{"id":212397,"date":"2020-11-06T06:30:59","date_gmt":"2020-11-05T22:30:59","guid":{"rendered":"\/\/m.iemloyee.com\/?p=212397"},"modified":"2020-11-05T20:31:10","modified_gmt":"2020-11-05T12:31:10","slug":"%e5%a4%a7%e6%94%be%e5%bc%82%e5%bd%a9%e7%9a%84mofscofs%e6%98%af%e5%a6%82%e4%bd%95%e6%88%90%e4%b8%bascience%e5%92%8cnature%e4%b8%8a%e7%9a%84vip%e6%9d%90%e6%96%99","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=212397","title":{"rendered":"\u5927\u653e\u5f02\u5f69\u7684MOFs&#038;COFs\u662f\u5982\u4f55\u6210\u4e3aScience\u548cNature\u4e0a\u7684VIP\u6750\u6599"},"content":{"rendered":"<p>\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u548c\u5171\u4ef7-\u6709\u673a\u6846\u67b6(COFs)\u7684\u7f51\u72b6\u5316\u5b66\u7814\u7a76\u8fdb\u5c55\u5c06\u91d1\u5c5e\u7edc\u5408\u7269\u548c\u6709\u673a\u5316\u5b66\u6269\u5c55\u5230\u65e0\u9650\u7684\u4e8c\u7ef4\u548c\u4e09\u7ef4\u5f62\u5f0f\u3002\u7531\u4e8eMOFs\u548cCOFs\u6750\u6599\u5177\u6709\u4e30\u5bcc\u7684\u5b54\u9699\u7ed3\u6784\u3001\u8d85\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u548c\u7ed3\u6784\u53ef\u8bbe\u8ba1\u6027\u7b49\u4f18\u70b9\uff0c\u56e0\u6b64\u5b83\u4eec\u5728\u6c14\u4f53\u5438\u9644\u3001\u50ac\u5316\u3001\u5316\u5b66\u4f20\u611f\u3001\u5316\u5b66\u5206\u79bb\u548c\u7535\u5316\u5b66\u50a8\u80fd\u7b49\u9886\u57df\u5c55\u73b0\u51fa\u975e\u5e38\u4f18\u5f02\u7684\u5e94\u7528\u4ef7\u503c\u3002\u8fd1\u5341\u5e74\u4e86\uff0cMOFs\u548cCOFs\u7684\u53d1\u6587\u91cf\u5448\u500d\u6570\u589e\u957f\uff0c\u6210\u4e3a\u4f17\u591a\u79d1\u7814\u5de5\u4f5c\u8005\u4eec\u5173\u6ce8\u7684\u5bf9\u8c61\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u6211\u4eec\u68b3\u7406\u4e86\u6700\u8fd1\u53d1\u8868\u5728Science\u548cNature\u671f\u520a\u4e0a\u7684MOFs&amp;COFs\u6587\u7ae0\uff0c\u770b\u770bMOFs&amp;COFs\u662f\u5982\u4f55\u957f\u671f\u6e38\u8d70\u4e8e\u9876\u520a\u4e4b\u95f4\u3002<\/p>\n<p><strong>Nature\uff1a\u4e8c\u6c27\u5316\u949b\uff08TiO<sub>2<\/sub>\uff09\u586b\u5145\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u5b54\u9699\u8fdb\u884cCO<sub>2<\/sub>\u5149\u8fd8\u539f<\/strong><\/p>\n<p>\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u56e0\u5176\u4e0e\u6c14\u4f53\u5206\u5b50\u7684\u7279\u6b8a\u76f8\u4e92\u4f5c\u7528\u800c\u95fb\u540d\uff0c\u518d\u52a0\u4e0a\u5176\u4e30\u5bcc\u6709\u5e8f\u7684\u5b54\u9699\u7387\uff0c\u4f7f\u5176\u6210\u4e3a\u5c06\u6c14\u4f53\u5206\u5b50\u5149\u50ac\u5316\u8f6c\u5316\u4e3a\u6709\u7528\u4ea7\u54c1\u7684\u6709\u5e0c\u671b\u7684\u5019\u9009\u6750\u6599\u3002\u7136\u800c\uff0c\u4f7f\u7528MOFs\u6216MOF\u57fa\u590d\u5408\u6750\u6599\u8fdb\u884cCO<sub>2<\/sub>\u5149\u8fd8\u539f\u7684\u5c1d\u8bd5\u901a\u5e38\u4f1a\u5bfc\u81f4\u8fdc\u4f4e\u4e8e\u4ece\u6700\u5148\u8fdb\u7684\u56fa\u6001\u6216\u5206\u5b50\u50ac\u5316\u5242\u83b7\u5f97\u7684CO<sub>2<\/sub>\u8f6c\u5316\u6548\u7387\uff0c\u5373\u4f7f\u5728\u727a\u7272\u8bd5\u5242\u7684\u4fc3\u8fdb\u4e0b\u4e5f\u662f\u5982\u6b64\u3002\u8fd1\u65e5\uff0c<strong><b>\u6b66\u6c49\u5927\u5b66\u9093\u9e64\u7fd4\u6559\u6388\u8bfe\u9898\u7ec4\u548c\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u7279\u8058\u6559\u6388<\/b><\/strong><strong><b>Osamu Terasaki<\/b><\/strong><strong><b>\u5408\u4f5c<\/b><\/strong>\u901a\u8fc7\u5728\u57fa\u4e8e\u5bf9\u82ef\u4e8c\u7532\u9178\u94ec\u7684MOF\uff08MIL-101\uff09\u53ca\u5176\u884d\u751f\u7269\u7684\u4e0d\u540c\u5b54\u9699\u4e2d\u751f\u957fTiO<sub>2<\/sub>\uff0c\u5728MOF\u6676\u4f53\u5185\u90e8\u5f62\u6210\u201c\u5206\u5b50\u9694\u95f4\u201d\u3002\u8fd9\u4f7f\u5f97\u5149\u5438\u6536\/\u4ea7\u751f\u7535\u5b50\u7684TiO<sub>2<\/sub>\u5355\u5143\u548cMOF\u4e3b\u5e72\u4e2d\u7684\u50ac\u5316\u91d1\u5c5e\u7c07\u4e4b\u95f4\u5b9e\u73b0\u534f\u540c\u4f5c\u7528\uff0c\u4ece\u800c\u4fc3\u8fdb\u5149\u50ac\u5316CO<sub>2<\/sub>\u8fd8\u539f\uff0c\u540c\u65f6\u4ea7\u751fO<sub>2<\/sub>\u3002\u5728\u542b\u670942%TiO<sub>2<\/sub>\u7684MIL-101\u884d\u751f\u7269\uff08\u537342%-TiO<sub>2<\/sub>-in-MIL-101-Cr-NO<sub>2<\/sub>\uff09\u7684\u590d\u5408\u6750\u6599\u4e2d\uff0c\u89c2\u5bdf\u5230\u5728350 nm\u6ce2\u957f\u4e0bCO<sub>2<\/sub>\u5149\u8fd8\u539f\u7684\u8868\u89c2\u91cf\u5b50\u6548\u7387\u4e3a11.3%\u3002\u636e\u4f30\u8ba1\uff0c\u8be5\u590d\u5408\u6750\u6599\u4e2d\u4e00\u79cd\u7c7b\u578b\u9694\u5ba4\u4e2d\u7684TiO<sub>2<\/sub>\u5355\u5143\u6bd4\u53e6\u4e00\u79cd\u7c7b\u578b\u7684\u9694\u5ba4\u4e2d\u7684TiO<sub>2<\/sub>\u5355\u5143\u6d3b\u6027\u9ad844\u500d\uff0c\u7a81\u51fa\u4e86TiO<sub>2<\/sub>\u5728\u8be5\u7cfb\u7edf\u4e2d\u7cbe\u786e\u5b9a\u4f4d\u7684\u4f5c\u7528\u3002\u8be5\u6210\u679c\u4ee5\u201cFilling metal\u2013organic framework mesopores with TiO<sub>2<\/sub>\u00a0for CO<sub>2<\/sub>\u00a0photoreduction\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nature\u4e0a\u3002DOI: 10.1038\/s41586-020-2738-2\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s41586-020-2738-2<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212399 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1.png\" alt=\"\" width=\"499\" height=\"441\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1.png 499w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-1-300x265.png 300w\" sizes=\"(max-width: 499px) 100vw, 499px\" \/><\/p>\n<p><strong>Science\uff1a\u591a\u53d8\u91cf\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u91d1\u5c5e\u7684\u6392\u5e8f<\/strong><\/p>\n<p>\u5927\u591a\u6570\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOFs)\u5728\u8fde\u63a5\u6709\u673a\u8fde\u63a5\u5668\u7684\u8282\u70b9\u4e2d\u53ea\u5305\u542b\u4e00\u79cd\u7c7b\u578b\u7684\u91d1\u5c5e\u3002\u542b\u6709\u591a\u79cd\u91d1\u5c5e\u7684\u591a\u5143MOFs\u5728\u5438\u9644\u548c\u50ac\u5316\u6027\u80fd\u65b9\u9762\u5177\u6709\u66f4\u5927\u7684\u9009\u62e9\u6027\uff0c\u4f46\u662f\u786e\u5b9a\u91d1\u5c5e\u5728\u8fd9\u4e9b\u6750\u6599\u4e2d\u7684\u6392\u5217\u662f\u5177\u6709\u6311\u6218\u6027\u7684\u3002\u8fd1\u65e5\uff0c<strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong><strong><b>Omar M. Yaghi<\/b><\/strong><strong><b>\u6559\u6388\u548c\u5fb7\u56fd\u6ce2\u9e3f\u9c81\u5c14\u5927\u5b66\u7684Tong<\/b><\/strong><strong><b>\u00a0Li<\/b><\/strong>\u56e2\u961f\u5408\u4f5c\u7ed8\u5236\u4e86\u591a\u5143\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOF-74)\u4e2d\u91d1\u5c5e\u6c27\u5316\u7269\u6676\u4f53\u5185\u7684\u91d1\u5c5e\u5e8f\u5217\u56fe\uff0c\u5176\u4e2d\u5143\u7d20\u542b\u6709\u94b4\uff08Co\uff09\u3001\u9549\uff08Cd\uff09\u3001\u94c5\uff08Pb\uff09\u548c\u9530\uff08Mn\uff09\u7684\u6df7\u5408\u7ec4\u5408\u3002\u8fd9\u4e9b\u6676\u4f53\u901a\u8fc7\u539f\u5b50\u63a2\u9488\u5c42\u6790\u6210\u50cf\u63ed\u793a\u4e86\u91d1\u5c5e\u79bb\u5b50\u7684\u975e\u5747\u5300\u7a7a\u95f4\u5e8f\u5217\u7684\u5b58\u5728\uff0c\u8fd9\u53d6\u51b3\u4e8e\u91d1\u5c5e\u548c\u5408\u6210\u6e29\u5ea6\uff0c\u4f8b\u5982\u968f\u673a\u7684\uff08Co\uff0cCd\uff0c120 \u00b0C\uff09\uff0c\u77ed\u7684\u91cd\u590d\uff08Co\uff0cCd\uff0c85 \u00b0C\uff09\uff0c\u957f\u91cd\u590d\u7684\uff08Co\uff0cPb\uff0c85 \u00b0C\uff09\u548c\u63d2\u5165\u7684\uff08Co\uff0cMn\uff0c85 \u00b0C\uff09\u3002\u6bcf\u4e00\u79cd\u5e8f\u5217\u7c7b\u578b\u6d4b\u8bd5\u4e86\u4e09\u79cd\u6676\u4f53\uff0c\u89c2\u5bdf\u5230\u6240\u670912\u4e2a\u6837\u54c1\u4e2dCo\u7684\u6469\u5c14\u5206\u6570\u57280.4\u52300.9\u4e4b\u95f4\u53d8\u5316\uff0c\u800c\u5e8f\u5217\u6ca1\u6709\u6539\u53d8\u7c7b\u578b\u3002\u5728\u4e0e\u91d1\u5c5e\u6c27\u5316\u7269\u6bd4\u8f83\u4e2d\uff0c\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u5bf9\u4e0d\u540c\u5c3a\u5bf8\u7684\u91d1\u5c5e\u5728\u5176\u68d2\u72b6\u4f53\u4e2d\u5171\u5b58\uff0c\u4e14\u5177\u6709\u5f88\u9ad8\u7684\u8010\u53d7\u6027\uff0c\u56e0\u6b64\u5448\u73b0\u51fa\u4e0d\u540c\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cSequencing of metals in multivariate metal-organic frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI:\u00a010.1126\/science.aaz4304\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/369\/6504\/674<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212400 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-6-1.png\" alt=\"\" width=\"600\" height=\"181\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-6-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-6-1-300x91.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>Science\uff1a\u56db\u80fa\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u534f\u540c\u78b3\u6355\u96c6\u4e0e\u84b8\u6c7d\u518d\u751f<\/strong><\/p>\n<p>\u5929\u7136\u6c14\u5df2\u6210\u4e3a\u4e3b\u8981\u7684\u7535\u529b\u6765\u6e90\uff0c\u800c\u80fd\u591f\u6709\u6548\u53bb\u9664\u5929\u7136\u6c14\u53d1\u7535\u5382\u70df\u9053\u6392\u653e\u7269\u4e2d\u4e8c\u6c27\u5316\u78b3\uff08CO<sub>2<\/sub>\uff09\u7684\u6280\u672f\u53ef\u4ee5\u964d\u4f4e\u5176\u78b3\u5f3a\u5ea6\u3002\u7136\u800c\uff0c\u9274\u4e8e\u70df\u6c14\u4e2d\u4e8c\u6c27\u5316\u78b3\u5206\u538b\u8f83\u4f4e\uff0c\u5206\u79bb\u4e8c\u6c27\u5316\u78b3\u5c24\u5176\u5177\u6709\u6311\u6218\u6027\u3002<strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong><strong><b>Jeffrey R. Long<\/b><\/strong><strong><b>\u6559\u6388\u548c<\/b><\/strong><strong><b>Rebecca L. Siegelman<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u4ece\u4e8c\u80fa\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u7684\u6676\u4f53\u7ed3\u6784\u4e2d\u8868\u73b0\u51fa\u4e24\u6b65\u534f\u540cCO<sub>2<\/sub>\u5438\u9644\u5f97\u5230\u7075\u611f\uff0c\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u4fdd\u6301\u534f\u540c\u6027\u7684\u575a\u56fa\u7684\u56db\u80fa\u5b98\u80fd\u5316\u6846\u67b6\uff0c\u5bfc\u81f4\u5728\u4e0e\u5929\u7136\u6c14\u70df\u9053\u6392\u653e\u76f8\u5173\u7684\u6781\u7aef\u6761\u4ef6\u4e0b\uff0c\u6355\u83b7\u4e8c\u6c27\u5316\u78b3\u7684\u6548\u7387\u6781\u9ad8\u3002\u56db\u80fa\u7684\u6709\u5e8f\u591a\u91d1\u5c5e\u914d\u4f4d\u4f7f\u6750\u6599\u5177\u6709\u975e\u51e1\u7684\u7a33\u5b9a\u6027\uff0c\u53ef\u7528\u4e8e\u6a21\u62df\u6f6e\u6e7f\u70df\u6c14\u7684\u5438\u9644-\u89e3\u5438\u5faa\u73af\uff0c\u5e76\u53ef\u4f7f\u7528\u4f4e\u6e29\u84b8\u6c7d\u8fdb\u884c\u518d\u751f\uff0c\u800c\u4e0d\u662f\u6602\u8d35\u7684\u538b\u529b\u6216\u6e29\u5ea6\u6ce2\u52a8\u3002\u8be5\u6210\u679c\u4ee5\u201cCooperative carbon capture and steam regeneration with tetraamine-appended metal\u2013organic frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI\uff1a10.1126\/science.abb3976<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/369\/6502\/392<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212401 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-10.png\" alt=\"\" width=\"600\" height=\"455\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-10-300x228.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>Science\uff1a\u5316\u5b66\u9009\u62e9\u6027\u7094\u70c3\/\u70ef\u70c3\u5206\u79bb\u6cb8\u77f3\u5b54\u9699\u5185\u90e8\u7684\u63a7\u5236<\/strong><\/p>\n<p>\u9ad8\u6548\u53bb\u9664\u805a\u5408\u7269\u7ea7\u4f4e\u70ef\u70c3\u751f\u4ea7\u4e2d\u7684\u7094\u6742\u8d28\u5bf9\u8bb8\u591a\u884c\u4e1a\u6765\u8bf4\u662f\u4e00\u4e2a\u91cd\u8981\u4e14\u5177\u6709\u6311\u6218\u6027\u7684\u76ee\u6807\u3002<strong><b>\u5357\u5f00\u5927\u5b66\u674e\u5170\u51ac\u6559\u6388\u548c\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u6768\u56db\u6d77\u56e2\u961f<\/b><\/strong>\u62a5\u544a\u4e86\u4e00\u79cd\u63a7\u5236\u516b\u9762(FAU)\u6cb8\u77f3\u5185\u90e8\u5b54\u9699\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u9694\u79bb\u7684\u5f00\u653e\u954d(II)\u4f4d\u70b9\u5728\u5176\u516d\u5143\u73af\u4e2d\u3002\u5728\u73af\u5883\u6761\u4ef6\u4e0b\uff0cNi@FAU\u5bf9\u7094\u7684\u5438\u9644\u6548\u679c\u663e\u8457\uff0c\u80fd\u6709\u6548\u5206\u79bb\u4e59\u7094\/\u4e59\u70ef\u3001\u4e19\u70ef\/\u4e19\u70ef\u548c\u4e01\u70ef\/1,3-\u4e01\u4e8c\u70ef\u6df7\u5408\u7269\uff0c\u52a8\u6001\u5206\u79bb\u9009\u62e9\u6027\u5206\u522b\u8fbe\u5230\u4e86\u524d\u6240\u672a\u6709\u7684100\u300192\u548c83\u3002\u539f\u4f4d\u4e2d\u5b50\u884d\u5c04\u548c\u975e\u5f39\u6027\u4e2d\u5b50\u6563\u5c04\u8868\u660e\uff0c\u5c40\u9650\u954d(II)\u4f4d\u70b9\u4f7f\u5316\u5b66\u9009\u62e9\u6027\u6210\u4e3a\u53ef\u80fd\u901a\u8fc7\u5f62\u6210\u4e9a\u7a33\u6001[Ni(II)(C<sub>2<\/sub>H<sub>2<\/sub>)<sub>3<\/sub>]\u914d\u5408\u7269\u53ef\u9006\u7ed3\u5408\u4e59\u7094\u3002\u63a7\u5236\u5bb9\u6613\u4f38\u7f29\u7684\u6cb8\u77f3\u5185\u90e8\u5b54\u9699\u7684\u5316\u5b66\u6027\u8d28\uff0c\u5df2\u7ecf\u5728\u6311\u6218\u5de5\u4e1a\u5206\u79bb\u4e2d\u91ca\u653e\u4e86\u5b83\u4eec\u7684\u6f5c\u529b\u3002\u8be5\u6210\u679c\u4ee5\u201cControl of zeolite pore interior for chemoselective alkyne\/olefin separations\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI:\u00a010.1126\/science.aay8447<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/368\/6494\/1002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212402 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-12-1.png\" alt=\"\" width=\"600\" height=\"419\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-12-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-12-1-300x210.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>Science\uff1a\u6e05\u6d01\u80fd\u6e90\u9ad8\u5b54\u6750\u6599\u7684\u4f53\u79ef\u548c\u91cd\u91cf\u5438\u6536\u5e73\u8861<\/strong><\/p>\n<p>\u79d1\u5b66\u5bb6\u4eec\u9762\u4e34\u7684\u4e00\u4e2a\u5de8\u5927\u6311\u6218\u662f\u5f00\u53d1\u5438\u9644\u5242\u6750\u6599\uff0c\u8fd9\u79cd\u6750\u6599\u5177\u6709\u8d85\u9ad8\u7684\u5b54\u9699\u5ea6\uff0c\u540c\u65f6\u53c8\u80fd\u4fdd\u6301\u91cd\u91cf\u548c\u4f53\u79ef\u8868\u9762\u79ef\u4e4b\u95f4\u7684\u5e73\u8861\uff0c\u7528\u4e8e\u8231\u8f7d\u6c22\u6c14\u548c\u7532\u70f7\u7684\u50a8\u5b58\u2014\u8fd9\u662f\u4f20\u7edf\u5316\u77f3\u71c3\u6599\u7684\u66ff\u4ee3\u54c1\u3002<strong><b>\u7f8e\u56fd\u897f\u5317\u5927\u5b66<\/b><\/strong><strong><b>Omar K. Farha<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u57fa\u4e8e\u91d1\u5c5e\u4e09\u6838\u7c07\u5408\u7269\uff0c\u5373NU-1501-M\uff08M=Al\u6216Fe\uff09\u7684\u8d85\u591a\u5b54\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u7684\u6a21\u62df\u9a71\u52a8\u5408\u6210\u3002\u4e0e\u5176\u4ed6\u8d85\u591a\u5b54MOFs\u76f8\u6bd4\uff0cNU-1501-Al\u540c\u65f6\u8868\u73b0\u51fa7310 m<sup>2<\/sup>\u00a0g<sup>\u22121<\/sup>\u7684\u9ad8\u91cd\u91cfBET\u9762\u79ef\u548c2060 m<sup>2 <\/sup>cm<sup>\u22123<\/sup>\u7684\u4f53\u79efBET\u9762\u79ef\uff0c\u540c\u65f6\u6ee1\u8db3\u56db\u4e2aBET\u4e00\u81f4\u6027\u6807\u51c6\u3002\u8be5MOF\u7684\u9ad8\u5b54\u9699\u7387\u548c\u8868\u9762\u79ef\u4e3a\u6c22\u6c14\u548c\u7532\u70f7\u63d0\u4f9b\u4e86\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u91cd\u91cf\u548c\u4f53\u79ef\u5b58\u50a8\u6027\u80fd\uff1aNU-1501-Al\u5728100 bar\/270 K\u4e0b\u7684\u5438\u6536\u91cf\u4e3a0.66 g g<sup>\u22121<\/sup>[262 cm<sup>3<\/sup>(\u6807\u51c6\u6e29\u5ea6\u548c\u538b\u529b,STP)cm<sup>\u22123<\/sup>]\uff0c\u8d85\u8fc7\u4e86\u7f8e\u56fd\u80fd\u6e90\u90e8\u7684\u91cd\u91cf\u7532\u70f7\u50a8\u5b58\u76ee\u6807\uff080.5 g<sup>\u22121<\/sup>\uff09270 K\u65f6\uff0c5\u81f3100 bar\u7684\u5de5\u4f5c\u5bb9\u91cf\u4e3a0.60 g g<sup>\u22121<\/sup>[238 cm<sup>3<\/sup>(STP)cm<sup>\u22123<\/sup>]\uff1b\u5b83\u8fd8\u663e\u793a\u4e86\u5728\u6e29\u5ea6\u548c\u538b\u529b\u8054\u5408\u6446\u52a8\uff0877 K\/100 bar\u2192160 K\/5 bar\uff09\u4e0b\u7684\u6700\u4f73\u53ef\u4ea4\u4ed8\u6c22\u5bb9\u91cf\uff0814.0\u91cd\u91cf%\uff0c46.2 g L<sup>\u22121<\/sup>\uff09\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cBalancing volumetric and gravimetric uptake in highly porous materials for clean energy\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science\u7684\u671f\u520a\u4e0a\u3002DOI:\u00a010.1126\/science.aaz8881<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/368\/6488\/297<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212403 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-13.png\" alt=\"\" width=\"600\" height=\"598\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-13.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-13-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-13-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>Science\uff1a\u8d85\u9ad8\u573a<sup>67<\/sup>Zn NMR\u63ed\u793a\u4e86\u5206\u5b50\u7ed3\u6784\u54aa\u5511\u76d0\u73bb\u7483\u7684\u77ed\u7a0b\u65e0\u5e8f<\/strong><\/p>\n<p>\u901a\u8fc7\u7814\u7a76\u6cb8\u77f3\u54aa\u5511\u9aa8\u67b6\u73bb\u7483\u7684\u7ed3\u6784\uff0c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u4e86\u89e3\u5176\u73bb\u7483\u7684\u5f62\u6210\u673a\u7406\u3002<strong><b>\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u5cb3\u8fdc\u5f81\u6559\u6388\u548c\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6234\u7ef4\u65af\u5206\u6821<\/b><\/strong><strong><b>Sabyasachi Sen<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u5408\u4f5c\u5229\u7528\u8d85\u9ad8\u573aZn-67\u56fa\u4f53\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u76f4\u63a5\u68c0\u6d4b\u4e86ZIF\u73bb\u7483\u4e2d\u7684\u77ed\u7a0b\u65e0\u5e8f\u3002\u6bcd\u6676\u7684\u4e24\u4e2a\u4e0d\u540c\u7684\u950c\u4f4d\u5728\u7194\u5316\u65f6\u8f6c\u53d8\u6210\u4e00\u4e2a\u56db\u9762\u4f53\uff0c\u5177\u6709\u5e7f\u6cdb\u7684\u7ed3\u6784\u53c2\u6570\u5206\u5e03\u3002\u6b64\u5916\uff0c\u914d\u4f53\u5316\u5b66\u5bf9\u77ed\u7a0b\u65e0\u5e8f\u6ca1\u6709\u63a7\u5236\u4f5c\u7528\uff0c\u5c3d\u7ba1\u524d\u8005\u5f71\u54cd\u4e86\u5b83\u4eec\u7684\u76f8\u53d8\u884c\u4e3a\u3002\u8fd9\u4e9b\u53d1\u73b0\u63ed\u793a\u4e86\u7ed3\u6784\u4e0e\u6027\u80fd\u7684\u5173\u7cfb\uff0c\u6709\u52a9\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u73bb\u7483\u7684\u8bbe\u8ba1\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cUltrahigh-field <sup>67<\/sup>Zn NMR reveals short-range disorder in zeolitic imidazolate framework glasses\u201d\u4e3a\u9898\u53d1\u8868\u5728Science\u7684\u671f\u520a\u4e0a\u3002DOI:\u00a010.1126\/science.aaz0251<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/367\/6485\/1473<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212404 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-14.png\" alt=\"\" width=\"600\" height=\"194\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-14.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-14-300x97.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>Science\uff1a\u5171\u4ef7-\u6709\u673a\u6846\u67b6\u7684\u9ad8\u4ef7\u952e\u8bbe\u8ba1<\/strong><\/p>\n<p>\u5171\u4ef7-\u6709\u673a\u6846\u67b6(COFs)\u4e2d\u6784\u7b51\u5355\u5143\u7684\u4ef7\u6001(\u8fde\u901a\u6027)\u4e3b\u8981\u4e3a3\u548c4\uff0c\u5206\u522b\u5bf9\u5e94\u4e09\u89d2\u5f62\u548c\u6b63\u65b9\u5f62\u6216\u56db\u9762\u4f53\u3002\u8fd1\u65e5\uff0c<strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821<\/b><\/strong><strong><b>Omar M. Yaghi<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u62a5\u544a\u4e86\u4e00\u4e2a\u7b56\u7565\uff0c\u4f7fCOFs\u5177\u67098\u4ef7(\u7acb\u65b9\u4f53)\u548c\u201c\u66f4\u5927\u201d(\u68d2)\u3002\u5c06\u787c\u548c\u78f7\u4f5c\u4e3a\u78b3\u57fa\u5143\u7d20\u7684\u7b49\u7535\u5b50\u7ec4\u5408\u800c\u8bbe\u8ba1\u7684\u8fde\u63a5\u52421,4-\u787c\u82ef\u57fa\u81a6\u9178\u88ab\u6d53\u7f29\u6210\u591a\u5b54\u7684\u591a\u7acb\u65b9\u7ed3\u6784\uff08BP-COF-1\uff09\uff0c\u5176\u5f62\u5f0f\u4e3a(\u2013B<sub>4<\/sub>P<sub>4<\/sub>O<sub>12<\/sub>-)(\u2013C<sub>6<\/sub>H<sub>4<\/sub>-)<sub>4<\/sub>\u3002\u4f5c\u8005\u7528X\u5c04\u7ebf\u7c89\u672b\u884d\u5c04\u6280\u672f\u5bf9\u5176\u8fdb\u884c\u4e86\u8868\u5f81\uff0c\u53d1\u73b0\u4e86\u4e0e\u82ef\u57fa\u8fde\u63a5\u7684\u7acb\u65b9\u4f53\u3002\u5f02\u6784\u4f53\u5f62\u6001(BP-COF-2\u81f35)\u540c\u6837\u88ab\u5236\u5907\u548c\u8868\u5f81\u3002\u7531\u68d2\u72b6\u5355\u5143\u7ec4\u6210\u7684\u7ed3\u6784\u540c\u5206\u5f02\u6784\u4f53COF (BP-COF-6)\u7684\u5927\u5355\u6676\u4e5f\u88ab\u7528\u540c\u6837\u7684\u7b56\u7565\u5408\u6210\uff0c\u4ece\u800c\u63a8\u52a8COF\u5316\u5b66\u8fdb\u5165\u4e00\u4e2a\u65b0\u7684\u4ef7\u6001\u3002\u8be5\u9879\u7814\u7a76\u6210\u679c\u4ee5\u201cDesign of higher valency in covalent organic frameworks\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002DOI:\u00a010.1126\/science.abd6406.<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/science.sciencemag.org\/content\/370\/6515\/eabd6406.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212405 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-15.png\" alt=\"\" width=\"560\" height=\"533\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-15.png 560w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/11\/\u56fe\u7247-15-300x286.png 300w\" sizes=\"(max-width: 560px) 100vw, 560px\" \/><\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u548c\u5171\u4ef7-\u6709\u673a\u6846\u67b6(COFs)\u7684\u7f51\u72b6\u5316\u5b66\u7814\u7a76\u8fdb\u5c55\u5c06\u91d1\u5c5e\u7edc\u5408\u7269\u548c\u6709\u673a\u5316\u5b66\u6269\u5c55\u5230\u65e0\u9650\u7684\u4e8c\u7ef4\u548c\u4e09\u7ef4\u5f62\u5f0f\u3002\u7531\u4e8eMOFs\u548cCOFs\u6750\u6599\u5177\u6709\u4e30\u5bcc\u7684\u5b54&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":212398,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-212397","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212397"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=212397"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212397\/revisions"}],"predecessor-version":[{"id":212406,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212397\/revisions\/212406"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/212398"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=212397"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=212397"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=212397"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}