{"id":210285,"date":"2020-09-30T06:30:21","date_gmt":"2020-09-29T22:30:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=210285"},"modified":"2020-09-29T18:31:40","modified_gmt":"2020-09-29T10:31:40","slug":"mof%e5%9c%88%e5%a4%a7%e7%89%9b%ef%bc%9aroland-a-fischer%e3%80%81omar-m-yaghi%e3%80%81hong-cai-zhou%e3%80%81omar-k-farha%e8%bf%91%e6%9c%9f%e5%b7%a5%e4%bd%9c%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=210285","title":{"rendered":"MOF\u5708\u5927\u725b\uff1aRoland A. Fischer\u3001Omar M. Yaghi\u3001Hong-Cai Zhou\u3001Omar K. Farha\u8fd1\u671f\u5de5\u4f5c\u8fdb\u5c55"},"content":{"rendered":"<p>\u4f5c\u4e3a\u8fd1\u5e74\u6765\u6700\u5177\u6709\u7814\u7a76\u4ef7\u503c\u7684\u70ed\u95e8\u6750\u6599\u4e4b\u4e00\uff0cMOF\u53ef\u8c13\u662f\u62a2\u5c3d\u98ce\u5934\u3002\u65e0\u8bba\u662f\u5206\u79bb\u3001\u5438\u9644\uff0c\u8fd8\u662f\u50ac\u5316\u3001\u7535\u6c60\u3001\u751f\u7269\u533b\u836f\u7b49\u7b49\u9886\u57df\uff0cMOF\u51e0\u4e4e\u65e0\u5904\u4e0d\u5728\uff0c\u65e0\u5b54\u4e0d\u5165\u3002\u672c\u6587\u7279\u522b\u4e3a\u5927\u5bb6\u4ecb\u7ecd\u5728MOF\u9886\u57df\u4e2d\u56fd\u9645\u77e5\u540d\u5927\u725b\u7684\u8fd1\u671f\u5de5\u4f5c\u8fdb\u5c55\uff0c\u4ee5\u4f9b\u5b66\u4e60\u53c2\u8003\u3002<\/p>\n<p><strong><b>ACS C<\/b><\/strong><strong><b>atalysis\uff1a<\/b><\/strong><strong><b>\u5fae\u6676\u7f29\u5c0f\u4e0e\u8868\u9762\u951a\u56fa<\/b><\/strong><strong><b>\u76f8<\/b><\/strong><strong><b>\u7ed3\u5408\u63d0\u9ad8MOF\u50ac\u5316\u5242\u7684\u9891\u7387<\/b><\/strong><\/p>\n<p>\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66 Roland A. Fischer\u6559\u6388\u7b49\u4eba\u62a5\u9053\u4e86\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF) UiO-66\u8868\u9762\u951a\u5b9a\u7eb3\u7c73\u9897\u7c92\u7684\u5236\u5907(Zr<sub>6<\/sub>O<sub>4<\/sub>\u00a0(OH)<sub>4<\/sub>\u00a0(bdc)<sub>6<\/sub>;bdc<sup>2\u2212<\/sup>= 1, 4-benzene dicarboxylate)\u3002\u5236\u5907\u4e86\u8868\u9762\u951a\u5b9a\u7684\u7eb3\u7c73mofs (SA-NMOFs)\u901a\u8fc7\u5171\u4ef7\u951a\u5b9a\uff0c\u9884\u5408\u6210\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7\u8868\u9762\u6539\u6027\u7684\u529f\u80fd\u5316UiO-66 \u7eb3\u7c73MOF\uff08NMOF\uff09\u3002SA-NMOFs\u8868\u73b0\u51fa\u79bb\u6563\u6027\u3001\u4e0d\u805a\u5408 (&lt;30 nm)\u3002\u8be5SA-NMOFs\u4fdd\u7559\u4e86\u4e00\u4e2a\u9ad8\u8868\u9762\u79ef\uff0c\u6210\u4e3a\u9ad8\u6548\u7684\u50ac\u5316\u5242\u3002\u6bd4\u8f83\u4e86SA-NMOFs\u4e0e\u4f53\u6001\u5206\u6563\u7684UiO-66\u5728\u82ef\u7532\u919b\u6c30\u57fa\u5316\u53cd\u5e94\u4e2d\u7684\u50ac\u5316\u6d3b\u6027\u3002SA-NMOFs\u7684\u6d3b\u6027\u63d0\u9ad8\u4e8610<sup>5<\/sup>&#8211; 10<sup>6<\/sup>\u500d\uff0c\u8fd9\u662f\u56e0\u4e3aNMOFs\u7684\u8868\u9762\u79ef\u66f4\u5927\uff0c\u8868\u9762\u56fa\u5b9a\u5316\u6291\u5236\u4e86\u7eb3\u7c73\u7c92\u5b50\u7684\u805a\u96c6\u3002\u901a\u8fc7\u6bd4\u8f83\u50ac\u5316\u5242\u4f53\u7cfb\u5bf9\u73af\u52a0\u6210\u53cd\u5e94\u7684\u6d3b\u6027\uff0c\u8bc1\u660e\u4e86\u8be5\u65b9\u6cd5\u5bf9\u5176\u4ed6\u8def\u6613\u65af\u9178\u50ac\u5316\u53cd\u5e94\u7684\u666e\u904d\u9002\u7528\u6027\u3002\u4e8c\u6c27\u5316\u78b3\u548c\u73af\u6c27\u4e19\u70f7\u5408\u6210\u78b3\u9178\u4e19\u70f7\uff0c\u5176\u4e2dSA-NMOFs\u7684\u6027\u80fd\u8fdc\u8fdc\u4f18\u4e8e\u4f53\u5757MOFs\u548c\u7f3a\u9677\u5de5\u7a0bMOF\u3002\u8fd9\u4e00\u53d1\u73b0\u4e3aSA-NMOFs\u4f5c\u4e3a\u9ad8\u6548\u50ac\u5316\u5242\u6750\u6599\u7684\u5e94\u7528\u94fa\u5e73\u4e86\u9053\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSubstantial Turnover Frequency Enhancement of MOF Catalysts by Crystallite Downsizing Combined with Surface Anchoring\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Catalysis\u4e0a\u3002<\/p>\n<p>DOI: 10.1021\/acscatal.0c00550<\/p>\n<p>\u56fe1\u00a0NMOF 1\u548c2\u50ac\u5316\u82ef\u7532\u919b\u7684\u6c30\u57fa\u5316\u53cd\u5e94<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210286 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/1-9.png\" alt=\"\" width=\"600\" height=\"255\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/1-9.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/1-9-300x128.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>An<\/b><\/strong><strong><b>gew.\uff1a<\/b><\/strong><strong><b>\u8868\u9762<\/b><\/strong><strong><b>\u951a\u5b9aM<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u53cc\u529f\u80fd<\/b><\/strong><strong><b>0<\/b><\/strong><strong><b>RR\/ORE<\/b><\/strong><strong><b>\u7535<\/b><\/strong><strong><b>\u50ac\u5316<\/b><\/strong><strong><b>\u5242<\/b><\/strong><\/p>\n<p>\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u53ca\u5176\u884d\u751f\u7269\u88ab\u8ba4\u4e3a\u662f\u6c27\u8fd8\u539f(ORR)\u548cOER\u7684\u6709\u524d\u9014\u7684\u50ac\u5316\u5242\uff0c\u8fd9\u5bf9\u8bb8\u591a\u80fd\u6e90\u63d0\u4f9b\u6280\u672f\u5f88\u91cd\u8981\uff0c\u5982\u7535\u89e3\u69fd\u3001\u71c3\u6599\u7535\u6c60\u548c\u67d0\u4e9b\u7c7b\u578b\u7684\u5148\u8fdb\u7535\u6c60\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66 Roland A. Fischer\u6559\u6388\u8054\u5408\u4e2d\u56fd\u7535\u5b50\u79d1\u6280\u5927\u5b66Liujiang Zhou\u6559\u6388\u7b49\u4eba\u4e3a\u4e86\u8bbe\u8ba1\u4e00\u79cd\u5148\u8fdb\u7684\u53cc\u529f\u80fdORR\/OER\u7535\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u4f7f\u7528\u8868\u9762\u951a\u5b9a\u7684NiFe-MOFs\u5e94\u7528\u4e86\u4e00\u79cd\u201c\u5e94\u53d8\u8c03\u5236\u201d\u65b9\u6cd5\u3002\u8be5\u6750\u6599\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u8868\u73b0\u51fa\u6781\u597d\u7684OER\u6d3b\u6027\uff0c\u5728\u4ec5\u4e3a210mv\u7684\u8fc7\u7535\u4f4d\u4e0b\u8fbe\u5230\u5de5\u4e1a\u76f8\u5173\u7535\u6d41\u5bc6\u5ea6200 mA cm<sup>-2<\/sup>\u3002\u5373\u4f7f\u5728500 mA cm<sup>-2<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5b83\u4e5f\u80fd\u957f\u671f\u7a33\u5b9a\u8fd0\u884c\uff0c\u5e76\u663e\u793a\u51fa\u8fc4\u4eca\u4e3a\u6b62\u6700\u7a84\u7684\u201c\u8fc7\u7535\u4f4d\u7a97\u53e3\u201d\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAdvanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface-Mounted Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Angew.\u4e0a\u3002<\/p>\n<p>DOI: 10.1002\/ange.201916507<\/p>\n<p>\u56fe2\u00a0NiFe-BDC (X) SURMOFs (X=NH<sub>2<\/sub>, H, OCH<sub>3 <\/sub>and Br)\u5236\u5907\u53ca\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210287 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/2-6.png\" alt=\"\" width=\"600\" height=\"372\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/2-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/2-6-300x186.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Science<\/b><\/strong><strong><b>: \u591a\u53d8\u91cf\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u91d1\u5c5e\u7684\u6392\u5e8f<\/b><\/strong><\/p>\n<p>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u6559\u6388\u8054\u5408\u5fb7\u56fd\u6ce2\u9e3f\u9c81\u5c14\u5927\u5b66Tong Li\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u68c0\u6d4b\u548c\u8c03\u63a7\u5bf9\u7ec4\u5206MOFs\u4e2d\u591a\u79cd\u91d1\u5c5e\u6392\u5217\u7684\u65b0\u8fdb\u5c55\u3002\u5728\u5305\u542b\u94b4(Co)\u3001\u9549(Cd)\u3001\u94c5(Pb)\u548c\u9530(Mn)\u7684\u591a\u5143\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF-74\uff09\u4e2d\u7ed8\u5236\u4e86\u91d1\u5c5e\u6c27\u5316\u7269\u68d2\u6676\u4f53\u4e2d\u7684\u91d1\u5c5e\u5e8f\u5217\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u901a\u8fc7\u6539\u53d8\u4e0d\u540c\u91d1\u5c5e\u7684\u6bd4\u4f8b\u4ee5\u53ca\u5408\u6210\u6e29\u5ea6\uff0c\u53ef\u4ee5\u7cbe\u786e\u8c03\u63a7\u591a\u7ec4\u5206MOFs\u4e2d\u91d1\u5c5e\u7684\u6392\u5217\u60c5\u51b5\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6392\u5217\u53ef\u4ee5\u662f\u968f\u673a\u7684(Co, Cd, 120\u00b0C)\uff0c\u4e5f\u53ef\u4ee5\u662f\u77ed\u7684\u91cd\u590d\u5355\u5143(Co, Cd, 85\u00b0C)\uff0c\u4e5f\u53ef\u4ee5\u662f\u957f\u7684\u91cd\u590d\u5355\u5143(Co, Pb, 85\u00b0C)\uff0c\u8fd8\u53ef\u4ee5\u662f\u91d1\u5c5e\u63d2\u5165\u7684\u5f62\u5f0f(Co, Mn, 85\u00b0C)\u3002\u57283\u79cd\u6676\u4f53\u4e2d\uff0c\u4e0d\u9700\u8981\u6539\u53d8\u5bf9\u91d1\u5c5e\u6392\u5217\u65b9\u5f0f\uff0c\u7814\u7a76\u4eba\u5458\u53ef\u4ee5\u572812\u4e2a\u6837\u54c1\u4e2d\uff0c\u5b9e\u73b0\u4e86Co\u91d1\u5c5e\u5143\u7d20\u7684\u6469\u5c14\u6bd4\u5c31\u57280.4-0.9\u4e4b\u95f4\u7cbe\u51c6\u8c03\u63a7\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cSequencing of metals in multivariate metal-organic frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Science\u4e0a\u3002<\/p>\n<p>DOI: 10.1126\/science.aaz4304<\/p>\n<p>\u56fe3 MOF-74\u5355\u6676\u4e2d\u91d1\u5c5e\u7684APT\u6d4b\u91cf\u548c\u6392\u5e8f<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210288 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/3-8.png\" alt=\"\" width=\"600\" height=\"800\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/3-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/3-8-225x300.png 225w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Ch<\/b><\/strong><strong><b>em<\/b><\/strong><strong><b>\uff1a\u4e09\u4ef7<\/b><\/strong><strong><b>\u91d1\u50ac\u5316\u5242\u5728\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u7684\u7ed3\u6784\u7a33\u5b9a\u5316<\/b><\/strong><\/p>\n<p>\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4e2d\uff0c\u5355\u5206\u5b50\u5206\u89e3\u9014\u5f84\u662f\u5177\u6709\u6311\u6218\u6027\u7684\uff0c\u800c\u4e14\u4ee5\u524d\u5e76\u6ca1\u6709\u901a\u8fc7\u52a0\u5165\u5230\u4e00\u4e2a\u575a\u56fa\u7684\u652f\u6491\u4e2d\u800c\u88ab\u6291\u5236\u3002\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821Omar M. Yaghi\u3001F. Dean Toste\u6559\u6388\u62a5\u9053\u4e86\u4e24\u4e2a\u575a\u56fa\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6(IRMOF-10\u548cbio-MOF-100)\u7528\u4e8e\u4e09\u4ef7\u91d1\u7684\u50ac\u5316\u5242\u7684\u7ed3\u6784\u7a33\u5b9a\u5316\u3002\u5229\u7528\u8fd9\u4e9b\u6750\u6599\u7684\u56fa\u6709\u521a\u6027\u6765\u6392\u9664\u5355\u5206\u5b50\u5206\u89e3\u9014\u5f84-\u8fd8\u539f\u6d88\u9664\u3002\u901a\u8fc7\u8fd9\u79cd\u7ed3\u6784\u7a33\u5b9a\u5316\u7b56\u7565\uff0c\u91d1(III)\u50ac\u5316\u5242\u5728\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e2d\u7684\u5206\u89e3\u8fc7\u7a0b\u6ca1\u6709\u89c2\u5bdf\u5230\u3002\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u5728\u8fd9\u4e9b\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u9632\u6b62\u6d78\u51fa\u548c\u4f7f\u53ef\u56de\u6536\u6027\uff0c\u8fd9\u662f\u751f\u4ea7\u591a\u76f8\u50ac\u5316\u7684\u5173\u952e\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cArchitectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Chem\u4e0a\u3002<\/p>\n<p>DOI: 10.1016\/j.chempr.2019.10.022<\/p>\n<p>\u56fe4\u00a0IPrAu(III)Cl-IRMOF-10\u548cIPrAu(III)Cl-bio-MOF\u7684\u7ed3\u6784<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210289 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/4-6.png\" alt=\"\" width=\"600\" height=\"549\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/4-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/4-6-300x275.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>M<\/b><\/strong><strong><b>atter\uff1a<\/b><\/strong><strong><b>\u8d85\u758f\u6c34\u6027<\/b><\/strong><strong><b>\u5f15\u5165<\/b><\/strong><strong><b>\u5230\u4ecb\u5b54<\/b><\/strong><strong><b>M<\/b><\/strong><strong><b>OF\u4e2d\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565<\/b><\/strong><\/p>\n<p>\u8bbe\u8ba1\u5177\u6709\u8868\u9762\u8d85\u758f\u6c34\u6027\u3001\u9ad8\u8868\u9762\u79ef\u3001\u5927\u800c\u5747\u5300\u7684\u5b54\u5f84\u4ee5\u53ca\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u7684\u6750\u6599\u662f\u5408\u6210\u5316\u5b66\u5bb6\u6240\u9762\u4e34\u7684\u4e00\u4e2a\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u7684\u9886\u57df\u3002\u5728\u6b64\uff0c\u5fb7\u514b\u8428\u65afA&amp;M\u5927\u5b66\u7684\u5468\u5b8f\u624d\u6559\u6388\u7b49\u4eba\u5c55\u793a\u4e86\u4e00\u79cd\u751f\u7269\u542f\u53d1\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565\uff0c\u901a\u8fc7\u9009\u62e9\u6027\u5730\u4fee\u9970\u5185\u90e8\u6676\u683c\u91cd\u6392\u7684\u4ecb\u5b54\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u7684\u5916\u8868\u9762\u6765\u6784\u5efa\u8d85\u758f\u6c34\u4ecb\u5b54MOF\u3002\u7f3a\u9677\u591a\u5b54\u6750\u6599AlTz-53\u7684\u8868\u9762\u901a\u8fc7\u758f\u6c34\u70f7\u57fa\u94fe\u7684\u70b9\u51fb\u53cd\u5e94\u8fdb\u884c\u4e86\u521d\u6b65\u6539\u6027\uff0c\u968f\u540e\uff0c\u5185\u90e8\u6846\u67b6\u5728\u6eb6\u5242\u89e3\u5438\u4f5c\u7528\u4e0b\u8fdb\u884c\u6676\u683c\u91cd\u6392\uff0c\u5bfc\u81f4\u5185\u90e8\u5b54\u9699\u7387\u548c\u6750\u6599\u7ed3\u6676\u5ea6\u663e\u8457\u63d0\u9ad8\u3002\u529f\u80fd\u5316\u540e\u7684AlTz-68\u8868\u9762\u5177\u6709\u8d85\u758f\u6c34\u6027\uff0c\u6c34\u63a5\u89e6\u89d2\u4e3a173.6\u00ba\u3002AlTz-68-C18\u662f\u5728\u76ee\u524d\u6240\u6709\u62a5\u9053\u7684\u8d85\u758f\u6c34\u9aa8\u67b6\u6750\u6599\u4e2d\uff0c\u8868\u73b0\u51fa\u6700\u5927\u7684BET\u8868\u9762\u79ef\u4e4b\u4e00\u7684\u6750\u6599\u3002\u6b64\u5916\uff0c\u8bc1\u660e\u4e86\u8d85\u758f\u6c34\u7684AlTz-68-C18\u548c\u76f8\u5e94\u7684\u6539\u6027\u6d77\u7ef5\u5728\u6cb9\u6c34\u5206\u79bb\u65b9\u9762\u90fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6027\u80fd\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cAn Encapsulation-Rearrangement Strategy to Integrate\u00a0Superhydrophobicity into Mesoporous Metal-Organic Frameworks\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Matter\u4e0a\u3002<\/p>\n<p>DOI:\u00a010.1016\/j.matt.2020.01.015<\/p>\n<p>\u56fe5\u8d85\u758f\u6c34MOF\u7684\u5c01\u88c5\u91cd\u6392\u7b56\u7565<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210290 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/5-7.png\" alt=\"\" width=\"600\" height=\"599\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/5-7.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/5-7-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/5-7-300x300.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>Nature Chemistry\uff1a\u5feb\u901f\u53bb\u6eb6\u5242\u5316\u89e6\u53d1MOFs\u591a\u7c73\u8bfa\u578b\u6676\u683c\u91cd\u6392<\/b><\/strong><\/p>\n<p>MOFs\u6750\u6599\u5728\u5b8c\u5168\u4e0d\u540c\u7684\u76f8\u4e4b\u95f4\u8fdb\u884c\u62d3\u6251\u8f6c\u6362\u901a\u5e38\u9700\u8981\u82db\u523b\u7684\u6761\u4ef6\uff0c\u4ee5\u7834\u574f\u5316\u5b66\u952e\u5e76\u901a\u8fc7\u6539\u53d8\u5176\u76f8\u5173\u7684\u952e\u5408\u73af\u5883\u6765\u514b\u670d\u5bf9\u539f\u59cb\u7ed3\u6784\u9020\u6210\u7684\u5e94\u529b\u3002\u5728\u672c\u5de5\u4f5c\u4e2d\uff0c\u5468\u5b8f\u624d\u6559\u6388\u7b49\u591a\u56e2\u961f\u5408\u4f5c\u63d0\u51fa\u4e86\u4e00\u4e2a\u6848\u4f8b\u7cfb\u7edf\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5feb\u901f\u91cd\u6392\u6574\u4e2aMOF\u901a\u8fc7\u591a\u7c73\u8bfa\u9aa8\u578b\u6539\u53d8\u952e\u8fde\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u3002\u5728\u6d3b\u5316(\u6eb6\u5242\u4ea4\u6362\u548c\u8131\u6eb6\u5242\u4f5c\u7528)\u540e\u768440 s\u5185\uff0c\u8be5\u4f53\u7cfb\u4ece\u4f4e\u5b54\u9699\u7387\u7684\u65e0\u5e8f\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6\u8f6c\u53d8\u4e3a\u9ad8\u5b54\u9699\u548c\u7ed3\u6676\u7684\u5f02\u6784\u4f53\uff0c\u5bfc\u81f4\u8868\u9762\u79ef\u4ece725\u52302749 m<sup>2<\/sup>\u00a0g<sup>-1<\/sup>\u7684\u5927\u5e45\u589e\u52a0\u3002\u5149\u8c31\u6d4b\u91cf\u8868\u660e\uff0c\u8fd9\u79cd\u53cd\u76f4\u89c9\u7684\u70b9\u9635\u91cd\u6392\u6d89\u53ca\u5230\u4e00\u79cd\u4e9a\u7a33\u6001\u4e2d\u95f4\u7269\uff0c\u8fd9\u79cd\u4e9a\u7a33\u6001\u4e2d\u95f4\u7269\u662f\u6eb6\u5242\u5728\u4e0d\u9971\u548c\u91d1\u5c5e\u7684\u914d\u4f4d\u4f4d\u70b9\u4e0a\u53bb\u9664\u7684\u7ed3\u679c\u3002\u8fd9\u79cd\u5728\u4e24\u4e2a\u62d3\u6251\u4e0d\u540c\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u4e4b\u95f4\u7684\u65e0\u5e8f\u6676\u4f53\u8f6c\u6362\u88ab\u8bc1\u660e\u5728\u6781\u6027\u6eb6\u5242\u7684\u6d3b\u5316\u548c\u518d\u6d78\u56db\u4e2a\u5faa\u73af\u4e2d\u662f\u53ef\u9006\u7684\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cRapid desolvation-triggered domino lattice rearrangement in a metal\u2013organic framework\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728Nature\u00a0Chemistry\u4e0a\u3002<\/p>\n<p>DOI: 10.1038\/s41557-019-0364-0<\/p>\n<p>\u56fe6\u00a0\u6676\u683c\u5728Al-MOF\u4e2d\u91cd\u6392<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210291 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/6-4.png\" alt=\"\" width=\"600\" height=\"465\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/6-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/6-4-300x233.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>A<\/b><\/strong><strong><b>CS C<\/b><\/strong><strong><b>ata<\/b><\/strong><strong><b>lysis<\/b><\/strong><strong><b>\uff1a\u6d1e\u5bdf\u954d\u57faM<\/b><\/strong><strong><b>OF\u7ed3\u6784<\/b><\/strong><strong><b>\u4e0e<\/b><\/strong><strong><b>\u6d3b<\/b><\/strong><strong><b>\u6027\u7684<\/b><\/strong><strong><b>\u5173\u7cfb<\/b><\/strong><strong><b>\u7528\u4e8e\u50ac\u5316<\/b><\/strong><strong><b>\u4e59\u70ef\u52a0\u6c22<\/b><\/strong><\/p>\n<p>\u56fa\u4f53\u8f7d\u4f53\u5728\u591a\u76f8\u50ac\u5316\u4e2d\u8d77\u7740\u4e0d\u53ef\u7f3a\u5c11\u7684\u4f5c\u7528\uff0c\u5b83\u76f4\u63a5\u5f71\u54cd\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5f88\u96be\u83b7\u5f97\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u7684\u7cbe\u786e\u7ed3\u6784\u4fe1\u606f\uff0c\u8fd9\u79cd\u8f7d\u4f53\u7684\u5177\u4f53\u4f5c\u7528\u4ecd\u6709\u5f85\u9610\u660e\u3002\u7f8e\u56fd\u897f\u5317\u5927\u5b66Omar K. Farha\u6559\u6388\u7b49\u4eba\u4e3a\u4e86\u4e86\u89e3MOF\u62d3\u6251\u7ed3\u6784\u3001\u5b54\u9699\u73af\u5883\u548c\u8282\u70b9\u8f7d\u4f53\u7684\u91d1\u5c5e\u7279\u6027\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u5f71\u54cd\uff0c\u4ee58\u8282\u70b9MOF(M-NU-1200, M-NU-1000, M-NU-1008, and M-NU-1010 (M = Zr, Hf))\u4e3a\u57fa\u7840\uff0c\u5c06Ni\u50ac\u5316\u5242\u8d1f\u8f7d\u5728Zr-\u6216Hf-MOFs\u4e0a\u3002\u91c7\u7528SCXRD\u3001DRIFTS\u548cXPS\u5bf9\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u7ed3\u6784\u8fdb\u884c\u4e86\u8868\u5f81\u3002\u4ee5\u4e59\u70ef\u52a0\u6c22\u53cd\u5e94\u4e3a\u6a21\u62df\u53cd\u5e94\uff0c\u8003\u5bdf\u4e86\u8f7d\u4f53\u5bf9\u8d1f\u8f7d\u954d\u50ac\u5316\u5242\u6d3b\u6027\u7684\u5f71\u54cd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6240\u6709\u7684Hf -MOF\u8d1f\u8f7d\u7684Ni\u50ac\u5316\u5242\u90fd\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5176\u5468\u8f6c\u7387\uff08TOFs\uff09\u81f3\u5c11\u662f\u540c\u7ed3\u6784Zr\u50ac\u5316\u5242\u7684\u4e24\u500d\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u62d3\u6251\u7ed3\u6784\u548c\u5468\u56f4\u7684\u5b54\u9699\u73af\u5883\uff0c\u91d1\u5c5e\u951a\u70b9\u8f83\u5c11\u7684MOFs\u4ea7\u751f\u8f83\u9ad8\u7684TOFs\uff0c\u8fd9\u8868\u660e\u8f7d\u4f53\u5728\u51b3\u5b9a\u50ac\u5316\u5242\u53ef\u53ca\u6027\u548c\u6d3b\u6027\u65b9\u9762\u7684\u91cd\u8981\u6027\u3002\u8ba1\u7b97\u5206\u6790\u8865\u5145\u4e86\u5b9e\u9a8c\u89c2\u5bdf\uff0c\u5e76\u63d0\u4f9b\u4e86\u6d1e\u5bdf\u53cd\u5e94\u52bf\u5792\u5dee\u5f02\u548c\u4ed6\u4eec\u7684\u6027\u80fd\u53d8\u5316\u3002\u672c\u7814\u7a76\u8bc1\u660e\u4e86\u8f7d\u4f53\u7684\u91cd\u8981\u4f5c\u7528\uff0c\u5e76\u4e3a\u591a\u76f8\u50ac\u5316\u4e2d\u9009\u62e9\/\u8bbe\u8ba1\u5408\u9002\u7684\u8f7d\u4f53\u63d0\u4f9b\u4e86\u601d\u8def\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cInsights into the Structure-Activity Relationships in Metal-Organic Framework-Supported Nickel Catalysts for Ethylene Hydrogenation\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Catalysis\u4e0a\u3002<\/p>\n<p>DOI: 10.1021\/acscatal.0c01844<\/p>\n<p>\u56fe7\u00a0\u4e59\u70ef\u52a0\u6c22\u6027\u80fd\u6bd4\u8f83<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210292 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/7-4.png\" alt=\"\" width=\"600\" height=\"482\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/7-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/7-4-300x241.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>ACS Appl. Mater. Interfaces<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><strong><b>\u9506<\/b><\/strong><strong><b>\u57faM<\/b><\/strong><strong><b>OF<\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u50ac\u5316\u6c34\u89e3\u6709\u673a\u78f7\u795e\u7ecf\u6bd2\u5242<\/b><\/strong><\/p>\n<p>\u6709\u673a\u78f7\u795e\u7ecf\u6bd2\u5242\u662f\u4eba\u7c7b\u5df2\u77e5\u7684\u6700\u5177\u6bd2\u6027\u7684\u5316\u5b66\u7269\u8d28\u4e4b\u4e00\uff0c\u5c3d\u7ba1\u56fd\u9645\u4e0a\u7981\u6b62\u4f7f\u7528\uff0c\u4f46\u7531\u4e8e\u8fd1\u671f\u7684\u4e0d\u65ad\u4f7f\u7528\uff0c\u8feb\u5207\u9700\u8981\u5f00\u53d1\u80fd\u6709\u6548\u964d\u89e3\u8fd9\u4e9b\u795e\u7ecf\u6bd2\u5242\u7684\u6750\u6599\u3002\u5728\u8fc7\u53bb\u7684\u5341\u5e74\u91cc\uff0c\u4ee5\u9506\u4e3a\u57fa\u7840\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6(Zr-MOFs)\u4f5c\u4e3a\u4e00\u79cd\u751f\u7269\u542f\u53d1\u7c7b\u6750\u6599\u51fa\u73b0\uff0c\u80fd\u591f\u5feb\u901f\u6c34\u89e3\u8fd9\u4e9b\u5316\u5408\u7269\uff0c\u5e76\u663e\u8457\u964d\u4f4e\u5176\u6bd2\u6027\u3002\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7684\u6d1e\u5bdf\u529b\u6307\u5bfc\u4e86Zr-MOFs\u7684\u8bbe\u8ba1\uff0c\u5bfc\u81f4\u4e86\u80fd\u591f\u89e3\u6bd2\u795e\u7ecf\u6bd2\u5242\u548c\u6a21\u62df\u7269\u7684\u50ac\u5316\u5242\u7684\u53d1\u5c55\uff0c\u8fd9\u4e9b\u5316\u5b66\u7269\u8d28\u5177\u6709\u7c7b\u4f3c\u7684\u529f\u80fd\uff0c\u4f46\u6bd2\u6027\u66f4\u4f4e\uff0c\u53ef\u4ee5\u5728\u51e0\u79d2\u949f\u5185\u5728\u57fa\u672c\u7684\u6c34\u6eb6\u6db2\u4e2d\u6c34\u89e3\u3002\u867d\u7136\u5176\u5728\u9500\u6bc1\u5e93\u5b58\u6750\u6599\u65b9\u9762\u662f\u53ef\u4ee5\u63a5\u53d7\u7684\uff0c\u5c06\u8fd9\u79cd\u50ac\u5316\u6027\u80fd\u8f6c\u5316\u4e3a\u53ef\u7528\u4e8e\u53e3\u7f69\u6216\u9632\u62a4\u670d\u7684Zr-MOFs\u8fc7\u6ee4\u5668\u5e76\u975e\u6613\u4e8b\u3002\u56e0\u6b64\uff0c\u6700\u8fd1\u7684\u7814\u7a76\u91cd\u70b9\u662f\u5c06\u8fd9\u4e9b\u6c34\u89e3\u50ac\u5316\u5242\u96c6\u6210\u5230\u9632\u62a4\u670d\u88c5\u548c\u88c5\u5907\u4e2d\uff0c\u540c\u65f6\u4fdd\u6301\u57fa\u4e8e\u6eb6\u6db2\u7684\u50ac\u5316\u7cfb\u7edf\u7684\u6027\u80fd\u3002\u7f8e\u56fd\u897f\u5317\u5927\u5b66Omar K. Farha\u6559\u6388\u7b49\u4eba\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6982\u8ff0\u7684\u53d1\u5c55Zr-MOFs\u50ac\u5316\u6c34\u89e3\u6709\u673a\u78f7\u57fa\u677f\uff0c\u5305\u62ec\u8bbe\u8ba1\u539f\u5219\u548c\u673a\u68b0\u89c1\u89e3\u7684\u89e3\u51b3\u65b9\u6848\u4e3a\u57fa\u7840\u548c\u7ec7\u7269\u6d82\u5c42\u7cfb\u7edf\u3002\u6700\u540e\uff0c\u5f3a\u8c03\u4e86\u5c1a\u5f85\u89e3\u51b3\u7684\u6311\u6218\uff0c\u5e76\u5bf9\u8be5\u9886\u57df\u7684\u672a\u6765\u65b9\u5411\u63d0\u4f9b\u4e86\u5c55\u671b\u3002\u76f8\u5173\u7814\u7a76\u4ee5\u201cZirconium-Based Metal-Organic Frameworks for the Catalytic Hydrolysis of Organophosphorus Nerve Agents\u201d\u4e3a\u9898\u76ee\uff0c\u53d1\u8868\u5728ACS Appl. Mater. Interfaces\u4e0a\u3002<\/p>\n<p>DOI: 10.1021\/acsami.9b20154<\/p>\n<p>\u56fe8\u00a0\u6c34\u89e3\u50ac\u5316\u5242\u96c6\u6210\u7ec7\u7269\u793a\u610f\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-210293 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/8-4.png\" alt=\"\" width=\"432\" height=\"242\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/8-4.png 432w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/8-4-300x168.png 300w\" sizes=\"(max-width: 432px) 100vw, 432px\" \/><\/p>\n<p>\u6587\u4e2d\u5982\u6709\u4e0d\u59a5\u4e4b\u5904\uff0c\u6b22\u8fce\u8bc4\u8bba\u533a\u7559\u8a00~<\/p>\n<p>\u672c\u6587\u7531Junas\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f5c\u4e3a\u8fd1\u5e74\u6765\u6700\u5177\u6709\u7814\u7a76\u4ef7\u503c\u7684\u70ed\u95e8\u6750\u6599\u4e4b\u4e00\uff0cMOF\u53ef\u8c13\u662f\u62a2\u5c3d\u98ce\u5934\u3002\u65e0\u8bba\u662f\u5206\u79bb\u3001\u5438\u9644\uff0c\u8fd8\u662f\u50ac\u5316\u3001\u7535\u6c60\u3001\u751f\u7269\u533b\u836f\u7b49\u7b49\u9886\u57df\uff0cMOF\u51e0\u4e4e\u65e0\u5904\u4e0d\u5728\uff0c\u65e0\u5b54\u4e0d\u5165\u3002\u672c\u6587\u7279\u522b\u4e3a\u5927\u5bb6\u4ecb&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":210294,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-210285","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210285"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=210285"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210285\/revisions"}],"predecessor-version":[{"id":210345,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/210285\/revisions\/210345"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/210294"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=210285"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=210285"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=210285"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}