{"id":209987,"date":"2020-10-01T06:55:32","date_gmt":"2020-09-30T22:55:32","guid":{"rendered":"\/\/m.iemloyee.com\/?p=209987"},"modified":"2020-09-30T21:55:44","modified_gmt":"2020-09-30T13:55:44","slug":"%e8%b7%9f%e7%9d%80%e9%a1%b6%e5%88%8a%e5%ad%a6%e6%b5%8b%e8%af%95%ef%bd%9crobert-j-messinger%e6%95%99%e6%8e%88acs-energy-lett%ef%bc%9a%e5%9b%ba%e6%80%81%e6%a0%b8%e7%a3%81%e6%8a%80%e6%9c%af%e5%9c%a8","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=209987","title":{"rendered":"\u8ddf\u7740\u9876\u520a\u5b66\u6d4b\u8bd5\uff5cRobert J. Messinger\u6559\u6388ACS Energy Lett\uff1a\u56fa\u6001\u6838\u78c1\u6280\u672f\u5728\u94dd\u79bb\u5b50\u5d4c\u5165\u6676\u4f53\u7535\u6781\u4e0a\u7684\u91cf\u5316\u7814\u7a76"},"content":{"rendered":"<p>\u56fa\u6001\u6838\u78c1\u5171\u632f(NMR)\u5149\u8c31\u4f7f\u7535\u6c60\u7814\u7a76\u4eba\u5458\u80fd\u591f\u6709\u9009\u62e9\u6027\u5730\u63a2\u6d4b\u63d2\u5c42\u79bb\u5b50\u672c\u8eab\uff0c\u4f8b\u5982\u8bc6\u522b\u4e0e\u63d2\u5c42\u4f4d\u7f6e\u76f8\u5173\u7684\u72ec\u7279\u7684\u5c40\u90e8\u7535\u5b50\u548c\u78c1\u73af\u5883\uff0c\u7814\u7a76\u5b83\u4eec\u7684\u52a8\u529b\u5b66\uff0c\u5e76\u91cf\u5316\u5b83\u4eec\u7684\u6570\u91cf\uff0c\u56fa\u6001\u6838\u78c1\u5171\u632f\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7814\u7a76\u9502\u79bb\u5b50\u5d4c\u5165\u7535\u6c60\u7535\u6781\u3002\u4f46\u5e38\u89c1\u7684\u591a\u4ef7\u79bb\u5b50\u5982Mg<sup>2+<\/sup>\u3001Ca<sup>2+<\/sup>\u548cZn<sup>2+<\/sup>\u7531\u4e8e\u5176\u4f4e\u65cb\u78c1\u6bd4\u548c\u5929\u7136\u4e30\u5ea6\u800c\u4e0d\u654f\u611f\uff0c\u56e0\u6b64\u5bf9\u5b83\u4eec\u7684NMR\u6d3b\u6027\u6838\uff08<sup>25<\/sup>Mg\u3001<sup>43<\/sup>Ca\u548c<sup>67<\/sup>Zn\uff09\u7684\u7814\u7a76\u5177\u6709\u6311\u6218\u6027\u3002\u503c\u5f97\u6ce8\u610f\u7684\uff0c\u5c3d\u7ba1\u6709\u5927\u91cf\u5173\u4e8e\u9541\u79bb\u5b50\u5d4c\u5165Mo<sub>6<\/sub>S<sub>8<\/sub>\u7684\u6587\u732e\uff0c\u4f46\u8fd8\u6ca1\u6709\u7528\u56fa\u6001<sup>25<\/sup>Mg-NMR\u5bf9\u5176\u8fdb\u884c\u7814\u7a76\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c<sup>27<\/sup>Al\u539f\u5b50\u6838\u7531\u4e8e\u5176\u9ad8\u81ea\u7136\u4e30\u5ea6\uff08100%\uff09\u548c\u65cb\u78c1\u6bd4\uff08\u7c7b\u4f3c\u4e8e<sup>13<\/sup>C\uff09\u800c\u654f\u611f\u3002\u56e0\u6b64\uff0c\u56fa\u6001<sup>27<\/sup>Al-NMR\u8c31\u6709\u671b\u6210\u4e3a\u7814\u7a76\u94dd\u79bb\u5b50\u5d4c\u5165\u7535\u6c60\u7535\u6781\u7684\u6709\u529b\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-209988 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72474-19.png\" alt=\"\" width=\"600\" height=\"199\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72474-19.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72474-19-300x100.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8fd1\u65e5\uff0c\u7ebd\u7ea6\u5e02\u7acb\u5927\u5b66<strong><b>Robert J. Messinger<\/b><\/strong>\u6559\u6388\u56e2\u961f\u5408\u4f5c\u4ee5\u201cQuantitative Molecular-Level Understanding of Electrochemical Aluminum-Ion Intercalation into a Crystalline Battery Electrode\u201d\u4e3a\u9898\u5728<em><i>ACS Energy Lett.<\/i><\/em>\u671f\u520a\u4e0a\u53d1\u8868\u91cd\u8981\u7814\u7a76\u6210\u679c\u3002\u8be5\u56e2\u961f\u62a5\u9053\u4e86\u4ee5\u8c22\u5f17\u96f7\u5c14\u76f8Mo<sub>6<\/sub>S<sub>8<\/sub>\u4e3a\u6a21\u578b\u6676\u4f53\u7535\u6781\u6750\u6599\uff0c\u91c7\u7528\u7535\u5316\u5b66\u548c\u56fa\u6001NMR\u65b9\u6cd5\uff0c\u4ece\u5206\u5b50\u6c34\u5e73\u4e0a\u5b9a\u91cf\u5730\u89e3\u91ca\u4e86\u94dd\u79bb\u5b50\u7684\u63d2\u5c42\u673a\u7406\u3002\u4e0e\u4e8c\u4ef7Mg<sup>2+<\/sup>\u79bb\u5b50\u4e0d\u540c\uff0c\u4e09\u4ef7Al<sup>3+<\/sup>\u79bb\u5b50\u5728\u4e0d\u540c\u7684\u6052\u6d41\u653e\u7535\u5e73\u53f0\u4e0a\u540c\u65f6\u63d2\u5165\u4e24\u4e2a\u7a7a\u8154\uff0c\u800c\u4e0d\u662f\u987a\u5e8f\u63d2\u5165\u3002\u8131\u5c42\u65f6\u53d1\u751f\u6700\u5c0f\u7684Al<sup>3+<\/sup>\u6355\u83b7\uff08&lt;7%\uff09\u3002\u540c\u65f6\u79bb\u5b50\u63d2\u5c42\u673a\u5236\u548c\u6162\u56fa\u76f8\u6269\u6563\u90fd\u53ef\u4ee5\u4eceAl<sup>3+<\/sup>\u79bb\u5b50\u7684\u9ad8\u7535\u8377\u5bc6\u5ea6\u6765\u7406\u89e3\u3002\u4f5c\u8005\u8fd8\u53d1\u73b0\uff0c\u5728\u79bb\u5b50\u6db2\u4f53\u7535\u89e3\u8d28\u4e2d\uff0c\u94dd\u79bb\u5b50\u4ece\u5206\u5b50\u6c2f\u94dd\u9178\u76d0\u9634\u79bb\u5b50\u8131\u6eb6\u65f6\uff0c\u4f1a\u5f62\u6210\u975e\u6676\u6001\u7684\u8868\u9762\u5c42\u3002\u7814\u7a76\u7ed3\u679c\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u5bf9\u94dd\u79bb\u5b50\u5728\u6a21\u578b\u6676\u4f53\u7535\u6781\u6750\u6599\u4e2d\u7684\u5d4c\u5165\u884c\u4e3a\u8fdb\u884c\u4e86\u5b9a\u91cf\u7684\u5206\u5b50\u6c34\u5e73\u4e0a\u7684\u7406\u89e3\uff0c\u4e3a\u53ef\u5145\u5f0f\u94dd\u79bb\u5b50\u7535\u6c60\u7684\u8868\u5f81\u5960\u5b9a\u4e86\u575a\u5b9e\u7684\u57fa\u7840<\/p>\n<p>\u91c7\u7528\u6052\u7535\u6d41\u5faa\u73af\u6cd5\u3001\u5faa\u73af\u4f0f\u5b89\u6cd5\u548c\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6cd5\uff08GITT\uff09\u5bf9\u94dd\u79bb\u5b50\u63d2\u5c42\u8fc7\u7a0b\u8fdb\u884c\u4e86\u7535\u5316\u5b66\u8868\u5f81\u3002\u572810 mA\/g\u548c25\u00b0C\u621650\u00b0C\u4e0b\u8fdb\u884cAl-Mo<sub>6<\/sub>S<sub>8<\/sub>\u7535\u6c60\u7684\u6052\u6d41\u5faa\u73af\uff08\u56fe1a\uff09\u3002\u7b2c\u4e00\u6b21\u653e\u7535\u65f6\uff0c\u5728\u5f00\u8def\u7535\u4f4d\uff081.6 V\uff09\u548c0.6 V\u4e4b\u95f4\u89c2\u5bdf\u5230\u503e\u659c\u7684\u7535\u538b\u5206\u5e03\uff0c\u8fd9\u662f\u7531\u4e8e\u4e0d\u53ef\u9006\u7684\u7535\u89e3\u8d28\u5206\u89e3\u5bfc\u81f4\u4e0d\u53ef\u9006\u5bb9\u91cf\u3002\u5728\u968f\u540e\u768450\u00b0C\u4e0b\u5faa\u73af\u540e\uff0c\u5206\u522b\u57280.55 V\u548c0.38 V\u4e0b\u89c2\u5bdf\u5230\u4e24\u4e2a\u653e\u7535\u5e73\u53f0\uff0c\u603b\u5bb9\u91cf\u4e3a128 mAh\/g\u3002\u5b9e\u9a8c\u5bb9\u91cf\u4e0e\u7406\u8bba\u5bb9\u91cf128 mAh\/g\u975e\u5e38\u4e00\u81f4\uff0c\u8fd9\u662f\u7531\u4e8e\u6bcfMo<sub>6<\/sub>S<sub>8<\/sub>\u5355\u5143\u4f20\u8f934\u4e2a\u7535\u5b50\u9020\u6210\u7684\u3002<\/p>\n<p><strong><b>\u56fe1. <\/b><\/strong><strong><b>Al-Mo<\/b><\/strong><strong><sub><b>6<\/b><\/sub><\/strong><strong><b>S<\/b><\/strong><strong><sub><b>8<\/b><\/sub><\/strong><strong><b>\u7535\u6c60\u7684\u7535\u5316\u5b66\u5faa\u73af<\/b><\/strong><strong><b>\u3002<\/b><\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-209989 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72475-17.png\" alt=\"\" width=\"600\" height=\"511\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72475-17.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72475-17-300x256.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\u7406\u89e3\u7535\u5316\u5b66\u94dd\u79bb\u5b50\u5d4c\u5165\u8c22\u5f17\u96f7\u5c14\u76f8Mo<sub>6<\/sub>S<sub>8<\/sub>\u7684\u673a\u7406\uff0c\u5728\u4e24\u4e2a\u6052\u6d41\u653e\u7535\u5145\u7535\u5faa\u73af\u7684\u4e0d\u540c\u7535\u8377\u72b6\u6001\u4e0b\uff0c\u5728\u5faa\u73af\u7535\u6781\u4e0a\u8fdb\u884c\u4e86\u56fa\u6001<sup>27<\/sup>Al\u5355\u8109\u51b2\u5e7b\u89d2\u65cb\u8f6c\uff08MAS\uff09NMR\u6d4b\u91cf\uff08\u56fe2\uff09\u3002NMR\u5b9e\u9a8c\u662f\u5728\u5b9a\u91cf\u6761\u4ef6\u4e0b\u4f7f\u7528\uff08i\uff09\u77ed\u5c04\u9891\uff08rf\uff09\u8109\u51b2\uff08\u03c0\/12\uff09\u5728\u7ebf\u6027\u6fc0\u52b1\u4e0b\u8fdb\u884c\u7684\u56db\u6781\u6027<sup>27<\/sup>Al\u6838\u548c\uff08ii\uff09\u5faa\u73af\u5ef6\u8fdf\uff080.1s\uff09\uff0c\u4f7f\u5f97<sup>27<\/sup>Al\u6838\u81ea\u65cb\u5728\u6d4b\u91cf\u4e4b\u95f4\u653e\u677e\u5230\u70ed\u5e73\u8861\u3002\u7528\u65e0\u6c34\u7532\u9187\u6e05\u6d17\u5faa\u73af\u7535\u6781\u4ee5\u53bb\u9664\u7535\u89e3\u6db2\u548c\u8868\u9762\u7269\u8d28\uff0c\u572862 ppm\u548c38 ppm\u65f6\u5206\u522b\u663e\u793a\u4e86\u63d2\u5728\u7a7a\u81541\u548c\u7a7a\u81542\u5185\u7684\u94dd\u79bb\u5b50\u7684<sup>27<\/sup>Al\u4fe1\u53f7\u3002\u968f\u7740Al<sup>3+<\/sup>\u79bb\u5b50\u5728Mo<sub>6<\/sub>S<sub>8<\/sub>\u7ed3\u6784\u4e2d\u7684\u63d2\u5c42\u548c\u8131\u63d2\uff0c\u5b83\u4eec\u7684\u7edd\u5bf9\u548c\u76f8\u5bf9\u6570\u91cf\u90fd\u53d1\u751f\u4e86\u53d8\u5316\uff0c\u660e\u786e\u5730\u5efa\u7acb\u4e86Al<sup>3+<\/sup>\u63d2\u5c42\u3002\u5b83\u4eec\u7684<sup>27<\/sup>Al\u4f4d\u79fb\u4e0e\u56db\u9762\u4f53\u914d\u4f4d\u7684\u94dd\u73af\u5883\u4e00\u81f4\uff0c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86Al<sup>3+<\/sup>\u7684\u5d4c\u5165\u3002<\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>.<\/b><\/strong><strong><b>\u00a0\u4ece<\/b><\/strong><strong><b>Al-Mo<\/b><\/strong><strong><sub><b>6<\/b><\/sub><\/strong><strong><b>S<\/b><\/strong><strong><sub><b>8<\/b><\/sub><\/strong><strong><b>\u7535\u6c60\u7684chevrel\u7535\u6781\u572810 mA\/g\u548c50<\/b><\/strong><strong><b>\u2103<\/b><\/strong><strong><b>\u7684\u6052\u6d41\u5faa\u73af\u5230\u4e0d\u540c\u7684\u8377\u7535\u72b6\u6001(\u5de6)\u7684\u56fa\u6001<\/b><\/strong><strong><sup><b>27<\/b><\/sup><\/strong><strong><b>Al\u5355\u8109\u51b2\u6838\u78c1\u5171\u632f\u6ce2\u8c31(\u53f3)\uff0c\u572820 kHz MAS\u548c14.1 T\u7684\u6761\u4ef6\u4e0b\uff0c\u4f7f\u7528\u5c04\u9891\u8109\u51b2<\/b><\/strong><strong><b>\u03c0<\/b><\/strong><strong><b>\/12\u83b7\u5f97<\/b><\/strong><strong><b>\u7684<\/b><\/strong><strong><b>\u3002<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-209990 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72476-14.png\" alt=\"\" width=\"600\" height=\"533\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72476-14.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72476-14-300x267.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u4e3a\u4e86\u5b9a\u91cf\u5728\u6052\u7535\u6d41\u5faa\u73af\u8fc7\u7a0b\u4e2d\u94dd\u79bb\u5b50\u7684\u5d4c\u5165\u91cf\uff0c\u5bf9\u56fa\u6001<sup>27<\/sup>Al\u5355\u8109\u51b2MAS-NMR\u8c31\u8fdb\u884c\u4e86\u89e3\u5377\u79ef\uff0c\u5b83\u4eec\u7684\u6570\u91cf\u88ab\u4f5c\u4e3a\u7535\u8377\u72b6\u6001\u7684\u51fd\u6570\u6765\u8ffd\u8e2a\u3002\u4f8b\u5982\uff0c\u5728\u521d\u59cb\u5145\u7535\u671f\u95f4\u5faa\u73af\u5230\u4e09\u79cd\u4e0d\u540c\u7535\u8377\u72b6\u6001\u7684\u7535\u6781\u663e\u793a\u4e86\u89e3\u5377\u79ef\u7684<sup>27<\/sup>Al NMR\u8c31\uff08\u56fe3\uff09\u3002\u56e0\u6b64\uff0c\u5728\u6574\u4e2a\u63d2\u5c42\u8fc7\u7a0b\u4e2d\uff0c\u6bcf\u4e2a\u7a7a\u8154\u4e2d\u94dd\u79bb\u5b50\u7684\u76f8\u5bf9\u6570\u91cf\u7531\u5176\u76f8\u5bf9\u79ef\u5206<sup>27<\/sup>Al\u4fe1\u53f7\u5f3a\u5ea6\u83b7\u5f97\u3002\u6b64\u5916\uff0c\u4e0e\u5d4c\u5165\u94dd\u79bb\u5b50\u76f8\u5173\u7684\u7edd\u5bf9<sup>27<\/sup>Al\u4fe1\u53f7\u5f3a\u5ea6\uff08\u6309\u6837\u54c1\u8d28\u91cf\u7f29\u653e\uff09\u7528\u4e8e\u91cf\u5316Al<sub>x<\/sub>Mo<sub>6<\/sub>S<sub>8<\/sub>\u7535\u6781\u6210\u5206\uff0c\u5176\u4e2d<sup>27<\/sup>Al\u5f3a\u5ea6\u5728\u5b8c\u5168\u63d2\u5c42\u7684\u7535\u6781\u88ab\u6821\u51c6\u5230Al<sub>4\/3<\/sub>Mo<sub>6<\/sub>S<sub>8<\/sub>\u3002\u8fd9\u4e00\u7ed3\u679c\u8868\u660e\uff0c\u7edd\u5bf9\u6838\u78c1\u5171\u632f\u4fe1\u53f7\u5f3a\u5ea6\u53ef\u7528\u4e8e\u4f30\u8ba1\u5faa\u73af\u7535\u6c60\u7535\u6781\u5185\u79bb\u5b50\u63d2\u5c42\u7684\u603b\u4f53\u8303\u56f4\u3002\u56e0\u6b64\uff0c\u5177\u6709\u5df2\u77e5\u6210\u5206\u548c\u8d28\u91cf\u7684\u7535\u6781\u6837\u54c1\u53ef\u4ee5\u4f5c\u4e3a\u65cb\u8f6c\u8ba1\u6570\u5b9e\u9a8c\u7684\u5916\u90e8\u6807\u51c6\u3002\u5fc5\u987b\u786e\u4fdd\u6837\u672c\u4e4b\u95f4\u7684\u4e00\u81f4\u8c03\u4f18\u548c\u5339\u914d\u3002<\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u5728\u7b2c\u4e00\u6b21\u5145\u7535\u65f6\u83b7\u5f97<\/b><\/strong><strong><b>\u7684\u56fa\u76f8\u5b9a\u91cf\u89e3\u5377\u79ef<\/b><\/strong><strong><sup><b>27<\/b><\/sup><\/strong><strong><b>Al\u5355\u8109\u51b2\u6838\u78c1\u5171\u632f\u6ce2\u8c31<\/b><\/strong><strong><b>\u3002<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-209991 size-full\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72477-12.png\" alt=\"\" width=\"375\" height=\"550\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72477-12.png 375w, \/\/m.iemloyee.com\/wp-content\/uploads\/2020\/09\/\u56fe\u72477-12-205x300.png 205w\" sizes=\"(max-width: 375px) 100vw, 375px\" \/><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u9996\u6b21\u4ece\u5206\u5b50\u6c34\u5e73\u4e0a\u5b9a\u91cf\u5206\u6790\u4e86\u94dd\u79bb\u5b50\u5728\u6676\u4f53\u7535\u6c60\u7535\u6781\u8c22\u5f17\u96f7\u5c14\u76f8Mo<sub>6<\/sub>S<sub>8<\/sub>\u4e2d\u7684\u53ef\u9006\u7535\u5316\u5b66\u63d2\u5c42\u73b0\u8c61\u3002\u7535\u5316\u5b66\u3001XRD\u3001SEM\u548c\u56fa\u6001\u6838\u78c1\u5171\u632f\u6d4b\u91cf\u786e\u5b9a\u4e86\u9ad8\u5ea6\u53ef\u9006\u7684\u94dd\u79bb\u5b50\u5d4c\u5165\u8c22\u5f17\u96f7\u5c14\u76f8Mo<sub>6<\/sub>S<sub>8<\/sub>\u4e2d\u3002\u5b9a\u91cf\u56fa\u6001<sup>27<\/sup>Al\u5355\u8109\u51b2MAS\u6d4b\u91cf\u8868\u660e\uff0c\u94dd\u79bb\u5b50\u5728\u6bcf\u4e2a\u6052\u7535\u6d41\u653e\u7535\u5e73\u53f0\u671f\u95f4\u540c\u65f6\u63d2\u5165\u4e24\u4e2a\u4e0d\u540c\u7684\u7a7a\u8154\uff0c\u800c\u4e0d\u662f\u987a\u5e8f\u63d2\u5165\u3002\u540c\u65f6\uff0c\u63d2\u5c42\u88ab\u7535\u5316\u5b66\u4e0a\u5faa\u73af\u4f0f\u5b89\u4e2d\u51fa\u73b0\u7684\u989d\u5916\u7684\u8fd8\u539f\u5cf0\u6240\u8bc1\u5b9e\u3002\u5728\u8131\u5c42\u65f6\uff0c\u6355\u83b7\u7684Al<sup>3+<\/sup>\u79bb\u5b50\u7684\u6700\u5c0f\u6570\u91cf\u4ecd\u7136\u5b58\u5728(&lt;7%)\u3002\u56fa\u6001\u7f13\u6162\u7684\u79bb\u5b50\u6269\u6563\u548c\u540c\u6b65\u7684\u79bb\u5b50\u63d2\u5c42\u673a\u5236\u90fd\u53ef\u4ee5\u4ece\u4e09\u4ef7Al<sup>3+<\/sup>\u9633\u79bb\u5b50\u7684\u9ad8\u7535\u8377\u5bc6\u5ea6\u6765\u7406\u89e3:Al<sup>3+<\/sup>\u9633\u79bb\u5b50\u4e0e\u9634\u79bb\u5b50\u786b\u7cfb\u7ed3\u6784\u4e4b\u95f4\u7684\u5f3a\u9759\u7535\u5438\u5f15\u4f5c\u7528\u4f7f\u56fa\u6001\u6269\u6563\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u5316\u80fd\uff0c\u800c\u968f\u7740\u79bb\u5b50\u63d2\u5c42\u7a0b\u5ea6\u7684\u589e\u52a0\uff0c\u5206\u5b50\u4e0a\u8fd1\u4f3c\u7684Al<sup>3+<\/sup>\u79bb\u5b50\u4e4b\u95f4\u7684\u5f3a\u9759\u7535\u6392\u65a5\u4f5c\u7528\u4f7f\u5176\u5728\u7a7a\u8154\u95f4\u201c\u8df3\u8dc3\u201d\uff0c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u6269\u6563\u7684\u6d3b\u5316\u80fd\u3002\u603b\u7684\u6765\u8bf4\uff0c\u8fd9\u4e9b\u7ed3\u679c\u63ed\u793a\u4e86\u6a21\u578b\u7535\u6781\u7cfb\u7edf\u4e2d\u94dd\u79bb\u5b50\u63d2\u5c42\u8fc7\u7a0b\u7684\u5b9a\u91cf\u5206\u5b50\u6c34\u5e73\uff0c\u5e76\u5efa\u7acb\u4e86\u56fa\u6001<sup>27<\/sup>Al MAS NMR\u662f\u7814\u7a76\u53ef\u5145\u7535\u94dd\u79bb\u5b50\u7535\u6c60\u7684\u4e00\u79cd\u5f3a\u6709\u529b\u7684\u5206\u6790\u6280\u672f\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aQuantitative Molecular-Level Understanding of Electrochemical Aluminum-Ion Intercalation into a Crystalline Battery Electrode,\u00a0<strong><em><b><i>ACS Energy Lett. <\/i><\/b><\/em><\/strong>2020. DOI:\u00a010.1021\/acsenergylett.0c01138<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/pubs.acs.org\/doi\/10.1021\/acsenergylett.0c01138<\/p>\n<p>\u672c\u6587\u7531\u79d1\u7814\u767e\u6653\u751f\u4f9b\u7a3f\u3002<\/p>\n<p>\u672c\u5185\u5bb9\u4e3a\u4f5c\u8005\u72ec\u7acb\u89c2\u70b9\uff0c\u4e0d\u4ee3\u8868\u6750\u6599\u4eba\u7f51\u7acb\u573a\u3002<\/p>\n<p>\u672a\u7ecf\u5141\u8bb8\u4e0d\u5f97\u8f6c\u8f7d\uff0c\u6388\u6743\u4e8b\u5b9c\u8bf7\u8054\u7cfbkefu@cailiaoren.com\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u56fa\u6001\u6838\u78c1\u5171\u632f(NMR)\u5149\u8c31\u4f7f\u7535\u6c60\u7814\u7a76\u4eba\u5458\u80fd\u591f\u6709\u9009\u62e9\u6027\u5730\u63a2\u6d4b\u63d2\u5c42\u79bb\u5b50\u672c\u8eab\uff0c\u4f8b\u5982\u8bc6\u522b\u4e0e\u63d2\u5c42\u4f4d\u7f6e\u76f8\u5173\u7684\u72ec\u7279\u7684\u5c40\u90e8\u7535\u5b50\u548c\u78c1\u73af\u5883\uff0c\u7814\u7a76\u5b83\u4eec\u7684\u52a8\u529b\u5b66\uff0c\u5e76\u91cf\u5316\u5b83\u4eec\u7684\u6570\u91cf\uff0c\u56fa\u6001&#8230;<\/p>\n","protected":false},"author":11454,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1187],"tags":[],"class_list":["post-209987","post","type-post","status-publish","format-standard","hentry","category-zhuanlan"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/209987"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11454"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=209987"}],"version-history":[{"count":1,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/209987\/revisions"}],"predecessor-version":[{"id":209992,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/209987\/revisions\/209992"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=209987"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=209987"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=209987"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}