{"id":212141,"date":"2020-10-31T06:30:29","date_gmt":"2020-10-30T22:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=212141"},"modified":"2020-10-30T22:17:48","modified_gmt":"2020-10-30T14:17:48","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e9%99%88%e5%bf%a0%e4%bc%9fchem-soc-rev-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e6%9c%80%e5%85%a8%e7%9a%84%e9%94%82%e7%94%b5%e5%a4%8d%e5%90%88%e5%9b%ba%e6%80%81%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=212141","title":{"rendered":"\u9648\u5fe0\u4f1fChem.Soc.Rev.\u7efc\u8ff0\uff1a\u6700\u5168\u7684\u9502\u7535\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u603b\u7ed3"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u5168\u56fa\u6001\u9502\u7535\u6c60\uff08all-solid-state lithium batteries, ASSLBs\uff09\u7531\u4e8e\u5176\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7b49\u4f18\u52bf\u88ab\u8ba4\u4e3a\u662f\u6781\u5177\u53d1\u5c55\u524d\u666f\u7684\u5173\u952e\u50a8\u80fd\u6280\u672f\u3002\u4f5c\u4e3a\u5168\u56fa\u6001\u9502\u7535\u7684\u6838\u5fc3\u90e8\u4ef6\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u7684\u53d1\u5c55\u53d7\u5230\u79d1\u7814\u754c\u548c\u5de5\u4e1a\u754c\u7684\u6781\u5927\u5173\u6ce8\u3002\u76ee\u524d\u7684\u56fa\u6001\u7535\u89e3\u8d28\u4e3b\u8981\u5206\u4e3a\u4e24\u7c7b\uff0c\u5305\u62ec\u4ee5\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u7b49\u4e3a\u4ee3\u8868\u7684\u7684\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u548c\u4ee5\u805a\u6c27\u5316\u4e59\u70ef\uff08PEO\uff09\u7b49\u805a\u5408\u7269\u4e3a\u4ee3\u8868\u7684\u6709\u673a\u56fa\u6001\u7535\u89e3\u8d28\u3002\u8003\u8651\u5230\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u5728\u7ed3\u5408\u4e24\u8005\u4f18\u52bf\u65b9\u9762\u6781\u5177\u53d1\u5c55\u6f5c\u529b\uff0c\u8fd1\u5e74\u6765\u4eba\u4eec\u5bf9\u5176\u8fdb\u884c\u4e86\u5927\u91cf\u7814\u7a76\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u6ed1\u94c1\u5362\u5927\u5b66\u7684<strong><b>\u9648\u5fe0\u4f1f\u6559\u6388<\/b><\/strong>\u7cfb\u7edf\u603b\u7ed3\u5e76\u8be6\u5c3d\u5206\u6790\u4e86\u9502\u7535\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff08composite solid-state electrolytes, CSSEs\uff09\u7684\u57fa\u672c\u60c5\u51b5\uff0c\u5305\u62ec\u65e9\u671f\u53d1\u5c55\u7b80\u53f2\u6982\u8ff0\uff0c\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u7b49\u57fa\u7840\u4ecb\u7ecd\uff0c\u4ee5\u53caCSSEs\u7684\u5173\u952e\u6750\u6599\u3001\u5148\u8fdb\u7ed3\u6784\u3001\u539f\u4f4d\u6d4b\u8bd5\u65b9\u6cd5\u3001\u4eba\u5de5\u667a\u80fd\/\u673a\u5668\u5b66\u4e60\u7b49\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u5176\u4e2d\u4f5c\u8005\u9996\u6b21\u5c06\u6709\u673a\/\u65e0\u673aCSSEs\u7684\u6750\u6599\u4e0e\u7ed3\u6784\u7cfb\u7edf\u603b\u7ed3\u4e3a\u56db\u5927\u7c7b\uff0c\u5305\u62ec\u65e0\u673a\u6750\u6599\u586b\u5145\uff0c\u5c42\u72b6\u7ed3\u6784\uff0c\u4e09\u7ef4\u8fde\u7eed\u7ed3\u6784\uff0c\u548c\u5f00\u653e\u9aa8\u67b6\u7ed3\u6784\uff0c\u5bf9\u5176\u4e2d\u6d89\u53ca\u7684\u7ed3\u6784\u8bbe\u8ba1\u7b56\u7565\u548c\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u5206\u6790\u3002\u6700\u540e\uff0c\u4f5c\u8005\u603b\u7ed3\u5e76\u63d0\u51fa\u4e86CSSEs\u9762\u4e34\u7684\u4e3b\u8981\u6311\u6218\u548c\u672a\u6765\u53d1\u5c55\u65b9\u5411\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<strong><b>A review of composite solid-state electrolytes for lithium batteries: fundamentals,<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>key materials and advanced structures<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u8457\u540d\u671f\u520a<strong><em><b><i>Chemical Society Reviews<\/i><\/b><\/em><\/strong>\u4e0a\uff0c\u8be5\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u662f\u6ed1\u94c1\u5362\u5927\u5b66\u535a\u58eb\u540e<strong><b>\u90d1\u4e91<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212183\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u72472-2.png\" alt=\"\" width=\"600\" height=\"393\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u72472-2.png 1269w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u72472-2-300x196.png 300w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u72472-2-768x503.png 768w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u72472-2-1024x671.png 1024w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u7efc\u8ff0\u5bfc\u89c8\u56fe\uff08\u6587\u7ae0\u63d0\u7eb2\uff09<\/b><\/strong><\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong>\u4e00\u3001\u57fa\u672c\u4ecb\u7ecd<\/strong><\/p>\n<p>\u5168\u56fa\u6001\u9502\u7535\u6c60\u7684\u57fa\u672c\u539f\u7406\u548c\u4e3b\u8981\u7ed3\u6784\u5982\u56fe1\u6240\u793a\uff0c\u4e3b\u8981\u7531\u4ee5\u91d1\u5c5e\u9502\u4e3a\u4ee3\u8868\u7684\u8d1f\u6781\uff0c\u4ee5LFP\uff08LiFePO<sub>4<\/sub>\uff09\u3001NMC\uff08LiNi<sub>x<\/sub>Mn<sub>y<\/sub>Co<sub>(1-x-y)<\/sub>O<sub>2<\/sub>\uff09\u7b49\u6750\u6599\u4e3a\u4ee3\u8868\u7684\u7684\u6b63\u6781\uff0c\u548c\u56fa\u6001\u7535\u89e3\u8d28\u6784\u6210\u3002\u56fa\u6001\u7535\u89e3\u8d28\u5bf9\u5e94\u6027\u80fd\u7684\u5173\u952e\u8bc4\u4ef7\u6307\u6807\u4e3b\u8981\u5305\u62ec\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u9502\u79bb\u5b50\u8fc1\u79fb\u6570\u3001\u673a\u68b0\u6027\u80fd\u3001\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u7535\u6c60\u6d4b\u8bd5\u6027\u80fd\u7b49\u3002\u4e3b\u8981\u7684\u5355\u76f8\u6750\u6599\u5305\u62ec\u9499\u949b\u77ff\u578b\u3001\u77f3\u69b4\u77f3\u578b\u3001NASICON\u578b\u3001LISICON\u578b\u3001\u786b\u5316\u7269\u7c7b\u3001\u548c\u805a\u5408\u7269\u7c7b\u3002\u5bf9\u5e94\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u4e3b\u8981\u6d89\u53ca\u5230\u7a7a\u4f4d\u673a\u7406\u3001\u95f4\u9699\u673a\u7406\uff0c\u6216\u81ea\u7531\u4f53\u79ef\u6a21\u578b\u7b49\u3002<\/p>\n<p>\u672c\u6587\u4e3b\u8981\u805a\u7126\u4e8e\u6709\u673a\/\u65e0\u673a\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u4ece\u7ed3\u5408\u65b9\u5f0f\u4e0a\u6765\u770b\uff0c\u5982\u56fe\u6240\u793a\u53ef\u4ee5\u5927\u81f4\u5206\u4e3a\u4e09\u7c7b\uff0c\u5411\u6709\u673a\u56fa\u6001\u4e2d\u586b\u5145\u65e0\u673a\u6210\u5206\uff08Inorganic fillers in the polymer matrix\uff09\uff0c\u6709\u673a\/\u65e0\u673a\u53cc\u5c42\u6216\u591a\u5c42\u7ed3\u6784\uff08Heterogeneous layered structure\uff09\uff0c\u5411\u4e09\u7ef4\u8fde\u7eed\u65e0\u673a\u7ed3\u6784\u4e2d\u586b\u5145\u6709\u673a\u6210\u5206\uff083D inorganic continuous framework with filled polymer\uff09\uff1b\u5176\u4e2dMOFs\uff0cCOFs\u548cPOCs\u7b49\u5f00\u653e\u9aa8\u67b6\u7ed3\u6784\u6750\u6599\u76f8\u5173\u7684\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff08Open-framework-related composite electrolytes\uff09\u5728\u7ed3\u5408\u65b9\u5f0f\u4e0a\u4e3b\u8981\u5c5e\u4e8e\u7b2c\u4e00\u7c7b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-212148 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-4-16.png\" alt=\"\" width=\"600\" height=\"418\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-4-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-4-16-300x209.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>1<\/b><\/strong><strong><b>.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u9502\u7535\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u4e09\u79cd\u5178\u578b\u7ed3\u5408\u65b9\u5f0f<\/b><\/strong><\/p>\n<p><strong>\u4e8c\u3001\u6750\u6599\u4e0e\u7ed3\u6784<\/strong><\/p>\n<p>\u7b2c\u4e00\u7c7b\u7ed3\u5408\u65b9\u5f0f\u6240\u6d89\u53ca\u7684\u65e0\u673a\u6750\u6599\u4e3b\u8981\u4e3a\u60f0\u6027\u7684\u91d1\u5c5e\u6c27\u5316\u7269\/\u975e\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u6d3b\u6027\u7684\u51e0\u7c7b\u5355\u76f8\u65e0\u673a\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599\uff0c\u5176\u4e2d\u60f0\u6027\u4e0e\u6d3b\u6027\u7684\u5224\u65ad\u4f9d\u636e\u4e3a\u662f\u5426\u80fd\u6709\u6548\u4f20\u5bfc\u9502\u79bb\u5b50\uff1b\u6709\u673a\u90e8\u5206\u5219\u4e3b\u8981\u662f\u4ee5PEO\u4e3a\u4ee3\u8868\u7684\u805a\u5408\u7269\uff08\u542b\u6709\u9502\u76d0\uff09\u3002\u6839\u636e\u586b\u5145\u6750\u6599\u7279\u5f81\u7684\u4e0d\u540c\uff0c\u6587\u7ae0\u5c06\u5176\u603b\u7ed3\u4e3a0D\uff0c1D\u548c2D\uff0c\u5206\u522b\u5bf9\u5e94\u7eb3\u7c73\u9897\u7c92\uff0c\u7eb3\u7c73\u7ebf\/\u68d2\uff0c\u548c\u4e8c\u7ef4\u7247\u72b6\u6750\u6599\u3002\u6240\u5f97\u5230CSSEs\u7684\u5ba4\u6e29\u4e0b\u79bb\u5b50\u7535\u5bfc\u7387\uff0810<sup>&#8211;<\/sup><sup>6<\/sup>-10<sup>&#8211;<\/sup><sup>3<\/sup>\u00a0S\u00a0cm<sup>-1<\/sup>\uff09\u76f8\u5bf9\u5355\u76f8\u6750\u6599\u53ef\u4ee5\u63d0\u9ad8\u51e0\u500d\u5230\u4e00\u767e\u591a\u500d\u4e0d\u7b49\uff1b\u5176\u4e2d\u60f0\u6027\uff08TiO<sub>2<\/sub>, SiO<sub>2<\/sub>, ZrO<sub>2<\/sub>, BaTiO<sub>3<\/sub>, SrBi<sub>4<\/sub>Ti<sub>4<\/sub>O<sub>15<\/sub>, CNT, MMT, LDH, etc.\uff09\u6216\u6d3b\u6027\u65e0\u673a\u7269\uff08LLZO, LLTO, LATP, etc.\uff09\u586b\u5145\u5728\u6027\u80fd\u63d0\u5347\u673a\u7406\u4e0a\u6709\u6240\u4e0d\u540c\uff0c\u6587\u7ae0\u5bf9\u6b64\u8fdb\u884c\u4e86\u8be6\u7ec6\u5206\u6790\u3002\u56fe2\u548c\u56fe3\u4e3a\u90e8\u5206\u7814\u7a76\u793a\u4f8b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212145 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-19.png\" alt=\"\" width=\"600\" height=\"431\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-19.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-19-300x216.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe2<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u96f6\u7ef4\uff080D\uff09\u65e0\u673a\u60f0\u6027\u6750\u6599\u586b\u5145\u4e8e\u805a\u5408\u7269\u4e2d\u5f62\u6210\u7684\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212146 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-2-16.png\" alt=\"\" width=\"600\" height=\"371\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-2-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-2-16-300x186.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>3. <\/b><\/strong><strong><b>\u4e00\u7ef4\uff08<\/b><\/strong><strong><b>1<\/b><\/strong><strong><b>D\uff09\u65e0\u673a\u60f0\u6027\u6750\u6599\u586b\u5145\u4e8e\u805a\u5408\u7269\u4e2d\u5f62\u6210\u7684\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n<p>\u7b2c\u4e8c\u7c7b\u7ed3\u5408\u65b9\u5f0f\u4e3a\u975e\u5747\u76f8\u6709\u673a\/\u65e0\u673a\u5c42\u72b6\uff0c\u4e3b\u8981\u5305\u62ec\u53cc\u5c42\uff08Double-layered architecture\uff09\u3001\u5bf9\u79f0\u4e09\u5c42\uff08Symmetrical sandwiched architecture\uff09\u548c\u975e\u5bf9\u79f0\u4e09\u5c42\uff08Asymmetric sandwiched architecture\uff09\u3002\u5176\u4e2dPEO\u3001PEGDA\u3001PAN\u3001PMA\u7b49\u6709\u673a\u5c42\u53ef\u4ee5\u660e\u663e\u63d0\u9ad8\u65e0\u673a\u5c42\u4e0e\u7535\u6781\u4e4b\u95f4\u7684\u63a5\u89e6\uff0c\u751a\u81f3\u53ef\u4ee5\u63d0\u9ad8\u7535\u89e3\u8d28\u7684\u8010\u6c27\u5316\u6216\u8010\u8fd8\u539f\u6027\u80fd\u4ee5\u589e\u5f3a\u7535\u6c60\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff1b\u800c\u5176\u4e2d\u7684LAGP\u3001LLZO\u7b49\u65e0\u673a\u5c42\u5219\u53ef\u4ee5\u63d0\u9ad8\u590d\u5408\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u548c\u673a\u68b0\u5f3a\u5ea6\u7b49\u91cd\u8981\u6027\u80fd\u3002\u5c11\u6570\u6848\u4f8b\u5982\u56fe4\u6240\u793a\uff0c\u66f4\u591a\u76f8\u5173\u5185\u5bb9\u8be6\u89c1\u6587\u7ae0\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212153 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-18-3.png\" alt=\"\" width=\"600\" height=\"470\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-18-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-18-3-300x235.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe4<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u53cc\u5c42\u6216\u4e09\u5c42\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n<p>\u7b2c\u4e09\u7c7b\u7ed3\u5408\u65b9\u5f0f\u4e3a\u5411\u65e0\u673a\u4e09\u7ef4\u8fde\u7eed\u7ed3\u6784\u4e2d\u586b\u5145\u6709\u673a\u6210\u5206\u3002\u6839\u636e\u65e0\u673a\u4e09\u7ef4\u8fde\u7eed\u7ed3\u6784\u7684\u7279\u70b9\u4e0d\u540c\uff0c\u672c\u6587\u5c06\u5176\u5927\u6982\u5206\u4e3a\u4e09\u79cd\u7c7b\u578b\uff1a\uff081\uff09\u4e09\u7ef4\u7ea4\u7ef4\u7f51\u7edc\uff083D interconnected fiber network\uff09\uff0c\uff082\uff09\u4e09\u7ef4\u8fde\u7eed\u9aa8\u67b6\uff083D continuous framework\uff09\uff0c\u548c\uff083\uff09\u4e09\u7ef4\u7ebf\u6027\u7ed3\u6784\uff08Vertically aligned 3D framework\uff09\uff0c\u5177\u4f53\u7ed3\u6784\u7279\u70b9\u5982\u56fe5\u548c\u56fe6\u6240\u793a\u3002\u4e0e\u7b2c\u4e00\u7c7b\u76840D\u52302D\u65e0\u673a\u6750\u6599\u4e0e\u6709\u673a\u805a\u5408\u7269\u7684\u6df7\u5408\u4e0d\u540c\uff0c\u4e09\u7ef4\u8fde\u7eed\u7ed3\u6784\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u751a\u81f3\u907f\u514d\u65e0\u673a\u9502\u79bb\u5b50\u5bfc\u4f53\u9897\u7c92\u4e4b\u95f4\u7684\u754c\u9762\u7535\u963b\uff0c\u4ece\u800c\u63d0\u9ad8\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u80fd\u529b\u3002\u76f8\u5bf9\u4e8e\u524d\u4e24\u79cd\u4e09\u7ef4\u8fde\u7eed\u7ed3\u6784\uff0c\u7b2c\uff083\uff09\u79cd\u7ed3\u6784\u80fd\u591f\u8fdb\u4e00\u6b65\u4f18\u5316\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u8def\u5f84\u3001\u907f\u514d\u9502\u79bb\u5b50\u201c\u8d70\u5f2f\u8def\u201d\u3002\u8be6\u7ec6\u7684\u6848\u4f8b\u5206\u6790\u548c\u673a\u7406\u4ecb\u7ecd\u5728\u539f\u6587\u4e2d\u5747\u6709\u6d89\u53ca\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212155 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-20-1.png\" alt=\"\" width=\"600\" height=\"429\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-20-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-20-1-300x215.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>5.\u00a0<\/b><\/strong><strong><b>\u542b\u6709\u4e09\u7ef4\u7ea4\u7ef4\u7f51\u7edc\u548c\u4e09\u7ef4\u8fde\u7eed\u9aa8\u67b6\u7684\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212156 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-21-1.png\" alt=\"\" width=\"600\" height=\"416\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-21-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-21-1-300x208.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>6. <\/b><\/strong><strong><b>\u542b\u6709\u4e09\u7ef4\u7ebf\u6027\u8fde\u7eed\u7ed3\u6784\u7684\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28<\/b><\/strong><\/p>\n<p>\u6700\u540e\u4e00\u4e2a\u5206\u7c7b\u6d89\u53ca\u4e09\u79cd\u6700\u8fd1\u975e\u5e38\u70ed\u95e8\u7684\u5f00\u653e\u9aa8\u67b6\u7ed3\u6784\u6750\u6599\uff0c\u8be5\u7c7b\u591a\u5b54\u6750\u6599\u5177\u6709\u5b54\u9699\u7387\u9ad8\uff08\uff1e90%\uff09\u3001\u5185\u8868\u9762\u79ef\u5927\uff086000 m<sup>2<\/sup>\u00a0g<sup>\u22121<\/sup>\uff09\u3001\u53ef\u8bbe\u8ba1\u6027\u3001\u5b54\u9053\u5c3a\u5bf8\u53ef\u8c03\u8282\u6027\u3001\u5b54\u9053\u8868\u9762\u6613\u529f\u80fd\u5316\u7b49\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u7814\u7a76\u5e94\u7528\u4e8e\u836f\u7269\u8f93\u9001\u3001\u6c14\u4f53\u5206\u79bb\u3001\u80fd\u91cf\u8f6c\u5316\u7b49\u9886\u57df\u3002\u8003\u8651\u5176\u4e00\u5b9a\u7684\u7279\u6b8a\u6027\uff0c\u672c\u6587\u5c06\u8be5\u7c7b\u6750\u6599\u76f8\u5173\u7684\u56fa\u6001\/\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u4e13\u95e8\u4f5c\u4e3a\u4e00\u8282\u8fdb\u884c\u603b\u7ed3\u5206\u6790\uff0c\u5177\u4f53\u5305\u62ecMOFs\uff08Metal\u2013organic frameworks\uff0c\u56fe7\uff09\u3001COFs\uff08Covalent organic frameworks\uff0c\u56fe8\uff09\u548cPOCs\uff08Porous organic cages\uff0c\u56fe9\uff09\u76f8\u5173\u7684\u56fa\u6001\u7535\u89e3\u8d28\u3002\u7814\u7a76\u8868\u660e\uff0c\u8be5\u7c7b\u6750\u6599\u7684\u6dfb\u52a0\u6709\u5229\u4e8e\u56fa\u6001\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u4e00\u5230\u4e24\u4e2a\u6570\u91cf\u7ea7\u7684\u63d0\u5347\u3002\u8be6\u7ec6\u7684\u6027\u80fd\u5bf9\u6bd4\u548c\u4f18\u5316\u673a\u7406\u5206\u6790\u5728\u539f\u6587\u4e2d\u4e5f\u8fdb\u884c\u4e86\u4e13\u95e8\u603b\u7ed3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212154 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-19-3.png\" alt=\"\" width=\"600\" height=\"355\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-19-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-19-3-300x178.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe7.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>MOF<\/b><\/strong><strong><b>s<\/b><\/strong><strong><b>\u76f8\u5173\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u76f8\u5173\u7814\u7a76<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212149 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-5-12.png\" alt=\"\" width=\"600\" height=\"278\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-5-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-5-12-300x139.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe8.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>COF<\/b><\/strong><strong><b>s<\/b><\/strong><strong><b>\u76f8\u5173\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u76f8\u5173\u7814\u7a76<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212150 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-7-10.png\" alt=\"\" width=\"600\" height=\"412\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-7-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-7-10-300x206.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe9.\u00a0POCs\u76f8\u5173\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u76f8\u5173\u7814\u7a76<\/strong><\/p>\n<p><strong>\u4e09\u3001\u5148\u8fdb\u65b0\u5174\u6280\u672f<\/strong><\/p>\n<p>\u672c\u6587\u8fd8\u603b\u7ed3\u4e86\u4e13\u95e8\u9488\u5bf9\u4e8e\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5148\u8fdb\u65b0\u5174\u6280\u672f\uff0c\u5177\u4f53\u5305\u62ec\uff081\uff09\u9488\u5bf9\u6027\u7684\u539f\u4f4d\u8868\u5f81\u6280\u672f\uff0c\uff082\uff09\u65b0\u5174\u7684\u6a21\u62df\u6280\u672f\uff0c\u548c\uff083\uff09\u975e\u5e38\u70ed\u95e8\u7684\u4eba\u5de5\u667a\u80fd\/\u673a\u5668\u5b66\u4e60\u5728\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u65b9\u9762\u7684\u7814\u7a76\u5e94\u7528\u3002<\/p>\n<p>\u5176\u4e2d<em><i>I<\/i><\/em><em><i>n situ<\/i><\/em>\u00a0NDP\u3001solid-state NMR\u3001<em><i>operando<\/i><\/em>\u00a0XTM\u7b49\u8868\u5f81\u65b9\u6cd5\u5bf9\u56fa\u6001\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u3001\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u3001\u9502\u679d\u6676\u7b49\u95ee\u9898\u7684\u7814\u7a76\u5177\u6709\u72ec\u7279\u4f18\u52bf\u3002\u65b0\u5174\u7684\u6a21\u62df\u6280\u672f\u4ece\u5934\u8ba1\u7b97\u5206\u5b50\u6a21\u62df\uff08AIMD\uff0c\u56fe10\uff09\u6bd4\u4f20\u7edf\u7684DFT\u548cMD\u66f4\u9002\u5408\u63a2\u7a76\u9502\u79bb\u5b50\u5728\u56fa\u6001\u6750\u6599\u4e2d\u7684\u4f20\u8f93\u8def\u5f84\uff0c\u8fdb\u800c\u4f18\u5316\u6750\u6599\u7b5b\u9009\u548c\u8bbe\u8ba1\u3002<\/p>\n<p>\u4f5c\u4e3a\u4eba\u5de5\u667a\u80fd\uff08AI\uff09\u7684\u91cd\u8981\u5206\u652f\uff0c\u673a\u5668\u5b66\u4e60\uff08ML\uff09\u76ee\u524d\u5728\u56fa\u6001\/\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u65b9\u9762\u7684\u5e94\u7528\u4e3b\u8981\u5305\u62ec\u6750\u6599\u7b5b\u9009\u3001\u7ed3\u6784\u6027\u80fd\u63a2\u7a76\u3001\u79bb\u5b50\u4f20\u8f93\u673a\u7406\u63a2\u7a76\uff0c\u4ee5\u53ca\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6784\u6210\u4f18\u5316\u7b49\u56db\u4e2a\u65b9\u9762\u3002\u5177\u4f53\u6848\u4f8b\u5982\u56fe11\u6240\u793a\uff0c\u8be6\u7ec6\u603b\u7ed3\u548c\u5206\u6790\u89c1\u539f\u6587\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212152 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-4.png\" alt=\"\" width=\"531\" height=\"481\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-4.png 531w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-4-300x272.png 300w\" sizes=\"(max-width: 531px) 100vw, 531px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>10. <\/b><\/strong><strong><b>\u4ece\u5934\u8ba1\u7b97\u5206\u5b50\u6a21\u62df\uff08A<\/b><\/strong><strong><b>I<\/b><\/strong><strong><b>MD\uff09\u5728\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-212151 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-12-5.png\" alt=\"\" width=\"600\" height=\"386\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-12-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-12-5-300x193.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong><b>\u56fe<\/b><\/strong><strong><b>11. <\/b><\/strong><strong><b>\u4eba\u5de5\u667a\u80fd\/\u673a\u5668\u5b66\u4e60\uff08AI<\/b><\/strong><strong><b>\/ML<\/b><\/strong><strong><b>\uff09\u5728\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u7684\u5e94\u7528<\/b><\/strong><\/p>\n<p><strong><b>\u3010\u5c0f\u7ed3\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n<p>\u672c\u6587\u4ece\u53d1\u5c55\u7b80\u53f2\u3001\u57fa\u7840\u4ecb\u7ecd\u3001\u6750\u6599\u4e0e\u7ed3\u6784\u3001\u5148\u8fdb\u65b0\u5174\u6280\u672f\u7b49\u56db\u4e2a\u65b9\u9762\u5bf9\u9502\u7535\u590d\u5408\u56fa\u6001\u7535\u89e3\u8d28\uff08CSSEs\uff09\u7684\u76f8\u5173\u7814\u7a76\u8fdb\u884c\u4e86\u7cfb\u7edf\u5168\u9762\u7684\u603b\u7ed3\u548c\u5206\u6790\u3002\u5c24\u5176\u5bf9CSSEs\u7684\u5173\u952e\u6750\u6599\u548c\u5148\u8fdb\u7ed3\u6784\u4ece\u56db\u4e2a\u65b9\u9762\u8fdb\u884c\u4e86\u7cfb\u7edf\u5206\u7c7b\u548c\u8be6\u7ec6\u6982\u8ff0\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u672c\u6587\u8fd8\u63d0\u51fa\u4e86\u8be5\u9886\u57df\u76ee\u524d\u5b58\u5728\u7684\u4e3b\u8981\u6311\u6218\u8fdb\u884c\u4e86\u603b\u7ed3\uff0c\u5e76\u9488\u5bf9\u6027\u5730\u63d0\u51fa\u4e86\u56db\u4e2a\u65b9\u9762\u7684\u5e94\u5bf9\u7b56\u7565\uff1a\uff081\uff09CSSEs\u4e2d\u9502\u79bb\u5b50\u4f20\u5bfc\u673a\u7406\u548c\u6750\u6599\u884c\u4e3a\u7684\u6df1\u5165\u7814\u7a76\uff1b\uff082\uff09\u5f00\u53d1\u65b0\u6750\u6599\/\u4f18\u5316\u7ed3\u6784\u4ee5\u63d0\u9ad8CSSEs\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff1b\uff083\uff09\u4f18\u5316\u63d0\u5347\u9ad8\u7535\u538b\u3001\u5bbd\u6e29\u5ea6\u8303\u56f4\u4e0bCSSEs\u7684\u7a33\u5b9a\u6027\uff1b\uff084\uff09\u63d0\u9ad8\u542bCSSEs\u5168\u56fa\u6001\u9502\u7535\u7684\u6280\u672f\u6210\u719f\u5ea6\u548c\u7ecf\u6d4e\u53ef\u884c\u6027\u4ee5\u4fc3\u8fdb\u5176\u8fdb\u4e00\u6b65\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a\u201cYun\u00a0Zheng <em>et al.<\/em>, <strong><b>A review of composite solid-state electrolytes for lithium batteries: fundamentals, key materials and advanced structures<\/b><\/strong>\u201d (<strong><em><b><i>Chemical Society Reviews<\/i><\/b><\/em><\/strong>,\u00a02020, 473, 228607, <a href=\"https:\/\/doi.org\/10.1039\/D0CS00305K\"><u>https:\/\/doi.org\/10.1039\/D0CS00305K<\/u><\/a>).<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u8bfe\u9898\u7ec4\u4ecb\u7ecd<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u9648\u5fe0\u4f1f<\/b><\/strong>\uff0c\u52a0\u62ff\u5927\u6ed1\u94c1\u5362\u5927\u5b66(University of Waterloo)\u5316\u5b66\u5de5\u7a0b\u7cfb\u6559\u6388\uff0c\u52a0\u62ff\u5927\u7687\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u5de5\u7a0b\u9662\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u56fd\u5bb6\u9996\u5e2d\u79d1\u5b66\u5bb6(CRC-Tier 1)\uff0c\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u9662\u526f\u4e3b\u5e2d\uff0c\u6ed1\u94c1\u5362\u5927\u5b66\u7535\u5316\u5b66\u80fd\u6e90\u4e2d\u5fc3\u4e3b\u4efb\uff0c\u62c5\u4efbACS Applied &amp; Material Interfaces\u526f\u4e3b\u7f16\u3002\u9648\u5fe0\u4f1f\u9662\u58eb\u5e26\u9886\u4e00\u652f\u7ea670\u4eba\u7684\u7814\u7a76\u56e2\u961f\u5e38\u5e74\u81f4\u529b\u4e8e\u5148\u8fdb\u6750\u6599\u548c\u7535\u6781\u7684\u53d1\u5c55\u7528\u4e8e\u53ef\u6301\u7eed\u80fd\u6e90\u4f53\u7cfb\u7684\u7814\u53d1\u548c\u4ea7\u4e1a\u5316\uff0c\u5305\u62ec\u71c3\u6599\u7535\u6c60\uff0c\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\uff0c\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u9502\u786b\u7535\u6c60\uff0c\u6db2\u6d41\u7535\u6c60\uff0c\u56fa\u6001\u7535\u6c60\uff0cCO<sub>2<\/sub>\u6355\u96c6\u548c\u8f6c\u5316\u7b49\u3002\u8fd1\u5e74\u6765\u5df2\u5728<em><i>Nature Energy, Nature Nanotechnology, Chemical Reviews, Chemical Society Reviews, Joule, Matter, Nature Communication, Journal of the American Chemical Society, Angewandte Chemie International Edition, Advanced Materials, Energy &amp; Environmental Science, ACS Nano<\/i><\/em>\u7b49\u56fd\u9645\u9876\u7ea7\u671f\u520a\u53d1\u8868\u8bba\u6587330\u4f59\u7bc7\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u6587\u7ae0\u5df2\u5f15\u7528\u6b21\u6570\u8fbe29000\u4f59\u6b21, H-index \u6307\u6570\u4e3a87\u3002<\/p>\n<p>\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<a href=\"http:\/\/chemeng.uwaterloo.ca\/zchen\/\"><u>http:\/\/chemeng.uwaterloo.ca\/zchen\/<\/u><\/a><\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u90d1\u4e91\u6295\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5168\u56fa\u6001\u9502\u7535\u6c60\uff08all-solid-state lithium batteries, ASSLBs\uff09\u7531\u4e8e\u5176\u9ad8\u5b89\u5168\u6027\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7b49\u4f18\u52bf\u88ab\u8ba4\u4e3a\u662f\u6781\u5177\u53d1\u5c55\u524d\u666f&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-212141","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212141"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=212141"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212141\/revisions"}],"predecessor-version":[{"id":212233,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/212141\/revisions\/212233"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=212141"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=212141"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=212141"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}