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\u80cc\u666f\u4ecb\u7ecd<\/b><\/strong><\/p>\n

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\u6210\u679c\u7b80\u4ecb<\/b><\/strong><\/p>\n

MOF\u6846\u67b6\u7684\u67d4\u6027\u4f1a\u5f71\u54cd\u5176\u6c14\u4f53\u5206\u5b50\u7684\u7b5b\u5206\u6027\u80fd\u3002\u4e3a\u4e86\u6291\u5236MOF\u6846\u67b6\u7684\u67d4\u6027\uff0c\u5b81\u6ce2\u5927\u5b66\u674e\u781a\u7855\u6559\u6388\u56e2\u961f\u4e0e\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u6f58\u5b9c\u660c\u6559\u6388<\/b><\/strong>\u5408\u4f5c\uff0c\u9996\u6b21\u63d0\u51fa\u4e86\u201c\u7a7a\u95f4\u9650\u57df\u201d\u7b56\u7565\uff08Mater. Horiz., 2020,7, 223-228\uff09\uff0c\u5373\u5229\u7528\u521a\u6027\u94fe\u6bb5\u7684\u805a\u5408\u7269\u9650\u5236MOF\u7684\u67d4\u6027\u6846\u67b6\uff0c\u4ee5\u4fc3\u8fdb\u6df7\u5408\u57fa\u8d28\u819c\uff08MMMs\uff09\u7684\u6c14\u4f53\u5206\u5b50\u7b5b\u5206\u6548\u679c\u3002\u57fa\u4e8e\u4e0a\u8ff0\u7b56\u7565\uff0c\u8fd1\u671f\uff0c\u5b81\u6ce2\u5927\u5b66\u674e\u781a\u7855\u6559\u6388\u56e2\u961f<\/b><\/strong>\u5229\u7528\u4e00\u79cd\u73bb\u7483\u6001\u9ad8\u5206\u5b50OPBI\uff0c\u901a\u8fc7\u201c\u7a7a\u95f4\u9650\u57df\u201d\u6548\u5e94\u6291\u5236\u4e86MOF\u6846\u67b6\u67d4\u6027\u7684\u53d8\u5316\uff0c\u7528\u4e8e\u4fc3\u8fdbMMMs\u7684H2<\/sub>\/CO2<\/sub>\u5206\u79bb\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u6210\u679c\u4ee5\u9898\u4e3a\u201cMetal\u2212Organic Frameworks Corset with a Thermosetting Polymer\u00a0for Improved Molecular-Sieving Property of Mixed-Matrix\u00a0Membranes\u201d\u53d1\u8868\u5728\u6750\u6599\u9886\u57df\u4e13\u4e1a\u671f\u520aACS Appl. Mater. Interfaces\u4e0a\u3002<\/p>\n

\u56fe\u4e00 ZIF-7\u76f8\u53d8\u7684\u8868\u5f81<\/strong><\/p>\n

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a\u00a0\u6df7\u5408\u57fa\u8d28\u819c\u4e2d\u53ef\u63a7ZIF-7\u76f8\u53d8\u7684\u793a\u610f\u56fe\uff1bb CO2<\/sub>\u5438\u9644\u8bf1\u5bfcZIF-7\u7eb3\u7c73\u9897\u7c92\u53d1\u751f\u76f8\u53d8\uff1bc\u00a0XRD\u8868\u5f81ZIF-7\u7eb3\u7c73\u9897\u7c92\u5728\u540e\u5904\u7406\u8fc7\u7a0b\u4e2d\u7684\u76f8\u53d8\uff1bd\u00a0ZIF-7\u7eb3\u7c73\u9897\u7c92\u7684TG\u66f2\u7ebf\u3002<\/p>\n

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a\u00a0MMMs\u7684XRD\u8868\u5f81\uff1bb\u00a0MMMs\u7684\u7ea2\u5916\u8868\u5f81\uff1bc\u00a0MMMs\u5728\u6eb6\u5242\u4e2d\u7684\u7a33\u5b9a\u6027\uff1bd\u00a0MMMs\u5728180\u5ea6CO2<\/sub>\u6c14\u6c1b\u4e0b\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe\u4e09 \u819c\u7684\u7535\u955c\u8868\u5f81<\/strong><\/p>\n

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a-d\u00a0\u819c\u7684\u65ad\u9762\u548c\u5c40\u90e8\u653e\u5927SEM\u7535\u955c\u56fe\uff1be,f ZIF-7\u7eb3\u7c73\u9897\u7c92\u7684SAED\u884d\u5c04\u56fe\u3002<\/p>\n

\u56fe\u56db \u5355\u7ec4\u4efd\u6c14\u4f53\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

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a\u00a0\u5355\u7ec4\u4efd\u6c14\u4f53\u6e17\u900f\u6027\u8bc4\u4ef7\uff1bb\u00a0H2<\/sub>\u548cCO2<\/sub>\u7684\u6e17\u900f\u6027\u548c\u7406\u60f3\u9009\u62e9\u6027\u3002<\/p>\n

\u56fe\u4e94 \u673a\u7406\u63a2\u7a76<\/strong><\/p>\n

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a\u00a0\u819c\u7684CO2<\/sub>\u6269\u6563\u7cfb\u6570\u5bf9\u6bd4\uff1bb\u00a0\u819c\u7684\u6d3b\u5316\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\u56fe\u516d \u53cc\u7ec4\u4efd\u6c14\u4f53\u6027\u80fd\u6d4b\u8bd5\u00a0<\/strong><\/p>\n

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a\u00a0\u4e0d\u540c\u6e29\u5ea6\u4e0bH2<\/sub>\/CO2<\/sub>\u7684\u5206\u79bb\u6027\u80fd\uff1bb\u00a0\u4e0d\u540c\u538b\u529b\u4e0bH2<\/sub>\/CO2<\/sub>\u7684\u5206\u79bb\u6027\u80fd<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aMetal\u2212Organic Frameworks Corset with a Thermosetting Polymer\u00a0for Improved Molecular-Sieving Property of Mixed-Matrix\u00a0Membranes,\u00a0ACS Appl. Mater. Interfaces<\/i><\/em>, 2020, https:\/\/dx.doi.org\/10.1021\/acsami.0c17426<\/p>\n

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