{"id":217990,"date":"2021-02-21T06:28:22","date_gmt":"2021-02-20T22:28:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=217990"},"modified":"2021-02-20T21:28:39","modified_gmt":"2021-02-20T13:28:39","slug":"%e8%b4%ba%e6%9b%a6%e6%95%8f%e6%9c%b1%e6%96%b0%e8%bf%9c-adv-mater-%ef%bc%9a%e9%80%9a%e7%94%a8%e5%b9%b3%e5%8f%b0%ef%bc%81%e5%88%a9%e7%94%a8%e7%a6%bb%e5%ad%90%e7%89%b9%e5%bc%82%e6%80%a7%e5%88%b6","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=217990","title":{"rendered":"\u8d3a\u66e6\u654f&\u6731\u65b0\u8fdc Adv. Mater.\uff1a\u901a\u7528\u5e73\u53f0\uff01\u5229\u7528\u79bb\u5b50\u7279\u5f02\u6027\u5236\u5907\u529b\u5b66\u6027\u80fd\u5927\u8303\u56f4\u53ef\u8c03\u7684\u805a\u4e59\u70ef\u9187\u6c34\u51dd\u80f6"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821\u8d3a\u66e6\u654f\u6559\u6388\u548c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u6731\u65b0\u8fdc\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eHofmeister\u6548\u5e94\uff0c\u63d0\u51fa\u4e86\u901a\u8fc7\u79bb\u5b50\u8c03\u8282\u805a\u5408\u7269\u94fe\u7684\u805a\u96c6\u72b6\u6001\u6765\u53ef\u9006\u5730\u5927\u8303\u56f4\u5730\u6539\u53d8\u6c34\u51dd\u80f6\u7684\u529b\u5b66\u6027\u80fd\u7684\u7b56\u7565\u3002\u4f5c\u8005\u5236\u5907\u4e86\u8d85\u97e7\u6027\u7684\u805a\u4e59\u70ef\u9187\uff08PVA\uff09\u6c34\u51dd\u80f6\u4f5c\u4e3a\u793a\u4f8b\u6027\u6750\u6599\uff08\u97e7\u6027150\u00b120 MJ\/m3<\/sup>\uff09\uff0c\u5b83\u8d85\u8fc7\u4e86\u805a\uff08\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\uff09PDMS\u3001\u5408\u6210\u6a61\u80f6\u548c\u5929\u7136\u8718\u86db\u4e1d\u7b49\u5408\u6210\u805a\u5408\u7269\u3002\u901a\u8fc7\u6539\u53d8\u79bb\u5b50\u79cd\u7c7b\u548c\u6d53\u5ea6\uff0cPVA\u6c34\u51dd\u80f6\u7684\u529b\u5b66\u6027\u80fd\u5f97\u5230\u4e86\u5927\u8303\u56f4\u7684\u8c03\u63a7\uff1a\u62c9\u4f38\u5f3a\u5ea6\u4ece50\u00b19 kPa\u523015\u00b11 MPa\uff0c\u97e7\u6027\u4ece0.0167\u00b10.003 MJ \/m3<\/sup>\u5230150\u00b120 MJ\/m3<\/sup>\uff0c\u5ef6\u4f38\u7387\u4ece300\u00b1100\uff05\u81f32100\u00b1300\uff05\uff0c\u6a21\u91cf\u4ece24\u00b12 kPa\u81f32500\u00b1140 kPa\u3002\u5176\u4e2d\uff0c\u7528\u9971\u548cNa2<\/sub>SO4<\/sub>\u6d78\u6ce1\u7684\u6c34\u51dd\u80f6\u663e\u793a\u51fa\u6781\u4f18\u79c0\u7684\u529b\u5b66\u6027\u80fd\uff0c\u4e0d\u4ec5\u4f18\u4e8e\u5148\u524d\u62a5\u9053\u7684\u5927\u591a\u6570\u6c34\u51dd\u80f6\uff0c\u5176\u97e7\u6027\u8fd8\u4f18\u4e8ePDMS\u3001\u5408\u6210\u6a61\u80f6\u548c\u5929\u7136\u8718\u86db\u4e1d\u3002\u7528\u4e8e\u8c03\u63a7\u6c34\u51dd\u80f6\u529b\u5b66\u6027\u80fd\u7684\u79bb\u5b50\u4e0d\u662f\u6c34\u51dd\u80f6\u7684\u7ec4\u5206\uff0c\u5728\u79bb\u5b50\u6eb6\u6db2\u4e2d\u6d78\u6ce1\u5904\u7406\u540e\uff0c\u5176\u53ef\u88ab\u5b8c\u5168\u6d17\u51fa\uff0c\u6700\u7ec8\u7684\u65e0\u79bb\u5b50PVA\u6c34\u51dd\u80f6\u53ef\u4ee5\u5f88\u597d\u5730\u4fdd\u6301\u5176\u529b\u5b66\u6027\u80fd\u548c\u975e\u5e38\u7406\u60f3\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0c\u800c\u4e0d\u4f1a\u53d7\u5236\u5907\u6c34\u51dd\u80f6\u65f6\u4f7f\u7528\u79bb\u5b50\u7684\u5f71\u54cd\u3002\u901a\u8fc7\u8fd9\u79cd\u7b80\u4fbf\u7684\u65b9\u6cd5\u6765\u5927\u8303\u56f4\u8c03\u63a7\u51dd\u80f6\u529b\u5b66\u6027\u80fd\uff0c\u6709\u671b\u6ee1\u8db3\u4ece\u751f\u7269\u533b\u5b66\u5230\u8f6f\u4f53\u673a\u5668\u4eba\u6280\u672f\u548c\u53ef\u7a7f\u6234\u7535\u5b50\u4ea7\u54c1\u7b49\u591a\u4e2a\u9886\u57df\u7684\u9700\u6c42\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cPoly(vinyl alcohol) Hydrogels with Broad-Range Tunable Mechanical Properties via the Hofmeister Effect\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdvanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

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\n \"\"a\uff09\u79bb\u5b50\u3001\u805a\u5408\u7269\u94fe\u548c\u6c34\u5206\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff1b<\/p>\n

b\uff09\u7531\u4e8e\u76d0\u6790\u6548\u5e94\uff0c\u79bb\u5b50\u5728PVA\u805a\u5408\u7269\u94fe\u4e4b\u95f4\u5f62\u6210\u6c22\u952e\uff1b<\/p>\n

c\uff09\u7531\u4e8e\u76d0\u6eb6\u6548\u5e94\uff0c\u79bb\u5b50\u8bf1\u5bfc\u7684PVA\u805a\u5408\u7269\u94fe\u4e4b\u95f4\u7684\u6c22\u952e\u65ad\u88c2\uff1b<\/p>\n

d-e\uff09\u7531\u4e0d\u540c\u6d53\u5ea6\u7684\u4e0d\u540c\u79bb\u5b50\u8bf1\u5bfc\u7684PVA\u6210\u80f6\u72b6\u6001\u7684\u603b\u7ed3\u3002<\/p>\n

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\n \"\"a-c\uff09\u6d78\u6ce1\u57281 M \u94a0\u76d0\u30013 M \u6c2f\u76d0\u548cNa2<\/sub>SO4<\/sub>\u6d53\u5ea6\u8303\u56f4\u4e3a0 M\u81f3\u9971\u548c\u4e2d\u7684PVA\u6c34\u51dd\u80f6\u7684\u4ee3\u8868\u6027\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff1b<\/p>\n

d-f\uff09\u7531\u5404\u79cd\u9634\u79bb\u5b50\uff08Na+<\/sup>\u4e3a\u6052\u5b9a\u6297\u8861\u79bb\u5b50\uff09\u3001\u4e0d\u540c\u7684\u9633\u79bb\u5b50\uff08Cl–<\/sup>\u4e3a\u6052\u5b9a\u6297\u8861\u79bb\u5b50\uff09\u548cNa2<\/sub>SO4<\/sub>\u6d53\u5ea6\u8303\u56f4\u4e3a0<\/p>\n

M\u81f3\u9971\u548c\u8c03\u6574\u7684PVA\u6c34\u51dd\u80f6\u7684\u5f3a\u5ea6\u3001\u97e7\u6027\u548c\u6a21\u91cf\uff1b<\/p>\n

g\uff09\u5bf9\u6bd4\u5df2\u62a5\u9053\u7684\u5176\u4ed6\u6c34\u51dd\u80f6\u548c\u805a\u5408\u7269\uff0c\u4e0d\u540c\u79bb\u5b50\u5904\u7406\u7684\u6c34\u51dd\u80f6\u7684\u6781\u9650\u5f3a\u5ea6\u4e0e\u6781\u9650\u5e94\u53d8\uff08g1<\/sub>\uff09\u7684\u5173\u7cfb\u56fe\u4ee5\u53ca\u97e7\u6027\u4e0e\u6781\u9650\u5e94\u53d8\uff08g2<\/sub>\uff09\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

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\n \"\"a-b\uff09\u75281.0 M Na2<\/sub>SO4<\/sub>\u548cNaNO3<\/sub>\u6d78\u6ce1\u7684PVA\u6c34\u51dd\u80f6\u7684XRD\uff1b<\/p>\n

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f\uff09PVA-SO4<\/sub>\u548cPVA-NO3<\/sub>\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u4e8c\u8005\u5177\u6709\u4e0d\u540c\u5bc6\u5ea6\u7684\u7eb3\u7c73\u7ea4\u7ef4\u548c\u7ed3\u6676\u533a\uff0c\u4f7f\u5176\u5bf9\u88c2\u7eb9\u5177\u6709\u4e0d\u540c\u7684\u949d\u5316\u548c\u9489\u624e\u6548\u5e94\u3002<\/p>\n

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\n \"\"a\uff09\u9971\u548cNa2<\/sub>SO4<\/sub>\u548c3 M CaCl2<\/sub>\u6eb6\u6db2\u6d78\u6ce1\u540e\uff0cPVA\u6c34\u51dd\u80f6\u7684\u5149\u5b66\u56fe\u50cf\uff1b<\/p>\n

b1\uff09PVA\u6c34\u51dd\u80f6\u901a\u8fc71 M Na2<\/sub>SO4<\/sub>\u589e\u5f3a\uff0c\u5176\u53ef\u63d2\u5165\u5230\u4eff\u4eba\u8111\u7ec4\u7ec7\u7684\u4f4e\u6a21\u91cf\u6c34\u51dd\u80f6\u4e2d\uff1b<\/p>\n

b2\uff09\u75281 M CaCl2<\/sub>\u5904\u7406\u8fc7\u7684\u67d4\u8f6fPVA\u6c34\u51dd\u80f6\uff0c\u4e0d\u80fd\u63d2\u5165\u76f8\u540c\u7684\u4eff\u4eba\u8111\u7ec4\u7ec7\u7684\u4f4e\u6a21\u91cf\u6c34\u51dd\u80f6\u4e2d\uff1b<\/p>\n

c\uff09\u5c06\u63d2\u6709\u6c34\u51dd\u80f6\u63a2\u9488\u7684\u4eff\u4eba\u8111\u7ec4\u7ec7\u4f4e\u6a21\u91cf\u6c34\u51dd\u80f6\u6d78\u51652 M Fe(NO3<\/sub>)3<\/sub>\u6eb6\u6db2\u4e2d\u539f\u4f4d\u8f6f\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aPoly(vinyl alcohol) Hydrogels with Broad-Range Tunable Mechanical Properties via the Hofmeister Effect<\/a><\/strong>. Adv. Mater.<\/em>, 2021<\/strong>, DOI: 10.1002\/adma.202007829.<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

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\u8bfe\u9898\u7ec4\u7f51\u9875\uff1ahttp:\/\/www.seas.ucla.edu\/xhe-lab\/index.html<\/strong><\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

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