{"id":210394,"date":"2020-10-01T06:30:45","date_gmt":"2020-09-30T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=210394"},"modified":"2020-10-01T00:22:44","modified_gmt":"2020-09-30T16:22:44","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e3%80%91%e6%82%89%e5%b0%bc%e5%a4%a7%e5%ad%a6%e9%99%88%e5%85%83%e6%95%99%e6%8e%88angew-%e5%85%b7%e6%9c%89%e8%b6%85%e9%ab%98%e8%83%bd%e9%87%8f%e5%af%86%e5%ba%a6%e5%92%8c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=210394","title":{"rendered":"\u6089\u5c3c\u5927\u5b66\u9648\u5143\u6559\u6388Angew: \u5177\u6709\u8d85\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u8d85\u957f\u5faa\u73af\u5bff\u547d\u7684\u67d4\u6027\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\uff1aZnCl2\u7535\u89e3\u8d28\u7684\u5173\u952e\u4f5c\u7528"},"content":{"rendered":"<p>\u3010<strong><b>\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n<p>\u968f\u7740\u67d4\u6027\u4fbf\u643a\u7535\u5b50\u8bbe\u5907\u7684\u98de\u901f\u53d1\u5c55\uff0c\u4e0e\u4e4b\u76f8\u5339\u914d\u7684\u4f4e\u6210\u672c\uff0c\u9ad8\u6027\u80fd\u548c\u5b89\u5168\u7684\u50a8\u80fd\u5668\u4ef6\u6210\u4e3a\u4e86\u7814\u7a76\u7684\u6838\u5fc3\u95ee\u9898\u3002\u91d1\u5c5e\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7ed3\u5408\u4e86\u7535\u6c60\u7535\u6781\u548c\u8d85\u7ea7\u7535\u5bb9\u7535\u6781\uff0c\u65e8\u5728\u80fd\u591f\u53d6\u4e8c\u8005\u4e4b\u957f\u5b9e\u73b0\u4e92\u8865\u4f18\u52bf\uff0c\u5728\u63d0\u4f9b\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u540c\u65f6\uff0c\u4fdd\u6301\u4f18\u5f02\u7684\u529f\u7387\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u3002 \u5728\u4f17\u591a\u50a8\u80fd\u5668\u4ef6\u4e2d\uff0c\u6c34\u7cfb\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u56e0\u4e3a\u5176\u4f4e\u6210\u672c\u548c\u4f18\u8d8a\u7684\u5b89\u5168\u6027\u5907\u53d7\u5173\u6ce8\u3002\u591a\u5b54\u78b3\u6750\u6599\u53ef\u4ee5\u63d0\u4f9b\u4e30\u5bcc\u7684\u50a8\u950c\u4f4d\u70b9\uff0c\u56e0\u800c\u6210\u4e3a\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u4e2d\u6700\u5e38\u89c1\u7684\u6b63\u6781\u6750\u6599\u3002\u5c3d\u7ba1\u950c\u79bb\u5b50\u7684\u5c3a\u5bf8\u5f88\u5c0f\uff08\u76f4\u5f841.48 \u00c5\uff09\uff0c\u4f46\u5176\u5728\u6c34\u6eb6\u6db2\u4e2d\u5f62\u6210\u7684\u516d\u6c34\u5408\u950c\u79bb\u5b50\u57fa\u56e2\u5c3a\u5bf8\u8fbe8.60\u00a0\u00c5\uff1b\u7531\u4e8e\u591a\u5b54\u78b3\u7535\u6781\u7684\u5206\u5b50\u7b5b\u9009\u4f5c\u7528\uff0c\u8be5\u6eb6\u5242\u5316\u7684\u6c34\u5408\u950c\u79bb\u5b50\u81f4\u4f7f\u591a\u5b54\u78b3\u6750\u6599\u7684\u80fd\u91cf\u5bc6\u5ea6\u4e25\u91cd\u53d7\u9650\u3002<\/p>\n<p>\u3010<strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n<p>\u6700\u8fd1\uff0c<strong><b>\u6fb3\u5927\u5229\u4e9a\u6089\u5c3c\u5927\u5b66\u88f4\u589e\u590f\u535a\u58eb<\/b><\/strong>\u3001<strong><b>\u9648\u5143\u6559\u6388<\/b><\/strong>\u548c<strong><b>\u5408\u80a5\u5e08\u8303\u5927\u5b66\u7684\u5b5f\u5f3a\u5f3a<\/b><\/strong>\u535a\u58eb\u5408\u4f5c\uff0c\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aAngewandte Chemie International Edition\u4e0a\u53d1\u8868\u4e86\u9898\u4e3aToward\u00a0flexible zinc-ion hybrid capacitors with superhigh energy density and ultralong cycling life: the pivotal role of ZnCl<sub>2<\/sub>\u00a0salt-based electrolytes\u7684\u8bba\u6587\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u9996\u6b21\u63d0\u51fa\u4e86\u4e00\u79cd\u901a\u8fc7\u9634\u79bb\u5b50\u8c03\u63a7\u6c34\u5408\u950c\u79bb\u5b50\u57fa\u56e2\u53bb\u6eb6\u5242\u5316\u80fd\u7684\u7b56\u7565\uff0c\u4e3a\u89e3\u51b3\u4e0a\u8ff0\u95ee\u9898\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u601d\u8def\u3002\u5177\u4f53\u800c\u8a00\uff0c\u4f5c\u8005\u53d1\u73b0\u5728\u6240\u6709\u5e38\u89c1\u950c\u76d0\u6eb6\u6db2\u4e2d\uff0cZnCl<sub>2<\/sub>\u7535\u89e3\u6db2\u6240\u72ec\u5177\u7684\u542b\u6c2f\u6eb6\u5242\u5316\u7ed3\u6784\u53ef\u4ee5\u663e\u8457\u6539\u53d8\u7535\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8fdb\u800c\u8d4b\u4e88\u591a\u5b54\u6d3b\u6027\u70ad\u6750\u6599\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u901a\u8fc7\u5b9e\u9a8c\u7ed3\u5408DFT\u7406\u8bba\u8ba1\u7b97\uff0c\u4f5c\u8005\u8bc1\u5b9e\u6c2f\u79bb\u5b50\u7684\u5f15\u5165\u53ef\u6709\u6548\u964d\u4f4e\u6c34\u5408\u950c\u79bb\u5b50\u57fa\u56e2\u7684\u53bb\u6eb6\u5242\u5316\u80fd\u5792\uff0c\u56e0\u6b64\u589e\u5f3a\u4e86\u540e\u8005\u7684\u53bb\u6eb6\u5242\u5316\u7a0b\u5ea6\u5e76\u51cf\u5c0f\u4e86\u5176\u5c3a\u5bf8\uff0c\u6700\u7ec8\u4f7f\u591a\u5b54\u78b3\u6750\u6599\u4e2d\u7684\u5fae\u5b54\u5f97\u4ee5\u5145\u5206\u5229\u7528\uff0c\u4ece\u800c\u53ef\u5c55\u73b0\u51fa\u9ad8\u7535\u5316\u5b66\u50a8\u80fd\u5bb9\u91cf\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u8be5\u7b56\u7565\u5bf9\u540c\u4e3a\u4e8c\u4ef7\u4e14\u6c34\u5408\u7ed3\u6784\u76f8\u4f3c\u7684\u9541\u79bb\u5b50\u4e5f\u540c\u6837\u9002\u7528\u3002<\/p>\n<p>\u3010<strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong>\u3011<\/p>\n<p>\u56fe1.\u00a0\u57fa\u4e8e\u6d3b\u6027\u70ad\u7535\u6781\u7684\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u5728\u4e0d\u540c\u950c\u76d0\u6c34\u6eb6\u6db2\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210395 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-1-3.png\" alt=\"\" width=\"467\" height=\"385\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-1-3.png 467w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-1-3-300x247.png 300w\" sizes=\"(max-width: 467px) 100vw, 467px\" \/><\/p>\n<p>a) \u4e0d\u540c\u950c\u76d0\u6eb6\u6db2\u4e2d\u7684\u8d28\u91cf\u6bd4\u7535\u5bb9\uff1bb) \u4e0d\u540c\u7535\u89e3\u8d28\u4e2d\u7684\u963b\u6297\uff1bc) \u572850 mV s<sup>-1<\/sup>\u65f6\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1bd) \u57281A g<sup>-1<\/sup>\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002<\/p>\n<p><span style=\"line-height: 1.5;\">\u56fe2.\u00a0\u9634\u79bb\u5b50\u8c03\u63a7\u6c34\u5408\u950c\u79bb\u5b50\u57fa\u56e2\u53bb\u6eb6\u5242\u5316\u80fd\u7684\u7b56\u7565\u793a\u610f\u56fe<\/span><\/p>\n<p><span style=\"line-height: 1.5;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210396 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-2-3.png\" alt=\"\" width=\"600\" height=\"364\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-2-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-2-3-300x182.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/span><\/p>\n<p>a)<b><\/b>\u4e0d\u540c\u6d53\u5ea6\u6c2f\u5316\u950c\u6eb6\u6db2\uff0c\u786b\u9178\u950c\u6eb6\u6db2\u548c\u53bb\u79bb\u5b50\u6c34\u7684\u62c9\u66fc\u5149\u8c31\uff1bb) [Zn(H\u001f<sub>2<\/sub>O)<sub>6<\/sub>]<sup>2+ <\/sup>\u548c\u00a0[ZnCl(H<sub>2<\/sub>O)<sub>5<\/sub>]<sup>+<\/sup>\u6c34\u5408\u79bb\u5b50\u57fa\u56e2\u7684\u5206\u6b65\u53bb\u6eb6\u5242\u5316\u80fd\uff1b\u00a0c) [Zn(H\u001f<sub>2<\/sub>O)<sub>6<\/sub>]<sup>2+ <\/sup>\u548c\u00a0[ZnCl(H<sub>2<\/sub>O)<sub>5<\/sub>]<sup>+<\/sup>\u53bb\u6eb6\u5242\u5316\u4e2d\u95f4\u4ea7\u7269\u7684\u5206\u5b50\u7a7a\u95f4\u6784\u578b\u3002<\/p>\n<p><span style=\"line-height: 1.5;\">\u56fe3.\u00a0\u67d4\u6027\u7535\u89e3\u8d28\u7684\u5408\u6210\u4e0e\u6027\u80fd<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210397 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-3-4.png\" alt=\"\" width=\"600\" height=\"342\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-3-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-3-4-300x171.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) PAM\u6c34\u51dd\u80f6\u7684\u5408\u6210\u793a\u610f\u56fe\uff1bb) \u51bb\u5e72PAM\u6c34\u51dd\u80f6\u7684\u5f62\u6001\uff1bc) \u4e0d\u540c\u6d53\u5ea6\u6c2f\u5316\u950c\u586b\u5145\u7684PAM\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5bf9\u5e94PAM\u7684\u5916\u89c2\uff1bd) 25 <sup>o<\/sup>C\u4e0b\u4e0d\u540c\u6d53\u5ea6\u6c2f\u5316\u950c\u586b\u5145\u7684PAM\u51dd\u80f6\u7535\u89e3\u6db2\u7684\u62c9\u4f38\u6027\u80fd\u3002<\/p>\n<p><span style=\"line-height: 1.5;\">\u56fe4.\u00a0\u57fa\u4e8e\u6d3b\u6027\u70ad\u7684\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u67d4\u6027\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210398 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-4-3.png\" alt=\"\" width=\"600\" height=\"374\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-4-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-4-3-300x187.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) \u67d4\u6027\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7ed3\u6784\uff1bb) \u4e0d\u540c\u7535\u4f4d\u7a97\u53e3\u7684\u5faa\u73af\u66f2\u7ebf\uff1bc) \u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1bd) \u8d28\u91cf\u6bd4\u7535\u5bb9\uff1be) 5 A g<sup>-1<\/sup>\u7684\u5faa\u73af\u6027\u6d4b\u8bd5\uff1b\u00a0f) \u4e0e\u5176\u4ed6\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7684\u5faa\u73af\u5bff\u547d\u5bf9\u6bd4\uff1bg)\u00a0\u4e0d\u540c\u6d53\u5ea6\u6c2f\u5316\u950c\u586b\u5145\u7684PAM\u57282 \u00b0C min<sup>-1<\/sup>\u7684\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\u6d4b\u8bd5\uff1bh) \u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u8d28\u91cf\u6bd4\u7535\u5bb9\uff0c\u00a0\u63d2\u5165\u56fe\u4e3a\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u7387, \u7535\u89e3\u8d28\u5bfc\u7535\u70b9\u4eaeLED\u706f\u793a\u610f\u56fe\uff1b\u00a0i) -20 <sup>o<\/sup>C\u4e0b\u57285 A g<sup>-1<\/sup>\u7684\u5faa\u73af\u5bff\u547d\u6d4b\u8bd5\u3002<\/p>\n<p><span style=\"line-height: 1.5;\">\u56fe5.\u00a0\u57fa\u4e8eZn-SAC\u7684\u950c\u79bb\u5b50\u6df7\u5408\u67d4\u6027\u7535\u5bb9\u5668\u7684\u7535\u5316\u5b66\u6027\u80fd\u53ca\u5e94\u7528\u8303\u4f8b<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210399 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-5-4.png\" alt=\"\" width=\"600\" height=\"363\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-5-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u7247-5-4-300x182.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) SAC\u572877 K\u4e0b\u7684\u6c2e\u5438\u9644-\u89e3\u5438\u7b49\u6e29\u7ebf\uff1bb) SAC\u7684\u5b54\u5f84\u5206\u90e8\uff1bc) \u57fa\u4e8eSAC\u7684GCD\u66f2\u7ebf\uff1b\u00a0d) \u57fa\u4e8eSAC\u7684\u8d28\u91cf\u6bd4\u5bb9\u91cf\uff1b\u00a0e) SAC\u548c\u6d3b\u6027\u70ad\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5fae\u5b54\u9762\u79ef,\u4ee5\u53ca\u5bf9\u5e94\u5668\u4ef6\u57285 A g<sup>-1<\/sup>\u7684\u80fd\u91cf\u5bc6\u5ea6\uff1b\u00a0f) \u672c\u6587\u4e0e\u5176\u4ed6\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7684Ragone\u56fe\u5bf9\u6bd4\uff1b<sup>\u00a0<\/sup>g) 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<sup>o<\/sup>C\u73af\u5883\u4e0b\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u4e0e\u673a\u68b0\u67d4\u6027\u3002\u8be5\u7814\u7a76\u7684\u7ed3\u8bba\u4e3a\u5236\u9020\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684\u67d4\u6027\u950c\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u63d0\u4f9b\u4e86\u53ef\u884c\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u540c\u65f6\u4e5f\u4e3a\u5176\u4ed6\u7c7b\u4f3c\u50a8\u80fd\u8bbe\u5907\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6709\u76ca\u7684\u542f\u793a\u3002<\/p>\n<p><strong><b>\u6587\u732e\u94fe<\/b><\/strong><strong><b>\u63a5<\/b><\/strong><\/p>\n<p>Toward flexible zinc\u2010ion hybrid capacitors with superhigh energy density and ultralong cycling life: the pivotal role of ZnCl2 salt\u2010based electrolytes.\u00a0Angew. Chem. Int. Ed. 2020, DOI: 10.1002\/anie.202012030<\/p>\n<p>\u672c\u6587\u7531\u4f5c\u8005\u56e2\u961f\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u968f\u7740\u67d4\u6027\u4fbf\u643a\u7535\u5b50\u8bbe\u5907\u7684\u98de\u901f\u53d1\u5c55\uff0c\u4e0e\u4e4b\u76f8\u5339\u914d\u7684\u4f4e\u6210\u672c\uff0c\u9ad8\u6027\u80fd\u548c\u5b89\u5168\u7684\u50a8\u80fd\u5668\u4ef6\u6210\u4e3a\u4e86\u7814\u7a76\u7684\u6838\u5fc3\u95ee\u9898\u3002\u91d1\u5c5e\u79bb\u5b50\u6df7\u5408\u7535\u5bb9\u5668\u7ed3\u5408\u4e86\u7535\u6c60\u7535\u6781\u548c\u8d85\u7ea7\u7535\u5bb9\u7535\u6781\uff0c\u65e8\u5728\u80fd&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-210394","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210394"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=210394"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210394\/revisions"}],"predecessor-version":[{"id":210433,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210394\/revisions\/210433"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=210394"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=210394"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=210394"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}