{"id":211305,"date":"2020-10-17T06:30:23","date_gmt":"2020-10-16T22:30:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=211305"},"modified":"2020-10-16T20:41:51","modified_gmt":"2020-10-16T12:41:51","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e5%8c%97%e5%a4%a7%e6%bd%98%e9%94%8b%e6%95%99%e6%8e%88nano-energy%e9%86%87%e7%b1%bb%e6%b7%bb%e5%8a%a0%e5%89%82%e8%b0%83%e6%8e%a7%e9%94%8c%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=211305","title":{"rendered":"\u5317\u5927\u6f58\u950b\u6559\u6388Nano Energy:\u9187\u7c7b\u6dfb\u52a0\u5242\u8c03\u63a7\u950c\u79bb\u5b50\u914d\u4f4d\u73af\u5883\u6291\u5236\u91d1\u5c5e\u8d1f\u6781\u679d\u6676\u751f\u957f"},"content":{"rendered":"<p><strong><b>\u3010\u524d\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5177\u6709\u672c\u5f81\u5b89\u5168\u6027\u3001\u73af\u5883\u53cb\u597d\u6027\u3001\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u8f83\u5f3a\u7684\u7ecf\u6d4e\u6027\uff0c\u662f\u9ad8\u6027\u80fd\u5927\u89c4\u6a21\u50a8\u80fd\u7528\u7535\u6c60\u7cfb\u7edf\u7684\u6709\u529b\u7ade\u4e89\u8005\uff0c\u53d7\u5230\u5b66\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u950c\u8d1f\u6781\u5b58\u5728\u950c\u679d\u6676\u3001\u526f\u53cd\u5e94\u7b49\u95ee\u9898\u3002\u7531\u4e8e\u950c\u79bb\u5b50\u4e0d\u5747\u5300\u6c89\u79ef\uff0c\u5bfc\u81f4\u5c40\u90e8\u679d\u6676\u8fc5\u901f\u751f\u957f\uff0c\u5230\u4e00\u5b9a\u5c3a\u5bf8\u53ef\u4ee5\u523a\u7a7f\u9694\u819c\u5f15\u53d1\u77ed\u8def\u5931\u6548\uff0c\u800c\u8131\u843d\u7684\u679d\u6676\u5c16\u7aef\uff08\u201c\u6b7b\u950c\u201d\uff09\u548c\u526f\u53cd\u5e94\u7b49\u5f15\u8d77\u5e93\u4f26\u6548\u7387\u4e0b\u964d\u3002\u8fd9\u4e9b\u95ee\u9898\u4e25\u91cd\u5236\u7ea6\u4e86\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u53d1\u5c55\u548c\u5e94\u7528\u3002\u901a\u8fc7\u7ecf\u6d4e\u3001\u9ad8\u6548\u7684\u624b\u6bb5\u6291\u5236\u950c\u679d\u6676\u548c\u526f\u53cd\u5e94\u3001\u63d0\u9ad8\u950c\u8d1f\u6781\u6027\u80fd\uff0c\u5438\u5f15\u4e86\u4f17\u591a\u79d1\u7814\u5de5\u4f5c\u8005\u7684\u5174\u8da3\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u671f\uff0c\u5317\u4eac\u5927\u5b66\u6df1\u5733\u7814\u7a76\u751f\u9662\u6f58\u950b\u6559\u6388\u56e2\u961f\u5728\u56fd\u9645\u8457\u540d\u79d1\u6280\u671f\u520aNano Energy\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cTuning Zn<sup>2+<\/sup>\u00a0coordination environment to suppress dendrite formation for high-performance Zn-ion batteries\u201d\u7684\u6587\u7ae0\u3002\u6587\u7ae0\u62a5\u9053\u4e86\u901a\u8fc7\u5728\u7535\u89e3\u6db2\u4e2d\u6dfb\u52a0\u9187\u7c7b\u6dfb\u52a0\u5242\u6765\u8c03\u63a7\u950c\u79bb\u5b50\u914d\u4f4d\u73af\u5883\uff0c\u8fdb\u800c\u6291\u5236\u950c\u679d\u6676\u53d1\u5c55\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u591a\u5143\u9187\u4e0e\u950c\u79bb\u5b50\u6709\u8f83\u597d\u7684\u914d\u4f4d\u80fd\u529b\uff0c\u6709\u5229\u4e8e\u950c\u679d\u6676\u63a7\u5236\u3002\u4ee5\u4e59\u4e8c\u9187\u4e3a\u4f8b\uff1a\u6dfb\u52a0\u4e59\u4e8c\u9187\u540e\uff0c\u6eb6\u5242\u5316\u950c\u79bb\u5b50[Zn(H<sub>2<\/sub>O)<sub>6<\/sub>]<sup>2+<\/sup>\u7ed3\u6784\u4e2d\u7684\u90e8\u5206\u6c34\u5206\u5b50\u88ab\u4e59\u4e8c\u9187\u5206\u5b50\u53d6\u4ee3\uff0c\u5f62\u6210[Zn(H<sub>2<\/sub>O)<sub>m<\/sub>(EG)<sub>n<\/sub>]<sup>2+<\/sup>\u7ed3\u6784\u3002\u8fd9\u79cd\u914d\u4f4d\u7ed3\u6784\u589e\u52a0\u4e86\u950c\u79bb\u5b50\u7684\u8131\u6eb6\u5242\u5316\u80fd\uff0c\u540c\u65f6\u5176\u8f83\u5927\u7684\u5c3a\u5bf8\u5177\u6709\u950c\u79bb\u5b50\u6269\u6563\u7684\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u3002\u5728\u9187\/\u6c34\u6df7\u5408\u7535\u89e3\u6db2\u4e2d\uff0c\u950c\u79bb\u5b50\u6c89\u79ef\u65f6\u6210\u6838\u8fc7\u7535\u4f4d\u63d0\u9ad8\uff0c\u6c89\u79ef\u4ea7\u7269\u6676\u7c92\u7ec6\u5316\uff0c\u679d\u6676\u751f\u957f\u8fc7\u7a0b\u5f97\u5230\u663e\u8457\u6291\u5236\uff0c\u950c\/\u950c\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u5bff\u547d\u6700\u9ad8\u53ef\u5ef6\u957f58\u500d\uff0c \u540c\u65f6\uff0cZn\/ZnVO\u5168\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u4e5f\u6709\u5f88\u5927\u63d0\u5347\u3002<\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p>\u56fe1.\u6dfb\u52a0\u4e0d\u540c\u542b\u91cf\u4e59\u4e8c\u9187\u540e\u950c\u8d1f\u6781\u5faa\u73af\u5bff\u547d\u548c\u5e93\u4f26\u6548\u7387<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-211308 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-1.png\" alt=\"\" width=\"600\" height=\"498\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-15-1-300x249.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><span style=\"line-height: 1.5;\">(a)\u4f4e\u7535\u6d41\u5bc6\u5ea6\u4e0bZn\/Zn\u5faa\u73af\u5bff\u547d\uff1b<\/span><\/p>\n<p>(b)\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0bZn\/Zn\u5faa\u73af\u5bff\u547d\uff1b<\/p>\n<p>(c) Zn\/Zn\u5faa\u73af\u5bff\u547d\u4e0e\u4e59\u4e8c\u9187\u6d53\u5ea6\u7684\u76f8\u5173\u6027\uff1b<\/p>\n<p>(d) Zn\/Zn\u6781\u5316\u4e0e\u4e59\u4e8c\u9187\u6d53\u5ea6\u7684\u76f8\u5173\u6027\uff1b<\/p>\n<p>(e)Zn\u5faa\u73af\u5e93\u4f26\u6548\u7387\u4e0e\u4e59\u4e8c\u9187\u6d53\u5ea6\u7684\u5173\u7cfb\u3002<\/p>\n<p>\u56fe2.\u6df7\u5408\u7535\u89e3\u6db2\u4e2d\u950c\u8d1f\u6781\u8868\u9762\u6c89\u79ef\u4ea7\u7269\u5f62\u8c8c\u7684\u6fc0\u5149\u5171\u805a\u7126\u7167\u7247<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-211306 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-4.png\" alt=\"\" width=\"600\" height=\"315\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-1-4-300x158.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u7a7a\u767d\u6eb6\u6db2\u4e2d\u6c89\u79ef1h\uff1b<\/p>\n<p>(b)\u6dfb\u52a010%\u4e59\u4e8c\u9187\u7684\u7535\u89e3\u6db2\u4e2d\u6c89\u79ef1h\uff1b<\/p>\n<p>(c) \u6dfb\u52a068%\u4e59\u4e8c\u9187\u7684\u7535\u89e3\u6db2\u4e2d\u6c89\u79ef1h\uff1b<\/p>\n<p>(d) \u7a7a\u767d\u6eb6\u6db2\u4e2d\u5faa\u73af40h\uff1b<\/p>\n<p>(e) \u6dfb\u52a010%\u4e59\u4e8c\u9187\u7535\u89e3\u6db2\u4e2d\u5faa\u73af200h\uff1b<\/p>\n<p>(f) \u6dfb\u52a068%\u4e59\u4e8c\u9187\u7535\u89e3\u6db2\u4e2d\u5faa\u73af200h\u3002<\/p>\n<p>\u56fe3.\u950c\u79bb\u5b50\u914d\u4f4d\u73af\u5883\u548c\u6df7\u5408\u7535\u89e3\u6db2\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-211309 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-16-1.png\" alt=\"\" width=\"600\" height=\"496\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-16-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-16-1-300x248.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u950c\u79bb\u5b50\u5265\u79bb\/\u6c89\u79ef\u793a\u610f\u56fe\uff1b<\/p>\n<p>(b)\u950c\u79bb\u5b50\u4e0d\u540c\u914d\u4f4d\u5f62\u5f0f\u548c\u7a7a\u95f4\u4f4d\u963b\u6548\u5e94\u793a\u610f\u56fe\uff1b<\/p>\n<p>(c) \u6df7\u5408\u7535\u89e3\u6db2\u7535\u5bfc\u7387\u53d8\u5316\uff1b<\/p>\n<p>(d)\u6df7\u5408\u7535\u89e3\u6db2CV\uff1b<\/p>\n<p>(e\u3001f) \u6df7\u5408\u7535\u89e3\u6db2FTIR\u7ed3\u679c\uff1b<\/p>\n<p>(g) \u6df7\u5408\u7535\u89e3\u6db2HER\u6027\u80fd\u3002<\/p>\n<p>\u56fe4.\u6df7\u5408\u7535\u89e3\u6db2\u7684\u5168\u7535\u6c60\u6027\u80fd\u548c\u4f4e\u6e29\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-211307 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-14-1.png\" alt=\"\" width=\"600\" height=\"490\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-14-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/10\/\u56fe\u7247-14-1-300x245.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>(a)\u6df7\u5408\u7535\u89e3\u6db2\u4e2dZn\/ZnVO\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n<p>(b)\u5168\u7535\u6c60\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n<p>(c) \u5168\u7535\u6c60\u500d\u7387\u6027\u80fd\uff1b<\/p>\n<p>(d)\u6df7\u5408\u7535\u89e3\u6db2\u4e2dZn\/Zn\u4f4e\u6e29\u6027\u80fd\uff1b<\/p>\n<p><strong><b>\u7ed3\u8bba<\/b><\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u901a\u8fc7\u5728\u6c34\u6eb6\u6db2\u4e2d\u6dfb\u52a0\u9187\u7c7b\u6dfb\u52a0\u5242\u8c03\u63a7\u950c\u79bb\u5b50\u7684\u914d\u4f4d\u73af\u5883\uff0c\u8fbe\u5230\u6291\u5236\u950c\u679d\u6676\u751f\u957f\u7684\u76ee\u7684\u3002\u9187\/\u6c34\u6df7\u5408\u6eb6\u6db2\u4e2d\uff0c\u5f62\u6210\u4e86\u950c\u79bb\u5b50\u4e0e\u6c34\u5206\u5b50\/\u9187\u5206\u5b50\u5171\u914d\u4f4d\u7684\u7ed3\u6784\uff0c\u589e\u5927\u4e86\u6210\u6838\u8fc7\u7535\u4f4d\uff0c\u7ec6\u5316\u4e86\u6c89\u79ef\u5f62\u8c8c\uff1b\u540c\u65f6\u964d\u4f4e\u4e86\u6c34\u7684\u6d3b\u5ea6\uff0c\u6291\u5236\u4e86\u526f\u53cd\u5e94\u3002\u5e94\u7528\u8fd9\u79cd\u8c03\u63a7\u7b56\u7565\uff0c\u6dfb\u52a0\u4e59\u4e8c\u9187\u7684\u6df7\u5408\u7535\u89e3\u6db2Zn\/Zn\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u5bff\u547d\u6700\u9ad8\u53ef\u8fbe2668h\uff0cZn\/ZnVO\u5168\u7535\u6c60\u5faa\u73af\u5bff\u547d\u548c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e5f\u6709\u5f88\u5927\u63d0\u5347\u3002\u540c\u65f6\uff0c\u9187\/\u6c34\u6df7\u5408\u7535\u89e3\u6db2\u5177\u6709\u6297\u7ed3\u51b0\u6027\u80fd\u548c\u963b\u71c3\u6027\u80fd\uff0c\u5177\u6709\u5f88\u9ad8\u7684\u5b9e\u7528\u6027\u3002\u8fd9\u79cd\u8c03\u63a7\u7b56\u7565\u4e3a\u6291\u5236\u950c\u679d\u6676\u751f\u957f\u63d0\u4f9b\u4e86\u6709\u6548\u89e3\u51b3\u65b9\u6848\uff0c\u6709\u52a9\u4e8e\u6784\u5efa\u4f4e\u6210\u672c\u9ad8\u6027\u80fd\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u4f53\u7cfb\u3002<\/p>\n<p><strong><b>\u6587\u7ae0\u94fe\u63a5<\/b><\/strong><\/p>\n<p>Tuning Zn<sup>2+<\/sup>\u00a0coordination environment to suppress dendrite formation for high-performance Zn-ion batteries<\/p>\n<p><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285520310533\"><u>https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285520310533<\/u><\/a><\/p>\n<p><strong><b>\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong><\/p>\n<p>\u535a\u58eb\u540e\u79e6\u6da6\u4e4b\u3001\u535a\u58eb\u751f\u738b\u4e50\u6d9b\u3001\u5f20\u660e\u6b63\u662f\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p>\u674e\u821c\u5b81\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u5316\u5b66\u8fc7\u7a0b\u7684\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u6a21\u62df\u7814\u7a76\uff0c\u548c\u7535\u6c60\u6750\u6599\u4e0e\u50ac\u5316\u6750\u6599\u7684\u9ad8\u901a\u91cf\u8ba1\u7b97\u7b5b\u9009\u3002\u5728 Mater.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u658730\u4f59\u7bc7\u3002<\/p>\n<p>\u8d75\u5e86\u8d3a\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u50ac\u5316\u5242\u6750\u6599\u8bbe\u8ba1\u53ca\u6c34\u7cfb\u7535\u6c60\u5f00\u53d1\u76f8\u5173\u7684\u7814\u7a76\uff0c\u5728 Mater.\u3001Angew. Chem.\u3001Adv. Funct. 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