{"id":213330,"date":"2020-11-21T06:12:00","date_gmt":"2020-11-20T22:12:00","guid":{"rendered":"\/\/m.iemloyee.com\/?p=213330"},"modified":"2020-11-20T21:12:13","modified_gmt":"2020-11-20T13:12:13","slug":"%e5%90%88%e6%88%90%e9%a1%b6%e5%88%8amacromolecules%ef%bc%9a%e4%bd%bf%e7%94%a8%e7%bc%a9%e8%81%9a%e6%8a%80%e6%9c%af%e5%88%b6%e5%a4%87%e5%87%ba%e9%ab%98%e6%8b%89%e4%bc%b8%ef%bc%8c%e5%8f%af%e5%9b%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=213330","title":{"rendered":"\u5408\u6210\u9876\u520aMacromolecules\uff1a\u4f7f\u7528\u7f29\u805a\u6280\u672f\u5236\u5907\u51fa\u9ad8\u62c9\u4f38\uff0c\u53ef\u56de\u6536\uff0c\u5e76\u80fd\u5728\u5ba4\u6e29\u5feb\u901f\u81ea\u4fee\u590d\u7684\u751f\u7269\u57fa\u5f39\u6027\u4f53"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7528\u751f\u7269\u57fa\u6a61\u80f6\u66ff\u4ee3\u77f3\u6cb9\u57fa\u81ea\u4fee\u590d\u5f39\u6027\u4f53\u5bf9\u4e8e\u53d1\u5c55\u53ef\u6301\u7eed\u5316\u7684\u6a61\u80f6\u5de5\u4e1a\u81f3\u5173\u91cd\u8981\uff0c\u800c\u6a61\u80f6\u5de5\u4e1a\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u5408\u6210\u7a0b\u5e8f\u7684\u7b80\u4fbf\u6027\u3002\u672c\u6587\u62a5\u9053\u4e86\u5728\u5c11\u91cf\u7518\u6cb9\u4f5c\u4e3a\u4ea4\u8054\u5242\u7684\u5b58\u5728\u4e0b\uff0c\u901a\u8fc7\u7425\u73c0\u9178\u3001\u5df1\u4e8c\u9178\u3001\u7678\u4e8c\u9178\u548c1,4-\u4e01\u4e8c\u9187\u7684\u7f29\u805a\u53cd\u5e94\u5408\u6210\u4e86\u9ad8\u5ea6\u53ef\u62c9\u4f38\u3001\u53ef\u56de\u6536\u548c\u53ef\u81ea\u4fee\u590d\u7684\u751f\u7269\u57fa\u5f39\u6027\u4f53\u3002\u8be5\u5f39\u6027\u4f53\u7684\u5b8f\u89c2\u6027\u80fd\uff0c\u5305\u62ec\u70ed\u3001\u673a\u68b0\u3001\u5e94\u529b\u677e\u5f1b\u548c\u81ea\u4fee\u590d\u6027\u80fd\uff0c\u90fd\u53ef\u4ee5\u901a\u8fc7\u5fae\u89c2\u5316\u5b66\u548c\u62d3\u6251\u7ed3\u6784\u8fdb\u884c\u7cbe\u7ec6\u8c03\u8282\u3002\u5176\u62c9\u4f38\u6027\u9ad8\u8fbe1700\uff05\uff0c\u51e0\u4e4e\u6ca1\u6709\u673a\u68b0\u6027\u80fd\u4e0b\u964d\u7684\u53ef\u56de\u6536\u6027\uff0c\u4ee5\u53ca\u53ef\u4ee5\u5728\u5ba4\u6e29\u4e0b\u5feb\u901f\u81ea\u4fee\u590d\uff08\u572820\u5206\u949f\u4e4b\u5185\uff09\u3002\u8fd9\u662f\u7b2c\u4e00\u6b21\u5b9e\u73b0\u4e86\u542b\u8102\u80aa\u65cf\u4e8c\u786b\u952e\u7684\u805a\u5408\u7269\u7684\u5ba4\u6e29\u5feb\u901f\u81ea\u4fee\u590d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u901a\u8fc7\u4e8c\u7fa7\u9178\uff0c<\/strong>1,4-<\/strong>\u4e01\u4e8c\u9187\uff0c\u7518\u6cb9\u548c<\/strong>3,3′-<\/strong>\u4e8c\u786b\u4ee3\u4e8c\u4e19\u9178\u7684\u7f29\u805a\u5408\u6210\u751f\u7269\u57fa\u5f39\u6027\u4f53<\/strong><\/p>\n

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\u56fe<\/strong>2\u00a0<\/strong>\u50a8\u80fd\u6a21\u91cf\uff08<\/strong>E’<\/strong>\uff09\u548c<\/strong>Tan\u03b4<\/strong>\u4e0e\u6e29\u5ea6\u7684\u5173\u7cfb<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>3 DSC<\/strong>\u51b7\u5374\u626b\u63cf\u548c\u52a0\u70ed\u626b\u63cf<\/strong><\/p>\n

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\u56fe<\/strong>4 <\/strong>\u5149\u5b66\u56fe\u7247<\/strong><\/p>\n

\"\"\uff08a\uff09\u539f\u59cbBEG1<\/sub>S0<\/sub>\uff1b<\/p>\n

\uff08b\uff09\u538b\u7f29\u6210\u578bBEG1<\/sub>S0<\/sub>\uff1b<\/p>\n

\uff08c\uff09\u539f\u59cbBEG1<\/sub>S10<\/sub>\uff1b<\/p>\n

\uff08d\uff09\u538b\u7f29\u6210\u578bBEG1<\/sub>S10\u3002<\/sub><\/p>\n

\u56fe<\/strong>5 <\/strong>\u529b\u5b66\u6027\u80fd<\/strong><\/p>\n

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\u5728\u5ba4\u6e29\uff0830\u00b0C\uff09\u4e0b\u6d4b\u5f97\u7684BEGx<\/sub>S10<\/sub>s\uff08a\uff09\u548cBE1<\/sub>Gy<\/sub>s\uff08b\uff09\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u4ee5\u53caBEGx<\/sub>S10<\/sub>s\uff08c\uff09\u548cBE1<\/sub>Gy<\/sub>s\uff08d\uff09\u7684\u5faa\u73af\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>6 <\/strong>\u53ef\u56de\u6536\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\u4ee5BEG1<\/sub>S10<\/sub>\u4e3a\u4ee3\u8868\u7684\u538b\u7f29\u6210\u578b\u52a0\u5de54\u6b21\u540e\uff0c\u73bb\u7483\u6001\u5f39\u6027\u4f53\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff08a\uff09\u548cFT-IR\u5149\u8c31\uff08b\uff09\u3002<\/p>\n

\u56fe<\/strong>7\u00a0<\/strong>\u5e94\u529b\u677e\u5f1b\u66f2\u7ebf<\/strong><\/p>\n

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\u56fe<\/strong>8 BEG1<\/sub>S10<\/sub><\/strong>\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5e94\u529b\u677e\u5f1b\u66f2\u7ebf\u5e76\u57fa\u4e8e<\/strong>Arrhenius<\/strong>\u65b9\u7a0b\u8fdb\u884c\u7ebf\u6027\u62df\u5408\u4ee5\u8ba1\u7b97\u677e\u5f1b\u6d3b\u5316\u80fd<\/strong><\/p>\n

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\u56fe<\/strong>9\u00a0<\/strong>\u5ba4\u6e29\u4e0b\u7684\u81ea\u6108\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/strong>\u56fe<\/strong>10 <\/strong>\u81ea\u4fee\u590d\u6027\u80fd<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u00a0<\/strong>\u56fe\u50cf\u663e\u793a\u4e86\u526a\u65ad\u540e\u7684\u5f39\u6027\u4f53\u5728\u5ba4\u6e29\u4e0b\u4fdd\u630110 s\uff08a\uff0cb\uff09\u540e\u7684\u81ea\u4fee\u590d\u6027\uff0c\u5f39\u6027\u4f53\uff08\u5178\u578b\u793a\u4f8b\u4e3aBEG1<\/sub>S10<\/sub>\uff09\u4fee\u590d\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff08c\uff09\u548c\u5404\u5f39\u6027\u4f53\u7684\u6700\u7ec8\u4fee\u590d\u6548\u7387\uff08d\uff09\u3002<\/p>\n

\u56fe<\/strong>11 <\/strong>\u81ea\u4fee\u590d\u673a\u7406<\/strong><\/p>\n

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\u00a0<\/strong><\/p>\n

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 <\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aHighly Stretchable, Recyclable, and Fast Room Temperature Self- Healable Biobased Elastomers Using Polycondensation<\/a> \uff08Macromolecules\uff0c2020, DOI\uff1adx.doi.org\/10.1021\/acs.macromol.0c01665\uff09<\/p>\n","protected":false},"excerpt":{"rendered":"

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