{"id":211063,"date":"2020-10-13T06:42:29","date_gmt":"2020-10-12T22:42:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=211063"},"modified":"2020-10-12T19:42:42","modified_gmt":"2020-10-12T11:42:42","slug":"%e5%8c%97%e5%a4%a7%e6%bd%98%e9%94%8bafm%ef%bc%9a%e7%b1%bb%e6%99%ae%e9%b2%81%e5%a3%ab%e8%93%9d%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%e5%9c%a8%e8%83%bd%e6%ba%90%e5%ad%98%e5%82%a8%e5%92%8c%e8%bd%ac","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=211063","title":{"rendered":"\u5317\u5927\u6f58\u950bAFM\uff1a\u7c7b\u666e\u9c81\u58eb\u84dd\u6846\u67b6\u6750\u6599\u5728\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u5316\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

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\"\" \u56fe1<\/b><\/strong>\u00a0PBAs\u6750\u6599\u5728\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u5316\u4e2d\u7684\u6311\u6218\u3001\u4f18\u5316\u7b56\u7565\u548c\u672a\u6765\u5c55\u671b<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

\u56fe4<\/b><\/strong>\u00a0<\/b><\/strong>\u5178\u578b\u78b1\u571f\u91d1\u5c5e\u79bb\u5b50\u5d4c\u5165\u673a\u5236\u3002\uff08a\uff09Zn2+<\/sup>\u5728CoHCF\u6846\u67b6\u7ed3\u6784\u4e2d\u53ef\u9006\u5d4c\u5165\/\u8131\u51fa\uff1b\uff08b\uff09\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u53ca\uff08c\uff09\u76f8\u5e94\u7684XRD\u53d8\u5316\u3002<\/p>\n

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\"\"<\/p>\n

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Goodenough\u7b49[5]<\/sup>\u62a5\u9053\u4e86\u901a\u8fc7\u964d\u4f4e\u7ed3\u6676\u6c34\u542b\u91cf\uff0c\u53ef\u6539\u53d8Na2\u2212\u03b4<\/sub>MnHCF\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u8fdb\u800c\u6539\u53d8\u4e86\u7535\u5316\u5b66\u66f2\u7ebf\u7279\u5f81\uff1bDou\u7b49[6]<\/sup>\u62a5\u9053\uff0c\u901a\u8fc7\u63d0\u9ad8Na1+x<\/sub>Fe[Fe(CN)6<\/sub>]\u4e2dNa+<\/sup>\u6d53\u5ea6\uff0c\u53ef\u6709\u6548\u964d\u4f4e\u6676\u4f53\u7f3a\u9677\uff0c\u5e76\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe6<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

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Hu\u7b49[9]<\/sup>\u62a5\u9053\uff0cFe\u63ba\u6742\u7684\u5bccMn\u7684Kx<\/sub>Fey<\/sub>Mn1\u2212y<\/sub>[Fe(CN)6<\/sub>]w<\/sub>\u00b7zH2<\/sub>O\u6b63\u6781\uff0c\u76f8\u6bd4\u65e0Fe\u63ba\u6742\u6b63\u6781\uff0c\u5bfc\u7535\u6027\u589e\u52a0\uff0cK+\u6269\u6563\u52bf\u5792\u964d\u4f4e\uff0c\u4e14\u7535\u5316\u5b66\u5faa\u73af\u66f4\u7a33\u5b9a\u3002\uff08\u56fe8<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

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Peng\u7b49[3]<\/sup>\u62a5\u9053\uff0c\u901a\u8fc7\u8c03\u63a7Nix<\/sub>Co1-x<\/sub>[Fe(CN)6<\/sub>]\u4e2dNi\/Co\u6bd4\u4f8b\uff0c\u53ef\u5b9e\u73b0\u4e0d\u540c\u7684\u7535\u6781\u53cd\u5e94\u3002\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u7684\u539f\u56e0\u5728\u4e8e\uff1a1\uff09\u5f15\u5165Ni\u964d\u4f4e\u5145\u653e\u7535\u8fc7\u7a0b\u6676\u80de\u53c2\u6570\u53d8\u5316\uff1b2\uff09\u63ba\u6742\u964d\u4f4e\u4e86\u7f3a\u9677\u542b\u91cf\u3002\uff08\u56fe9<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe9<\/b><\/strong>\u00a0<\/b><\/strong>Ni\/Co\u6bd4\u8c03\u63a7\u7535\u5316\u5b66\u6027\u80fd\u3002\uff08a\uff0cb\uff09Na0.79<\/sub>Ni[Fe(CN)6<\/sub>]0.74<\/sub>\u00a0(LQ-NiFe)\u3001Na0.86<\/sub>Co[Fe(CN)6<\/sub>]0.73<\/sub>\u00a0(LQ-CoFe)\u3001Na0.71<\/sub>Ni0.25<\/sub>Co0.75<\/sub>[Fe(CN)6<\/sub>]0.75<\/sub>\u00a0(LQ-NiCoFe)\u548cNa1.68 <\/sub>Ni0.14<\/sub>Co0.86<\/sub>[Fe(CN)6<\/sub>]0.84<\/sub>\u00a0(HQ-NiCoFe)\u6b63\u6781\u6750\u6599\u7684CV\u66f2\u7ebf\u548c\u500d\u7387\u6027\u80fd\uff1b\uff08c\uff09HQ-NiCoFe\u6b63\u6781\u539f\u4f4dXRD\u7ed3\u679c\u3002<\/p>\n

Li\u7b49[10]<\/sup>\u62a5\u9053\uff0cFe\u5728Na1.60<\/sub>Mn0.833<\/sub>Fe0.167<\/sub>[Fe(CN)6<\/sub>]\u4e2d\u63ba\u6742\uff0c\u53ef\u964d\u4f4eMn\u6eb6\u51fa\u548c\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u5e94\u529b\u00a0\uff0c\u63d0\u9ad8\u6676\u4f53\u70ed\u529b\u5b66\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u8868\u73b0\u51fa\u9ad8\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe10<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe10<\/b><\/strong>\u00a0Fe\u63ba\u6742\u5bf9\u5faa\u73af\u7a33\u5b9a\u6027\u5f71\u54cd\u673a\u5236\u3002\uff08a\uff0cb\uff09NiMnHCF\u548cNiMnFeHCF\u7684\u6676\u4f53\u7ed3\u6784\uff0c\uff08c\uff0cd\uff09\u53ca\u76f8\u5e94\u7684\u7ed3\u6784\u6f14\u53d8\u548c\uff08e\uff0cf\uff09\u5faa\u73af\u8fc7\u7a0b\u70ed\u529b\u5b66\u80fd\u91cf\u72b6\u6001\u7684\u53d8\u5316\u3002<\/p>\n

Hu\u7b49[11]<\/sup>\u6784\u7b51\u4e86\u68af\u5ea6NiMnHCF\u6750\u6599\uff08\u4ece\u5185\u5230\u5916Ni\u6d53\u5ea6\u9010\u6e10\u589e\u52a0\uff09\uff0c\u6709\u6548\u6291\u5236\u5faa\u73af\u8fc7\u7a0b\u6676\u4f53\u5185\u90e8\u7684\u7ed3\u6784\u5e94\u529b\u7d2f\u79ef\uff0c\u8fdb\u800c\u63d0\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe11<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe11<\/b><\/strong>\u00a0\u6784\u7b51\u68af\u5ea6\u6750\u6599\u83b7\u5f97\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08a\uff09g-NiMnHCF\u7684\u5408\u6210\u8fc7\u7a0b\uff0c\uff08b-d\uff09\u666e\u901aNiMnHCF\u548c\uff08e-f\uff09\u68af\u5ea6g-NiMnHCF\u5faa\u73af\u8fc7\u7a0b\u5e94\u529b\u5206\u5e03\u5bf9\u6bd4\u3002<\/p>\n

Yin\u7b49[12]<\/b><\/sup><\/strong>\u7814\u7a76\u4e86\u6838\u58f3\u7ed3\u6784\u7684CoNiHCF@NiHCF\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002TEM\u9a8c\u8bc1\u4e86CoNi-HCF\u8868\u9762\u7ea615 nm\u5de6\u53f3\u7684NiHCF\u5305\u8986\u5c42\uff0c\u8be5\u5305\u8986\u5c42\u6709\u6548\u964d\u4f4e\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u6676\u683c\u7d0a\u4e71\uff0c\u5e76\u6291\u5236\u526f\u53cd\u5e94\uff0c\u56e0\u6b64\u83b7\u5f97\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe12<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe12<\/b><\/strong>\u00a0CoNi-HCF@Ni-HCF\u6838\u58f3\u7ed3\u6784\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\uff08a\uff0cb\uff09\u5408\u6210\u8fc7\u7a0b\u53ca\u5fae\u89c2\u5f62\u8c8c\uff1b\uff08c-e\uff09\u7535\u5316\u5b66\u66f2\u7ebf\u53ca\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

Ren\u7b49[13]<\/sup>\u901a\u8fc7\u523b\u8680\u65b9\u6cd5\u83b7\u5f97\u7eb3\u7c73\u82b1\u72b6\u7ed3\u6784\u7684NiHCF-etch\uff0c\u8be5\u7279\u6b8a\u7ed3\u6784\u6781\u5927\u589e\u52a0\u7535\u6781\/\u7535\u89e3\u6db2\u6709\u6548\u63a5\u89e6\u9762\u79ef\uff0c\u4fc3\u8fdb\u79bb\u5b50\u4f20\u8f93\u52a8\u529b\u5b66\u3002\uff08\u56fe13<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe13<\/b><\/strong>\u00a0\u523b\u8680\u5904\u7406\u83b7\u5f97\u9ad8\u6bd4\u8868\u9762NiHCF-etch\u3002\uff08a\uff09\u5408\u6210\u53ca\u523b\u8680\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\uff08b-d\uff09NiHCF-etch\u4e0eNiHCF-cube\u4e24\u79cd\u6750\u6599CV\u66f2\u7ebf\u3001\u5145\u653e\u7535\u79bb\u5b50\u6269\u6563\u8fc7\u7a0b\u53ca\u6269\u6563\u7cfb\u6570\u5bf9\u6bd4\u3002<\/p>\n

Wei\u7b49[14]<\/sup>\u4ee5ZIF-67\u4e3a\u6a21\u677f\uff0c\u83b7\u5f97\u4e86\u4e2d\u7a7a\u7ed3\u6784\u7684CoHCF\uff0c\u6781\u5927\u589e\u52a0\u7535\u6781\/\u7535\u89e3\u6db2\u6709\u6548\u63a5\u89e6\u9762\u79ef\uff0c\u4fc3\u8fdb\u79bb\u5b50\u4f20\u8f93\u52a8\u529b\u5b66\uff0c\u500d\u7387\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u5747\u6709\u6240\u63d0\u9ad8\u3002\uff08\u56fe14<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe14<\/b><\/strong>\u00a0ZIF-67\u884d\u751f\u7684CoHCF\u4e2d\u7a7a\u7ed3\u6784\u5408\u6210\u53ca\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

Yang\u7b49[15]<\/sup>\u901a\u8fc7\u70ed\u5904\u7406\u5f97\u5230RGO\u548cFeHCF\u7684\u590d\u5408\u6750\u6599\uff0c\u5e76\u83b7\u5f97\u7ea67\u201310 \u03bcm\u7684\u4e8c\u6b21\u9897\u7c92\u3002\u8be5\u590d\u5408\u6750\u6599\u5177\u6709\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u3001\u4f4e\u7684\u7ed3\u6676\u6c34\u542b\u91cf\u53ca\u8f83\u5c11\u7684\u526f\u53cd\u5e94\uff0c\u56e0\u6b64\u8868\u73b0\u51fa\u9ad8\u500d\u7387\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe15<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe15<\/b><\/strong>\u00a0<\/b><\/strong>\u70ed\u5904\u7406\u5f97\u5230rGO\u4e0eFeHCF\u7684\u590d\u5408\u6750\u6599RGOPC\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u3002\uff08a\uff09\u70ed\u5904\u7406\u8fc7\u7a0b\uff0c\uff08b-e\uff09\u6240\u5f97PB\u548cRGOPC\u5fae\u89c2\u5f62\u8c8c\u548c\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

Tang\u7b49[16]<\/sup>\u5728FeHCF\u8868\u9762\u5305\u8986\u5bfc\u7535\u9ad8\u5206\u5b50PPy\uff0c\u7535\u5b50\u5bfc\u7535\u6027\u589e\u52a0\uff0c\u7535\u5316\u5b66\u53cd\u5e94\u6781\u5316\u964d\u4f4e\uff0c\u540c\u65f6\u526f\u53cd\u5e94\u7a0b\u5ea6\u964d\u4f4e\uff0c\u8fdb\u800c\u63d0\u9ad8\u500d\u7387\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe16<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe16<\/b><\/strong>\u00a0\u5bfc\u7535\u9ad8\u5206\u5b50PPy\u5305\u8986\u7684FeHCF\u3002\uff08a-c\uff09FeHCF\u5fae\u89c2\u5f62\u8c8c\u3001CV\u66f2\u7ebf\u53ca\u5faa\u73af\u540e\u5fae\u89c2\u5f62\u8c8c\uff1b\uff08d-f\uff09FeHCF@PPy\u5fae\u89c2\u5f62\u8c8c\u3001CV\u66f2\u7ebf\u53ca\u5faa\u73af\u540e\u5fae\u89c2\u5f62\u8c8c<\/p>\n

Lu\u7b49[17]<\/sup>\u5728ZnHCF\u8868\u9762\u5305\u8986MnO2<\/sub>\uff0c\u7528\u4f5c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\uff0c\u5176\u7535\u5316\u5b66\u884c\u4e3a\u517c\u5177MnO2<\/sub>\u7684\u7535\u5bb9\u7279\u5f81\uff0c\u548cZnHCF\u4e2dZn2+<\/sup>\u7684\u5d4c\u5165\/\u8131\u51fa\u884c\u4e3a\u7279\u5f81\u3002MnO2<\/sub>\u5305\u8986\u5c42\u8d77\u5230Zn2+<\/sup>\u7684\u6269\u6563\u7f13\u51b2\u5c42\u7684\u4f5c\u7528\uff0c\u8fdb\u800c\u63d0\u9ad8\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd\u3002\uff08\u56fe17<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe17<\/b><\/strong>\u00a0<\/b><\/strong>ZnHCF@MnO2<\/sub>\u4f5c\u4e3a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u3002\uff08a\uff0cb\uff09ZnHCF@MnO2<\/sub>\u5408\u6210\u65b9\u6cd5\u53ca\u5fae\u89c2\u5f62\u8c8c\uff0c\uff08c-e\uff09ZnHCF\u3001MnO2<\/sub>\u548cZnHCF@MnO2<\/sub>\u7535\u5316\u5b66\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

Zhang\u7b49[18]<\/sup>\u62a5\u9053\u4e86CNT\u94fe\u63a5\u7684CoHCF\u4f5c\u4e3aNa+<\/sup>\/Zn2+<\/sup>\u6df7\u5408\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u3002CNT\u8d77\u5230\u540c\u65f6\u63d0\u9ad8CoHCF\u672c\u5f81\u7535\u5bfc\u548c\u964d\u4f4eCoHCF\u9897\u7c92\u95f4\u963b\u6297\u7684\u4f5c\u7528\uff0c\u56e0\u6b64\u83b7\u5f97\u9ad8\u500d\u7387\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe18<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe18<\/b><\/strong>\u00a0<\/b><\/strong>CNT\u94fe\u63a5\u7684CoHCF\u6750\u6599\u7528\u4e8eNa+<\/sup>\/Zn2+<\/sup>\u6df7\u5408\u79bb\u5b50\u7535\u6c60\u3002\uff08a\uff09CoHCF\u6676\u4f53\u7ed3\u6784\uff0c\uff08b-c\uff09CoHCF\u548cCoHCF\/CNT\u5fae\u89c2\u5f62\u8c8c\u5bf9\u6bd4\uff0c\uff08d-e\uff09\u4e0d\u540c\u6750\u6599\u4e4b\u95f4\u500d\u7387\u548c\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\u3002<\/p>\n

\u8d85\u6d53\u7535\u89e3\u6db2\u63d0\u9ad8\u6c34\u7cfb\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u964d\u4f4e\u7535\u6c60\u526f\u53cd\u5e94\u3002Yang\u7b49\u00a0[<\/sup>19<\/sup>]<\/sup>\u53d1\u73b0\u8d85\u6d53\u7535\u89e3\u6db2\uff0821M LiTFSI + 1M Zn(TFSI)2<\/sub>\uff09\u4e2dFeHCF\u4e2dFe3+\/2+<\/sup>-C\u2261N\u7684\u6c27\u5316\/\u8fd8\u539f\u5728\u9ad8\u7535\u4f4d\u626b\u63cf\u6761\u4ef6\u4e0b\u4f1a\u9010\u6b65\u88ab\u6fc0\u53d1\uff0c\u8be5\u50a8\u80fd\u673a\u5236\u4f7fFeHCF\u83b7\u5f97\u9ad8\u7684\u653e\u7535\u7535\u538b\u3001\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u53ca\u9ad8\u7684\u500d\u7387\u3002\uff08\u56fe19<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe19<\/b><\/strong>\u00a0\u8d85\u6d53\u7535\u89e3\u6db2\u4e2d\uff0821M LiTFSI + 1M Zn(TFSI)2<\/sub>\uff09\u9ad8\u7535\u4f4d\u626b\u63cf\u8bf1\u5bfcFe3+\/2+<\/sup>-C\u2261N\u6c27\u5316\u8fd8\u539f\u3002\uff08a\uff09FeHCF\u6676\u4f53\u7ed3\u6784\uff0c\uff08b-d\uff09\u9ad8\u7535\u4f4d\u626b\u63cf\u6761\u4ef6\u4e0b\u7684\u7535\u5316\u5b66\u884c\u4e3a\uff0c\u53ca\u4e24\u4e2a\u7535\u538b\u5e73\u53f0\uff081.5\u00a0V\u548c0.9\u00a0V\uff09\u5bf9\u5bb9\u91cf\u8d21\u732e\uff0c\uff08e\uff09\u5faa\u73af\u7a33\u5b9a\u6027\u66f2\u7ebf\u3002<\/p>\n

Nakamoto\u7b49\u00a0[<\/sup>20<\/sup>]<\/sup>\u62a5\u5bfc\u4e86\u8d85\u6d53\u7535\u89e3\u6db2\uff08\u00a017M aqueous NaClO4 <\/sub>\uff09\u4e2dNa2<\/sub>MnFe(CN)6<\/sub>\u00a0\u6b63\u6781(Fe2+<\/sup>\/Fe3+<\/sup>, Mn2+<\/sup>\/Mn3+<\/sup>) \u548cKMnCr(CN)6 <\/sub>\u8d1f\u6781\u00a0(Cr2+<\/sup>\/Cr3+<\/sup>)\u7ec4\u6210\u7684\u5168\u7535\u6c60\u3002\u7531\u4e8ePBA\u6750\u6599\u6846\u67b6\u7ed3\u6784\u548c\u8d85\u6d53\u7535\u89e3\u6db2\u7684\u5e94\u7528\uff0c\u8be5\u7535\u6c60\u8868\u73b0\u51fa\u9ad8\u7535\u538b\u548c\u9ad8\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08\u56fe20<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe20<\/b><\/strong>\u00a0\u8d85\u6d53\u7535\u89e3\u6db2\uff0817 M NaClO4<\/sub>\uff09\u4e2dNa2<\/sub>Mn[Fe(CN)6<\/sub>]\u548cKMn[Cr(CN)6<\/sub>]\u7684CV\u66f2\u7ebf\u53ca\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

Wu\u7b49\u00a0[<\/sup>21<\/sup>]<\/sup>\u62a5\u9053\u4e86\u8d85\u6d53\u7535\u89e3\u6db2\uff08\u00a030 M ZnCl2 <\/sub>\uff09\u4e2dZn3<\/sub>[Fe(CN)6<\/sub>]2<\/sub>\u00a0\u6b63\u6781\u7684\u7535\u5316\u5b66\u884c\u4e3a\u3002\u91c7\u7528\u8d85\u6d53\u7535\u89e3\u6db2\uff0c\u5168\u7535\u6c60\u653e\u7535\u7535\u538b\u4ece0.6 V\u63d0\u9ad8\u90530.95 V\uff0c\u80fd\u91cf\u5bc6\u5ea6\u63d0\u9ad8\u3002\uff08\u56fe21<\/b><\/strong>\uff09<\/p>\n

\"\"<\/p>\n

\u56fe21<\/b><\/strong>\u00a0\u8d85\u6d53\u7535\u89e3\u6db2\uff0830 M ZnCl2<\/sub>\uff09\u4e2dZn3<\/sub>[Fe(CN)6<\/sub>]2<\/sub>\u00a0\u6b63\u6781\u7684\u7535\u5316\u5b66\u884c\u4e3a\u3002<\/p>\n

\u7efc\u4e0a\uff0c\u8d85\u6d53\u7535\u89e3\u6db2\u4e0ePBAs\u5e94\u7528\u7ed3\u5408\u7684\u4f18\u52bf\uff1a\u62d3\u5bbd\u7535\u89e3\u6db2\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u63d0\u9ad8PBAs\u6750\u6599\u653e\u7535\u7535\u538b\uff0c\u5e76\u6fc0\u6d3bFe3+\/2+<\/sup>-C\u2261N\u7684\u6c27\u5316\/\u8fd8\u539f\u3002<\/p>\n

Wu\u7b49\u00a0[<\/sup>22<\/sup>]<\/sup>\u63ed\u793a\u4e86Cu[Fe(CN)6<\/sub>]0.63<\/sub>\u2219\u25a10.37<\/sub>\u22193.4H2<\/sub>O \u4e2d\u8d28\u5b50\u8fc1\u79fb\u7684Grotthus\u673a\u5236\uff0c\u8be5\u50a8\u80fd\u673a\u5236\u4f7f\u5f97PBA\u6750\u6599\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u500d\u7387\u6027\u80fd\u3002\uff08\u56fe22<\/b><\/strong>\uff09\u3002\u6b64\u5916\uff0c\u672c\u7efc\u8ff0\u4e5f\u9488\u5bf9PBAs\u6750\u6599\u5728\u5176\u4ed6\u8f7d\u8377\u79bb\u5b50\uff08NH4<\/sub>+<\/sup>\u3001Zn2+<\/sup>\u3001Ca2+<\/sup>\u3001Mg2+<\/sup>\u3001Al3+<\/sup>\uff09\u50a8\u8fd0\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u505a\u4e86\u7efc\u8ff0\u3002<\/p>\n

\"\"<\/p>\n

\u56fe22<\/b><\/strong>\u00a0<\/b><\/strong>Cu-TBA\u6750\u6599\u4e2dH+<\/sup>\u7684\u8d85\u901f\u8fc1\u79fb\u3002\uff08a\uff09Cu-TBA\u6676\u4f53\u7ed3\u6784\uff0c\uff08b\uff0cc\uff09\u6676\u4f53\u7ed3\u6784\u5185H+<\/sup>\u4f20\u5bfc\u7f51\u7edc\uff0c\uff08d-f\uff09\u500d\u7387\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u5c55\u671b<\/b><\/strong><\/h2>\n

PBAs\u6750\u6599\u7684\u672c\u5f81\u7535\u5316\u5b66\u6027\u80fd\u53d7\u6676\u4f53\u7f3a\u9677\u7684\u5f71\u54cd\u6781\u5927\u3002\u6211\u4eec\u8ba4\u4e3a\uff0c\u901a\u8fc7\u8c03\u63a7\u5408\u6210\u8fc7\u7a0b\u83b7\u5f97\u9ad8\u7684\u7ed3\u6676\u6027\uff0c\u662f\u672a\u6765PBAs\u6750\u6599\u7814\u7a76\u7684\u91cd\u70b9\u3002\u6b64\u5916\uff0c\u5982\u4f55\u63d0\u9ad8PBAs\u6750\u6599\u7684\u7535\u5b50\u7535\u5bfc\u4e5f\u662f\u91cd\u8981\u7684\u7814\u7a76\u95ee\u9898\uff1b<\/p>\n

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\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong><\/h2>\n

\u535a\u58eb\u751f\u6613\u6d69\u806a\u548c\u535a\u58eb\u540e\u79e6\u6da6\u4e4b\u662f\u6587\u7ae0\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u8d75\u5e86\u8d3a\u526f\u7814\u7a76\u5458\u548c\u6f58\u950b\u6559\u6388\u662f\u6587\u7ae0\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n

\u8d75\u5e86\u8d3a\u535a\u58eb\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u526f\u7814\u7a76\u5458\uff0c\u76ee\u524d\u81f4\u529b\u4e8e\u7535\u50ac\u5316\u5242\u6750\u6599\u8bbe\u8ba1\u53ca\u6c34\u7cfb\u7535\u6c60\u5f00\u53d1\u76f8\u5173\u7684\u7814\u7a76\uff0c\u5728Adv. Mater.\u3001Angew. Chem.\u3001Adv. Funct. Mater.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u6587\u5341\u4f59\u7bc7\uff1b<\/p>\n

\u6f58\u950b\u6559\u6388\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u521b\u9662\u9662\u957f\u3001\u5317\u4eac\u5927\u5b66\u6559\u6388\uff0c\u79d1\u6280\u90e8\u201c\u7535\u52a8\u6c7d\u8f66\u52a8\u529b\u7535\u6c60\u4e0e\u6750\u6599\u56fd\u9645\u8054\u5408\u7814\u7a76\u4e2d\u5fc3\u201d\uff08\u56fd\u5bb6\u7ea7\u7814\u53d1\u4e2d\u5fc3\uff09\u4e3b\u4efb\u3002\u81f4\u529b\u4e8e\u6750\u6599\u57fa\u56e0\u4e0e\u5927\u6570\u636e\u7cfb\u7edf\u7814\u53d1\u3001\u7ed3\u6784\u5316\u5b66\u65b0\u8303\u5f0f\u63a2\u7d22\u3001 \u57fa\u4e8e\u4e2d\u5b50\u5927\u79d1\u5b66\u88c5\u7f6e\u7684\u6750\u6599\u548c\u5668\u4ef6\u7efc\u5408\u8868\u5f81\u7cfb\u7edf\u5efa\u8bbe\u4e0e\u5e94\u7528\u3002\u5148\u540e\u83b7\u56fd\u9645\u7535\u52a8\u8f66\u9502\u7535\u6c60\u534f\u4f1a\u6770\u51fa\u7814\u7a76\u5956(2016)\u3001\u7f8e\u56fd\u7535\u5316\u5b66\u5b66\u4f1a\u7535\u6c60\u79d1\u6280\u5956(2018)\u548c\u6df1\u5733\u5e02\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956(2019)\u3002\u5728Nature Nanotech.\u7b49\u671f\u520a\u53d1\u8868SCI\u8bba\u6587250\u4f59\u7bc7\uff0c2015-19\u8fde\u7eed5\u5e74\u5165\u9009\u7231\u601d\u552f\u5c14\u4e2d\u56fd\u9ad8\u88ab\u5f15\u5b66\u8005\u3002<\/p>\n

\u6587\u7ae0\u94fe\u63a5<\/b><\/strong><\/h2>\n

Structure and Properties of Prussian Blue Analogues in Energy Storage and Conversion Applications<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202006970<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/h2>\n

[1]\u00a0Liwei Jiang, X. S., Yaxiang Lu, Chenglong Zhao, Junmei Zhao, Xiqian Yu, Yong-Sheng Hu, Building aqueous K-ion batteries for energy storage. Nature energy <\/i><\/em>2019,<\/b><\/strong>\u00a04<\/i><\/em>, 495\u2013503.<\/p>\n

[2] Longtao Ma, S. C., Changbai Long, Xinliang Li, Yuwei Zhao, Zhuoxin Liu, Zhaodong Huang, Binbin Dong, Juan Antonio Zapien, and Chunyi Zhi, Achieving High-Voltage and High-Capacity Aqueous Rechargeable Zinc Ion Battery by Incorporating Two-Species Redox Reaction.\u00a0Adv. <\/i><\/em>Energy Mater. <\/i><\/em>2019<\/b><\/strong>, 1902446.<\/span><\/p>\n

[3] Jian Peng, J. W., Haocong Yi, WenJing Hu, Yonghui Yu, Jinwen Yin, Yi Shen, Yi Liu, Jiahuan Luo, Yue Xu, Peng Wei, Yuyu Li, Yu Jin, Yu Ding, Ling Miao, Jianjun Jiang, Jiantao Han, Yunhui Huang, A Dual-Insertion Type Sodium-Ion Full Cell Based on High-Quality Ternary-Metal Prussian Blue Analogs. Adv. <\/i><\/em>Energy Mater<\/i><\/em>. <\/i><\/em>2018<\/b><\/strong>, 1702856.<\/p>\n

[4]\u00a0Bingxing Xie, L. W., Jie Shu, Xiaoming Zhou, Zhenjiang Yu, Hua Huo, Yulin Ma, Xinqun Cheng, Geping Yin, and Pengjian Zuo, Understanding the Structural Evolution and Lattice Water Movement for Rhombohedral Nickel Hexacyanoferrate upon Sodium Migration. ACS Appl. Mater. Interfaces <\/i><\/em>2019,<\/b><\/strong>\u00a011<\/i><\/em>, 46705\u221246713.<\/p>\n

[5] Jie Song, L. W., Yuhao Lu, Jue Liu, Bingkun Guo, Penghao Xiao, Jong-Jan Lee, Xiao-Qing Yang, Graeme Henkelman, John B. Goodenough, Removal of Interstitial H2O in Hexacyanometallates for a Superior Cathode of a Sodium-Ion Battery. J.<\/em>\u00a0Am. Chem. Soc. <\/i><\/em>2015,<\/b><\/strong>137<\/i><\/em>, 2658\u22122664.<\/p>\n

[6] Alfaruqi, M. H. M., Vinod\uff1bGim, Jihyeon\uff1bKim, Sungjin\uff1bSong, Jinju\uff1bBaboo, Joseph P.\uff1bSun, H. Choi\uff1bKim, Jaekook, Electrochemically Induced Structural Transformation in a \u03b3-MnO2 Cathode of a High Capacity Zinc-Ion Battery System. Chemistry of Materials <\/i><\/em>2015,<\/b><\/strong>27<\/i><\/em>\u00a0(10),\u00a03609\u22123620.<\/p>\n

[7] Yang Liu, Y. Q., Wuxing Zhang, Zhen Li, Xiao Ji, Ling Miao, Lixia Yuan, Xianluo Hu, Yunhui Huang, Sodium storage in Na-rich NaxFeFe (CN)6 nanocubes. Nano Energy <\/i><\/em>2015,<\/b><\/strong>12<\/i><\/em>, 386\u2013393.<\/p>\n

[8] Dawei Su, A. M., Shi-Zhang Qiao, Guoxiu Wang, High-Capacity Aqueous Potassium-Ion Batteries for Large-Scale Energy Storage. Adv.<\/em>\u00a0Mater. <\/i><\/em>2017,<\/b><\/strong>29<\/i><\/em>, 1604007.<\/p>\n

[9] Jinpeng Wu, J. S., Kehua Dai, Zengqing Zhuo, L. Andrew Wray, Gao Liu, Zhi-xun Shen, Rong Zeng, Yuhao Lu, Wanli Yang, Modification of Transition-Metal Redox by Interstitial Water in Hexacyanometalate Electrodes for Sodium-Ion Batteries.J.<\/em>\u00a0 Am. Chem. Soc. <\/i><\/em>2017,<\/b><\/strong>139<\/i><\/em>, 18358\u221218364.<\/p>\n

[10] Weijie Li, C. H., Wanlin Wang, Qingbing Xia, Shulei Chou, Qinfen Gu, Bernt Johannessen, HuaKun Liu, and Shixue Dou, Stress Distortion Restraint to Boost the Sodium Ion Storage Performance of a Novel Binary Hexacyanoferrate. Adv.<\/em> Energy Mater. <\/i><\/em>2019<\/b><\/strong>, 1903006.<\/p>\n

[11] Pu Hu, W. P., Bo Wang, Dongdong Xiao, Utkarsh Ahuja, Julien Re\u0301thore\u0301, Katerina E. Aifantis, Concentration-Gradient Prussian Blue Cathodes for Na-Ion Batteries. ACS Energy Lett. <\/i><\/em>2020,<\/b><\/strong>5<\/i><\/em>, 100\u2212108.<\/p>\n

[12] Jinwen Yin, Y. S., Chang Li, ChenyangFan, Shixiong Sun, Yi Liu, Jian Peng, Li Qing, and JiantaoHan, In Situ Self-Assembly of Core\u2013Shell Multimetal Prussian Blue Analogues for High-Performance Sodium-Ion Batteries. ChemSusChem <\/i><\/em>2019,<\/b><\/strong>12<\/i><\/em>, 4786 \u20134790.<\/p>\n

[13] Wenhao Ren, M. Q., Zixuan Zhu, Mengyu Yan, Qi Li, Lei Zhang, Dongna Liu, Liqiang Mai, Activation of Sodium Storage Sites in Prussian Blue Analogues via Surface Etching. Nano Lett. <\/i><\/em>2017,<\/b><\/strong>17<\/i><\/em>,4713\u22124718.<\/p>\n

[14] Lingbo Ren, J.-G. W., Huanyan Liu, Minhua Shao, Bingqing Wei, Metal-organic-framework-derived hollow polyhedrons of prussian blue analogues for high power grid-scale energy storage. Electrochimica Acta <\/i><\/em>2019,<\/b><\/strong>321<\/i><\/em>, 134671.<\/p>\n

[15] Dezhi Yang, J. X., Xiao-Zhen Liao, Hong Wang, Yu-Shi He, Zi-Feng Ma, Prussian blue without coordinated water as a superior cathode for sodium-ion batteries. Chem.<\/em>\u00a0Commun. <\/i><\/em>2015,<\/b><\/strong>51<\/i><\/em>, 8181.<\/p>\n

[16] Yang Tang, W. Z., Lihong Xue, Xuli Ding, Ting Wang, Xiaoxiao Liu, Jing Liu, Xiaocheng Li, Yunhui Huang, Polypyrrole-promoted superior cyclability and rate capability of NaxFe[Fe(CN)6] cathodes for sodiumion batteries. J.\u00a0Mater. Chem. A <\/i><\/em>2016,<\/b><\/strong>4<\/i><\/em>, 6036.<\/p>\n

[17] Ke Lu, B. S., Yuxin Zhang, Houyi Ma, Jintao Zhang, Encapsulation of zinc hexacyanoferrate nanocubes with manganese oxide nanosheets for highperformance rechargeable zinc ion batteries.J.\u00a0Mater. Chem.\u00a0<\/i><\/em>A <\/i><\/em>2017,<\/b><\/strong>5<\/i><\/em>, 23628.<\/p>\n

[18] Dapeng Zhang, Z. Y., Junshu Zhang, Hongzhi Mao, Jian Yang, Yitai Qian, Truncated cobalt hexacyanoferrate nanocubes threaded by carbon nanotubes as a high-capacity and high-rate cathode material for dual-ion rechargable aqueous batteries. Journal of Power Sources <\/i><\/em>2018,<\/b><\/strong>399<\/i><\/em>, 1-7.<\/p>\n

[19] Qi Yang, F. M., Zhuoxin Liu, Longtao Ma, Xinliang Li, Daliang Fang, Shimou Chen, Suojiang Zhang, and Chunyi Zhi, Activating C-Coordinated Iron of Iron Hexacyanoferrate for Zn Hybrid-Ion Batteries with 10 000-Cycle Lifespan and Superior Rate Capability. Adv.<\/em>\u00a0Mater. <\/i><\/em>2019,<\/b><\/strong>31<\/i><\/em>, 1901521.<\/p>\n

[20] Kosuke Nakamoto, R. S., Yuki Sawada, Masato Ito, and Shigeto Okada, Over 2 V Aqueous Sodium-Ion Battery with Prussian Blue-Type Electrodes. Small Methods <\/i><\/em>2019,<\/b><\/strong>3<\/i><\/em>\u00a0(1800220).<\/p>\n

[21] Xianyong Wu, \u2020 Yunkai Xu,\u00a7,\u2020 Chong Zhang,\u2020 Daniel P. Leonard,\u2020 Aaron Markir,\u2020 Jun Lu,*,\u2021 and Xiulei Ji, Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte. J.\u00a0Am. Chem. Soc. <\/i><\/em>2019,<\/b><\/strong>141<\/i><\/em>, 6338\u22126344.<\/p>\n

[22] Xianyong Wu, J. J. H., Woochul Shin, Lu Ma, Tongchao Liu, Xuanxuan Bi, Yifei Yuan, Yitong Qi, T. Wesley Surta, Wenxi Huang, Joerg Neuefeind, Tianpin Wu, P. Alex Greaney, Jun Lu, Xiulei Ji\u200aDiffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries. Nature Energy <\/i><\/em>2019,<\/b><\/strong>4<\/i><\/em>, 123\u2013130.<\/p>\n

\u672c\u6587\u7531\u4f5c\u8005\u56e2\u961f\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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