{"id":213318,"date":"2020-11-23T06:04:38","date_gmt":"2020-11-22T22:04:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=213318"},"modified":"2020-11-22T22:04:46","modified_gmt":"2020-11-22T14:04:46","slug":"%e5%85%ab%e7%af%87%e6%96%87%e7%ab%a0%e5%b8%a6%e4%bd%a0%e4%ba%86%e8%a7%a3%e8%a1%a8%e9%9d%a2%e9%87%8d%e6%9e%84%e7%ad%96%e7%95%a5%e5%a6%82%e4%bd%95%e6%94%b9%e5%96%84oer%e7%94%b5%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=213318","title":{"rendered":"\u516b\u7bc7\u6587\u7ae0\u5e26\u4f60\u4e86\u89e3\u8868\u9762\u91cd\u6784\u7b56\u7565\u5982\u4f55\u6539\u5584OER\u7535\u50ac\u5316\u5242\u6027\u80fd"},"content":{"rendered":"

\u5f15\u8a00<\/b><\/strong><\/p>\n

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Science\uff1a\u7535\u50ac\u5316\u5242\u7ec4\u5206\u6d78\u51fa\u5b9e\u73b0\u4ea7\u751f\u7f3a\u9677\u7684\u8868\u9762\u91cd\u6784\u73b0\u8c61<\/b><\/strong><\/p>\n

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SrIrO<\/b><\/strong>3<\/b><\/sub><\/strong>OER\u7406\u8bba\u5206\u6790<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/science.sciencemag.org\/content\/353\/6303\/1011<\/p>\n

Nat. Commun.\uff1a\u79bb\u5b50\u6d78\u51fa\u6548\u5e94\u63d0\u5347\u6742\u5316\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684OER\u6027\u80fd<\/b><\/strong><\/p>\n

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\"\"<\/b><\/strong><\/p>\n

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\u8fd1\u671f\uff0c\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u90b5\u5b97\u5e73\u548c\u5468\u5d6c<\/b><\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u901a\u8fc7\u5728\u9ad8\u4ef7\u9499\u949b\u77ff\u7ed3\u6784\u4e2d\u5f15\u5165\u53ef\u6eb6\u7684\u5916\u90e8\u7ec4\u5206\uff08\u5373\u6c2f\u5316\u94a1\u548c\u6c2f\u5316\u9536\uff09\uff0c\u5b9e\u73b0\u5177\u6709\u79ef\u6781\u4f5c\u7528\u7684\u79bb\u5b50\u6d78\u51fa\u6548\u5e94\u7684\u540c\u65f6\u8fd8\u4fdd\u8bc1\u4e86\u9499\u949b\u77ff\u6676\u4f53\u57fa\u8d28\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u4f5c\u8005\u9996\u5148\u8bbe\u8ba1\u4e86\u9ad8\u4ef7\u6742\u5316Ba0.35<\/sub>Sr0.65<\/sub>Co0.8<\/sub>Fe0.2<\/sub>O3-\u03b4<\/sub>\uff08BSCF\uff09\u590d\u5408\u6750\u6599\uff0c\u5728\u7535\u89e3\u8d28\u4e2d\uff0c\u968f\u7740\u53ef\u6eb6\u7ec4\u5206\u7684\u52a0\u5165\uff0c\u754c\u9762\u6db2\u548c\u4e3b\u76f8\u4e4b\u95f4\u7684\u79bb\u5b50\u6d53\u5ea6\uff08\u94a1\u79bb\u5b50\u548c\u9536\u79bb\u5b50\uff09\u5dee\u5f02\u51cf\u5c0f\uff0c\u4ece\u800c\u4fdd\u62a4\u4e86\u9499\u949b\u77ff\u6676\u4f53\u57fa\u8d28\uff1b\u8fd9\u4e9b\u9884\u6d78\u51fa\u7ec4\u5206\u8fd8\u80fd\u591f\u521b\u9020\u7a33\u5b9a\u7684\u5171\u9762\/\u8fb9\u8868\u9762\u7ed3\u6784\uff0c\u4f7f\u5f97\u6750\u6599\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA\/cm2<\/sup>\u6761\u4ef6\u4e0b\u8fd8\u80fd\u7a33\u5b9a100\u5c0f\u65f6\u3002\u4e0e\u9ad8\u4ef7\u7eaf\u76f8BSCF\u76f8\u6bd4\uff0c\u8fd9\u7c7b\u5171\u9762\/\u8fb9\u7ed3\u6784\u7684\u6742\u5316BSCF\u5177\u6709\u66f4\u52a0\u7a33\u5b9a\u7684\u6676\u683c\u6c27\u6d3b\u6027\u4f4d\u70b9\uff0c\u94b4\u548c\u94b4\/\u94c1\u91d1\u5c5e\u6d3b\u6027\u4f4d\u70b9\u4e4b\u95f4\u7684\u53cd\u5e94\u8def\u5f84\u4e5f\u66f4\u77ed\uff0c\u80fd\u591f\u8fdb\u4e00\u6b65\u5f15\u53d1\u66f4\u591a\u7684\u6c22\u6c27\u6839\u79bb\u5b50\u5e76\u63d0\u5347OER\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/s41467-020-17108-5<\/p>\n

AM\uff1a\u638c\u63a7\u4e9a\u7a33\u6001\u5c16\u6676\u77f3\u6c27\u5316\u7269\u7684\u8868\u9762\u91cd\u6784<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.201807898<\/p>\n

Nat. Catal.\uff1a\u6c27\u914d\u4f53\u73af\u5883\u52a9\u529b\u7a7a\u7a74\u63ba\u6742\u6838\u58f3\u7535\u50ac\u5316\u5242\u5b9e\u73b0\u6c34\u6c27\u5316<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/s41929-018-0153-y<\/p>\n

JACS\uff1a\u901a\u8fc7\u5f15\u5165\u94c1\u79bb\u5b50\u6765\u6539\u5584\u7f9f\u57fa\u6c27\u5316\u954dOER\u7535\u50ac\u5316\u5242\u6027\u80fd<\/b><\/strong><\/p>\n

\u9664\u4e86\u79bb\u5b50\u6d78\u51fa\u6548\u5e94\u6709\u52a9\u4e8e\u8868\u9762\u91cd\u6784\u4ee5\u5916\uff0c\u52a8\u6001\u8868\u9762\u4e0e\u4ece\u7535\u89e3\u8d28\u4e2d\u5e76\u5165\u7684\u79bb\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u80fd\u591f\u8c03\u8282\u7535\u50ac\u5316\u5242\u7684\u8868\u9762\u4f4d\u70b9\uff08\u5373\u5b9e\u73b0\u8868\u9762\u91cd\u6784\uff09\uff0c\u5e76\u4e14\u540c\u65f6\u589e\u5f3aOER\u6027\u80fd\u3002\u4fc4\u52d2\u5188\u5927\u5b66\u7684S. W. Boettcher<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5c31\u7cfb\u7edf\u7814\u7a76\u4e86\u94c1\u7684\u9644\u5e26\/\u6545\u610f\u5f15\u5165\u5bf9\u8868\u9762\u7ed3\u6784\u6f14\u53d8\u7684\u5f71\u54cd\uff0c\u4ee5\u53ca\u968f\u4e4b\u5e26\u6765\u7684\u539f\u5b50\/\u7535\u5b50\u7ed3\u6784\u3001\u6c27\u4e2d\u95f4\u4f53\u5438\u9644\u7279\u6027\u4ee5\u53ca\u4e3b\u4f53\u7535\u50ac\u5316\u5242OER\u6027\u80fd\u7684\u53d8\u5316\u3002<\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/pubs.acs.org\/doi\/10.1021\/ja502379c<\/p>\n

Nat. Catal.\uff1a\u6c27\u5316\u94b4\u57fa\u5316\u5408\u7269\u7684\u50ac\u5316\u6d3b\u6027\u6001\u5177\u6709\u4e00\u81f4\u7684\u7ed3\u6784\u6a21\u5757<\/b><\/strong><\/p>\n

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\"\"<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/www.nature.com\/articles\/s41929-018-0141-2<\/p>\n

Angew\uff1a\u8fa8\u8bc6\u81ea\u6211\u91cd\u6784\u7684\u954d\u57fa\u6742\u5316\u7535\u50ac\u5316\u5242\u4e2dOER\u7684\u5173\u952e\u53ef\u9006\u4e2d\u95f4\u4f53<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\u4e0e\u7814\u7a76\u6c27\u5316\u94b4\u57fa\u7535\u50ac\u5316\u5242\u7684\u8868\u9762\u91cd\u6784\u4e0d\u540c\uff0c\u5357\u4eac\u7406\u5de5\u5927\u5b66\u7684\u9646\u745e\u950b\u548c\u7535\u5b50\u79d1\u6280\u5927\u5b66\u7684\u718a\u6770\u3001Xianfu Wang\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u7b49\u4eba\u5219\u7814\u7a76\u4e86\u8fc7\u6e21\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\uff08NiNPS\uff0c\u954d\u57fa\u78f7\/\u786b\u5316\u7269\uff09\u4e2d\u7684\u771f\u6b63OER\u6d3b\u6027\u4f4d\u70b9\u3002\u7ecf\u8fc7\u7535\u5316\u5b66\u6c27\u5316\u540e\uff0c\u7535\u50ac\u5316\u5242\u5c55\u793a\u51fa\u4e86\u5177\u6709\u975e\u6676\u6c27\u5316\u954d\u79cd\u7684\u91cd\u6784\u8868\u9762\u3002\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u663e\u793a\uff0cOER\u8fc7\u7a0b\u4e2d\u7684\u7535\u50ac\u5316\u5242\u81ea\u6211\u91cd\u6784\u9020\u6210\u4e86\u4eceNiNPS\u76f8\u5230\u03b1<\/i><\/em>-Ni(OH)2<\/sub>\u7684\u4e0d\u53ef\u9006\u8f6c\u53d8\uff0c\u5e76\u53cd\u8fc7\u6765\u53c2\u4e0e\u4e86\u5230\u03b3-<\/i><\/em>NiOOH\u7684\u53ef\u9006\u8f6c\u53d8\u3002\u8fd9\u4e00\u7ed3\u679c\u8868\u660e\uff0c\u57280V\u65f6\u5e76\u6ca1\u6709\u68c0\u6d4b\u5230\u6c27\u5316\u954d\u3001\u6c22\u6c27\u5316\u954d\u6216\u8005\u7f9f\u57fa\u6c27\u5316\u954d\u7684\u751f\u6210\uff1b\u53cd\u800c\u5f53\u7535\u52bf\u589e\u52a0\u52300.5V\u65f6\uff0c\u03b3-<\/i><\/em>NiOOH\u7684\u62c9\u66fc\u8c31\u5e26\u5f00\u59cb\u51fa\u73b0\uff0c\u8bc1\u5b9e\u4e86NiNPS \u2192\u00a0\u03b1-Ni(OH)2<\/sub>\u00a0\u21cc\u00a0\u03b3-NiOOH\u7684\u8868\u9762\u76f8\u8f6c\u53d8\u8fc7\u7a0b\u4f34\u968f\u7740OER\u6d3b\u6027\u7684\u6539\u5584\uff0c\u540c\u65f6\u4e5f\u8bc1\u5b9e\u4e86\u03b3-NiOOH\u662fOER\u8fc7\u7a0b\u7684\u5173\u952e\u6d3b\u6027\u79cd\u3002\u56e0\u6b64\uff0c\u5185\u90e8\u7684NiNPS\u57fa\u8d28\u548c\u5916\u90e8\u7f9f\u57fa\u6c27\u5316\u7269\u80fd\u591f\u534f\u540c\u63d0\u53471-2\u6570\u91cf\u7ea7\u7684OER\u6027\u80fd\u3002\u7814\u7a76\u8ba4\u4e3a\uff0c\u8fd9\u9879\u5de5\u4f5c\u80fd\u591f\u63a8\u52a8\u5bf9\u954d\u57faOER\u50ac\u5316\u5242\u5173\u952e\u6d3b\u6027\u7ed3\u6784\u7684\u6df1\u5165\u7406\u89e3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201910716<\/p>\n

AM\uff1a\u8ffd\u8e2a\u6c2f\u79bb\u5b50\u5728\u81ea\u6211\u91cd\u6784\u4e2d\u7684\u4f5c\u7528<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u81ea\u6211\u91cd\u6784<\/b><\/strong>Co<\/b><\/strong>2<\/b><\/sub><\/strong>(OH)<\/b><\/strong>3<\/b><\/sub><\/strong>Cl<\/b><\/strong>\u7535\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\u9664\u4e86\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u6eb6\u89e3\u3001\u5f15\u5165\u989d\u5916\u79bb\u5b50\u4ee5\u53ca\u539f\u4f4d\u91d1\u5c5e\u7535\u5316\u5b66\u6c27\u5316\u4ee5\u5916\uff0c\u7535\u50ac\u5316\u5242\u9634\u79bb\u5b50\u7ec4\u5206\u5728\u52a8\u6001\u7535\u50ac\u5316\u5242\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u81ea\u6211\u8c03\u8282\u4e5f\u80fd\u591f\u5f15\u53d1\u8868\u9762\u91cd\u6784\u5e76\u4e14\u589e\u5f3aOER\u52a8\u529b\u5b66\u3002\u4e2d\u79d1\u5927\u7684\u5b8b\u793c<\/b><\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5c31\u63ed\u793a\u4e86\u5faa\u73af\u4f0f\u5b89\u8fc7\u7a0b\u4e2d\uff0cCo2<\/sub>(OH)3<\/sub>Cl\u7535\u50ac\u5316\u5242\u7684\u6676\u683c\u6c2f\u79bb\u5b50\u81ea\u6211\u523b\u8680\u80fd\u591f\u9010\u6b65\u589e\u52a0OER\u6027\u80fd\u3002STEM\u56fe\u50cf\u663e\u793a\uff0c\u6c2f\u6269\u6563\u9020\u6210\u7684\u7ed3\u6784\u7f3a\u9677\u4e3aOER\u63d0\u4f9b\u4e86\u4e0d\u9971\u548c\u7684\u53ef\u914d\u4f4d\u4f4d\u70b9\uff1b\u540c\u65f6\u5728\u6c27\u5316\u7535\u4f4d\u4e0b\uff0c\u4ece\u7535\u50ac\u5316\u5242\u4e2d\u51fa\u73b0\u7684\u6c2f\u6269\u6563\u8fd8\u80fd\u589e\u52a0\u94b4\u6c27\u5316\u6001\uff08\u4e0e\u03b2<\/i><\/em>-CoOOH\u543b\u5408\uff09\u3002\u8fdb\u4e00\u6b65\u8868\u5f81\u4e5f\u53d1\u73b0\uff0c\u94b4\u6c27\u952e\u548c\u94b4\u94b4\u952e\u952e\u957f\u4e5f\u4e0e\u03b2<\/i><\/em>-CoOOH\u4e00\u81f4\uff0c\u56e0\u800c\u8bc1\u5b9e\u4e86\u8868\u9762\u91cd\u6784\u6f14\u53d8\u7684\u53d1\u751f\u3002\u7535\u5316\u5b66\u68c0\u6d4b\u4e5f\u8868\u660e\uff0c\u91cd\u6784\u884d\u751f\u7684\u7ec4\u5206\u80fd\u591f\u5728\u78b1\u6027\/\u4e2d\u6027\u7535\u89e3\u8d28\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u539f\u4f4d\u540c\u6b65\u8f90\u5c04X\u5c04\u7ebf\u8c31\u5b66\u548cDFT\u8ba1\u7b97\u4e5f\u5171\u540c\u63ed\u793a\u4e86\u6676\u683c\u6c2f\u79bb\u5b50\u523b\u8680\u662f\u89e6\u53d1\u91cd\u6784\u548c\u589e\u5f3a\u50ac\u5316\u6027\u80fd\u7684\u5173\u952e\u6240\u5728\u3002\u901a\u8fc7\u8fd9\u4e00\u5de5\u4f5c\uff0c\u4e3a\u7406\u89e3\u5f02\u8d28\u50ac\u5316\u5242\u81ea\u6211\u91cd\u6784\u76f8\u5173\u7684OER\u673a\u5236\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u8bc1\u636e\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.201805127<\/p>\n

\u672c\u6587\u7531nanoCJ\u4f9b\u7a3f\u3002<\/p>\n

\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n

\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n

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