{"id":215483,"date":"2021-01-03T19:48:22","date_gmt":"2021-01-03T11:48:22","guid":{"rendered":"\/\/m.iemloyee.com\/?p=215483"},"modified":"2021-01-03T08:03:34","modified_gmt":"2021-01-03T00:03:34","slug":"%e6%9d%8e%e7%81%bf%e9%99%a2%e5%a3%ab%e3%80%81%e5%bc%a0%e6%b6%9b%e9%99%a2%e5%a3%ab%e3%80%81%e6%9d%8e%e4%ba%9a%e6%a0%8b%e9%99%a2%e5%a3%ab%e4%b8%89%e5%a4%a7%e9%99%a2%e5%a3%ab%e7%bb%842020%e5%b9%b4","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=215483","title":{"rendered":"\u674e\u707f\u9662\u58eb\u3001\u5f20\u6d9b\u9662\u58eb\u3001\u674e\u4e9a\u680b\u9662\u58eb\u4e09\u5927\u9662\u58eb\u7ec42020\u5e74\u7814\u7a76\u5de5\u4f5c\u603b\u7ed3"},"content":{"rendered":"
<\/p>\n
\u674e\u707f\uff0c1960\u5e741\u6708\u751f\u4e8e\u7518\u8083\u6c38\u660c\uff0c\u7406\u5b66\u535a\u58eb\uff0c\u7814\u7a76\u5458\u3002\u73b0\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5b66\u4f4d\u59d4\u5458\u4f1a\u4e3b\u4efb\uff0c\u50ac\u5316\u57fa\u7840\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\u548c\u4e2d\u6cd5\u50ac\u5316\u8054\u5408\u5b9e\u9a8c\u5ba4\u4e2d\u65b9\u4e3b\u4efb\u30022003\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002\u4e3b\u8981\u7684\u7814\u7a76\u65b9\u5411\u6d89\u53ca\u50ac\u5316\u5242\u7684\u5149\u8c31\u8868\u5f81\u548c\u50ac\u5316\u53cd\u5e94\uff0c\u73af\u5883\u50ac\u5316\uff0c\u975e\u5747\u76f8\u624b\u6027\u50ac\u5316\u3002\u5148\u540e\u5728\u56fd\u9645\u4e0a\u63d0\u51fa\u4e86\u5f02\u76f8\u7ed3\u3001\u53cc\u529f\u80fd\u52a9\u50ac\u5316\u5242\u548c\u6676\u9762\u95f4\u4fc3\u8fdb\u5149\u751f\u7535\u8377\u5206\u79bb\u7684\u65b0\u6982\u5ff5\uff0c\u5728\u5149\u7535\u50ac\u5316\u9886\u57df\uff0c\u63d0\u51fa\u4e86\u52a9\u50ac\u5316\u5242\u3001\u7a7a\u7a74\u50a8\u5b58\u5c42\u3001\u754c\u9762\u6001\u80fd\u7ea7\u8c03\u63a7\u7b49\u91cd\u8981\u7b56\u7565\uff0c\u4e3a\u9ad8\u6548\u592a\u9633\u80fd\u8f6c\u5316\u4f53\u7cfb\u6784\u7b51\u63d0\u4f9b\u4e86\u79d1\u5b66\u57fa\u7840\u3002\u7814\u7a76\u91cd\u70b9\u662f\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\uff08\u5305\u62ec\u592a\u9633\u80fd\uff0c\u98ce\u80fd\u548c\u6c34\u80fd\uff09\u8fdb\u884c\u5149\u50ac\u5316\uff0c\u5149\u7535\u50ac\u5316\u548c\u7535\u50ac\u5316\u6c34\u5206\u89e3\u548cCO2<\/sub>\u8fd8\u539f\u3002<\/p>\n \u674e\u707f\u9662\u58eb\u5df2\u53d1\u8868800\u591a\u7bc7\u8bba\u6587\uff0c\u7ea632,000\u6b21\u5f15\u7528\uff0c\u7ea680\u9879\u6388\u6743\u4e13\u5229\u4ee5\u53ca\u5728\u56fd\u9645\u4f1a\u8bae\u4e0a\u8d85\u8fc7100\u6b21\u4e3b\u9898\u62a5\u544a\u3002\u5728\u4ed6\u7684\u6307\u5bfc\u4e0b\uff0c\u8d85\u8fc7150\u540d\u7814\u7a76\u751f\u83b7\u5f97\u4e86\u535a\u58eb\u5b66\u4f4d\u3002<\/p>\n \u53d1\u8868\u6210\u679c\u4e00\u89c8<\/b><\/strong><\/p>\n \u4e00\u3001\u5149\u50ac\u5316\u6c34\u5206\u89e3<\/b><\/strong><\/p>\n (1) Angew:\u8868\u9762\u6781\u6027\u8bf1\u5bfc\u7684\u7a7a\u95f4\u7535\u8377\u5206\u79bb\u4fc3\u8fdbGaN\u7eb3\u7c73\u68d2\u9635\u5217\u4e0a\u7684\u5149\u50ac\u5316\u5168\u6c34\u89e3<\/strong><\/p>\n \u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u4ee5\u6a21\u578b\u534a\u5bfc\u4f53\u6c2e\u5316\u9553\uff08GaN\uff09\u4e3a\u4f8b\uff0c\u7814\u7a76\u53d1\u73b0\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u53ef\u4ee5\u5728\u7a7a\u95f4\u4e0a\u5206\u79bb\u5230GaN\u7eb3\u7c73\u68d2\u9635\u5217\u7684\u975e\u6781\u6027\u548c\u6781\u6027\u8868\u9762\uff0c\u8fd9\u53ef\u80fd\u5f52\u56e0\u4e8e\u6c2e\u5316\u9553\u8868\u9762\u6781\u6027\u5f15\u8d77\u7684\u4e0d\u540c\u8868\u9762\u5e26\u5f2f\u66f2\u3002\u901a\u8fc7\u5171\u540c\u66b4\u9732\u6781\u6027\u548c\u975e\u6781\u6027\u8868\u9762\uff0c\u53ef\u4ee5\u5c06GaN\u7684\u5149\u751f\u7535\u8377\u5206\u79bb\u6548\u7387\u4ece\u5927\u7ea68\uff05\u663e\u7740\u63d0\u9ad8\u523080\uff05\u4ee5\u4e0a\u3002\u6b64\u5916\uff0c\u5728\u975e\u6781\u6027\u548c\u6781\u6027\u8868\u9762\u4e0a\u7a7a\u95f4\u7ec4\u88c5\u7684\u8fd8\u539f\u548c\u6c27\u5316\u52a9\u50ac\u5316\u5242\u53ef\u663e\u7740\u4fc3\u8fdb\u5149\u50ac\u5316\u7684\u5168\u89e3\u6c34\u6548\u7387\uff0c\u5176\u91cf\u5b50\u6548\u7387\u4ece\u8584\u819c\u5149\u50ac\u5316\u5242\u76840.9\uff05\u63d0\u9ad8\u5230\u7eb3\u7c73\u68d2\u9635\u5217\u5149\u50ac\u5316\u5242\u76846.9\uff05\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/anie.201912844<\/p>\n (2) Nature communications:<\/b><\/strong>\u00a0<\/b><\/strong>\u68af\u5ea6\u94bd\u63ba\u6742\u7684\u8d64\u94c1\u77ff\u540c\u8d28\u7ed3\u5149\u7535\u9633\u6781\u53ef\u540c\u65f6\u6539\u5584\u5149\u50ac\u5316\u6c34\u5206\u89e3\u7684\u5149\u7535\u6d41\u548c\u5f00\u542f\u7535\u538b<\/b><\/strong><\/p>\n \u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u901a\u8fc7\u6c34\u70ed\u518d\u751f\u548c\u6df7\u5408\u5fae\u6ce2\u9000\u706b\u76f8\u7ed3\u5408\u7684\u7b56\u7565\uff0c\u5408\u6210\u4e86\u5177\u6709\u6838\u58f3\u7ed3\u6784\u7684\u68af\u5ea6\u63ba\u6742\u94bd\u7684\u8d64\u94c1\u77ff\u540c\u8d28\u7ed3\u7eb3\u7c73\u68d2\uff0c\u8fd9\u589e\u5f3a\u4e86\u5149\u7535\u6d41\u5bc6\u5ea6\u5e76\u540c\u65f6\u964d\u4f4e\u4e86\u5f00\u542f\u7535\u538b\u3002\u4f18\u5f02\u7684\u53cc\u529f\u80fd\u6548\u5e94\u6e90\u81ea\u8868\u9762\u6001\u7684\u949d\u5316\u548c\u540c\u8d28\u7ed3\u5f62\u6210\u6240\u56fa\u6709\u7684\u5185\u7f6e\u7535\u573a\u3002\u5c24\u5176\u662f\u5728\u8f83\u4f4e\u7535\u52bf\u4e0b\uff0c\u78c1\u573a\u63d0\u4f9b\u7684\u9644\u52a0\u9a71\u52a8\u529b\u53ef\u4ee5\u6709\u6548\u5730\u6291\u5236\u5757\u4f53\u548c\u8d64\u94c1\u77ff\u8868\u9762\u4e2d\u7684\u7535\u8377-\u8f7d\u6d41\u5b50\u590d\u5408\u3002\u6b64\u5916\uff0c\u5408\u6210\u7684\u540c\u8d28\u7ed3\u663e\u793a\u51fa\u4e0eNiFe(OH)x<\/sub>\u52a9\u50ac\u5316\u5242\u7684\u663e\u7740\u534f\u540c\u4f5c\u7528\uff0c\u5e76\u663e\u7740\u6539\u5584\u4e86\u5149\u7535\u6d41\u5bc6\u5ea6\u548c\u5f00\u542f\u7535\u538b\u7684\u9634\u6781\u504f\u79fb\u3002\u8fd9\u9879\u5de5\u4f5c\u5f88\u597d\u5730\u5c55\u793a\u4e86\u68af\u5ea6\u63ba\u6742\uff0c\u540c\u8d28\u7ed3\u5f62\u6210\u548c\u52a9\u50ac\u5316\u5242\u6539\u6027\u7684\u591a\u79cd\u534f\u540c\u7b56\u7565\uff0c\u8be5\u6982\u5ff5\u53ef\u4ee5\u4e3a\u8bbe\u8ba1\u548c\u6784\u5efa\u592a\u9633\u80fd\u8f6c\u5316\u9886\u57df\u4e2d\u534a\u5bfc\u4f53\u5149\u7535\u6781\u7684\u9ad8\u6548\u7eb3\u7c73\u7ed3\u6784\u63d0\u4f9b\u53c2\u8003\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41467-020-18484-8<\/p>\n \u4e8c\u3001\u5149\u7535\u50ac\u5316<\/b><\/strong>H<\/b><\/strong>2<\/b><\/sub><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u5408\u6210<\/b><\/strong><\/p>\n EES:\u975e\u91d1\u5c5e\u805a\u82ef\u4e59\u70ef\u9ad8\u6548\u5408\u6210\u8fc7\u6c27\u5316\u6c22<\/b><\/strong><\/p>\n \u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u62a5\u9053\u4e86\u805a\u82ef\u4e59\u70ef\uff08pTTh\uff0c\u4e00\u79cd\u65e0\u91d1\u5c5e\u7684\u7a84\u5e26\u9699\u805a\u5408\u7269\u534a\u5bfc\u4f53\uff0c\uff09\u4f5c\u4e3a\u9ad8\u6548\u7684\u5149\u7535\u9634\u6781\uff0c\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u5149\u7535\u50ac\u5316\u4ea7\u751fH2<\/sub>O2<\/sub>\u3002ORR\u76842e-\u9009\u62e9\u6027\u53d6\u51b3\u4e8e\u7535\u89e3\u8d28\u7684pH\u503c\uff0c\u5e76\u4e14\u5728pH\u301c13\u65f6\u63a5\u8fd1100\uff05\u3002H2<\/sub>O2<\/sub>\u7684\u6d53\u5ea6\u8fbe\u5230\u4e86\u521b\u7eaa\u5f55\u7684110 mmol L-1<\/sup>\uff0c\u6bd4\u4e4b\u524d\u7684\u5149\u5408\u6210H2<\/sub>O2<\/sub>\u9ad8\u4e24\u4e2a\u6570\u91cf\u7ea7\u3002\u6b64\u5916\uff0c\u5149\u7535\u5316\u5b66\u88c5\u7f6e\u4e2d\u7684NiFeOx<\/sub>\/BiVO4<\/sub>\u2013pTTh\u53cc\u5149\u7535\u6781\u53ef\u5408\u6210\u6d53\u5ea6\u7ea6\u4e3a90 mmol L-1<\/sup>\u7684H2<\/sub>O2<\/sub>\uff0c\u6570\u4e2a\u5faa\u73af\u5185\u800c\u4e0d\u4f1a\u51fa\u73b0\u4efb\u4f55\u660e\u663e\u7684\u8870\u51cf\u3002\u8fd9\u79cd\u6781\u9ad8\u76842e–<\/sup>\u9009\u62e9\u6027\u5f52\u56e0\u4e8epTTh\u7684\u56fa\u6709\u7535\u5316\u5b66\u6027\u8d28\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c2e–<\/sup>\u8fc7\u7a0b\u4e2d\u9009\u62e9\u6027\u51b3\u901f\u6b65\u9aa4\u6bd44e–<\/sup>\u8def\u5f84\u5feb200\u500d\u4ee5\u4e0a\u3002\u8be5\u5de5\u4f5c\u4e3a\u4ea7\u751f\u6db2\u6001\u592a\u9633\u80fd\u71c3\u6599\u7684\u66ff\u4ee3\u65b9\u6cd5\u94fa\u5e73\u4e86\u9053\u8def\uff0c\u8fd9\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u975e\u5e38\u6709\u524d\u9014\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1039\/C9EE02247C<\/u><\/a><\/p>\n \u4e09\u3001C<\/b><\/strong>O<\/b><\/strong>2<\/b><\/sub><\/strong>\u52a0\u6c22\u5236\u7532\u9187<\/b><\/strong><\/p>\n \u4f7f\u7528\u53ef\u518d\u751f\u80fd\u6e90\u4ea7\u751f\u7684H2<\/sub>\u5c06CO2<\/sub>\u52a0\u6c22\u6210\u7532\u9187\u662f\u78b3\u6355\u83b7\u548c\u5229\u7528\u7684\u4e00\u79cd\u6709\u524d\u666f\u7684\u65b9\u6cd5\u3002\u56e0\u6b64\uff0c\u975e\u5e38\u9700\u8981\u5f00\u53d1\u51fa\u5177\u6709\u9ad8\u7532\u9187\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u3002\u9274\u4e8e\u6b64\uff0c\u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u53d1\u73b0\u901a\u8fc7\u5f15\u5165\u5c11\u91cf\u7684Pt\u53ef\u4ee5\u663e\u7740\u63d0\u9ad8In2<\/sub>O3<\/sub>\u50ac\u5316\u5242\u7684\u7532\u9187\u9009\u62e9\u6027\u3002\u5728220 \u00b0C\u4e0b\uff0c\u7532\u9187\u7684\u9009\u62e9\u6027\u53ef\u4ee5\u4ece72.2\uff05\uff08In2<\/sub>O3<\/sub>\uff09\u589e\u52a0\u523091.1\uff05\uff080.58 wt.\uff05Pt\/In2<\/sub>O3<\/sub>\uff09\u3002\u5f15\u5165\u7684Pt\u539f\u5b50\u88ab\u63ba\u6742\u5230In2<\/sub>O3<\/sub>\u4e2d\uff0c\u5f62\u6210\u539f\u5b50\u5206\u6563\u7684Ptn+<\/sup>\u7269\u8d28\u3002\u539f\u5b50\u5206\u6563\u7684Ptn+<\/sup>\u7269\u79cd\u662f\u589e\u5f3a\u7532\u9187\u9009\u62e9\u6027\u7684\u539f\u56e0\uff0c\u800cIn2<\/sub>O3<\/sub>\u4e0a\u7684Pt\u7eb3\u7c73\u9897\u7c92\u5219\u4e3b\u8981\u4fc3\u8fdb\u4e86\u9006\u6c34\u7164\u6c14\u8f6c\u6362\u53cd\u5e94\uff08CO2 <\/sub>+ H2<\/sub>\u2192CO + H2<\/sub>O\uff09\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.jcat.2020.06.018<\/p>\n \u56db\u3001\u5149\/\u7535\u50ac\u5316CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f<\/b><\/strong><\/p>\n (1) Nature communications:<\/b><\/strong>\u00a0\u76f4\u63a5\u548c\u95f4\u63a5Z\u578b\u5f02\u8d28\u7ed3\u6784\u8026\u5408\u5149\u7cfb\u7edf\uff0c\u53ef\u5b9e\u73b0CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u548cH<\/b><\/strong>2<\/b><\/sub><\/strong>O\u6c27\u5316<\/b><\/strong><\/p>\n \u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u901a\u8fc7\u63a7\u5236\u5149\u6c89\u79ef\u6784\u5efa\u4e86Cu2<\/sub>O-Pt\/SiC\/IrOx<\/sub>\u590d\u5408\u6750\u6599\u7136\u540e\u4ee5Nafion\u819c\u5c06\u8fd8\u539f\u548c\u6c27\u5316\u534a\u53cd\u5e94\u5206\u9694\u5f00\u3002\u8be5\u4eba\u9020\u7cfb\u7edf\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u5177\u6709\u51fa\u8272\u7684\u5149\u50ac\u5316\u6027\u80fd\uff0c\u53ef\u5c06CO2<\/sub>\u8fd8\u539f\u4e3aHCOOH\uff0c\u5e76\u5c06H2<\/sub>O\u6c27\u5316\u4e3aO2<\/sub>\u3002HCOOH\u548cO2<\/sub>\u7684\u4ea7\u7387\u51e0\u4e4e\u8fbe\u5230\u5316\u5b66\u8ba1\u91cf\u6bd4\uff0c\u5206\u522b\u9ad8\u8fbe896.7\u548c440.7 \u03bcmol\u00b7g-1<\/sup>h-1<\/sup>\u3002\u4eba\u9020\u7cfb\u7edf\u4e2dCO2<\/sub>\u8fd8\u539f\u548cH2<\/sub>O\u6c27\u5316\u7684\u9ad8\u6548\u7387\u5f52\u56e0\u4e8eCu2<\/sub>O-Pt\/SiC\/IrOx<\/sub>\u7684\u76f4\u63a5Z\u578b\u7535\u5b50\u7ed3\u6784\u4ee5\u53ca\u95f4\u63a5Z\u578b\u5206\u79bb\u7684\u8fd8\u539f\u548c\u6c27\u5316\u5355\u5143\uff0c\u4ece\u800c\u5927\u5927\u5ef6\u957f\u4e86\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u5bff\u547d\uff0c\u5e76\u9632\u6b62\u4e86\u4ea7\u7269\u7684\u540e\u53cd\u5e94\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u63d0\u9ad8\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u7684\u6548\u7387\u63d0\u4f9b\u4e86\u6709\u6548\u53ef\u884c\u7684\u7b56\u7565\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1038\/s41467-020-16742-3<\/u><\/a><\/p>\n (2) Applied Catalysis B: Environmental:<\/b><\/strong>\u00a0\u5d4c\u5165\u8fc7\u6e21\u91d1\u5c5e\u7684\u6c2e\u5316\u78b3\u7528\u4e8e\u9009\u62e9\u6027\u7535\u50ac\u5316\u8fd8\u539fCO<\/b><\/strong>2<\/b><\/sub><\/strong><\/p>\n \u9ad8\u6548CO2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\u7684\u5f00\u53d1\u5bf9\u4e8e\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u662f\u4e00\u4e2a\u6311\u6218\u3002\u9274\u4e8e\u6b64\uff0c\u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u62a5\u9053\u4e86\u5d4c\u5165\u8fc7\u6e21\u91d1\u5c5e\u7684\u77f3\u58a8\u6c2e\u5316\u78b3\uff08g-C3<\/sub>N4<\/sub>\uff09\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u6c34\u6027\u73af\u5883\u4e2d\u4e00\u7c7b\u65b0\u7684CO2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\u3002\u7531\u4e8e\u91d1\u5c5e\u7684\u534f\u540c\u4f5c\u7528\uff0c\u53d1\u73b0\u53cc\u91d1\u5c5e\uff08NiMn\u6216NiCu\uff09-C3<\/sub>N4<\/sub>\u50ac\u5316\u5242\u6bd4\u5355\u91d1\u5c5e\u50ac\u5316\u5242\u66f4\u6709\u6548\uff0c\u5728\u5f88\u5bbd\u7684\u7535\u4f4d\u8303\u56f4\uff08-0.6 V\u81f3-0.9 V\uff09\u4e0b\uff0c0.39 V\u7684\u4f4e\u8d85\u7535\u52bf\u4e0b\u4ea7\u751fCO\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e3a90\uff05\u5de6\u53f3\u3002\u9ad8\u6d3b\u6027\u6e90\u81eag-C3<\/sub>N4<\/sub>\u57fa\u8d28\u5bf9\u91d1\u5c5e\u539f\u5b50\u7684\u539f\u5b50\u4fee\u9970\u3002g-C3<\/sub>N4<\/sub>\u4e0d\u4ec5\u5145\u5f53\u914d\u4f4d\u6846\u67b6\uff0c\u800c\u4e14\u4e3aCO2<\/sub>\u8fd8\u539f\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u5c40\u90e8\u73af\u5883\u3002\u672c\u7814\u7a76\u6709\u52a9\u4e8e\u6211\u4eec\u5bf9\u8fd9\u79cd\u6750\u6599\u7684\u7ed3\u6784\u548c\u6d3b\u6027\u8d8b\u52bf\u7684\u7406\u89e3\uff0c\u5e76\u6307\u51fa\u5408\u7406\u8bbe\u8ba1\u66f4\u6709\u6548\u7684CO2<\/sub>\u8fd8\u539f\u50ac\u5316\u5242\u7684\u7b56\u7565\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.apcatb.2019.118391<\/p>\n \u4e94\u3001\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n AEM:<\/b><\/strong>\u00a0H-\u952e\u8f85\u52a9\u7684\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\u7684\u5206\u5b50\u987a\u5e8f\u8c03\u63a7\uff0c\u7528\u4e8e\u9ad8\u6548\u7684\u975e\u9000\u706b\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60<\/b><\/strong><\/p>\n \u5404\u79cd\u53d6\u4ee3\u57fa\u5df2\u63ba\u5165\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\uff08NFA\uff09\u4e2d\uff0c\u4ee5\u8c03\u8282\u5438\u6536\u8303\u56f4\u548c\u80fd\u7ea7\uff0c\u4ece\u800c\u63d0\u9ad8\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff08OSC\uff09\u7684\u6548\u7387\u3002\u901a\u8fc7\u8fd9\u4e9b\u53d6\u4ee3\u64cd\u4f5c\u6765\u63a7\u5236NFA\u7684\u5206\u5b50\u987a\u5e8f\u548c\u7ed3\u6676\u5ea6\u5bf9\u4e8eOSC\u6027\u80fd\u540c\u6837\u81f3\u5173\u91cd\u8981\uff0c\u4f46\u8fd9\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\u3002\u7136\u800c\uff0c\u7f9f\u57fa\u80fd\u591f\u5f62\u6210\u5f3a\u5206\u5b50\u95f4\u6c22\u952e\uff08H\u952e\uff09\u4fc3\u8fdb\u5206\u5b50\u91cd\u6392\uff0c\u76ee\u524d\u8fd8\u672a\u53d7\u5230\u91cd\u89c6\u3002\u9274\u4e8e\u6b64\uff0c\u5927\u8fde\u5316\u7269\u6240\u674e\u707f\u9662\u58eb\u56e2\u961f<\/b><\/strong>\u5408\u6210\u4e86\u5177\u6709\u4e24\u4e2a\u7f9f\u57fa\u5b98\u80fd\u5316\u7684\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\uff08NFA\uff09\uff0c\u4ee5\u8c03\u8282\u5206\u5b50\u5806\u79ef\u548c\u7ed3\u6676\u5ea6\u3002\u4e0e\u6bcd\u4f53ITIC\u76f8\u6bd4\uff0cIT-OH\u548cIT-DOH\u89c2\u5bdf\u5230\u6709\u5e8f\u7684\u5206\u5b50\u6392\u5217\u548c\u66f4\u9ad8\u7684\u7ed3\u6676\u5ea6\u3002\u8fd9\u88ab\u8ba4\u4e3a\u662f\u7531\u7f9f\u57fa\u8bf1\u5bfc\u7684\u5206\u5b50\u95f4\u6c22\u952e\u6240\u5f62\u6210\u7684\uff0c\u5b83\u5ef6\u957f\u4e86\u5206\u5b50\u5171\u8f6d\u5e73\u9762\uff0c\u901a\u8fc7\u03c0-\u03c0\u5806\u79ef\u5bfc\u81f4\u4e86\u957f\u7a0b\u6709\u5e8f\u7ed3\u6784\u3002\u901a\u8fc7\u9002\u5f53\u7684\u7ed3\u6676\u5ea6\u548c\u4e0e\u4f9b\u4f53\u805a\u5408\u7269\u7684\u6df7\u6eb6\u6027\uff0c\u57fa\u4e8eIT-DOH\u7684\u975e\u9000\u706bOSC\u53ef\u4ee5\u63d0\u4f9b12.5\uff05\u7684\u6548\u7387\u4ee5\u53ca\u826f\u597d\u7684\u5668\u4ef6\u7a33\u5b9a\u6027\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u901a\u8fc7\u5f15\u5165\u7f9f\u57fa\u6765\u8c03\u8282\u5206\u5b50\u5806\u79ef\u548c\u7ed3\u6676\u5ea6\u4ee5\u8bbe\u8ba1NFA\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u524d\u9014\u7684\u7b56\u7565\u3002<\/p>\n \u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1002\/aenm.201903650<\/p>\n \u5f20\u6d9b\uff0c1963\u5e74\u751f\u4e8e\u9655\u897f\u5b89\u5eb7\u3002\u4e2d\u5171\u515a\u5458\uff0c\u535a\u58eb\uff0c\u7814\u7a76\u5458\u30022013\u5e74\u5f53\u9009\u4e3a\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002<\/p>\n 1989\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u83b7\u535a\u58eb\u5b66\u4f4d\uff0c1989\u5e74\u81f31990\u5e74\u5728\u82f1\u56fd\u4f2f\u660e\u7ff0\u5927\u5b66\u505a\u8bbf\u95ee\u5b66\u8005\uff0c\u56de\u56fd\u540e\uff0c\u5386\u4efb\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7814\u7a76\u7ec4\u526f\u7ec4\u957f\u3001\u7ec4\u957f\u3001\u5ba4\u4e3b\u4efb\u3001\u526f\u6240\u957f\u3001\u515a\u59d4\u4e66\u8bb0\u7b49\u804c\u52a1\uff0c\u66fe\u517c\u4efb\u56fd\u5bb6\u50ac\u5316\u5de5\u7a0b\u6280\u672f\u7814\u7a76\u4e2d\u5fc3\u4e3b\u4efb\uff0c2007\u5e742\u6708\u81f32017\u5e742\u6708\u4efb\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u6240\u957f\u3002\u957f\u671f\u4ece\u4e8b\u5316\u5b66\u5316\u5de5\u9886\u57df\u7684\u7814\u7a76\uff0c\u8d1f\u8d23\u7814\u5236\u7684\u65b0\u578b\u50ac\u5316\u5242\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6211\u77f3\u6cb9\u5316\u5de5\u7b49\u9886\u57df\uff0c\u4e09\u6b21\u4ee5\u7b2c\u4e00\u5b8c\u6210\u4eba\u83b7\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u4e8c\u7b49\u5956\u3002\u8fd1\u671f\u4e3b\u8981\u4ece\u4e8b\u65e0\u6bd2\u63a8\u8fdb\u5242\u50ac\u5316\u5206\u89e3\u6280\u672f\u3001\u751f\u7269\u8d28\u50ac\u5316\u8f6c\u5316\u3001\u5355\u539f\u5b50\u50ac\u5316\u548c\u7eb3\u7c73\u50ac\u5316\u7b49\u65b9\u9762\u7684\u7814\u7a76\uff1b\u6240\u7387\u9886\u7684\u56e2\u961f\u5728\u56fd\u9645\u4e0a\u9996\u6b21\u53d1\u73b0\u7ea4\u7ef4\u7d20\u4e00\u6b65\u6cd5\u50ac\u5316\u8f6c\u5316\u5236\u4e59\u4e8c\u9187\u7684\u65b0\u53cd\u5e94\uff1b\u7387\u5148\u63d0\u51fa\u201c\u5355\u539f\u5b50\u50ac\u5316(Single-Atom Catalysis)\u201d\u7684\u6982\u5ff5\uff0c\u5df2\u5728\u56fd\u9645\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587\u56db\u767e\u4f59\u7bc7\uff0c\u7533\u8bf7\u53d1\u660e\u4e13\u5229\u4e24\u767e\u4f59\u4ef6\u3002<\/p>\n \u4e00\u3001<\/b><\/strong>\u5355\u539f\u5b50\u5927\u89c4\u6a21\u5408\u6210<\/b><\/strong><\/p>\n Nature communications: \u5f3a\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u5927\u89c4\u6a21\u751f\u4ea7\u70ed\u7a33\u5b9a<\/b><\/strong>\u6027<\/b><\/strong>\u5355\u539f\u5b50\u50ac\u5316\u5242<\/b><\/strong><\/p>\n \u5355\u539f\u5b50\u50ac\u5316\u5242\uff08SAC\uff09\u5728\u8bb8\u591a\u5f02\u76f8\u53cd\u5e94\u4e2d\u5747\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u7136\u800c\uff0c\u4ee5\u7b80\u5355\u4e14\u5927\u89c4\u6a21\u7684\u5236\u5907\u70ed\u7a33\u5b9a\u7684SAC\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u9274\u4e8e\u6b64\uff0c\u5f20\u6d9b\u9662\u58eb\u56e2\u961f\u7b49\u4eba<\/b><\/strong>\u62a5\u9053\u4e86\u901a\u8fc7\u5c06\u4e9a\u5fae\u7c73RuO2<\/sub>\u805a\u96c6\u4f53\u4e0eMgAl1.2<\/sub>Fe0.8<\/sub>O4<\/sub>\u5c16\u6676\u77f3\u8fdb\u884c\u7269\u7406\u6df7\u5408\uff0c\u4ece\u5546\u4e1aRuO2<\/sub>\u7c89\u672b\u5408\u6210Ru SAC\u3002\u901a\u8fc7\u7403\u5dee\u6821\u6b63\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548cX\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u786e\u8ba4\u4e86\u539f\u5b50\u5206\u6563\u7684Ru\u3002\u8be6\u7ec6\u7684\u7814\u7a76\u8868\u660e\uff0c\u5206\u6563\u8fc7\u7a0b\u4e0d\u662f\u7531\u6c14\u4f53\u539f\u5b50\u7684\u6355\u83b7\u673a\u5236\u5f15\u8d77\u7684\uff0c\u800c\u662f\u7531\u5f3a\u5171\u4ef7\u91d1\u5c5e-\u8f7d\u4f53\u76f8\u4e92\u4f5c\u7528\u4fc3\u8fdb\u7684\u53cd\u5965\u65af\u7279\u74e6\u5c14\u5fb7\u719f\u5316\u3002\u8fd9\u79cd\u5408\u6210\u7b56\u7565\u7b80\u5355\u6613\u884c\uff0c\u9002\u5408\u5927\u89c4\u6a21\u751f\u4ea7\u7528\u4e8e\u5de5\u4e1a\u5e94\u7528\u7684\u70ed\u7a33\u5b9aSAC\u3002<\/p>\n<\/p>\n
<\/b><\/strong><\/p>\n
<\/p>\n
<\/p>\n
<\/b><\/strong><\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n
<\/p>\n