u4f3c\u7269\u4f1a\u5728\u66f4\u4f4e\u7684\u6e29\u5ea6\u4e0b\u964d\u89e3\u3002\u8fd9\u4e9b\u8d8b\u52bf\u4e3a\u70ed\u5f39\u60272D COF\u6750\u6599\u63d0\u4f9b\u4e86\u8bbe\u8ba1\u6807\u51c6\u3002\u540c\u65f6\uff0c\u5c06\u4e3a\u66f4\u5e7f\u6cdb\u5730\u63a2\u7d22\u4e8c\u7ef4\u7f51\u7edc\u4e2d\u7684\u673a\u68b0\u53d8\u5f62\u63d0\u4f9b\u4fe1\u606f\uff0c\u4e3a\u5176\u5b9e\u9645\u5e94\u7528\u52a9\u529b\u3002<\/p>\n

\"\" \u00a0<\/b><\/strong><\/p>\n

\u591a\u7ba1\u9f50\u4e0b\uff01<\/b><\/strong><\/p>\n

8. Microporous Mesoporous Mater.<\/i><\/b><\/em><\/strong>: <\/b><\/strong>\u542bN\uff0cO\uff0cP\u7684\u53cc\u529f\u80fd\u5171\u4ef7\u6709\u673a\u6846\u67b6\u7528\u4e8e\u5438\u9644\u7898\u53ca\u5bf9\u785d\u57fa\u82ef\u915a\u548c\u7898\u7684\u8367\u5149\u4f20\u611f<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\"\"<\/b><\/strong><\/p>\n

\u672c\u6587\u7531Free-Writon\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u5bfc\u8bfb 2005\u5e74\u672b\uff0c\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08Covalent Organic Frameworks\uff0cCOFs\uff09\u6a2a\u7a7a\u51fa\u4e16\uff0c\u4f5c\u4e3a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u2014MOFs\u7684\u6700\u4f73\u62cd\u6863\uff0c\u5b83\u7684\u8bde\u751f…<\/p>\n","protected":false},"author":11454,"featured_media":219162,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-219160","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219160"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=219160"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219160\/revisions"}],"predecessor-version":[{"id":219183,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/219160\/revisions\/219183"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/219162"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=219160"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=219160"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=219160"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}