{"id":21554,"date":"2016-06-25T08:10:13","date_gmt":"2016-06-25T00:10:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=21554"},"modified":"2016-06-24T21:35:51","modified_gmt":"2016-06-24T13:35:51","slug":"nature-communications-%e6%be%b3%e5%ad%a6%e8%80%85%e5%bc%80%e5%8f%91%e9%87%91%e5%b1%9e%e9%94%82%e8%b4%9f%e6%9e%81%e9%a2%84%e5%a4%84%e7%90%86%e6%96%b9%e6%b3%95-%e6%98%be%e8%91%97%e6%8f%90%e9%ab%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=21554","title":{"rendered":"Nature Communications: \u6fb3\u5b66\u8005\u5f00\u53d1\u91d1\u5c5e\u9502\u8d1f\u6781\u9884\u5904\u7406\u65b9\u6cd5 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\/>\nSEM\u56fe\u50cf\u7684\u6bd4\u4f8b\u5c3a\u5747\u4e3a50um\uff0c\u53f3\u4e0a\u89d2\u63d2\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a10um\u3002<\/p>\n<p style=\"text-align: left;\"><strong>\u56fe2 \u9502\u5bf9\u79f0\u7535\u6c60\u57280.1mAcm-1\u7535\u6d41\u5bc6\u5ea6\u4e0b5000\u6b21\u5faa\u73af\u7684\u8868\u5f81<\/strong><\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-21917\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/2-39.jpg\" alt=\"2\" width=\"500\" height=\"440\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/2-39.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/2-39-300x264.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: left;\"><span style=\"line-height: 1.5;\">(a)(b)\u56fe\u5c55\u793a\u4e86\u672a\u9884\u5904\u7406\u7684Li|\u7535\u89e3\u8d28|Li\u5bf9\u79f0\u7535\u6c60\u5145\u653e\u7535\u5faa\u73af\u6d4b\u8bd5\u7684\u7535\u538b-\u65f6\u95f4\u56fe\u7ebf\uff0c\u5176\u4e2d(a)\u91c7\u7528\u542bLiPF6\u7684[C3mPyr+][FSI-]\u7535\u89e3\u6db2\uff0c\u7ecf\u8fc71300\u6b21\u5faa\u73af\uff08\u7ea6250h\uff09\u540e\u5931\u6548\uff0c\u4f46\u5728\u4f11\u7720\u4e8622\u5929\u540e\uff0c\u53c8\u5faa\u73af\u4e86100\u591a\u6b21\u624d\u5f7b\u5e95\u5931\u6548\u3002<\/span><span style=\"line-height: 1.5;\">(b)\u91c7\u7528\u542bLiAsF6\u7684[C3mPyr+][FSI-]\u7535\u89e3\u6db2\uff0c\u53ef\u4ee5\u5faa\u73af5000\u6b21\u3002<\/span><span style=\"line-height: 1.5;\">(c)-(h)\u7684SEM\u56fe\u50cf\u5c55\u793a\u4e86\u9502\u679d\u6676\u88ab\u6291\u5236\u7684\u60c5\u51b5\uff0c\u5176\u4e2d\u91c7\u7528LiFSI\/[C3mPyr+][FSI-]\u7535\u89e3\u6db2\u7684\u7535\u6c60\u8d1f\u6781\u89c1(c)\u56fe\uff0c\u9694\u819c\u89c1(d)\u56fe\uff1b\u91c7\u7528LiAsF6\/[C3mPyr+][FSI-]\u7535\u89e3\u6db2\u7684\u7535\u6c60\u8d1f\u6781\u89c1(e)\u56fe\uff0c\u9694\u819c\u89c1(f)\u56fe\uff1b\u91c7\u7528LiPF6\/[C3mPyr+][FSI-]\u7535\u89e3\u6db2\u7684\u7535\u6c60\u8d1f\u6781\u89c1(g)\u56fe\uff0c\u9694\u819c\u89c1(h)\u56fe,<\/span><span style=\"line-height: 1.5;\">SEM\u56fe\u50cf\u7684\u6bd4\u4f8b\u5c3a\u5747\u4e3a50um\uff0c\u53f3\u4e0a\u89d2\u63d2\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a10um\u3002<\/span>\u636e\u62a5\u9053\u91c7\u7528LiFSI\/[C3mPyr+][FSI-]\u7535\u89e3\u6db2\u7684\u7535\u6c60\u4e5f\u80fd\u5faa\u73af5000\u591a\u6b21\uff0c\u53ef\u89c1SEI\u819c\u7684\u7535\u5316\u5b66\u6027\u80fd\u4e0e\u9502\u76d0\u79cd\u7c7b\u6709\u5173\u3002<\/p>\n<p style=\"text-align: left;\">(a)\u56fe\u53ef\u4ee5\u8bf4\u660e\u7535\u6c60\u6700\u7ec8\u5931\u6548\u4e0d\u662f\u9502\u679d\u6676\u5f15\u8d77\u7684\u77ed\u8def\u95ee\u9898\uff0c(c)(e)(g)\u56fe\u4e2d\u9502\u8d1f\u6781\u8868\u9762\u4e5f\u6ca1\u6709\u660e\u663e\u7684\u679d\u6676\u751f\u6210\u3002\u5728(d)(f)(h)\u56fe\u4e2d\uff0c\u6211\u4eec\u53ef\u4ee5\u53d1\u73b0\u7535\u89e3\u6db2\u5206\u89e3\u4ea7\u7269\u5835\u585e\u4e86\u9694\u819c\u7684\u5b54\u9699\u7ed3\u6784\uff0c\u8fdb\u800c\u5f97\u51fa\u7535\u6c60\u5931\u6548\u7684\u5b9e\u9645\u539f\u56e0\uff0c\u5176\u5b9e\u662f\u9502\u8d1f\u6781\u8868\u9762\u79ef\u589e\u52a0\u7684\u901f\u5ea6\u8d76\u4e0d\u4e0a\u9694\u819c\u5b54\u9699\u88ab\u5835\u585e\u7684\u901f\u5ea6\uff0c\u963b\u788d\u4e86Li+\u7684\u4f20\u8f93\u3002<\/p>\n<p style=\"text-align: left;\"><strong>\u56fe3 \u672a\u5904\u7406\u548c\u9884\u5904\u740612\u5929\u540e\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31<\/strong><\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-21918\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/3-36.jpg\" alt=\"3\" width=\"429\" height=\"650\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/3-36.jpg 429w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/3-36-198x300.jpg 198w\" sizes=\"(max-width: 429px) 100vw, 429px\" \/><\/p>\n<p style=\"text-align: left;\">\u00a0(a)\u56fe\u4e3a\u672a\u5904\u7406\u7684\u4ee5LiAsF6\/[C3mPyr+][FSI-]\u4e3a\u7535\u89e3\u6db2\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u5948\u594e\u65af\u7279\u56fe\u8c31\uff0c\u5176\u4e2d\u9ed1\u7ebf\u8868\u793a\u521d\u59cb\u72b6\u6001\uff0c\u754c\u9762\u7535\u963b\u4e3a251.5\u2126cm-2;\u7ea2\u7ebf\u8868\u793a\u7535\u6d41\u5bc6\u5ea60.1mAcm-1\uff0c\u7ecf\u8fc75000\u6b21\u5faa\u73af\u540e\u7684\u72b6\u6001\uff0c\u7535\u6c60\u7684\u754c\u9762\u7535\u963b\u964d\u4e3a51.3\u2126cm-2 (b)\u56fe\u662f\u9502\u7535\u6781\u7ecf\u8fc712\u5929\u9884\u5904\u7406\u7684\u4ee5LiFSI\/[C3mPyr+][FSI-]\u4e3a\u7535\u89e3\u6db2\u7684\u7535\u6c60\u7684\u963b\u6297\u8c31\uff0c\u5176\u4e2d\u9ed1\u7ebf\u8868\u793a\u521d\u59cb\u72b6\u6001\uff1b\u7ea2\u7ebf\u8868\u793a\u7535\u6d41\u5bc6\u5ea61.0mAcm-1\uff0c\u9996\u6b21\u5145\u7535\u540e\u7684\u60c5\u51b5\uff1b\u84dd\u7ebf\u8868\u793a\u5728\u540c\u6837\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u7ecf\u8fc7333\u6b21\u5faa\u73af\u540e\u7684\u60c5\u51b5\uff0c\u7535\u6c60\u7684\u754c\u9762\u7535\u963b\u540c\u6837\u660e\u663e\u4e0b\u964d\u3002<\/p>\n<p style=\"text-align: left;\"><strong>\u56fe4 \u57281.0mAcm-1\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u4e0d\u540c\u9884\u5904\u7406\u65f6\u95f4\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u6bd4\u8f83<\/strong><\/p>\n<p style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-21919\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/4-24.jpg\" alt=\"4\" width=\"500\" height=\"458\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/4-24.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/4-24-300x275.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" 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style=\"text-align: left;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-21920\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/5-21.jpg\" alt=\"5\" width=\"500\" height=\"300\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/5-21.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/5-21-300x180.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: left;\">(a)\u56fe\u662f2.0mAcm-1\u4e0b500\u6b21\u5145\u653e\u7535\u5faa\u73af\u7684\u7535\u538b-\u5faa\u73af\u6b21\u6570\u66f2\u7ebf\uff1b<br \/>\n(b)\u56fe\u7535\u6d41\u5bc6\u5ea6\u4f9d\u6b21\u8bbe\u7f6e\u4e3a0.1mAcm-1\uff0c1mAcm-1\uff0c5mAcm-1\u548c10mAcm-1\uff0c\u5728\u6bcf\u79cd\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5747\u5145\u653e\u7535\u5faa\u73af50\u6b21\uff1b<br 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decoding=\"async\" class=\"aligncenter size-full wp-image-21921\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/6-23.jpg\" alt=\"6\" width=\"500\" height=\"379\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/6-23.jpg 500w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/06\/6-23-300x227.jpg 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" 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\/>\n\u7814\u7a76\u8005\u8fd8\u5229\u7528SEM\u6280\u672f\u89c2\u5bdf\u4e86\u8be5\u4f53\u7cfb\u7535\u6c60\u7684\u5fae\u89c2\u5f62\u8c8c\uff0c\u7ed3\u679c\u5982\u56fe(f)-(i)\u6240\u793a\uff0c\u5176\u4e2d(f)\u662f\u9502\u8d1f\u6781\uff1b(g)\u662f\u9502\u8d1f\u6781\u7684\u9ad8\u500d\u653e\u5927\u6548\u679c\uff1b(h)\u662f\u9502\u8d1f\u6781\u7684\u6a2a\u622a\u9762\uff1b(i)\u662f\u9694\u819c\u6750\u6599\uff0c\u56fe(g)\u4e2d\u7684\u6807\u5c3a\u4ee3\u886810um\uff0c\u5176\u4f59\u56fe\u7247\u4e2d\u5747\u4e3a100um.<\/p>\n<p>\u6587\u732e\u5730\u5740\uff1a<a href=\"http:\/\/www.nature.com\/ncomms\/2016\/160613\/ncomms11794\/full\/ncomms11794.html\" target=\"_blank\">Stabilizing lithium metal using ionic liquids for long-lived batteries<\/a><\/p>\n<p>\u611f\u8c22\u7f16\u8f91\u90e8\u7cef\u7c73\u63d0\u4f9b\u7d20\u6750<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u7b80\u4ecb\u3011 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