{"id":214525,"date":"2020-12-25T06:17:23","date_gmt":"2020-12-24T22:17:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=214525"},"modified":"2020-12-24T19:17:33","modified_gmt":"2020-12-24T11:17:33","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9cacs-catal%ef%bc%9a%e5%8e%9f%e4%bd%8d%e6%bc%ab%e5%8f%8d%e5%b0%84%e7%ba%a2%e5%a4%96%e5%85%89%e8%b0%b1-%e8%b4%a8%e8%b0%b1%e8%81%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=214525","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5cACS Catal\uff1a\u539f\u4f4d\u6f2b\u53cd\u5c04\u7ea2\u5916\u5149\u8c31-\u8d28\u8c31\u8054\u7528\u63ed\u793aRu\u50ac\u5316\u5242CO2\u52a0\u6c22\u53cd\u5e94\u4e2d\u7684CO\u4e2d\u6bd2\u673a\u7406\u00a0"},"content":{"rendered":"

\u6df7\u5408\u4f4e\u6e29\u7b49\u79bb\u5b50\u4f53(NTP)\u548c\u50ac\u5316(NTP-\u50ac\u5316)\u7cfb\u7edf\u53ef\u4ee5\u6fc0\u6d3b\u548c\u8f6c\u5316\u5404\u79cd\u7a33\u5b9a\u5206\u5b50\uff0c\u5982\u4e8c\u6c27\u5316\u78b3(CO2<\/sub>)\uff0c\u7532\u70f7(CH4<\/sub>)\u548c\u6c2e\u6c14(N2<\/sub>)\uff0c\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\uff0c\u6210\u4e3a\u6240\u9700\u7684\u4ea7\u7269\uff0c\u4f46\u662f\u6df7\u5408\u52a8\u529b\u7cfb\u7edf\u662f\u9ad8\u5ea6\u590d\u6742\u7684\u3002NTP-\u50ac\u5316\u4f53\u7cfb\u6709\u5229\u4e8e\u4f7f\u53cd\u5e94\u52a8\u529b\u5b66\u6216\u70ed\u529b\u5b66\u53d7\u9650\uff0c\u5305\u62ec\u7532\u70f7\u7684\u91cd\u6574\uff0c\u6c34\u7164\u6c14\u8f6c\u6362\u548c\u4e8c\u6c27\u5316\u78b3\u52a0\u6c22\u3002\u4e0e\u70ed\u50ac\u5316\u5242\u76f8\u6bd4\uff0cNTP-\u50ac\u5316\u5177\u6709\u964d\u4f4e\u50ac\u5316\u6240\u9700\u7684\u80fd\u5792\u548c\u6539\u53d8\u50ac\u5316\u5242\u8868\u9762\u53cd\u5e94\u9014\u5f84\u7684\u80fd\u529b\u3002\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\uff0c\u4e0e\u70ed\u50ac\u5316\u76f8\u4f3c\uff0c\u975e\u5747\u76f8\u50ac\u5316\u5242(\u5305\u62ec\u8f7d\u4f53)\u7684\u5185\u5728\u6027\u8d28\uff0c\u5982\u91d1\u5c5e\u5206\u6563\u548c\u5b54\u7ed3\u6784\uff0c\u5728NTP-\u50ac\u5316\u4e2d\u8d77\u5173\u952e\u4f5c\u7528\u3002\u4f8b\u5982\uff0c\u8bbe\u8ba1\u4e86\u4e00\u7cfb\u5217\u591a\u5b54\u7845-1(\u5177\u6709\u4e0d\u540c\u5b54\u7ed3\u6784)\u50ac\u5316\u5242\u8d1f\u8f7dNi\uff0c\u7814\u7a76\u4e86NTP\u6761\u4ef6\u4e0b\u7684CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u3002\u4f5c\u8005\u53d1\u73b0\u591a\u5b54\u7845-1\u8f7d\u4f53\u7684\u5b54\u7ed3\u6784\u51b3\u5b9a\u4e86Ni\u4f4d\u70b9\u7684\u5206\u6563\u548c\u4f4d\u7f6e\uff0c\u4ece\u800c\u51b3\u5b9a\u4e86\u7b49\u79bb\u5b50\u4f53\u751f\u6210\u53cd\u5e94\u7269\u8d28\u7684\u53ef\u5f97\u6027\uff0c\u4ece\u800c\u5f71\u54cd\u4e86NTP\u50ac\u5316\u7684\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

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\u56fe<\/b><\/strong>2. (a, c)\u70ed\u6761\u4ef6(330 \u2103)\u548c(b, d) NTP\u6761\u4ef6\u4e0b\u53cd\u5e94\u901f\u7387\u5bf9p<\/b><\/strong>H2<\/b><\/sub><\/strong>\u548cp<\/b><\/strong>CO2<\/b><\/sub><\/strong>\u7684\u4f9d\u8d56\u6027\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u5728NTP-off\u6761\u4ef6\u4e0b\uff0c\u4ee5\u53cd\u5e94\u6c14\u4f53\u4e3a\u539f\u6599(\u53733% CO2<\/sub>\/9%H2<\/sub>\/Ar)\uff0c\u9664\u4e86CO2<\/sub>\u6c14\u76f8\u5cf0(\u7ea6\u4e3a2360\u548c2342 cm\u22121<\/sup>\uff0c\u5982\u56fe3a\u6240\u793a)\uff0c\u8868\u9762\u78b3\u7269\u8d28\u6ca1\u6709\u88abDRIFTS\u68c0\u6d4b\u5230\uff0c\u4e5f\u6ca1\u6709\u89c2\u5bdf\u5230\u4efb\u4f55\u53cd\u5e94(\u6839\u636eMS)\u3002\u5728\u7b49\u79bb\u5b50\u4f53\u70b9\u706b\u65f6\uff0cMS\u5256\u9762\u77ac\u65f6\u51fa\u73b0CH4<\/sub>\u4fe1\u53f7\uff0c\u8bc1\u5b9eNTP\u6fc0\u6d3b\u4e0b\u50ac\u5316\u5242\u4e0a\u5f62\u6210\u4e86CH4<\/sub>\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u8868\u9762\u5f62\u6210\u7532\u9170(CHxO\uff0c\u7ea61284\u30011270\u548c1111 cm\u22121<\/sup>)\u548c\u7fb0\u57fa(\u5373\u57282034 cm\u22121<\/sup>\u5904\u5728Ru0<\/sup>\u8868\u9762\u7ebf\u6027\u5438\u9644\u7684COad<\/sub>\u548c\u57282084 cm\u22121<\/sup>\u5904\u7ebf\u6027\u5f62\u6001\u7684Ru\u03b4+<\/sup>-CO\uff0c\u5982\u56fe3b\u6240\u793a\u3002\u4e0eCO2<\/sub>\/Ar\u4e0b\u5f62\u6210\u7684COad<\/sub>\u8c31\u5e26\u76f8\u6bd4\uff0c\u4e24\u4e2a\u5cf0\u5411\u8f83\u4f4e\u9891\u7387\u79fb\u52a8\u4e86\u7ea610 cm\u22121<\/sup>\uff0c\u6865\u8054\u5438\u9644\u7684COad<\/sub>\u5cf0\u6d88\u5931\u4e86\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8eHad<\/sub>\u5728Ru\u8868\u9762\u7684\u7535\u5b50\u8d21\u732e\u3002\u5f53\u5173\u95ed\u7b49\u79bb\u5b50\u4f53\u540e\uff0cCH4<\/sub>\u6d53\u5ea6\u7acb\u5373\u4e0b\u964d\uff0c\u800c\u7532\u9170\u7269\u8d28\u5219\u7f13\u6162\u4e0b\u964d\uff0c\u8868\u660e\u5728\u6ca1\u6709\u7b49\u79bb\u5b50\u4f53\u653e\u7535\u7684\u4f53\u7cfb\u4e2dCH4<\/sub>\u7684\u5f62\u6210\u662f\u4e0d\u6d3b\u8dc3\u7684\u3002\u7532\u9170\u7684\u9010\u6e10\u51cf\u5c11(\u57284 min\u5185)\u53cd\u6620\u4e86\u5b83\u5728NTP-off\u6761\u4ef6\u4e0b\u7684\u89e3\u5438\u3002CO2<\/sub>\u52a0\u6c22\u53ef\u4ee5\u5728\u948c\u57fa\u50ac\u5316\u5242\u4e0a\u901a\u8fc7\u7532\u9170\u5316\u9014\u5f84\uff0c\u5305\u62ecCO2<\/sub>\u76f4\u63a5\u79bb\u89e3\u5230\u7fb0\u57fa(COad<\/sub>)\u548cOad<\/sub>\uff0c\u7136\u540eCOad<\/sub>\u52a0\u6c22\u3002COad<\/sub>\u968f\u540e\u7684\u52a0\u6c22\u53cd\u5e94\u5c06\u5f62\u6210\u7532\u9170\u7269\u79cd\uff0c\u4f5c\u4e3aCH4<\/sub>\u751f\u4ea7\u7684\u4e2d\u95f4\u4f53\u3002\u4e0e\u52a0\u70ed\u7cfb\u7edf\u7684DRIFTS\u7ed3\u679c(\u5373\u53ea\u89c2\u5bdf\u5230\u7fb0\u57fa\u7269\u79cd)\u76f8\u6bd4\uff0cNTP\u6761\u4ef6\u4e0b\u7fb0\u57fa\u548c\u7532\u9170\u7269\u8d28\u7684\u51fa\u73b0\u8868\u660e\uff0cNTP\u6761\u4ef6\u4e0bCO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u5b58\u5728\u53e6\u4e00\u79cd\u53cd\u5e94\u9014\u5f84(\u5373\u7532\u9170\u5316\u9014\u5f84)\u3002\u56e0\u6b64\uff0c\u8868\u9762\u7269\u79cd\u4f5c\u4e3aToS\u51fd\u6570\u7684\u8fdb\u5316\u4e0eCH4<\/sub>\u4fe1\u53f7\u5f3a\u5ea6(MS)\u7684\u53d8\u5316\u662f\u76f8\u5173\u7684\uff0c\u5982\u56fe3d\u6240\u793a\u3002<\/p>\n

\u56fe<\/b><\/strong>3. <\/b><\/strong>\u5728<\/b><\/strong>Ru\/SiO<\/b><\/strong>2<\/b><\/sub><\/strong>\u50ac\u5316\u5242\u4e0aCO<\/b><\/strong>2<\/b><\/sub><\/strong>\u52a0\u6c22\u7684\u8868\u9762<\/b><\/strong>\u7269\u8d28\u7684<\/b><\/strong>\u539f\u4f4dDRIFTS\u5149\u8c31\u3002<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u5728\u672c\u7814\u7a76\u4e2d\uff0cNTP\u50ac\u5316\u4f53\u7cfb\u5728Ru\/SiO2<\/sub>\u50ac\u5316\u5242\u4e0a\u53ef\u4ee5\u5b9e\u73b065%\u7684CO2<\/sub>\u8f6c\u5316\u7387\u548c63%\u7684CH4<\/sub>\u4ea7\u7387\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u7684\u56fa\u6709\u6027\u8d28\uff08\u5982\u8868\u9762\u79ef\uff09\u5728\u52a0\u70ed\u6761\u4ef6\u548cNTP\u6761\u4ef6\u4e0b\u90fd\u81f3\u5173\u91cd\u8981\u3002\u6bd4\u8f83\u52a8\u529b\u5b66\u548c\u539f\u4f4dDRIFTS\u2212MS\u7814\u7a76\u8868\u660e\uff0cNTP\u50ac\u5316\u53ef\u4ee5\u964d\u4f4e\u50ac\u5316\u6240\u9700\u7684\u80fd\u91cf\u52bf\u5792\uff0c\u5e76\u4f7f\u4e24\u8005\u90fd\u80fd\u5b9e\u73b0Langmuir\u2212Hinshelwood\u548cEley\u2212Rideal\u673a\u5236\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCO Poisoning of Ru Catalysts in CO2<\/sub>\u00a0Hydrogenation under Thermal and Plasma Conditions: A Combined Kinetic and Diffuse Reflectance Infrared Fourier Transform Spectroscopy\u2212Mass Spectrometry Stu,\u00a0ACS Catal<\/i><\/b><\/em><\/strong>. 2020, 10, 12828\u221212840. DOI\uff1a10.1021\/acscatal.0c03620.<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.0c03620.<\/p>\n

\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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