{"id":216629,"date":"2021-01-30T06:18:53","date_gmt":"2021-01-29T22:18:53","guid":{"rendered":"\/\/m.iemloyee.com\/?p=216629"},"modified":"2021-01-28T21:36:53","modified_gmt":"2021-01-28T13:36:53","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e5%bb%96%e8%b5%9b%e8%99%8enat-commun-%ef%bc%9a%e9%98%b3%e5%85%89%e4%b8%8b%e5%ae%9e%e7%8e%b0%e5%be%ae%e9%87%8f%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=216629","title":{"rendered":"\u798f\u5dde\u5927\u5b66\u5ed6\u8d5b\u864eNat. Commun. \uff1a\u9633\u5149\u4e0b\u5b9e\u73b0\u5fae\u91cf\u5149\u50ac\u5316\u5242\u7684\u6709\u673a\u50ac\u5316\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u4f20\u7edf\u7684\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408(ATRP)\u4f9d\u8d56\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u8fd9\u5c06\u5bfc\u81f4\u6700\u7ec8\u4ea7\u7269\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c61\u67d3\u3002\u56e0\u6b64\uff0c\u81eaATRP\u7684\u9996\u6b21\u53d1\u73b0\u4ee5\u6765\uff0c\u4eba\u4eec\u4e00\u76f4\u81f4\u529b\u4e8e\u964d\u4f4e\u50ac\u5316\u5242\u8d1f\u8f7d\u6216\u6b8b\u7559\u91d1\u5c5e\u7684\u53bb\u9664\u3002\u6700\u8fd1\u51fa\u73b0\u7684\u4f7f\u7528\u6709\u673a\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u7684\u6709\u673a\u50ac\u5316\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408(O-ATRP)\u65e0\u7591\u662f\u89e3\u51b3\u8fd9\u4e00\u6311\u6218\u6027\u95ee\u9898\u7684\u7406\u60f3\u65b9\u6848\u3002\u56e0\u6b64\uff0c\u5728O-ATRP\u4e2d\uff0c\u5f00\u53d1\u9ad8\u6548\u7387\u548c\u4f4e\u8d1f\u8f7d\u7684\u5149\u50ac\u5316\u5242\u5df2\u6210\u4e3a\u8fd1\u5e74\u6765\u5e7f\u6cdb\u7814\u7a76\u7684\u7126\u70b9\u3002\u7136\u800c\uff0cO-ATRP\u7684\u8bb8\u591a\u673a\u7406\u81f3\u4eca\u4ecd\u4e0d\u6e05\u695a\uff0c\u4e14\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u8fd8\u7f3a\u4e4f\u4e00\u822c\u7684\u6307\u5bfc\u6027\u539f\u5219\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u5ed6\u8d5b\u864e\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5728\u671f\u520a<em>Nat. Commun.<\/em> \u62a5\u9053\u4e86\u57fa\u4e8e\u591a\u73af\u82b3\u70c3\u7684\u6742\u539f\u5b50\u63ba\u6742\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u6848\uff0c\u53d1\u73b0\u4e86\u6c27\u63ba\u6742\u84bd\u5d4c\u84bd(ODA)\u53ef\u4f5c\u4e3a\u7528\u4e8eO-ATRP\u7684\u9ad8\u6548\u7684\u6709\u673a\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u3002ODA\u4e0e\u719f\u77e5\u7684\u6709\u673a\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u5177\u6709\u663e\u8457\u7684\u53ef\u89c1\u5149\u5438\u6536\u548c\u9ad8\u6469\u5c14\u6d88\u5149\u7cfb\u6570\uff08\u03b5<sub>455nm<\/sub>\u9ad8\u8fbe23,950 M<sup>\u20131<\/sup> cm<sup>\u20131<\/sup>\uff09\uff0c\u5141\u8bb8\u5728\u65e5\u5149\u4e0b\u4ee5\u4f4e\u8d1f\u8f7d\u7684\u50ac\u5316\u5242\u5b9e\u73b0\u53ef\u63a7\u805a\u5408\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u56fe1.O-ATRP\u7684\u50ac\u5316\u5242\u7684\u53d1\u5c55<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-216630\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig1_HTML.webp_.jpg\" alt=\"\" width=\"600\" height=\"598\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig1_HTML.webp_.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig1_HTML.webp_-150x150.jpg 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig1_HTML.webp_-300x300.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>a <\/strong>\u901a\u8fc7\u6838\u5fc3\u9aa8\u67b6\u6539\u6027\u5f00\u53d1\u50ac\u5316\u5242<\/p>\n<p><strong>b <\/strong>\u57fa\u4e8e\u6742\u539f\u5b50\u63ba\u6742\u7684O-ATRP\u7684\u5149\u50ac\u5316\u5242\u8bbe\u8ba1\uff08\u8fd9\u9879\u5de5\u4f5c\uff09<\/p>\n<p><strong>c <\/strong>O-ATRP\u7684\u50ac\u5316\u5faa\u73af\u673a\u7406<\/p>\n<p><strong>d <\/strong>\u9633\u5149\u4e0b\u7684\u805a\u5408\u53cd\u5e94\u548c\u4ea7\u7269\u989c\u8272\uff08PMMA\uff09<\/p>\n<p>\u56fe2.\u5149\u50ac\u5316\u5242\u7684\u5408\u6210\u548c\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-216633\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig2_HTML.webp_.jpg\" alt=\"\" width=\"600\" height=\"555\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig2_HTML.webp_.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig2_HTML.webp_-300x278.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>a <\/strong>ODA<strong>5a\u2013d<\/strong>\u7684\u5408\u6210<\/p>\n<p><strong>b <\/strong>\u7d2b\u5916-\u53ef\u89c1\u5149\u5438\u6536\u66f2\u7ebf<\/p>\n<p><strong>c <\/strong>5a\u548c5d\u7684SOMO\u8f68\u9053\u548c\u4e09\u91cd\u6fc0\u53d1\u6001\u7684\u8fd8\u539f\u80fd\u529b<\/p>\n<p><strong>d<\/strong> \u5149\u50ac\u5316\u5242<strong>5a\u20135d<\/strong>\u7684\u8868\u5f81\u6570\u636e<\/p>\n<p>\u56fe3. ODA 5d\u50ac\u5316\u7684MMA\u7684O-ATRP\u7684\u65f6\u5e8f\u63a7\u5236\u548c\u52a8\u529b\u5b66\u7814\u7a76<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-216632\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig3_HTML.webp_.jpg\" alt=\"\" width=\"600\" height=\"440\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig3_HTML.webp_.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig3_HTML.webp_-300x220.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>a<\/strong>\u00a0 \u5f00-\u5173\u706f\u5b9e\u9a8c\u548c\u5355\u4f53\u8f6c\u5316\u7387\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf<\/p>\n<p><strong>b<\/strong>\u00a0 \u65e0\u91d1\u5c5e\u50ac\u5316ATRP\u7684\u52a8\u529b\u5b66\u66f2\u7ebf<\/p>\n<p><strong>c<\/strong>\u00a0 \u00a0\u6301\u7eed\u5149\u7167\u4e0b\u7684MMA\u7684\u805a\u5408\u53cd\u5e94\u7684<em>M<sub>n<\/sub><\/em>\u548c<em>\u0110<\/em>\u4e0e\u5355\u4f53\u8f6c\u5316\u7387\u7684\u5173\u7cfb\u66f2\u7ebf<\/p>\n<p><strong>d<\/strong>\u00a0 (<strong>c<\/strong>)\u4e2d\u6bcf\u79cd\u805a\u5408\u7269\u7684GPC\u66f2\u7ebf<\/p>\n<p>\u56fe4.\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u5236\u5907<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-216631\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig4_HTML.webp_.jpg\" alt=\"\" width=\"600\" height=\"246\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig4_HTML.webp_.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2021\/01\/41467_2020_20645_Fig4_HTML.webp_-300x123.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>a<\/strong> \u7531PMMA\u5927\u5206\u5b50\u5f15\u53d1\u5242\uff08\u9ed1\uff09\u5236\u5907PMMA-<em>b<\/em>-PMMA\uff08\u7eff\uff09\u3001PMMA-<em>b<\/em>-PBnMA\uff08\u7ea2\uff09\u548cPMMA-<em>b<\/em>-PBA\uff08\u84dd\uff09<\/p>\n<p><strong>b <\/strong><strong>\u5bf9\u5e94\u7684<\/strong>PMMA\u3001PMMA-<em>b<\/em>-PMMA\u3001PMMA-<em>b<\/em>-PBnMA\u548cPMMA-<em>b<\/em>-PBA\u7684GPC\u66f2\u7ebf<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41467-020-20645-8?utm_source=other&amp;utm_medium=other&amp;utm_content=null&amp;utm_campaign=JRCN_1_LW01_CN_natureOA_article_paid_XMOL#author-information\">Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight<\/a>\uff08<i>Nat Commun\uff0c2021\uff0cDOI\uff1a<\/i>10.1038\/s41467-020-20645-8<i><\/i>\uff09<\/p>\n<p>\u672c\u6587\u7531kv1004\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u4f20\u7edf\u7684\u539f\u5b50\u8f6c\u79fb\u81ea\u7531\u57fa\u805a\u5408(ATRP)\u4f9d\u8d56\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u8fd9\u5c06\u5bfc\u81f4\u6700\u7ec8\u4ea7\u7269\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c61\u67d3\u3002\u56e0\u6b64\uff0c\u81eaATRP\u7684\u9996\u6b21\u53d1\u73b0\u4ee5\u6765\uff0c\u4eba\u4eec\u4e00\u76f4\u81f4\u529b\u4e8e\u964d\u4f4e\u50ac\u5316\u5242\u8d1f\u8f7d\u6216&#8230;<\/p>\n","protected":false},"author":1592,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-216629","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/216629"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/1592"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=216629"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/216629\/revisions"}],"predecessor-version":[{"id":216930,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/216629\/revisions\/216930"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=216629"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=216629"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=216629"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}