{"id":214716,"date":"2020-12-18T12:00:02","date_gmt":"2020-12-18T04:00:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=214716"},"modified":"2020-12-18T10:55:36","modified_gmt":"2020-12-18T02:55:36","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e4%b8%ad%e7%a7%91%e9%99%a2%e9%95%bf%e6%98%a5%e5%ba%94%e5%8c%96%e6%89%80%e6%98%8e%e5%86%9bacs-energy-lett-%ef%bc%9a%e6%8f%ad%e7%a4%ba%e7%a2%b3%e9%85%b8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=214716","title":{"rendered":"\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240\u660e\u519bACS Energy Lett.\uff1a\u63ed\u793a\u78b3\u9178\u4e59\u70ef\u916f\u6eb6\u5242\u5316\u58f3\u5728\u53ef\u5145\u7535\u91d1\u5c5e\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u65b0\u4f5c\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u78b3\u9178\u4e59\u70ef\u916f\uff08EC\uff09\u662f\u7535\u89e3\u8d28\u4e2d\u6700\u5e38\u7528\u7684\u52a9\u6eb6\u5242\uff0c\u5b83\u7684\u53d1\u73b0\u662f\u4fc3\u8fdb\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u5546\u4e1a\u5316\u7684\u6700\u5927\u6210\u5c31\u4e4b\u4e00\u3002\u8fd9\u662f\u56e0\u4e3aEC\u7684\u9ad8\u4ecb\u7535\u5e38\u6570\u53ef\u4ee5\u6709\u6548\u5730\u5206\u79bb\u91d1\u5c5e\u76d0\uff08\u5982LiPF6<\/sub>\uff09\uff0c\u800cEC\u7684\u8fd8\u539f\u4e5f\u53ef\u4ee5\u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u6240\u9700\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u95f4\u76f8\uff08SEI\uff09\uff0c\u4ece\u800c\u63d0\u9ad8\u7a33\u5b9a\u6027\u3002\u7279\u522b\u662f\uff0c\u4e0e\u4e4b\u524d\u62a5\u9053\u7684PC\u57fa\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cEC\u57fa\u7535\u89e3\u8d28\u80fd\u591f\u6709\u6548\u5730\u6291\u5236\u77f3\u58a8\u8d1f\u6781\u7684\u5265\u79bb\uff08\u5373\u7531Li+<\/sup>-\u6eb6\u5242\u5171\u6e17\u5f15\u8d77\uff09\u3002\u8fd9\u662f\u56e0\u4e3a\u7535\u89e3\u7535\u89e3\u8d28\u7684\u5206\u89e3\u53ef\u5728\u7535\u6781\u8868\u9762\u5f62\u6210\u575a\u56fa\u8010\u7528\u7684SEI\u819c\u3002\u8fd9\u4e9b\u6548\u679c\u4f7f\u5f97\u7535\u6c60\u7684\u7a33\u5b9a\u6027\u548c\u4f7f\u7528\u5bff\u547d\u66f4\u597d\u3002\u8fd9\u4e24\u79cd\u666e\u904d\u8ba4\u4e3aEC\u7684\u4f5c\u7528\u5728LIBs\u754c\u4e2d\u5f88\u6d41\u884c\uff0c\u5728\u76ee\u524d\u7684\u94a0\u548c\u94be\uff08\u79bb\u5b50\uff09\u7535\u6c60\u7684\u7535\u89e3\u8d28\u7814\u7a76\u4e2d\u4e5f\u88ab\u5f15\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u5316\u6240\u660e\u519b\u7814\u7a76\u5458<\/b><\/strong>\u548c\u97e9\u56fd\u6c49\u9633\u5927\u5b66Yang-Kook Sun<\/b><\/strong>\u3001\u6c99\u7279\u963f\u62c9\u4f2f\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66Husam N. Alshareef\u6559\u6388\u56e2\u961f<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u5bf9\u6700\u5e38\u7528\u7684\u78b3\u9178\u4e59\u70ef\u916f\uff08EC\uff09\u52a9\u6eb6\u5242\u5728\u7535\u89e3\u8d28-\u7535\u6781\u754c\u9762\u4e0a\u7684\u4f5c\u7528\u63d0\u51fa\u4e86\u65b0\u7684\u89c1\u89e3\u3002\u7814\u7a76\u53d1\u73b0\u4e86\u4e00\u4e2a\u65b0\u7684\u73b0\u8c61\uff0cEC\u9664\u4e86\u89e3\u79bb\u91d1\u5c5e\u76d0\u548c\u5f62\u6210\u56fa\u4f53\u7535\u89e3\u8d28\u95f4\u76f8\uff08SEI\uff09\u7684\u4f5c\u7528\u5916\uff0c\u8fd8\u6709\u52a9\u4e8e\u7a33\u5b9a\u7535\u89e3\u8d28\u3002\u4f5c\u4e3a\u4e00\u4e2a\u8303\u4f8b\uff0c\u56e2\u961f\u8bc1\u5b9e\uff0c\u4e0e\u5176\u4ed6\u79cd\u7c7b\u7684\u6eb6\u5242\uff08\u5982\u78b3\u9178\u4e59\u57fa\u7532\u57fa\u916f\uff09\u76f8\u6bd4\uff0cEC\u53ef\u4ee5\u4f18\u5148\u5f62\u6210Li+<\/sup>-EC\u5bf9\uff0c\u4ece\u800c\u6539\u53d8\u7535\u89e3\u8d28\u4e2dLi+<\/sup>-\u6eb6\u5242\u7684\u76f8\u4e92\u4f5c\u7528\u3002Li+<\/sup>-EC\u5bf9\u53ef\u4ee5\u4e3b\u5bfc\u7535\u6781\u754c\u9762\u7684\u53bb\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u56e0\u6b64\u7531\u4e8eLi+<\/sup>-EC\u5177\u6709\u8f83\u9ad8\u7684\u7a33\u5b9a\u6027\uff0c\u6291\u5236\u4e86Li+<\/sup>-\u6eb6\u5242\u7684\u5206\u89e3\u3002\u56e2\u961f\u7684\u89c2\u70b9\u5728\u9502\u3001\u94a0\u3001\u94be\u79bb\u5b50\u7535\u6c60\u7684\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u5f97\u5230\u4e86\u8bc1\u5b9e\uff0c\u5176\u4e2d\u5728Li+<\/sup>-\u6eb6\u5242\u5bf9\u4e0d\u592a\u7a33\u5b9a\u7684\u60c5\u51b5\u4e0b\uff0cSEI\u5bf9\u7a33\u5b9a\u7535\u6781\u7684\u4f5c\u7528\u6709\u9650\u3002\u56e2\u961f\u7684\u53d1\u73b0\u4e3aEC\u7684\u5f71\u54cd\u63d0\u4f9b\u4e86\u4e00\u4e2a\u4e00\u822c\u6027\u7684\u89e3\u91ca\uff0c\u5e76\u4e3a\u8bbe\u8ba1\u66f4\u53ef\u9760\u7684\u91d1\u5c5e\uff08\u79bb\u5b50\uff09\u7535\u6c60\u7684\u7535\u89e3\u8d28\u63d0\u4f9b\u4e86\u65b0\u7684\u6307\u5bfc\u65b9\u9488\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cUnraveling the New Role of an Ethylene Carbonate Solvation Shell in Rechargeable Metal Ion Batteries\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86ACS Energy Lett.<\/b><\/strong>\u4e0a\u3002\u7814\u7a76\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u674e\u831c\u7279\u522b\u7814\u7a76\u52a9\u7406\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1 \u78b3\u9178\u4e59\u70ef\u916f\uff08EC\uff09\u6eb6\u5242\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u4f5c\u7528\u793a\u610f\u56fe<\/b><\/strong>\"\"<\/p>\n

EC\u6eb6\u5242\u7684\u5e38\u89c4\u4f5c\u7528\u5305\u62ecSEI\u6210\u819c\u4f5c\u7528\u548c\u76d0\u89e3\u79bb\u6548\u5e94\u3002\u672c\u7814\u7a76\u63d0\u51fa\u5e76\u8be6\u7ec6\u5206\u6790\u4e86EC\u5728\u6291\u5236\u7535\u89e3\u8d28\u5206\u89e3\u4e2d\u7684\u65b0\u4f5c\u7528\u3002<\/p>\n

\u56fe2 \u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u9540\u9502\u884c\u4e3a\u7684\u53d8\u5316<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u9876\u90e8\u7684\u793a\u610f\u56fe\u6982\u8ff0\u4e86\u5173\u952e\u70b9\uff1a\u7535\u89e3\u8d28\u4e2dEC\u4f5c\u4e3a\u52a9\u6eb6\u5242\u7684\u5b58\u5728\u7a33\u5b9a\u4e86\u76f4\u94fe\u78b3\u9178\u916f\u7535\u89e3\u8d28\u3002<\/p>\n

\uff08b-j\uff09\u4f7f\u7528\u4ee5\u4e0b\u6eb6\u5242\u65f6\u89c2\u5bdf\u5230\u7684SEM\u56fe\u50cf\u548c\u9540\u9502\u884c\u4e3a\u7684\u6570\u7801\u7167\u7247\uff1a\uff08b\uff09EC\u3001\uff08c\uff09DEC\u3001\uff08d\uff09DMC\u3001\uff08e\uff09EMC\u3001\uff08f\uff09EC\/DEC = 1\/1\uff0c\uff08g\uff09 \u7535\u89e3\u8d28\u4e2dEC\/DMC = 1\/1\uff0c\uff08h\uff09EC\/EMC = 2\/1\uff0c\uff08i\uff09EC\/EMC = 1\/1\uff0c\uff08j\uff09EC\/EMC = 1\/2 \u7535\u89e3\u8d28\uff08LiPF6<\/sub>\u6d53\u5ea6\u4e3a1.0 M\uff09\uff09\u3002<\/p>\n

\u56fe3 \u6eb6\u5242\u5bf9\u9540\u9502\/\u5265\u79bb\u884c\u4e3a\u548c\u5e93\u4ed1\u6548\u7387\u7684\u5f71\u54cd<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff0cb\uff09\u5f53\uff08a\uff0cc\uff09\u5355\u4e00\u6eb6\u5242\uff08\u4f8b\u5982EC\u3001DEC\u3001DMC\u548cEMC\uff09\u65f6\uff0cLi|Li\u5bf9\u79f0\u7535\u6c60\u7684\u5178\u578b\u7535\u538b-\u65f6\u95f4\u66f2\u7ebf\u548c\uff08c\uff0cd\uff09\u4f7f\u7528Li|Cu\u534a\u7535\u6c60\u8fdb\u884c\u5e93\u4f26\u6548\u7387\u6bd4\u8f83\u6d4b\u8bd5\u3002\uff08b\uff09\u4e2d\u7684\u63d2\u56fe\u663e\u793a\u4e86\u7535\u538b\u968f\u65f6\u95f4\u53d8\u5316\u7684\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff0cd\uff09\u4e2d\u7684\u63d2\u56fe\u663e\u793a\u4e86\u5728\u7535\u89e3\u8d28\u4e2d\u4f7f\u7528\uff08c\uff09EMC\u548c\uff08d\uff09EC\/EMC\u6df7\u5408\u7269\u65f6\uff0cLi|Cu\u534a\u7535\u6c60\u4e2d\u7684\u5178\u578b\u7535\u538b\u4e0e\u5bb9\u91cf\u66f2\u7ebf\u3002\u7eff\u8272\u63d2\u56fe\u663e\u793a\u4e86\u76f8\u5e94\u7684\u7535\u6c60\u914d\u7f6e\u3002<\/p>\n

\u56fe4 \u4e0d\u540c\u7535\u89e3\u8d28\u7684SEI\u548cEC\u6548\u5e94<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u5728EC\/DEC\u6216EC\/EMC\u7535\u89e3\u8d28\u4e2d\uff0c\u5c06NCM523|Cu\u534a\u7535\u6c60\u88c5\u57281.0 M LiPF6<\/sub>\u4e2d\uff0c\u5236\u5907\u51faSEI\u5305\u8986\u7684Cu@Li\uff08\u5373Cu@Li-SEI\uff09\u3002<\/p>\n

\uff08b\uff0cc\uff09\u57281.0 M LiPF6<\/sub>\uff08b\uff09DEC\u548cEMC\u4e2d\u4ee5\u53ca\uff08c\uff09\u5728EC\/DEC\u548cEC\/EMC\u7535\u89e3\u8d28\u4e2d\u7ec4\u88c5Cu@Li-SEI|Cu@Li-SEI\u5bf9\u79f0\u7535\u6c60\uff0c\u5e76\u901a\u8fc7\u7535\u9540\/\u5265\u79bb\u5de5\u827a\u7ec4\u88c5\u548c\u6d4b\u8bd5\u3002<\/p>\n

\uff08d\uff09\u5728EC\/DEC\u548cEC\/EMC\u7535\u89e3\u8d28\u4e2d\uff0c\u901a\u8fc7\u57281.0 M LiPF6<\/sub>\u4e2d\u653e\u7535Li|Cu\u534a\u7535\u6c60\uff0c\u83b7\u5f97\u53e6\u4e00\u4e2aCu@Li-SEI\u7535\u6781\u3002<\/p>\n

\uff08e\uff0cf\uff09\u5728\uff08e\uff09DEC\u548cEMC\u4e2d\u4ee5\u53ca\u5728\uff08f\uff09EC\/DEC\u548cEC\/EMC\u7535\u89e3\u8d28\u7684\u65b0\u7535\u6c60\uff08Cu@Li-SEI|Cu@Li-SEI\uff09\u4e2d\uff0c\u57281.0 M LiPF6<\/sub>\u4e2d\u6d4b\u8bd5\u4e86\u5178\u578b\u7684\u6781\u5316\u66f2\u7ebf\u3002\u63d2\u56fe\u663e\u793a\u4e86\u76f8\u5e94\u7684\u7535\u6c60\u914d\u7f6e\u3002<\/p>\n

\u56fe5 \u94a0\u548c\u94be\u7535\u6c60\u4e2dEC\u52a9\u6eb6\u5242\u5bf9\u91d1\u5c5e\u9540\u5c42\u7684\u4e00\u822c\u5f71\u54cd<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u9876\u90e8\u7684\u793a\u610f\u56fe\u63cf\u8ff0\u4e86\u8fd9\u9879\u7814\u7a76\u4e2d\u63d0\u51fa\u7684EC\u52a9\u6eb6\u5242\u4f5c\u7528\uff08EC\u7a33\u5b9a\u4e86\u76f4\u94fe\u78b3\u9178\u916f\u6eb6\u5242\uff09\u3002<\/p>\n

\uff08b-j\uff09\u5728\uff08b\uff09EC\u3001\uff08c\uff09DEC\u3001\uff08d\uff09DMC\u3001\uff08e\uff09EMC\u3001\uff08f\uff09EC\/DEC = 1\/1\u3001\uff08g\uff09EC\/DMC = 1\/1\uff0c\uff08h\uff09EC\/EMC = 2\/1\uff0c\uff08i\uff09EC\/EMC = 1\/1\uff0c\uff08j\uff09EC\/EMC = 1\/2\u4e2d\u7684Cu@Na\u7535\u6781\u7684SEM\u56fe\u50cf\u548c\u6570\u5b57\u7167\u7247<\/p>\n

\uff08k-m\uff090.7 M KPF6<\/sub>\u5728\uff08k\uff09EC\u3001\uff08l\uff09EMC\u548c\uff08m\uff09EC\/EMC\u7535\u89e3\u8d28\u4e2d\u7535\u9540Cu@K\u7535\u6781\u7684SEM\u56fe\u50cf\u548c\u6570\u5b57\u7167\u7247\u3002<\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>\u00a0<\/b><\/strong>E<\/b><\/strong>C\u5bf9\u94a0\u6216\u94be\u7535\u9540\/\u5265\u79bb\u884c\u4e3a\u7684\u5f71\u54cd<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff0cb\uff09\u6bd4\u8f83Na|Na\u5bf9\u79f0\u7535\u6c60\u57281.0 M NaPF6<\/sub>\u7535\u89e3\u8d28\u4e2d\uff08a\uff09\u00a0EC\u3001DEC\u3001DMC\u3001EMC\u548c\uff08b\uff09EC\/DEC\u3001EC\/DMC\u3001EC\/EMC\u7684\u7535\u9540\/\u5265\u79bb\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff0cd\uff09\u6bd4\u8f83K|K\u5bf9\u79f0\u7535\u6c60\u57280.7 M KPF6<\/sub>\u7535\u89e3\u8d28\u4e2d\uff08c\uff09\u5355\u4e00\u6eb6\u5242\u5982EC\u3001DEC\u548cEMC\uff09\u548c\uff08d\uff09\u6df7\u5408\u6eb6\u5242\uff08\u5982EC\/DEC\u548cEC\/EMC\uff09\u7684\u7535\u9540\/\u5265\u79bb\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/b><\/strong>7<\/b><\/strong>\u00a0\u7535\u89e3\u8d28\u7684\u8868\u5f81\u53ca\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u754c\u9762\u6a21\u578b<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09C = O\u548c\uff08b\uff09PF6<\/sub>–<\/sup>\u632f\u52a8\u7684\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n

\uff08c\uff09EMC\uff08-CH3<\/sub>\uff09\u5728\u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u76841<\/sup>H NMR\u3002\uff08c\uff09\u7684\u63d2\u56fe\u5206\u522b\u663e\u793a\u4e86EMC-EMC\u3001EC-EMC\u3001Li+<\/sup>[EMC]4<\/sub>\u548cLi+<\/sup>[EC]3<\/sub>[EMC]\u53ef\u80fd\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u84dd\u8272\u7bad\u5934\u8868\u793a\u5728\u7b2c\u4e00\u4e2a\u6eb6\u5242\u5316\u58f3\u4e2d\u7684\u53e6\u5916\u4e24\u4e2a\u914d\u4f4d\u7684EMC\u5206\u5b50\u3002 EC\u3001EMC\u548cEC\/EMC\u57281.0 M LiPF6<\/sub>\u7535\u89e3\u8d28\u4e2d\uff08d-f\uff09\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u548c\uff08g-i\uff09\u63d0\u51fa\u7684\u754c\u9762\u6a21\u578b\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/b><\/strong>8<\/b><\/strong>\u00a0\u7535\u89e3\u8d28\u7684\u8868\u5f81\u4e0e\u6a21\u62df<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u5728EMC\uff0cEC\/EMC\u4e2d\u7684\u539f\u59cb\u7535\u89e3\u8d281.0 M LiPF6<\/sub>\u76841<\/sup>H NMR\uff08-OCH3<\/sub>\uff09\u548c\uff08b\uff0913<\/sup>C NMR\uff08-OCH3<\/sub>\uff09\u5149\u8c31\uff0c\u4ee5\u53ca\u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u540e\u4eceLi|Li\u5bf9\u79f0\u7535\u6c60\u4e2d\u6536\u96c6\u7684\u6b8b\u4f59\u7535\u89e3\u8d28\u3002<\/p>\n

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\uff08d\uff09\u63a5\u53d7\u4e00\u4e2a\u7535\u5b50\u524d\u540eLi+<\/sup>-\u6eb6\u5242\u7684LUMO\u548cHOMO’\u6a21\u62df\u56fe\u3002<\/p>\n

\uff08e\uff09\u65b0\u5f62\u6210\u7684HOMO’\u548c\u521d\u59cbLUMO\u4e4b\u95f4\u7684\u6bd4\u8f83\u80fd\u7ea7\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u56e2\u961f\u5bf9EC\u6eb6\u5242\u5728\u7535\u6c60\u7535\u89e3\u8d28\u4e2d\u7684\u4f5c\u7528\u63d0\u51fa\u4e86\u65b0\u7684\u89c1\u89e3\u3002EC\u4f5c\u4e3a\u52a9\u6eb6\u5242\u7684\u52a0\u5165\u5bf9\u7a33\u5b9a\u7535\u89e3\u8d28\u81f3\u5173\u91cd\u8981\uff0c\u5c24\u5176\u662f\u90a3\u4e9b\u542b\u6709\u5e38\u7528\u7684\u76f4\u94fe\u78b3\u9178\u76d0\u6eb6\u5242\u3002EC\u53ef\u4ee5\u6539\u53d8\u7535\u6781\u754c\u9762\u7684Li+<\/sup>\u6eb6\u5242\u5316\u7ed3\u6784\uff0c\u63a7\u5236\u7535\u6781\u754c\u9762\u7684\u6eb6\u5242\u5316\u884c\u4e3a\u3002Li+<\/sup>-EC\u6bd4\u5176\u4ed6Li+<\/sup>-\u6eb6\u5242\u5bf9\uff08\u5982Li+<\/sup>-DMC\u3001Li+<\/sup>-EMC\u3001Li+<\/sup>-DEC\u7b49\uff09\u7684\u7a33\u5b9a\u6027\u66f4\u9ad8\uff0c\u88ab\u8bc1\u5b9e\u662f\u6291\u5236\u7535\u89e3\u8d28\u5206\u89e3\u7684\u5173\u952e\u56e0\u7d20\u3002\u8fd9\u4e00\u53d1\u73b0\u4e0d\u540c\u4e8eEC\u5728\u89e3\u79bb\u9502\u76d0\u548c\u5f62\u6210SEI\u7684\u4f5c\u7528\u3002\u7279\u522b\u5730\uff0c\u56e2\u961f\u8bc1\u660e\u4e86\u5982\u679cLi+<\/sup>-\u6eb6\u5242\u5bf9\u4e0d\u591f\u7a33\u5b9a\uff0cSEI\u7684\u7a33\u5b9a\u6548\u5e94\u5c31\u4f1a\u964d\u4f4e\u3002\u672c\u7814\u7a76\u62a5\u9053\u4e86EC\u6eb6\u5242\u5728\u9502\u3001\u94a0\u3001\u94be\u91d1\u5c5e\uff08\u79bb\u5b50\uff09\u7535\u6c60\u7535\u89e3\u8d28\u4e2d\u7684\u65b0\u529f\u80fd\u3002\u7814\u7a76\u53d1\u73b0\u4e3a\u5f00\u53d1\u66f4\u53ef\u9760\u7684\u91d1\u5c5e\uff08\u79bb\u5b50\uff09\u7535\u6c60\u7535\u89e3\u8d28\u63d0\u4f9b\u4e86\u65b0\u7684\u6307\u5bfc\u65b9\u9488\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1aUnraveling the New Role of an Ethylene Carbonate Solvation Shell in Rechargeable Metal Ion Batteries<\/u><\/a>\uff08ACS Energy Lett.,\u00a02020,\u00a0DOI:10.1021\/acsenergylett.0c02140\uff09<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/b><\/strong><\/p>\n

\u660e\u519b\uff0c\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u7814\u7a76\u8bfe\u9898\u4e3b\u8981\u5305\u62ec\u7535\u6c60\u7535\u89e3\u6db2\u53ca\u7535\u6781\u754c\u9762\u7814\u7a76\u3002\u7814\u7a76\u5185\u5bb9\u7acb\u8db3\u4e8e\u57fa\u7840\uff0c\u4ee5\u89e3\u51b3\u4f01\u4e1a\u754c\u5728\u7535\u6c60\u6750\u6599\u5236\u5907\u3001\u7535\u89e3\u6db2\u914d\u65b9\u4ee5\u53ca\u7535\u6c60\u8bbe\u8ba1\u7b49\u65b9\u9762\u7684\u96be\u9898\u4e3a\u76ee\u6807\uff0c\u670d\u52a1\u4e8e\u7535\u6c60\u4ea7\u54c1\u7684\u5b9e\u9645\u5e94\u7528\u3002\u9996\u6b21\u63d0\u51faLi+<\/sup>\u6eb6\u5242\u5316\u7ed3\u6784\u5bf9\u7535\u6781\u7a33\u5b9a\u6027\u7684\u91cd\u8981\u5f71\u54cd\uff0c\u91cd\u65b0\u8ba4\u8bc6\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u4f5c\u7528\uff0c\u4ee5\u53ca\u6784\u7b51\u5206\u5b50\u754c\u9762\u6a21\u578b\u66ff\u4ee3SEI\u819c\u9884\u6d4b\u7535\u6781\u7a33\u5b9a\u6027\u3002\u8fd15\u5e74\u5728Adv<\/i><\/em>. Mater.\u3001<\/i><\/em>ACS Energy Lett.<\/i><\/em>\u3001<\/i><\/em>Adv<\/i><\/em>. Energy<\/i><\/em>\u00a0<\/i><\/em>Mater<\/i><\/em>.<\/i><\/em>\u3001<\/i><\/em>A<\/i><\/em>CS Nano\u3001<\/i><\/em>A<\/i><\/em>dv. Funct. Mater.\u3001<\/i><\/em>N<\/i><\/em>ano Lett.\u3001<\/i><\/em>Mater<\/i><\/em>.<\/i><\/em>\u00a0Sci. Eng.: R: Rep.<\/i><\/em>\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u53d1\u8868\u4e0e\u91d1\u5c5e\uff08\u79bb\u5b50\uff09\u7535\u6c60\u7814\u7a76\u76f8\u5173\u5b66\u672f\u8bba\u6587100\u4f59\u7bc7\uff0c\u5176\u4e2d\uff0c\u7b2c\u4e00\u4f5c\u8005\u53ca\u901a\u8baf\u4f5c\u8005\u8bba\u658760\u4f59\u7bc7\uff0cH-index 32\u3002\u76ee\u524d\uff0c\u7533\u8bf7\u7f8e\u56fd\u53d1\u660e\u4e13\u52294\u9879\uff0c\u4e2d\u56fd\u53d1\u660e\u4e13\u52291\u9879\uff0c\u4e0e\u7f8e\u56fd\u3001\u5fb7\u56fd\u3001\u745e\u58eb\u3001\u97e9\u56fd\u3001\u65e5\u672c\u3001\u6c99\u7279\u3001\u610f\u5927\u5229\u7b49\u56fd\u5bb6\u7684\u7535\u6c60\u77e5\u540d\u8bfe\u9898\u7ec4\u5efa\u6709\u826f\u597d\u7684\u5408\u4f5c\u5173\u7cfb\uff08https:\/\/www.x-mol.com\/groups\/Ming_Jun\uff09\u3002<\/p>\n

\u8fd1\u4e94\u5e74\u4ee3\u8868\u4f5c\uff1a<\/p>\n

    \n
  1. Q. Li, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, Ming*<\/b><\/u><\/strong>, Unraveling the New Role of an Ethylene Carbonate Solvation Shell in Rechargeable Metal Ion Batteries, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, 6, 69-78.<\/li>\n
  2. Zhou, et.al, <\/i><\/em>J. Ming,*<\/b><\/u><\/strong>Electrolyte-mediated Stabilization of High Capacity Micro-sized Antimony Anodes for Potassium Ion Batteries,\u00a0Advanced Materials<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, adma.202005993R1. Accepted.<\/i><\/em><\/li>\n
  3. Zhang, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J. Ming*<\/b><\/u><\/strong>, Model-based Design\u00a0of Stable Electrolytes in Potassium Ion Batteries, ACS E<\/i><\/b><\/em><\/strong>nergy<\/i><\/b><\/em><\/strong>\u00a0L<\/i><\/b><\/em><\/strong>etters<\/i><\/b><\/em><\/strong>,\u00a0<\/b><\/strong>2020<\/b><\/strong>, 5, 3124-3131.<\/li>\n
  4. Zhang, <\/i><\/em>et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>,\u00a0J. Ming<\/b><\/u><\/strong>,<\/b><\/u><\/strong>*<\/b><\/u><\/strong>\u00a0Model-based Design of Graphite Compatible Electrolyte in Potassium Ion Batteries, ACS E<\/i><\/b><\/em><\/strong>nergy<\/i><\/b><\/em><\/strong>\u00a0L<\/i><\/b><\/em><\/strong>etters<\/i><\/b><\/em><\/strong>,\u00a0<\/b><\/strong>2020<\/b><\/strong>, 5, 2651-2661.<\/li>\n
  5. Liu,<\/i>et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, J. Ming*<\/b><\/u><\/strong>, Additives Engineered Non-flammable Electrolyte for Safer Potassium Ion Battery, Advanced Functional Materials<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, 2001934.<\/i><\/em>\u00a0<\/li>\n
  6. Zhou,et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, J. Ming<\/b><\/u><\/strong>,<\/u>*<\/b><\/u><\/strong>\u00a0Electrolyte Engineering Enables High Stability and Capacity Alloying Anodes for Sodium and Potassium Ion Batteries, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, 5, 766-776. \u00a0<\/li>\n
  7. Xue, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J<\/b><\/u><\/strong>.<\/b><\/u><\/strong>\u00a0Ming,*<\/b><\/u><\/strong>\u00a0Unraveling Metal Oxide Role for Exfoliating Graphite: New Strategy to Construct High-Performance Graphene-modified SiOx<\/sub>-based Anode for Lithium-ion Batteries, Advanced Functional Materials<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, 2001934.\u00a0<\/b><\/strong>\u00a0<\/li>\n
  8. Wu,et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>,\u00a0J. Ming,*<\/b><\/u><\/strong>\u00a0An Empirical Model for High-Energy Battery Design beyond 300 Wh\/kg, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 20<\/b><\/strong>20<\/b><\/strong>, 5, 807-816.\u00a0<\/li>\n
  9. L.Zhou,\u00a0et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, J<\/b><\/u><\/strong>.<\/b><\/u><\/strong>\u00a0Ming<\/b><\/u><\/strong>,<\/u>*<\/b><\/u><\/strong>\u00a0Engineering Sodium-Ion Solvation Structure to Stabilize Sodium Anode: Universal Strategy for Fast-charging and Safer Sodium-ion Batteries, Nano Letters<\/i><\/b><\/em><\/strong>, 2020<\/b><\/strong>, 20, <\/i><\/em>3247-325\u00a0<\/li>\n
  10. Zhou, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J. Ming,*<\/b><\/u><\/strong>\u00a0Understanding Ostwald Ripening and Surface Charging Effects in Solvothermally-Prepared Metal Oxide-Carbon Anodes for High-Performance Rechargeable Batteries, Advanced Energy Materials<\/i><\/b><\/em><\/strong>, 2019<\/b><\/strong>, 1902194.\u00a0<\/li>\n
  11. Y.Wu,\u00a0<\/i><\/em>et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, Ming,*<\/b><\/u><\/strong>\u00a0An Exploration of New Energy Storage System: High Energy Density, High Safety and Fast Charging Lithium-Ion Battery, Advanced Functional Materials<\/i><\/b><\/em><\/strong>, 2019<\/b><\/strong>, 29,<\/i><\/em>\u00a01805978.\u00a0<\/li>\n
  12. <\/b> Ming<\/b><\/u><\/strong>, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, Molecular-Scale Interfacial Model for Predicting Electrode Performance in Rechargeable Batteries, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2019<\/b><\/strong>, 4, 1584-1593.<\/li>\n
  13. <\/b> Ming<\/b><\/u><\/strong>,<\/b>et.al<\/i><\/em>, New Insight\u00a0on the Role of Electrolyte Additives in Rechargeable Lithium-Ion Batteries, ACS Energy Letters<\/i><\/b><\/em><\/strong>,<\/i><\/em>\u00a0<\/i><\/em>2019<\/b><\/strong>,\u00a0<\/i><\/em>4, 2613-2622.\u00a0<\/li>\n
  14. Wu, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J. Ming,*<\/b><\/u><\/strong>\u00a0New Organic Complex for Lithium Layered Oxide Modification: Ultra-thin Coating, High-Voltage and Safety Performances, ACS Energy Letters <\/i><\/b><\/em><\/strong>2019<\/b><\/strong>, 4,<\/i><\/em>\u00a0656-665.<\/i><\/em>\u00a0\u00a0<\/li>\n
  15. <\/b> Ming<\/b><\/u><\/strong>,<\/b><\/strong>et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, Zinc Ion Batteries: Progress, Challenges and Perspectives, Materials Science and Engineering: R: Reports, <\/i><\/b><\/em><\/strong>2019<\/b><\/strong>,\u00a0135, 58-84.\u00a0<\/li>\n
  16. Wahyudi, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J. Ming<\/b><\/u><\/strong>,*<\/b><\/strong>\u00a0<\/b><\/strong>Phase Inversion Strategy to Flexible Freestanding Electrode: Critical Coupling of Binders and Electrolytes for High Performance Li-S Battery,\u00a0Advanced Functional Materials<\/i><\/b><\/em><\/strong>,\u00a02018<\/b><\/strong>, 28 (34), 1802244.\u00a0<\/li>\n
  17. Wang, et<\/i><\/em>.<\/i><\/em>al,<\/i><\/em>\u00a0J. Ming,*<\/b><\/u><\/strong>\u00a0<\/b><\/strong>Recognizing the Mechanism of Sulfurized Polyacrylonitrile Cathode Material for Li-S Battery and beyond in Al-S battery, ACS Energy Letters<\/i><\/b><\/em><\/strong>,\u00a0<\/i><\/b><\/em><\/strong>2018<\/b><\/strong>, 3, <\/i><\/em>2899-2907.<\/li>\n
  18. <\/b> Ming<\/b><\/u><\/strong>, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, New Insights on Graphite Anode Stability in Rechargeable Batteries: Li Ion Coordination Structures Prevail over Solid Electrolyte Interphases,\u00a0<\/b><\/strong>ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2018<\/b><\/strong>, 3, <\/i><\/em>335.<\/i><\/em>\u00a0\u00a0<\/li>\n
  19. Li, et<\/i><\/em>.<\/i><\/em>al<\/i><\/em>, J. Ming,<\/b><\/u><\/strong>*<\/b><\/strong>\u00a0L. J. Li,*<\/b><\/strong>\u00a0Metal-Organic Framework-Based Separators for Enhancing Li-S Battery Stability: Mechanism of Mitigating Polysulfide Diffusion, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2017<\/b><\/strong>, 2, 2362.\u00a0<\/li>\n
  20. <\/b> Ming<\/b><\/u><\/strong>,*<\/b><\/strong>et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, Multilayer Approach for Advanced Hybrid Lithium Battery, ACS Nano<\/i><\/b><\/em><\/strong>, 2016<\/b><\/strong>, 10, 6037.<\/li>\n
  21. <\/b> Ming<\/b><\/u><\/strong>,*<\/b><\/strong>et<\/i><\/em>.<\/i><\/em>\u00a0al<\/i><\/em>, Redox Species-Based Electrolytes for Advanced Rechargeable Lithium-Ion Battery, ACS Energy Letters<\/i><\/b><\/em><\/strong>, 2016<\/b><\/strong>, 1, 529.\u00a0<\/li>\n<\/ol>\n

    \u672c\u6587\u7531\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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