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\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n \u5bf9\u5316\u77f3\u71c3\u6599\u7684\u8fc7\u5ea6\u4f9d\u8d56\u548c\u65e5\u76ca\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\uff0c\u6b63\u63a8\u52a8\u4eba\u4eec\u4ee5\u66f4\u6e05\u6d01\u548c\u53ef\u6301\u7eed\u7684\u65b9\u5f0f\u53d1\u5c55\u80fd\u6e90\u7ecf\u6d4e\u3002\u53ef\u5145\u7535\u91d1\u5c5e\u7535\u6c60\u5177\u6709\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u6027\u548c\u957f\u5bff\u547d\u7b49\u7279\u70b9\uff0c\u5728\u5927\u89c4\u6a21\u53ef\u518d\u751f\u80fd\u6e90\uff08\u5982\u592a\u9633\u80fd\u3001\u98ce\u80fd\u548c\u6f6e\u6c50\u80fd\uff09\u50a8\u5b58\u548c\u7535\u52a8\u6c7d\u8f66\u7b49\u9886\u57df\u5f15\u8d77\u5e7f\u6cdb\u5173\u6ce8\u3002\u91d1\u5c5e\u8d1f\u6781\u6613\u4e8e\u52a0\u5de5\u4e14\u53ef\u6279\u91cf\u5236\u5907\uff0c\u662f\u53ef\u5145\u7535\u91d1\u5c5e\u7535\u6c60\u6700\u5e38\u7528\u7684\u7535\u6781\u5f62\u5f0f\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u7535\u6781\u9762\u4e34\u7740\u4f53\u79ef\u53d8\u5316\u5927\u3001\u526f\u53cd\u5e94\u4e25\u91cd\u7b49\u7f3a\u70b9\u3002\u4ee5\u950c\uff08Zn\uff09\u91d1\u5c5e\u8d1f\u6781\u4e3a\u4f8b\uff0c\u91d1\u5c5eZn\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f53\u79ef\u53d8\u5316\u5927\uff0c\u5c06\u589e\u52a0\u7535\u6781\u4e0d\u7a33\u5b9a\u6027\uff1b\u800c\u6c34\u7cfb\u950c\u7535\u6781\u7684\u526f\u53cd\u5e94\uff08\u5305\u62ec\u5316\u5b66\u6c27\u5316\u548c\u7535\u5316\u5b66\u6790\u6c22\uff09\u4ea7\u751f\u6c14\u4f53\u7b49\u526f\u4ea7\u7269\uff0c\u963b\u788dZn2+<\/sup>\u79bb\u5b50\u8f6c\u79fb\uff0c\u8fdb\u800c\u52a0\u5267\u7535\u6781\u7684\u6027\u80fd\u52a3\u53d8\u3002\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u548c\u9ad8\u9762\u79ef\u5bb9\u91cf\u7684\u6df1\u5ea6\u5faa\u73af\u4e0b\uff0c\u8fd9\u4e9b\u95ee\u9898\u5c06\u66f4\u52a0\u4e25\u91cd\u3002\u53ea\u6709\u540c\u65f6\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\uff0c\u624d\u80fd\u5b9e\u73b0\u53ef\u6df1\u5ea6\u5faa\u73af\u7684\u6c34\u7cfbZn\u7535\u6c60\u3002<\/p>\n \u9274\u4e8e\u6b64\uff0c\u7f8e\u56fd<\/b><\/strong>\u65af\u5766\u798f\u5927\u5b66\u5d14\u5c79<\/b><\/strong>\u6559\u6388\u548c<\/b><\/strong>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5b59\u6c38\u660e<\/b><\/strong>\u6559\u6388<\/b><\/strong>\uff08<\/b><\/strong>\u5171\u540c<\/b><\/strong>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u7f6e\u6362\u53cd\u5e94\u5236\u5907\u4e09\u7ef4\u53c9\u6307\u5f0f\u91d1\u5c5e\u950c\/\u56fa\u6001\u7535\u89e3\u8d28\u590d\u5408\u7ed3\u6784\u7535\u6781\uff0c\u72ec\u7279\u7684\u4e09\u7ef4\u53c9\u6307\u5f0f\u7ed3\u6784\u6291\u5236\u4e86\u7535\u6781\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u8868\u89c2\u4f53\u79ef\u53d8\u5316\uff0c\u540c\u65f6\u56fa\u6001\u7535\u89e3\u8d28\u907f\u514d\u4e86\u6d3b\u6027\u91d1\u5c5e\u4e0e\u6c34\u76f8\u7535\u89e3\u6db2\u7684\u76f4\u63a5\u63a5\u89e6\u4ee5\u6291\u5236\u526f\u53cd\u5e94\uff0c\u7531\u6b64\u5b9e\u73b0\u91d1\u5c5e\u8d1f\u6781\u9ad8\u5ea6\u7535\u5316\u5b66\u53ef\u9006\u3002\u53c9\u6307\u5f0f\u91d1\u5c5e\u950c\/\u56fa\u6001\u7535\u89e3\u8d28\u590d\u5408\u7535\u6781\u901a\u8fc7\u591a\u6676\u91d1\u5c5eZn\u7b94\u548cInCl3<\/sub>\u7684\u7f6e\u6362\u53cd\u5e94\u5236\u5907\uff0c\u7f6e\u6362\u7684\u94df\u91d1\u5c5e\u5728\u950c\u7b94\u8868\u9762\u6c89\u79ef\u5e76\u901a\u8fc7\u6676\u754c\u5411\u4f53\u76f8\u6269\u6563\uff0c\u5f62\u6210\u4e09\u7ef4\u53c9\u6307\u5f0f\u7ed3\u6784\u3002\u6240\u6c89\u79ef\u7684\u94df\u91d1\u5c5e\u5728\u7535\u5316\u5b66\u6d3b\u5316\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u6c27\u5316\u4e3a\u78b1\u5f0f\u786b\u9178\u94df\u57fa\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5176\u5177\u6709\u8f83\u9ad8\u7684Zn2+<\/sup>\u5bfc\u7535\u6027\uff0856.9\u00b11.8 mS cm-1<\/sup>\uff09\uff0c\u8f83\u5927\u7684Zn2+<\/sup>\u8fc1\u79fb\u6570\uff080.55\uff09\u548c\u9ad8\u7684\u7535\u963b\u7387(2.08\u00b10.01)\u00d7103<\/sup>\u00a0\u03a9\u00a0cm-1<\/sup>\u3002\u6240\u8bbe\u8ba1\u7684\u53c9\u6307\u5f0f\u950c\/\u78b1\u5f0f\u786b\u9178\u94df\uff08Zn\/IHS\uff09\u57fa\u7535\u6781\u5c55\u793a\u51fa\u7a33\u5b9aZn\u6c89\u79ef\/\u5265\u79bb\u884c\u4e3a\uff0c\u57281 mA cm-2<\/sup>\u548c0.5 mAh cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\u53ef\u5faa\u73af700\u5c0f\u65f6\u4ee5\u4e0a\uff0c\u4e14\u8fc7\u7535\u4f4d\u4ec5\u4e3a8 mV\u3002\u6b64\u5916\uff0c\u8be5Zn\/HIS\u7535\u6781\u572820 mA cm-2<\/sup>\u548c20 mAh cm-2<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u548c\u9ad8\u9762\u79ef\u5bb9\u91cf\u4e0b\u5b9e\u73b0\u4e86\u7a33\u5b9a\u5faa\u73af\u4e14\u8fc7\u7535\u4f4d\u4ec5\u4e3a10 mV\uff0c\u4f18\u4e8e\u76ee\u524d\u5df2\u62a5\u9053\u7684\u6240\u6709Zn\u91d1\u5c5e\u7535\u6781\u3002\u53c9\u6307\u5f0fZn\/IHS\u7535\u6781\u7684\u7f6e\u6362\u53cd\u5e94\u5236\u5907\u65b9\u6cd5\u53ef\u6269\u5c55\u5230\u5176\u5b83\u91d1\u5c5e\u5bf9\uff0c\u4f8b\u5982Zn\/Sn\u3001Zn\/Co\uff0c\u8fd9\u4e3a\u4e0b\u4e00\u4ee3\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u5bff\u547d\u7684Zn\u91d1\u5c5e\u7535\u6c60\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u5b9d\u8d35\u7ecf\u9a8c\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cA Replacement Reaction Enabled Interdigitated Metal\/Solid Electrolyte<\/b><\/strong>\u00a0<\/b><\/strong>Architecture for Battery Cycling at 20 mA cm<\/b><\/strong>–<\/b><\/sup><\/strong>2<\/b><\/sup><\/strong>\u00a0and 20 mAh cm<\/b><\/strong>–<\/b><\/sup><\/strong>2<\/b><\/sup><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728J. Am. Chem. Soc.<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n \u56fe<\/b><\/strong>\u4e00<\/b><\/strong>\u3001<\/b><\/strong>Zn<\/b><\/strong>\/IHS\u7535\u6781\u5728\u6c34<\/b><\/strong>\u7cfb<\/b><\/strong>\u7535\u6c60\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/b><\/strong> \uff08a\uff09Zn\/IHS\u7535\u6781\u5236\u5907\u539f\u7406\u56fe\uff1b<\/p>\n \uff08b\uff0cc\uff09Zn||Zn\u548cZn\/IHS||Zn\/IHS\u5bf9\u79f0\u7535\u6c60\u57281 mA cm-2<\/sup>\u548c0.5 mAh cm-2<\/sup>\u4e0e20 mA cm-2<\/sup>\u548c20 mAh cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\u5faa\u73af\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n \uff08d\uff09Zn\/IHS\u7535\u6781\u7684\u6c89\u79ef\\\u6eb6\u89e3\u884c\u4e3a\u793a\u610f\u56fe\uff1b<\/p>\n \uff08e-g\uff09\u7eafZn\u7535\u6781\u6eb6\u89e320 mAh cm-2<\/sup>\u91d1\u5c5eZn\u540e\u7684\u5149\u5b66\u663e\u5fae\u955c\uff08OM\uff09\u56fe\u50cf\uff08e\uff09\uff0cZn\/IHS\u7535\u6781\u6eb6\u89e320 mAh cm-2<\/sup>\u91d1\u5c5eZn\u540e\u7684OM\u56fe\u50cf\uff08f\uff09\uff0cZn\/IHS\u7535\u6781\u572820 mA cm-2<\/sup>\u548c20 mAh cm-2<\/sup>\u6761\u4ef6\u4e0b\u7535\u5316\u5b66\u5faa\u73af\u540e\u7684OM\u56fe\u50cf\uff08g\uff09\u3002<\/p>\n \u56fe<\/b><\/strong>\u4e8c\u3001Zn\/IHS\u7535\u6781\u7684\u5236\u5907\u4e0e\u8868\u5f81<\/b><\/strong><\/b> \uff08a\uff09Zn\/In\u548cZn\/IHS\u7535\u6781\u7684XRD\u56fe\uff0c\u8868\u660e\u7f6e\u6362\u53cd\u5e94\u6210\u529f\u5730\u5c06In\u91d1\u5c5e\u5f15\u5165Zn\uff0c\u5e76\u5728\u7535\u5316\u5b66\u6d3b\u5316\u540e\u53d8\u4e3a\u975e\u6676\u6001\uff1b<\/p>\n \uff08b\uff09Zn\/IHS\u7535\u6781\u7684EPMA\u7ed3\u679c\uff0c\u8868\u660e\u53c9\u6307\u5f0fZn\/IHS\u7ed3\u6784\u5f62\u6210\uff1b<\/p>\n \uff08c\uff09Zn\/IHS\u7535\u6781\u7684FTIR\u5149\u8c31\uff1b<\/p>\n \uff08d\uff09Zn\/IHS\u7535\u6781\u7684K-edge XANES\u5149\u8c31\uff1b<\/p>\n \uff08e\uff09\u5728Zn\/IHS\u7535\u6781\u7684K-edge EXAFS\u6570\u636e\u4e2d\uff0ck2<\/sup>\u52a0\u6743\u5085\u91cc\u53f6\u53d8\u6362\u3002<\/p>\n \u56fe<\/b><\/strong>\u4e09<\/b><\/strong>\u3001\u5728IHS\u56fa<\/b><\/strong>\u6001<\/b><\/strong>\u7535\u89e3\u8d28\u5c42\u4e0b<\/b><\/strong>\u7684<\/b><\/strong>\u7535\u5316\u5b66Zn\u6c89\u79ef<\/b><\/strong> \uff08a\uff09ZnSO4<\/sub>\u6c34\u76f8\u7535\u89e3\u6db2\u548cIHS\u56fa\u6001\u7535\u89e3\u8d28\u7684\u62c9\u66fc\u5149\u8c31\uff1b<\/p>\n \uff08b\uff09\u5728IHS\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u7684Zn2+<\/sup>\u6269\u6563\u793a\u610f\u56fe\uff1b<\/p>\n \uff08c\uff09\u57fa\u4e8eGF\u548cIHS\u56fa\u6001\u7535\u89e3\u8d28\u7684Zn2+<\/sup>\u8fc1\u79fb\u6570\uff1b<\/p>\n \uff08d\uff09\u7eafZn\u548cZn\/IHS\u7535\u6781\u5728\u5916\u52a0\u7535\u6d41\u5bc6\u5ea6\u4e3a5 mA cm-2<\/sup>\u4e0b\u7684\u7535\u538b\u53d8\u5316\u66f2\u7ebf\uff0c\u8bf4\u660eIHS\u56fa\u6001\u7535\u89e3\u8d28\u5177\u6709\u8f83\u9ad8\u7684\u7535\u963b\uff1b<\/p>\n \uff08e\uff09Zn\u91d1\u5c5e\u548cIHS\u56fa\u6001\u7535\u89e3\u8d28\u7684\u7535\u963b\u7387\u5bf9\u6bd4\uff1b<\/p>\n \uff08f\uff09IHS\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6001\u5bc6\u5ea6\u8ba1\u7b97\u7ed3\u679c\uff1b<\/p>\n \uff08g\uff09\u91d1\u5c5eZn\u7535\u5316\u5b66\u6c89\u79ef\uff0810 mAh cm-2<\/sup>\uff09\u540eZn\/IHS\u7535\u6781\u7684EPMA\u56fe\u50cf\u3002<\/p>\n \u56fe<\/b><\/strong>\u56db<\/b><\/strong>\u3001<\/b><\/strong>Zn<\/b><\/strong>\/IHS\u7535\u6781\u6790\u6c22\u7684\u5b9a\u6027\u548c\u5b9a\u91cf\u5206\u6790<\/b><\/strong> \uff08a\uff0cb\uff09\u5728\u65bd\u52a0\u7535\u6d41\u5bc6\u5ea6\u4e3a1 mA cm-2<\/sup>\u7684\u5bf9\u79f0\u7535\u6c60\u4e2d\uff0c\u7eafZn\u7535\u6781\u548cZn\/IHS\u7535\u6781\u7684\u539f\u4f4dOM\u56fe\u50cf\uff1b<\/p>\n \uff08c\uff09\u5728pH\u4e3a4\u7684\u7f13\u51b2\u6eb6\u6db2\u4e2d\uff0c\u7eafZn\u548cZn\/IHS\u7535\u6781\u7684\u6790\u6c22\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n \uff08d\uff09\u572850\u6b21\u6eb6\u89e3\/\u6c89\u79ef\u5faa\u73af\u540e\uff0cZn\/IHS\u7535\u6781\u7684\u7535\u5316\u5b66\u5265\u79bb\u53ca\u5e93\u4f26\u6548\u7387\u6d4b\u8bd5\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u7b80\u5355\u7684\u7f6e\u6362\u53cd\u5e94\u8bbe\u8ba1\u5236\u5907\u4e09\u7ef4\u53c9\u6307\u5f0fZn\/IHS\u7535\u6781\uff0c\u4ee5\u6291\u5236\u6c34\u7cfb\u950c\u91d1\u5c5e\u8d1f\u6781\u7684\u4f53\u79ef\u53d8\u5316\u548c\u526f\u53cd\u5e94\uff0c\u4ece\u800c\u63d0\u9ad8\u5176\u7535\u5316\u5b66\u53ef\u9006\u6027\uff0c\u7279\u522b\u662fZn\u91d1\u5c5e\u7535\u6781\u7684\u6df1\u5ea6\u5faa\u73af\u6027\u80fd\u3002\u4e09\u7ef4\u53c9\u6307\u5f0fZn\/IHS\u590d\u5408\u7ed3\u6784\u63d0\u9ad8\u4e86\u7535\u6781\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u5e76\u4fc3\u8fdbZn2+<\/sup>\u6269\u6563\u3002\u57281 mA cm-2<\/sup>\u548c0.5 mAh cm-2<\/sup>\u7684\u6761\u4ef6\u4e0b\uff0cZn\/IHS||Zn\/IHS\u5bf9\u79f0\u7535\u6c60\u53ef\u5faa\u73af700\u5c0f\u65f6\u4ee5\u4e0a\uff0c\u8fc7\u7535\u4f4d\u4f4e\u81f38 mV\u3002\u6b64\u5916\uff0c\u5728\u5927\u7535\u6d41\u5bc6\u5ea6\u548c\u9ad8\u9762\u79ef\u5bb9\u91cf\uff0820 mAh cm-2<\/sup>\u548c20 mAh cm-2<\/sup>\uff09\u7684\u6761\u4ef6\u4e0b\uff0cZn\/IHS\u7535\u6781\u5b9e\u73b0\u4e86\u7a33\u5b9a\u7684\u6c89\u79ef\/\u6eb6\u89e3\u5faa\u73af\uff0c\u4e14\u8fc7\u7535\u4f4d\u4ec5\u4e3a10 mV\u3002\u4e0a\u8ff0\u4e09\u7ef4\u53c9\u6307\u5f0fZn\/IHS\u590d\u5408\u7ed3\u6784\u4e3a\u8bbe\u8ba1\u5177\u6709\u9ad8\u673a\u68b0\u7a33\u5b9a\u6027\u548c\u826f\u597d\u53ef\u9006\u6027\u7684\u6c34\u7cfbZn\u91d1\u5c5e\u7535\u6781\u63d0\u4f9b\u4e86\u65b0\u7684\u89c6\u89d2\uff0c\u4e3a\u5b9e\u73b0\u5148\u8fdb\u6c34\u7cfbZn\u91d1\u5c5e\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<\/p>\n
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