{"id":217332,"date":"2021-02-08T06:56:38","date_gmt":"2021-02-07T22:56:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=217332"},"modified":"2021-02-07T20:56:53","modified_gmt":"2021-02-07T12:56:53","slug":"adv-energy-mater-%ef%bc%9a%e6%97%a0%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e5%8d%a4%e5%8c%96%e7%89%a9%e9%92%99%e9%92%9b%e7%9f%bf-%e4%b8%8b%e4%b8%80%e4%bb%a3%e5%85%89%e7%94%b5%e5%99%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=217332","title":{"rendered":"Adv. Energy Mater.\uff1a\u65e0\u91d1\u5c5e\u6709\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u2014\u2014\u4e0b\u4e00\u4ee3\u5149\u7535\u5668\u4ef6\u7684\u65b0\u6750\u6599"},"content":{"rendered":"
\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n \u91d1\u5c5e\u6709\u673a\u5364\u5316\u7269\u9499\u949b\u77ff\u7531\u4e8e\u5176\u6781\u9ad8\u7684\u5149\u5438\u6536\u3001\u957f\u7684\u7535\u8377\u5bff\u547d\/\u6269\u6563\u957f\u5ea6\u5728\u5149\u7535\u5e94\u7528\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u7136\u800c\u91d1\u5c5e\u57fa\u9499\u949b\u77ff\u6750\u6599\u4ecd\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\u30021\uff09\u5236\u9020\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u7684\u6709\u6bd2\u6eb6\u5242\uff1b2\uff09\u6709\u6bd2\u7269\u8d28\u4e0e\u53ef\u7a7f\u6234\u8bbe\u5907\u4e0d\u517c\u5bb9\uff1b3\uff09\u57fa\u4e8ePb\u7684\u9499\u949b\u77ff\u6613\u53d7\u6f6e\u6c14\u4fb5\u8680\uff0c\u4ece\u800c\u5bfc\u81f4\u6750\u6599\u964d\u89e3\u3002\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u662f\u9499\u949b\u77ff\u5bb6\u65cf\u7684\u4e00\u79cd\u65b0\u578b\u6750\u6599\u3002\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u4e0d\u4ec5\u5177\u6709\u4f20\u7edf\u9499\u949b\u77ffABX3<\/sub>\u7684\u7ed3\u6784\uff0c\u8fd8\u5177\u6709\u6709\u673a\u6750\u6599\u7684\u53ef\u8c03\u8282\u6027\u3001\u591a\u6837\u6027\u548c\u8f7b\u8d28\u6027\u3002\u540c\u65f6\uff0c\u65e0\u91d1\u5c5e\u53ef\u4ee5\u4ece\u6c34\u6eb6\u6db2\u4e2d\u5236\u5f97\uff0c\u53ef\u4ee5\u5b8c\u5168\u964d\u89e3\uff0c\u8fd9\u4e3a\u73af\u4fdd\u5236\u9020\u548c\u5e94\u7528\u63d0\u4f9b\u4e86\u57fa\u7840\u3002<\/p>\n \u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n \u8fd1\u65e5\uff0c\u9655\u897f\u5e08\u8303\u5927\u5b66\u5218\u751f\u5fe0\u6559\u6388\u3001\u8d75\u594e\u6559\u6388\uff0c\u4ee5\u8272\u5217\u9b4f\u8328\u66fc\u79d1\u5b66\u7814\u7a76\u9662<\/strong>Gary Hodes<\/strong>\u6559\u6388<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u9655\u897f\u5e08\u8303\u5927\u5b66\u535a\u58eb\u751f\u5b8b\u946b<\/strong>\u8ba8\u8bba\u4e86\u65e0\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u6676\u4f53\u7ed3\u6784\u3001\u5408\u6210\u4ee5\u53ca\u76ee\u524d\u65e0\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u7684\u7814\u7a76\u7279\u6027\u548c\u5e94\u7528\u3002\u4ece\u5316\u5b66\u591a\u6837\u6027\u3001\u7ed3\u6784\u53ef\u8c03\u6027\u3001\u5408\u6210\u5de5\u827a\u3001\u6f5c\u5728\u6027\u80fd\u3001\u5149\u7535\u548c\u80fd\u6e90\u7b49\u76f8\u5173\u5e94\u7528\u8ba8\u8bba\u4e86\u5176\u672a\u6765\u7684\u524d\u666f\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Metal-Free Organic Halide Perovskite: A New Class for Next Optoelectronic Generation Devices<\/strong>\u201d\u53d1\u8868\u5728Advanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n \u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n \u56fe<\/strong> 1 <\/strong>\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n \uff08A\uff09C4<\/sub>N2<\/sub>H12<\/sub>NH4<\/sub>Cl\u2e31H2<\/sub>O\uff1b<\/p>\n \uff08B\uff09C6<\/sub>N2<\/sub>H14<\/sub>NH4<\/sub>Cl3<\/sub>\uff1b<\/p>\n \uff08C\uff09R-3AQ-NH4<\/sub>Br3<\/sub> \u4f4e\u6e29\u76f8(LTP)\uff1b<\/p>\n \uff08D\uff09R-3AQ-NH4<\/sub>Br3<\/sub> \u4f4e\u6e29\u76f8 (HTP)\uff1b<\/p>\n \uff08E\uff09R-3AQ-NH4<\/sub>I3<\/sub> LTP\uff1b<\/p>\n \uff08F\uff09R-3AQ-NH4<\/sub>I3<\/sub> HTP\uff1b<\/p>\n \uff08G\uff09hmta-NH4<\/sub>Br3<\/sub>\uff1b<\/p>\n \uff08H\uff09H2<\/sub>DABCO-NH4<\/sub>BF4<\/sub>\uff1b<\/p>\n \uff08I\uff09DAP-O4<\/sub>\uff1b<\/p>\n \uff08J\uff09PIP-M4<\/sub>\u3002<\/p>\n \u56fe<\/strong> 2 MDABCO-NH4<\/sub>I3<\/sub><\/strong>\u7684\u94c1\u7535\u6027\u80fd<\/strong><\/p>\n \uff08A\uff09\u5728T0<\/sub>=448 K\u65f6\uff0cMDABCO-NH4<\/sub>I3<\/sub>\u7684\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff08DSC\uff09\u56fe\uff1b<\/p>\n \uff08B\uff09\u4e0d\u540c\u9891\u7387\u4e0b\uff0c\u590d\u4ecb\u7535\u5e38\u6570\u5b9e\u90e8\uff08\u0190’\uff09\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff1b<\/p>\n \uff08C\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b\uff0cPE\u78c1\u6ede\u56de\u7ebf\uff1b<\/p>\n \uff08D\uff09\u81ea\u53d1\u6781\u5316Ps\u548c\u4e8c\u9636\u975e\u7ebf\u6027\u5149\u5b66\u7cfb\u6570\u03c7(2)\u7684\u51fd\u6570\uff1b<\/p>\n \uff08E\uff09\u6587\u732e\u4e2d\u7ecf\u5178\u94c1\u7535\u4f53\u5bf9\u6bd4\u3002<\/p>\n \u56fe<\/strong> 3 hmtaH2<\/sub>-NH4<\/sub>Br3<\/sub><\/strong>\u7684\u94c1\u7535\u6027\u80fd<\/strong><\/p>\n \uff08A\uff09\u5355\u6676hmtaH2<\/sub>-NH4<\/sub>Br3<\/sub>\u7684P-E\u78c1\u6ede\u56de\u7ebf;<\/p>\n \uff08B\uff09\u591a\u6676hmtaH2<\/sub>-NH4<\/sub>Br3<\/sub>\u7684P-E\u78c1\u6ede\u56de\u7ebf\u3002<\/p>\n \u56fe<\/strong> 4 <\/strong>(H2<\/sub>DABCO)(NH4<\/sub>)[BF4<\/sub>]3<\/sub><\/strong>\u7684\u4ecb\u7535\u6027\u80fd<\/strong><\/p>\n \uff08A\uff09\u5728300-360 K\uff0c\u65e0\u91d1\u5c5e\u5316\u5408\u72691(H2<\/sub>DABCO)(NH4<\/sub>)[BF4<\/sub>]3<\/sub>\u548c\u5316\u5408\u72692(H2<\/sub>DABCO)Rb[BF4<\/sub>]3<\/sub>\u7684DSC\u66f2\u7ebf\uff1b<\/p>\n \uff08B\uff09\u57281 MHz\u4e0b\uff0c\u5316\u5408\u72691\u548c2\u7684\u538b\u7f29\u7c89\u672b\u7684\u4ecb\u7535\u5e38\u6570\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n \uff08C\uff0cD\uff09\u52a0\u70ed\u65f6\uff0c\u57281 MHz\u5904\uff0c\u5316\u5408\u72691\u548c\u5316\u5408\u72692\u6676\u4f53\u6837\u54c1\u7684a\uff0cb\u548cc\u8f74\u4e0a\u4ecb\u7535\u5e38\u6570\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb\uff1b<\/p>\n \uff08E\uff09\u5728\u76f8\u53d8\u6e29\u5ea6\u4ee5\u4e0b\u548c\u76f8\u53d8\u6e29\u5ea6\u4ee5\u4e0a\uff0c\u5316\u5408\u72691\u548c2\u9633\u79bb\u5b50\u7684\u6709\u5e8f\u65e0\u5e8f\u8f6c\u5316\u56fe\u3002<\/p>\n \u56fe<\/strong> 5<\/strong> MDABCO-NH4<\/sub>I3<\/sub><\/strong>\u7684\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n \uff08A\uff09MDABCO-NH4<\/sub>-X3<\/sub>\u7684\u538b\u7535\u6a21\u62dfa\uff09\u5e94\u53d8\u548cb\uff09\u5e94\u529b\u56fe\uff1b<\/p>\n \uff08B\uff09MDABCO-NH4<\/sub>I3<\/sub>\u7684\u6a21\u62df\u5f39\u6027\u67d4\u91cf\u5f20\u91cf\u56fe\uff1b<\/p>\n \uff08C\uff09MDABCO-NH4<\/sub>I3<\/sub>\u6837\u54c1\u7684\u56fa\u6001\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n \uff08D\uff09MDABCO-NH4<\/sub>I3<\/sub>\u6676\u4f53\u6837\u54c1\u7684\u5149\u81f4\u53d1\u5149\u6fc0\u53d1\u5149\u8c31\u548c\u5149\u81f4\u53d1\u5149\u53d1\u5c04\u5149\u8c31\u3002<\/p>\n \u56fe<\/strong> 6<\/strong> DABCO-NH4<\/sub>Br3<\/sub><\/strong>\u7684\u7ed3\u6784\u548c\u6027\u80fd<\/strong><\/p>\n \uff08A\uff09DABCO-NH4<\/sub>Br3<\/sub>\u6676\u4f53\u76f4\u63a5\u8dc3\u8fc1\u7684Tauc\u56fe\uff1b<\/p>\n \uff08B\uff09DABCO-NH4<\/sub>Br3<\/sub>\u6676\u4f53\u7684\u80fd\u5e26\u7ed3\u6784\uff1b<\/p>\n \uff08C\uff09\u9ed1\u6697\u4e0b\uff0c\u4e09\u4e2a\u4e0d\u540c\u7684\u5782\u76f4Au\/DABCO-NH4<\/sub>Br3<\/sub>\/Au\u6837\u54c1\u7684I-V\u66f2\u7ebf\uff1b<\/p>\n \uff08D\uff09\u7a7a\u7a74\u548c\u7535\u5b50\u5668\u4ef6\u7684\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n \uff08E\uff09\u7a7a\u7a74\u548c\u7535\u5b50DABCO-NH4<\/sub>Br3<\/sub>\u6676\u4f53\u5668\u4ef6\u7684\u504f\u538b\u4f9d\u8d56\u6027\u5149\u7535\u5bfc\u7387\uff1b<\/p>\n \uff08F\uff09\u572850 V\u504f\u538b\u4e0b\uff0cDABCO-NH4<\/sub>Br3<\/sub>\u6676\u4f53\u68c0\u6d4b\u5668\u7684X\u5c04\u7ebf\u654f\u611f\u6027\uff1b<\/p>\n \uff08G\uff09\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u7684\u6a21\u62df\u5e26\u9699\u548c\u4ecb\u7535\u5e38\u6570\u7684\u5173\u7cfb\uff1b<\/p>\n \uff08H\uff09\u57281 GPa\u548c\u4e0d\u540c\u7535\u573a\u53d8\u5316\u4e0b\uff0c\u5355\u6676EC DABCO-NH4<\/sub>Br3<\/sub>\u7684\u6e29\u5ea6\u53d8\u5316\u0394TEC<\/sub>\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n \u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u5177\u6709\uff081\uff09\u5316\u5b66\u591a\u6837\u6027\uff1a\u6839\u636eA\u3001B\u548cX\u7684\u6027\u8d28\uff0cABX3<\/sub>\u578b\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u53ef\u4ee5\u5206\u4e3a\u4e0d\u540c\u7684\u7c7b\u578b\u3002\u91d1\u5c5e\u57fa\u9499\u949b\u77ff\u7684\u79bb\u5b50\u534a\u5f84\u548c\u952e\u5408\u4f1a\u5f71\u54cd\u7a7a\u95f4\u586b\u5145\u3001\u7535\u8377\u5e73\u8861\u4ee5\u53ca\u7ed3\u6784\u5316\u5b66\uff0c\u8fdb\u800c\u6539\u53d8\u7269\u7406\u6027\u8d28\u3002\uff082\uff09\u7ed3\u6784\u53ef\u8c03\u6027\uff1aABX3<\/sub>\u7ed3\u6784\u5177\u6709\u76f8\u7ed3\u6784\u7ea6\u675f\u3002\u5f53\u589e\u52a0A\u79bb\u5b50\u7684\u5c3a\u5bf8\u65f6\uff0c\u53ef\u4ee5\u5f97\u5230\u4e00\u7cfb\u5217\u4f4e\u7ef4\u9499\u949b\u77ff\u3002\u8fd9\u4e3a\u5236\u5907\u7ed3\u6784\u591a\u6837\u6027\u7684\u6676\u4f53\u7ed3\u6784\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\uff083\uff09\u53ef\u52a0\u5de5\u6027\uff1a\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u53ef\u5b9e\u73b0\u4f4e\u6210\u672c\u548c\u5feb\u901f\u5370\u5237\u3002\uff084\uff09\u7535\u8377\u4f20\u8f93\u5c5e\u6027\uff1a\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u7684\u7535\u8377\u4f20\u8f93\u7814\u7a76\u8fd8\u4e0d\u5b8c\u5584\u3002\u57fa\u4e8e\u6709\u9650\u7684\u5149\u5b66\u7814\u7a76\uff0c\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u5177\u6709\u975e\u5e38\u5927\u7684\u5e26\u9699\uff08\u7ea65 eV\uff09\uff0c\u8fd9\u4f7f\u8bbe\u5907\u4e0d\u80fd\u5728\u53ef\u89c1\u5149\u4e0b\u8fd0\u884c\u3002\u7531\u4e8e\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u53ef\u4ee5\u5728\u6df1\u7d2b\u5916\u533a\u57df\u6216\u9ad8\u80fd\u8f90\u5c04\u8fdb\u884c\u5149\u6fc0\u53d1\uff0c\u56e0\u6b64\u5b83\u4eec\u5f88\u9002\u5408\u4f5c\u4e3a\u9ad8\u80fd\u8f90\u5c04\u7684\u63a2\u6d4b\u5668\u3002\uff085\uff09\u7a33\u5b9a\u6027\uff1a\u5c3d\u7ba1\u65e0\u91d1\u5c5e\u9499\u949b\u77ff\u7684\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u5176\u5927\u89c4\u6a21\u7684\u5546\u4e1a\u5e94\u7528\u3002<\/p>\n 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