{"id":210245,"date":"2020-10-16T12:00:29","date_gmt":"2020-10-16T04:00:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=210245"},"modified":"2020-10-16T10:33:39","modified_gmt":"2020-10-16T02:33:39","slug":"%e3%80%90%e5%b7%b2%e6%a0%a1%e7%a8%bf%e3%80%91%e5%bc%a0%e4%b9%83%e5%ba%86%e5%ad%99%e5%85%8b%e5%ae%81adv-mater-%e6%b0%b4%e5%90%88%e4%ba%8c%e6%b0%a7%e5%8c%96%e4%ba%8c%e9%92%92%e6%8f%92%e5%b1%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=210245","title":{"rendered":"\u5f20\u4e43\u5e86&\u5b59\u514b\u5b81Adv. Mater.: \u6c34\u5408\u4e8c\u6c27\u5316\u4e8c\u9492\u63d2\u5c42\u8d5d\u7535\u5bb9Zn2+\u5b58\u50a8\u5b9e\u73b0\u8d85\u9ad8\u500d\u7387\u6027\u80fd"},"content":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u5f20\u4e43\u5e86\u6559\u6388\u4e0e\u5b59\u514b\u5b81\u6559\u6388<\/strong>\u8054\u5408\u63d0\u51fa\u4e86\u4e00\u79cd\u5177\u6709\u4e2d\u7b49\u4f20\u8f93\u9014\u5f84\u7684\u6c34\u5408\u4e8c\u6c27\u5316\u9492\u7eb3\u7c73\u5e26\uff08HVO\uff09\u7684\u5236\u5907\u65b9\u6cd5\u3002\u4e0e\u4f17\u4e0d\u540c\u7684\u662f\uff0c\u53d1\u73b0\u4e86HVO\u7684\u63d2\u5c42\u8d5d\u7535\u5bb9\u53cd\u5e94\u673a\u7406\uff0c\u4e0e\u7535\u6c60\u578b\u63d2\u5c42\u53cd\u5e94\u76f8\u6bd4\uff0cHVO\u5177\u6709\u9ad8\u500d\u7387\u7684\u5bb9\u6027\u7535\u8377\u5b58\u50a8\u80fd\u529b\u3002\u4e3b\u8981\u539f\u56e0\u662f\u6709\u7f3a\u9677\u7684\u6676\u4f53\u7ed3\u6784\u4e3a\u9633\u79bb\u5b50\u7684\u5feb\u901f\u8fc1\u79fb\u63d0\u4f9b\u4e86\u5408\u9002\u7684\u73af\u5883\u95f4\u8ddd\u3002\u56e0\u6b64\uff0cHVO\u63d0\u4f9b\u4e86\u5feb\u901f\u7684Zn2+<\/sup>\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u548c\u4f4e\u7684Zn2+<\/sup>\u6269\u6563\u52bf\u5792\u3002\u63d2\u5c42\u8d5d\u7535\u5bb9\u7684\u7535\u5316\u5b66\u7ed3\u679c\u8868\u660e\uff0c\u57280.05 A g-1<\/sup>\u4e0b\u5177\u6709396 mAh g-1<\/sup>\u7684\u9ad8\u53ef\u9006\u5bb9\u91cf\uff0c\u572850 A g-1<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u751a\u81f3\u53ef\u4ee5\u7ef4\u630188 mAh g-1<\/sup>\u3002\u8be5\u6587\u7ae0\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201cIntercalation Pseudocapacitive Zn2+<\/sup> Storage with Hydrated Vanadium Dioxide toward Ultrahigh Rate Performance<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdv. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u5236\u5907\u7684<\/strong>HVO<\/strong>\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09HVO\u7684SEM\u56fe\u50cf\uff0cTEM\u56fe\u50cf\u548cHR-TEM\u56fe\u50cf\u3002<\/p>\n

\uff08d\uff09HVO\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\uff08e-f\uff09VO\u548cHVO\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

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\uff08i\uff09HVO\u7684TGA\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e8c\u3001\u7535\u5316\u5b66\u6027\u80fd\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09HVO\u7535\u6781\u57280.1 mV s-1<\/sup>\u65f6\u7684CV\u66f2\u7ebf\u3002<\/p>\n

\uff08b-c\uff09\u4e0d\u540c\u5faa\u73af\u6570\u4e0b\u7684\u6052\u7535\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u53ca\u76f8\u5e94HVO\u548cVO\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\uff08d\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a0.05~50 A g-1<\/sup>\u7684HVO\u548cVO\u9634\u6781\u7684\u500d\u7387\u6d4b\u8bd5\u3002<\/p>\n

\uff08e\uff09\u4e0e\u5176\u4ed6\u9634\u6781\u6750\u6599\u76f8\u6bd4\u7684Ragone\u56fe\u3002<\/p>\n

\uff08f\uff0910 A g-1<\/sup>\u7684\u957f\u5bff\u547d\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe\u4e09\u3001\u7535\u5316\u5b66\u52a8\u529b\u5b66\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff09\u57281.0 mV s-1<\/sup>\u65f6\u7684\u7535\u5bb9\u8d21\u732e\u3002<\/p>\n

\uff08c\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7535\u5bb9\u548c\u6269\u6563\u8d21\u732e\u7684\u767e\u5206\u6bd4\u3002<\/p>\n

\uff08d\uff09\u7535\u6d41\u548c\u626b\u63cf\u901f\u7387\u4e3a1-200 mV s-1<\/sup>\u7684\u5bf9\u6570\u5173\u7cfb\u3002<\/p>\n

\uff08e\uff09\u57281-200 mV s-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u5f52\u4e00\u5316\u5bb9\u91cf\u4e0ev-1\/2<\/sup>\u66f2\u7ebf\u7684\u5173\u7cfb\u3002<\/p>\n

\uff08f\uff09\u9634\u6781\u5cf0\u7535\u4f4d\u7684\u53d8\u5316\u4e0e\u626b\u63cf\u901f\u7387\u7684\u5173\u7cfb\u3002<\/p>\n

\u56fe\u56db\u3001\u79bb\u5b50\u6269\u6563\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-b\uff09\u7528GITT\u6d4b\u8bd5\u4e86HVO\u9634\u6781\u7684\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\uff08c\uff09\u76f8\u5e94\u7684\u6269\u6563\u80fd\u5792\u66f2\u7ebf\u3002<\/p>\n

\uff08d-g\uff09Zn\u79bb\u5b50\u6269\u6563\u7684\u8fc1\u79fb\u8def\u5f84\u3002<\/p>\n

\uff08h-k\uff09\u5dee\u7535\u8377\u5bc6\u5ea6\u8ba1\u7b97\u3002<\/p>\n

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\"\"<\/p>\n

\uff08a-c\uff09\u5728\u5404\u79cd\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0b\u7684\u7b2c\u4e00\u4e2a\u5faa\u73af\u4e2d\uff0cHVO\u9634\u6781\u7684XRD\u5206\u6790\u3002<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aIntercalation Pseudocapacitive Zn2+<\/sup> Storage with Hydrated Vanadium Dioxide toward Ultrahigh Rate Performance<\/a> (Adv. Mater.<\/em>, 2020<\/strong>, DOI: 10.1002\/adma.201908420)<\/p>\n

\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n

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