{"id":217284,"date":"2021-02-07T06:30:16","date_gmt":"2021-02-06T22:30:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=217284"},"modified":"2021-03-03T11:46:07","modified_gmt":"2021-03-03T03:46:07","slug":"%e7%94%b5%e5%ad%90%e7%a7%91%e5%a4%a7%e8%8b%8f%e5%a4%a7-adv-funct-mater-%ef%bc%9a%e6%b0%a2%e9%94%ae%e8%be%85%e5%8a%a9%e7%9a%84%e6%bf%80%e5%9f%ba%e5%a4%8d%e5%90%88%e7%89%a9%e5%8f%91%e5%b0%84%e4%bd%93","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=217284","title":{"rendered":"\u7535\u5b50\u79d1\u5927&\u82cf\u5927 Adv. Funct. Mater.\uff1a\u6c22\u952e\u8f85\u52a9\u7684\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u5b9e\u73b0\u4e86\u9ad8\u6548\u7387\u4e14\u7a33\u5b9a\u7684OLED"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

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\u8fd1\u65e5\uff0c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u90d1\u624d\u4fca\u7814\u7a76\u5458\u548c\u82cf\u5dde\u5927\u5b66\u5f20\u6653\u5b8f\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5728\u4f9b\u7535\u5b50\u548c\u53d7\u7535\u5b50\u6784\u6210\u5206\u5b50\uff08D\u548cA\uff09\u4e4b\u95f4\u5f15\u5165\u5206\u5b50\u95f4\u6c22\u952e\uff08HB\uff09\u6765\u6291\u5236\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u7684\u975e\u8f90\u5c04\u8dc3\u8fc1\u7684\u65b0\u578b\u7b56\u7565\uff0c\u4ece\u800c\u6765\u63d0\u9ad8\u5176\u5728OLEDs\u4e2d\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\u3002\u4f5c\u8005\u4ee51, 3-\u4e8c\uff0810H-\u5429\u6076\u55ea-10-\u57fa\uff09\u82ef\uff0813PXZB\uff09\u4e3a\u4f9b\u4f53\uff0c4, 6-\u4e8c\uff083, 5-\u4e8c\uff08\u5421\u5576-4-\u57fa\uff09\u82ef\u57fa\uff09-2-\u7532\u57fa\u5627\u5576\uff08B4PyMPM\uff09\u30014, 6-\u4e8c\uff083, 5-\u4e8c\uff08\u5421\u5576-3-\u57fa\uff09\u82ef\u57fa\uff09-2-\u7532\u57fa\u5627\u5576\uff08B3PyMPM\uff09\u548c4, 6-\u4e8c\uff083, 5-\u4e8c\uff08\u5421\u5576-2-\u57fa\uff09\u82ef\u57fa\uff09-2-\u7532\u57fa\u5627\u5576\uff08B2PyMPM\uff09\u4e3a\u53d7\u4f53\u6784\u5efa\u4e86\u4e09\u79cd\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u3002\u5176\u4e2d\uff0c\u5177\u6709\u5206\u5b50\u95f4HBs\u6700\u591a\u768413PXZB: B4PyMPM\uff0c\u663e\u793a\u51fa\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08\u03a6<\/em>PL<\/sub>\uff09\u6700\u9ad8\u8fbe\u523069.6\uff05\u548c\u6700\u4f4e\u7684\u4e09\u91cd\u6001\u6fc0\u5b50\u975e\u8f90\u5c04\u8fc7\u7a0b\u901f\u7387\u5e38\u6570\uff08k<\/em>nr<\/sub>T<\/sup>\uff09\u4e3a3.4\u00d7105<\/sup> S-1<\/sup>\uff09\u3002\u540c\u65f6\uff0c\u5728OLEDs\u4e2d\uff0c\u4f7f\u752813PXZB: B4PyMPM\u548c13PXZB: B3PyMPM\u7684\u6700\u5927\u5916\u90e8\u91cf\u5b50\u6548\u7387\uff08EQEs\uff09\u5206\u522b\u4e3a14.6\uff05\u548c10.0\uff05\uff0c\u5206\u522b\u662fEQE\u4e3a6.2\uff05\u768413PXZB: B2PyMPM\u76842.3\u548c1.6\u500d<\/strong>\u3002\u6b64\u5916\uff0cD\u548cA\u5206\u5b50\u4e4b\u95f4\u7684\u5206\u5b50\u95f4HB\u6709\u5229\u4e8e\u63d0\u9ad8\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u7684\u7535\u81f4\u53d1\u5149\uff08EL\uff09\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c13PXZB: B4PyMPM\u7684\u534a\u8870\u671f\uff08LT50<\/sub>\uff09\u5206\u522b\u662f\u6bd413PXZB: B3PyMPM\u548c13PXZB: B2PyMPM\u76844.8\u500d\u548c8.2\u500d\u3002\u603b\u4e4b\uff0c\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u8bc1\u660e\u4e86D\u548cA\u5206\u5b50\u95f4\u7684HBs\u53ef\u4ee5\u6539\u5584\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u7684\u6027\u80fd\uff0c\u800c\u4e14\u4e3a\u7814\u5236\u9ad8\u6548\u7a33\u5b9a\u7684\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u5f00\u8f9f\u4e86\u4e00\u6761\u65b0\u7684\u9014\u5f84\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cHydrogen-Bond-Assisted Exciplex Emitters Realizing Improved Efficiencies and Stabilities in Organic Light Emitting Diodes\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aAdv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n

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\u56fe\u4e00\u3001\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u4ee5\u53ca\u76f8\u5bf9\u8f90\u5c04\u548c\u975e\u8f90\u5c04\u8fc7\u7a0b\u7684Jablonski\u80fd\u91cf\u56fe<\/strong><\/p>\n

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\n \"\"a\uff0913PXZB\u3001B4PyMPM\u3001B3PyMPM\u548cB2PyMPM\u7684\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

b\uff09\u5728\u56fa\u6001\u8584\u819c\u4e2d13PXZB: B4PyMPM\u53ca\u5176\u521d\u59cb\u6750\u6599\u7684\u5438\u6536\u5149\u8c31\u548cPL\u5149\u8c31\uff1b<\/p>\n

c\uff09\u5728\u56fa\u6001\u8584\u819c\u4e2d13PXZB: B3PYMPM\u53ca\u5176\u521d\u59cb\u6750\u6599\u7684\u5438\u6536\u5149\u8c31\u548cPL\u5149\u8c31\uff1b<\/p>\n

d\uff09\u5728\u56fa\u6001\u8584\u819c\u4e2d13PXZB: B2PyMPM\u53ca\u5176\u521d\u59cb\u6750\u6599\u7684\u5438\u6536\u5149\u8c31\u548cPL\u5149\u8c31\u3002<\/p>\n

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\n \"\"a\uff09\u5177\u6709\u4e0d\u540c\u91cd\u91cf\u6bd4\uff088: 2\u30017: 3\u548c5: 5\uff09\u768413PXZB: B4PyMPM\u53ca\u5176\u6784\u6210\u6210\u5206\uff0c\u6ce2\u6570\u4e3a2900-3150 cm-1\uff1b<\/p>\n

b\uff09\u5177\u6709\u4e0d\u540c\u91cd\u91cf\u6bd4\uff088: 2\u30017: 3\u548c5: 5\uff09\u768413PXZB: B3PyMPM\u53ca\u5176\u6784\u6210\u6210\u5206\uff0c\u6ce2\u6570\u4e3a2900-3150 cm-1\u3002<\/p>\n

c\uff09\u5177\u6709\u4e0d\u540c\u91cd\u91cf\u6bd4\uff088: 2\u30017: 3\u548c5: 5\uff09\u768413PXZB: B2PyMPM\u53ca\u5176\u6784\u6210\u6210\u5206\uff0c\u6ce2\u6570\u4e3a2900-3150 cm-1\u3002<\/p>\n

\u56fe\u56db\u3001\u5173\u952e\u539f\u5b50\u7684\u5e73\u5747\u9759\u7535\u52bf\uff08ESP\uff09\u7edf\u8ba1\u6570\u636e<\/strong>
\n \"\"a\uff0913PXZB\uff1b<\/p>\n

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\n \"\"a\uff09B4PyMPM\u548cB4PyMPM\uff1b<\/p>\n

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\n \"\"a\uff09\u7535\u6d41\u5bc6\u5ea6-\u4eae\u5ea6-\u7535\u538b\u7279\u6027\uff1b<\/p>\n

b\uff09EQE-\u4eae\u5ea6\u56fe\uff1b<\/p>\n

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\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u5728D\u548cA\u5206\u5b50\u4e4b\u95f4\u5f15\u5165\u5206\u5b50\u95f4HBs\u6765\u63d0\u9ad8\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u6027\u80fd\u7684\u65b0\u7b56\u7565\u3002\u6587\u4e2d\uff0c\u4f5c\u8005\u6784\u9020\u4e8613PXZB: B4PyMPM\u300113PXZB: B3PyMPM\u548c13PXZB: B2PyMPM\u4e09\u79cd\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5149\u4f53\u3002\u6839\u636eDFT\u8ba1\u7b97\u548cFT-IR\u6d4b\u91cf\u7684\u7ed3\u679c\uff0c\u9884\u6d4b13PXZB: B4PyMPM\u5728D\u548cA\u5206\u5b50\u4e4b\u95f4\u7684\u5206\u5b50\u95f4HBs\u6bd413PXZB: B3PyMPM\u591a\uff0c\u800c13PXZB: B2PyMPM\u4e4b\u95f4\u4e0d\u80fd\u5f62\u6210\u5206\u5b50\u95f4HBs\u3002\u56e0\u6b64\uff0c\u5728\u4e09\u79cd\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u4e2d\uff0c13PXZB: B4PyMPM\u7684\u03a6<\/em>PL<\/sub>\u6700\u9ad8\u4e3a69.6\uff05\uff0c\u6700\u4f4ek<\/em>nr<\/sub>T<\/sup>\u4e3a3.4\u00d7105<\/sup> S-1<\/sup>\u3002\u5728OLED\u4e2d\uff0c13PXZB: B4PyMPM\u7684\u6700\u5927EQE\u4e3a14.6\uff05\uff0c\u660e\u663e\u9ad8\u4e8e\u5176\u4ed6\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u3002\u540c\u65f6\uff0c13PXZB: B4PyMPM\u57faOLED\u7684LT50\u5206\u522b\u662f13PXZB: B3PyMPM\u57fa\u548c13PXZB: B2PyMPM\u57faOLED\u76844.8\u548c8.2\u500d\u3002\u6b64\u5916\uff0c\u5bf9\u6bd413PXZB-\u548c13AB-\u57fa\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u4e4b\u95f4\u7684\u6027\u80fd\uff0c\u53d1\u73b0HB-\u8f85\u52a9\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u7684\u6027\u80fd\u5f97\u5230\u4e86\u6539\u5584\uff0c\u4e3b\u8981\u662f\u56e0\u4e3aD\u548cA\u5206\u5b50\u4e4b\u95f4\u7684\u5206\u5b50\u95f4HBs\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660eHB-\u8f85\u52a9\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u7684\u4f18\u8d8a\u6027\uff0c\u4e3a\u5f00\u53d1\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684\u6fc0\u57fa\u590d\u5408\u7269\u53d1\u5c04\u4f53\u63d0\u4f9b\u4e86\u4e00\u6761\u65b0\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHydrogen-Bond-Assisted Exciplex Emitters Realizing Improved Efficiencies and Stabilities in Organic Light Emitting Diodes<\/a><\/strong>. Adv. Funct. Mater.<\/em>, 2021<\/strong>, DOI: 10.1002\/adfm.202010100.<\/p>\n

 <\/p>\n

1\u3001\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong>\u672c\u5de5\u4f5c\u7814\u7a76\u56e2\u961f\u4e00\u76f4\u81f4\u529b\u4e8e\u6709\u673a\u5149\u7535\u6750\u6599\u76f8\u5173\u9886\u57df\u7814\u7a76\uff0c\u4e3b\u8981\u4ece\u4e8b\u6709\u673a\u5149\u7535\u6750\u6599\u7684\u8bbe\u8ba1\uff0c\u5408\u6210\u548c\u5236\u5907\u9ad8\u6548\u7684\u6709\u673a\u7535\u81f4\u53d1\u5149\u5668\u4ef6\uff0c\u53d1\u5c55\u548c\u5b8c\u5584\u4e86\u70ed\u6fc0\u6d3b\u5ef6\u8fdf\u8367\u5149\u6fc0\u57fa\u590d\u5408\u7269\u7684\u53d1\u5149\u673a\u5236\u548c\u5668\u4ef6\u6027\u80fd\u3002<\/p>\n

2\u3001\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5728\u57fa\u4e8e\u70ed\u6fc0\u53d1\u5ef6\u8fdf\u8367\u5149\u6fc0\u57fa\u590d\u5408\u7269OLED\u65b9\u9762\u53d6\u5f97\u4e00\u7cfb\u5217\u7814\u7a76\u6210\u679c\u3002<\/p>\n

1. Prediction and Design of Efficient Exciplex Emitters for High-Efficiency, Thermally Activated Delayed-Fluorescence Organic Light-Emitting Diodes, Adv. Mater.<\/em>, 2015<\/strong>, 27<\/em>, 2378\u20132383;<\/p>\n

2. Nearly 100% Triplet Harvesting in Conventional Fluorescent Dopant-Based Organic Light-Emitting Devices Through Energy Transfer from Exciplex, Adv. Mater.<\/em>, 2015<\/strong>, 27<\/em>, 2025\u20132030;<\/p>\n

3. Novel Strategy to Develop Exciplex Emitters for High Performance OLEDs by Employing Thermally Activated Delayed Fluorescence Materials, Adv. Funct. Mater.<\/em>, 2016<\/strong>, 26<\/em>, 2002\u20132008;<\/p>\n

4.Tricomponent Exciplex Emitter Realizing over 20% External Quantum Efficiency in Organic Light\u2010Emitting Diode with Multiple Reverse Intersystem Crossing Channels, Adv. Sci.<\/em>, 2019<\/strong>, 6<\/em>, 1801938<\/p>\n

5. Novel small-molecule electron donor for solution-processed ternary exciplex with 24% external quantum efficiency in organic light-emitting diode, Mater. Horiz.<\/em>, 2019<\/strong>, 6<\/em>, 1425-1432.<\/p>\n

6. Thermally activated delayed fluorescence exciplex emitters for high-performance organic light-emitting diodes, Mater. Horiz.<\/em>, 2021<\/strong>, DOI: 10.1039\/D0MH01245A.<\/p>\n

7. Hydrogen\u2010Bond\u2010Assisted Exciplex Emitters Realizing Improved Efficiencies and Stabilities in Organic Light Emitting Diodes, Adv. Funct. Mater.<\/em>, 2021<\/strong>, DOI: 10.1002\/adfm.202010100.<\/p>\n

3. \u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350<\/strong><\/p>\n

\u6700\u8fd1\u53d1\u8868\u7684\u6587\u732e\u63a8\u8350:<\/strong><\/p>\n

1. Thermally activated delayed fluorescence exciplex emitters for high-performance organic light-emitting diodes, Mater. Horiz.<\/em>, 2021<\/strong>, DOI: 10.1039\/D0MH01245A;<\/p>\n

2. Tricomponent Exciplex Emitter Realizing over 20% External Quantum Efficiency in Organic Light\u2010Emitting Diode with Multiple Reverse Intersystem Crossing Channels, Adv. Sci.<\/em>, 2019<\/strong>, 6<\/em>, 1801938<\/p>\n

\u672c\u6587\u7531CQR\u7f16\u8bd1\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"

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