{"id":209808,"date":"2020-09-27T06:40:06","date_gmt":"2020-09-26T22:40:06","guid":{"rendered":"\/\/m.iemloyee.com\/?p=209808"},"modified":"2020-09-26T19:40:45","modified_gmt":"2020-09-26T11:40:45","slug":"%e5%8d%8e%e5%b7%a5adv-funct-mater-%ef%bc%9a%e5%85%b7%e6%9c%89%e9%95%bf%e6%9c%9f%e7%8e%af%e5%a2%83%e7%a8%b3%e5%ae%9a%e6%80%a7%e5%92%8c%e5%a4%9a%e5%8a%9f%e8%83%bd%e6%80%a7%e7%9a%84mxene%e5%9f%ba","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=209808","title":{"rendered":"\u534e\u5de5Adv. Funct. Mater.\uff1a\u5177\u6709\u957f\u671f\u73af\u5883\u7a33\u5b9a\u6027\u548c\u591a\u529f\u80fd\u6027\u7684MXene\u57fa\u5bfc\u7535\u6709\u673a\u6c34\u51dd\u80f6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/p>\n

\u4e00\u822c\u6765\u8bf4\uff0c\u6c34\u51dd\u80f6\u7684\u5bcc\u6c34\u7ed3\u6784\u4f7f\u5176\u8868\u73b0\u5f97\u50cf\u56fa\u4f53\u4e00\u6837\uff0c\u4f46\u4ecd\u80fd\u50cf\u6db2\u4f53\u4e00\u6837\u5b9e\u73b0\u5feb\u901f\u7535\u8377\u4f20\u8f93\u3002\u7136\u800c\uff0c\u4ee5\u7eaf\u6c34\u4f5c\u4e3a\u5206\u6563\u4ecb\u8d28\u7684\u5e38\u89c4\u5bfc\u7535\u6c34\u51dd\u80f6\u666e\u904d\u5b58\u5728\u7684\u4e24\u4e2a\u95ee\u9898\uff08\u4f4e\u6e29\u4e0b\u51bb\u7ed3\u548c\u5f00\u653e\u73af\u5883\u4e0b\u8131\u6c34\u5931\u6548\u95ee\u9898\uff09\uff0c\u6781\u5927\u5730\u9650\u5236\u4e86\u6c34\u51dd\u80f6\u7684\u64cd\u4f5c\u6e29\u5ea6\u8303\u56f4\uff0c\u5927\u5927\u7f29\u77ed\u4e86\u5ba4\u6e29\u4e0b\u6c34\u51dd\u80f6\u7684\u5bff\u547d\u3002\u56e0\u6b64\uff0c\u5728\u4fdd\u6301\u5e38\u89c4\u6c34\u51dd\u80f6\u4f18\u52bf\u7684\u540c\u65f6\uff0c\u5f00\u53d1\u5177\u6709\u957f\u671f\u73af\u5883\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u5bfc\u7535\u6c34\u51dd\u80f6\u662f\u975e\u5e38\u53ef\u53d6\u7684\u3002<\/p>\n

\u8fd1\u5e74\u6765\uff0c\u901a\u8fc7\u5f15\u5165\u8bf8\u5982\u4e59\u4e8c\u9187(EG)\u3001\u7518\u6cb9(Gly)\u7b49\u4f4e\u6325\u53d1\u6027\u51b7\u51bb\u4fdd\u62a4\u5242\uff0c\u663e\u8457\u6539\u5584\u4e86\u6c34\u51dd\u80f6\u7684\u9632\u51bb\u548c\u6297\u5e72\u71e5\u6027\u80fd\uff0c\u8fd9\u7c7b\u65b0\u578b\u6c34\u51dd\u80f6\u88ab\u79f0\u4e4b\u4e3a\u6709\u673a\u6c34\u51dd\u80f6\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u6709\u673a\u6c34\u51dd\u80f6\u7684\u73af\u5883\u7a33\u5b9a\u6027\u5f97\u5230\u4e86\u5f88\u5927\u7684\u6539\u5584\uff0c\u4f46\u7531\u4e8e\u542b\u6c34\u7387\u7684\u964d\u4f4e\uff0c\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7535\u5bfc\u7387\u4e5f\u968f\u4e4b\u964d\u4f4e\uff0c\u8fd9\u9650\u5236\u4e86\u6709\u673a\u6c34\u51dd\u80f6\u5728\u53ef\u7a7f\u6234\u5e94\u53d8\u4f20\u611f\u5668\u9886\u57df\u7684\u6f5c\u5728\u5e94\u7528\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u4e00\u79cd\u5178\u578b\u7684\u7b56\u7565\u662f\u901a\u8fc7\u5f15\u5165\u5bfc\u7535\u7ec4\u5206\u6765\u6784\u5efa\u590d\u5408\u51dd\u80f6\uff0c\u4f8b\u5982\u5bfc\u7535\u805a\u5408\u7269\u3001\u91d1\u5c5e\u79bb\u5b50\u3001\u6db2\u4f53\u91d1\u5c5e\u3001\u79bb\u5b50\u6db2\u4f53\u3001\u78b3\u7eb3\u7c73\u7ba1\u3001\u77f3\u58a8\u70ef\u3001PEDOT:PSS\u548cMXene\u7eb3\u7c73\u7247\u3002\u5176\u4e2d\uff0c\u7531\u4e8eMXene\u5177\u6709\u4f18\u826f\u7684\u5bfc\u7535\u6027\u3001\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3001\u4f18\u5f02\u7684\u4eb2\u6c34\u6027\u548c\u4f18\u5f02\u7684\u529b\u5b66\u6027\u80fd\uff0c\u5b83\u4eec\u5728\u5236\u5907\u5bfc\u7535\u6709\u673a\u6c34\u51dd\u80f6\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u7136\u800c\uff0c\u4f5c\u4e3a\u4e00\u79cd\u65b0\u5174\u7684\u5bfc\u7535\u6709\u673a\u6c34\u51dd\u80f6\uff0c\u5f53\u524d\u62a5\u9053\u7684MXene\u57fa\u6709\u673a\u6c34\u51dd\u80f6\u5927\u591a\u5173\u6ce8\u4e8e\u5728\u673a\u68b0\u6216\u7535\u6c14\u6027\u80fd\u65b9\u9762\u7684\u6539\u5584\uff0c\u800c\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u5ffd\u89c6\u4e86\u5bfc\u7535\u6709\u673a\u6c34\u51dd\u80f6\u7684\u5176\u4ed6\u5e94\u7528\u5c5e\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u7684\u9648\u6e2f\u6559\u6388\u548c\u51b5\u5b87\u8fea\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5728\u671f\u520aAdv. Funct. Mater.\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5f15\u5165\u5355\u5b81\u9178\u4fee\u9970\u7684\u7ea4\u7ef4\u7d20\u7eb3\u7c73\u7ea4\u7ef4(TA@CNF)\u548c\u5bfc\u7535\u7684MXene\u7eb3\u7c73\u7247\uff0c\u5230Gly\/\u6c34\u53cc\u7ec4\u5206\u6eb6\u5242\u6e17\u900f\u7684\u805a\u4e19\u70ef\u9170\u80fa(PAAm)\u5171\u4ef7\u4ea4\u8054\u7f51\u7edc\u4e2d\uff0c\u8fdb\u800c\u5236\u5907\u5f97\u5230\u5177\u6709\u4f18\u5f02\u7684\u73af\u5883\u7a33\u5b9a\u6027\u3001\u8d85\u5f3a\u62c9\u4f38\u6027\u3001\u81ea\u7c98\u6027\u548c\u81ea\u4fee\u590d\u6027\u7684\u5bfc\u7535\u6709\u673a\u6c34\u51dd\u80f6(PAAm-TA@CNF-MXene-Gly\u6216\u8005PTCM-Gly)\u3002\u7531\u4e8e\u6c34\u548cGly\u4e4b\u95f4\u6709\u4e30\u5bcc\u7684\u6c22\u952e\uff0c\u5408\u6210\u7684\u6709\u673a\u6c34\u51dd\u80f6\u8868\u73b0\u51fa\u663e\u8457\u7684\u8010\u4f4e\u6e29\u6027(\u4f4e\u4e8e- 36\u2103)\u548c\u957f\u671f\u4fdd\u6e7f\u80fd\u529b(\u5927\u4e8e7\u5929)\u3002\u6b64\u5916\uff0c\u7531\u97e7\u6027\u7684TA@CNF\u7f51\u7edc\u3001\u5171\u4ef7\u4ea4\u8054\u7684PAAm\u7f51\u7edc\u548c\u5bfc\u7535\u7684MXene\u7eb3\u7c73\u7247\u7f51\u7edc\u7ec4\u6210\u7684\u4e09\u5143\u6df7\u5408\u7f51\u7edc\uff0c\u5145\u5206\u5438\u6536\u5404\u7ec4\u5206\u7684\u4f18\u70b9\uff0c\u8d4b\u4e88\u6709\u673a\u6c34\u51dd\u80f6\u4f18\u5f02\u7684\u62c9\u4f38\u6027(\u9ad8\u8fbe1500%\u5e94\u53d8)\u548c\u9ad8\u5e94\u53d8\u7075\u654f\u5ea6(\u5e94\u53d8\u7cfb\u6570\u4e3a8.21)\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u4e09\u5143\u6df7\u5408\u7f51\u7edc\u5b58\u5728\u5927\u91cf\u7684\u90bb\u82ef\u4e8c\u915a\u57fa\u56e2\u548c\u52a8\u6001\u53ef\u9006\u952e(\u6c22\u952e\u548c\u52a8\u6001\u787c\u9178\u916f\u952e)\uff0c\u5236\u5907\u7684\u6709\u673a\u6c34\u51dd\u80f6\u8fdb\u4e00\u6b65\u8868\u73b0\u51fa\u826f\u597d\u7684\u7c98\u9644\u6027\u548c\u81ea\u4fee\u590d\u80fd\u529b\u3002\u57fa\u4e8e\u6b64\u6709\u673a\u6c34\u51dd\u80f6\u7ec4\u88c5\u5236\u5907\u7684\u5e94\u53d8\u4f20\u611f\u5668\uff0c\u5728\u53ef\u7a7f\u6234\u7535\u5b50\u65b9\u9762\u5c55\u73b0\u51fa\u826f\u597d\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

\u56fe1.<\/p>\n

\"\"<\/p>\n

a-e) TA@CNF\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

f) \u6709\u673a\u6c34\u51dd\u80f6\u4e2dTA@CNF\/PAAm\/MXene\u4e92\u7a7f\u7f51\u7edc\u7684\u5f62\u6210\u793a\u610f\u56fe\u3002<\/p>\n

g) MXene\u5bfc\u7535\u9aa8\u67b6\u3001TA@CNF\u589e\u5f3a\u9aa8\u67b6\u548cPAAm\u5f39\u6027\u9aa8\u67b6\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u5173\u7cfb\u793a\u610f\u56fe\u3002<\/p>\n

h) \u96f6\u4e0b\u6e29\u5ea6\u73af\u5883\u4e2d\uff0c\u6709\u673a\u6c34\u51dd\u80f6(\u4e0a)\u548c\u5e38\u89c4\u6c34\u51dd\u80f6(\u4e0b)\u4e2d\u6c34\u5206\u5b50\u6210\u952e\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2.<\/p>\n

\"\"a) CNF\u7684AFM\u56fe\u50cf(\u5de6)\u548cAFM\u56fe\u50cf\u4e2d\u9ad8\u5ea6\u66f2\u7ebf(\u53f3)\u3002<\/p>\n

b) \u5265\u79bb\u540eTi3<\/sub>C2<\/sub>Tx<\/sub>\u7eb3\u7c73\u7247\u7684AFM\u56fe\u50cf\u548c\u9ad8\u5ea6\u66f2\u7ebf\u3002<\/p>\n

c,d) PTCM-Gly5\u548cPTCM-Gly1\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7167\u7247\uff0c\u63d2\u56fe\u4e3a\u539f\u59cb\u6df7\u5408\u7269\u6599\u7684\u7167\u7247\u3002<\/p>\n

e,f) \u51b7\u51bb\u5e72\u71e5\u540e\uff0cPTCM-Gly5\u548cPTCM-Gly1\u6709\u673a\u6c34\u51dd\u80f6\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe3.<\/p>\n

\"\"<\/p>\n

a)\u5347\u6e29\u8fc7\u7a0b(\u4ece\u221280\u2103\u5230 50\u2103)\u4e2d\uff0c\u6709\u673a\u6c34\u51dd\u80f6\u7684DSC\u66f2\u7ebf\u3002<\/p>\n

b) \u4f4e\u6e29\u4e0b\uff0cPTCM-Gly5\u548cPTCM-Gly1\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7167\u7247\u3002<\/p>\n

c) \u539f\u59cbPTCM-Gly5\u548c\u51b7\u51bb\u540ePTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6(\u5728\u221224\u2103\u4e0b\u4fdd\u5b5848h)\u7684\u62c9\u4f38\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

d) \u572820-25\u2103\u548c35-45%\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0cPTCM-Gly5\u548cPTCM-Gly0\u6709\u673a\u6c34\u51dd\u80f6\u7684\u5b58\u50a8\u5931\u91cd\u66f2\u7ebf\u3002<\/p>\n

e)\u00a0\u5728\u5f00\u653e\u73af\u5883\u4e2d\u66b4\u97327\u5929\u524d\u540e\uff0cPTCM-Gly5\u548cPTCM-Gly0\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7167\u7247\u3002<\/p>\n

f) \u5728\u5f00\u653e\u73af\u5883\u4e2d\u66b4\u97327\u5929\u524d\u540e\uff0cPTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u62c9\u4f38\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

g)\u00a0\u4e0d\u540c\u5e94\u53d8\u4e0b\uff0cPTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u52a0\u5378\u8f7d\u8bd5\u9a8c\u66f2\u7ebf\u3002<\/p>\n

h\u2013i) \u5e94\u53d8\u5206\u522b\u4e3a1000%\u548c100%\u65f6\uff0cPTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u8fde\u7eed\u8fdb\u884c15\u6b21\u52a0\u5378\u8f7d\u8bd5\u9a8c\u7684\u5faa\u73af\u66f2\u7ebf\u3002<\/p>\n

\u56fe4.<\/p>\n

\"\"a) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u76f8\u5bf9\u7535\u963b\u968f\u5e94\u53d8\u53d8\u5316\u7684\u66f2\u7ebf\u3002<\/p>\n

b) \u5728\u5e94\u53d8\u4e3a100%\u7684\u5faa\u73af\u52a0\u5378\u8f7d\u8bd5\u9a8c\u4e2d\uff0cPTCM-Gly5\u7684\u76f8\u5bf9\u7535\u963b\u968f\u4e0d\u540c\u62c9\u4f38\u901f\u5ea6\u7684\u53d8\u5316\u60c5\u51b5\u3002<\/p>\n

c,d) \u5c0f\u5e94\u53d8(1-5%)\u548c\u5927\u5e94\u53d8(20-320%)\u4e0b\uff0cPTCM-Gly5\u7684\u76f8\u5bf9\u7535\u963b\u53d8\u5316\u60c5\u51b5\u3002<\/p>\n

e) \u221224\u2103\u5b58\u653e48\u5c0f\u65f6\u540e\uff0cPTCM-Gly5\u548cPTCM-Gly1\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7535\u5bfc\u7387\u3002<\/p>\n

f) \u221224\u2103\u4f4e\u6e29\u4e0b\uff0cPTCM-Gly5\u6216PTCM-Gly1\u548c\u7eff\u8272LED\u6307\u793a\u706f\u7ec4\u6210\u4e32\u8054\u7535\u8def\u3002<\/p>\n

g) \u5728\u221236 – 60\u2103\u6e29\u5ea6\u8303\u56f4\u5185\uff0cPTCM-Gly5\u7684\u7535\u5bfc\u7387\u53d8\u5316\u60c5\u51b5\u3002<\/p>\n

h) \u7518\u6cb9\u5206\u5b50\u548c\u6c34\u5206\u5b50\u4e4b\u95f4\u7684\u6c22\u952e\u952e\u5408\u4f5c\u7528\u793a\u610f\u56fe\u3002<\/p>\n

i) \u5b58\u653e\u4e0d\u540c\u5929\u6570\u540e\uff0cPTCM-Gly5\u548cPTCM-Gly0\u7684\u7535\u5bfc\u7387\u53d8\u5316\u60c5\u51b5\u3002<\/p>\n

\u56fe5.<\/p>\n

\"\"a) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u5bf9\u4e0d\u540c\u57fa\u6750\u8868\u9762\u5747\u8868\u73b0\u51fa\u826f\u597d\u7684\u7c98\u9644\u6027\uff0c\u5305\u62ec\u76ae\u80a4\u3001\u805a\u56db\u6c1f\u4e59\u70ef\u3001\u6728\u6750\u3001\u91d1\u5c5e\u3001\u5851\u6599\u3001\u6a61\u80f6\u548c\u73bb\u7483\u3002<\/p>\n

b\u2013c) \u5728\u62c9\u4f38\u548c\u5f2f\u66f2\u5b9e\u9a8c\u4e2d\uff0cPTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7c98\u9644\u6027\u8868\u73b0\u3002<\/p>\n

d) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7c98\u9644\u6027\u6d4b\u8bd5\u793a\u610f\u56fe\u3002<\/p>\n

e) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u5bf9\u5404\u79cd\u57fa\u6750\u7684\u7c98\u9644\u5f3a\u5ea6\u548c\u91cd\u590d\u4f7f\u7528\u6027\u80fd\u3002<\/p>\n

f) \u5207\u5272\u524d\u548c\u81ea\u4fee\u590d\u540e\uff0cPTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u7535\u6d41\u53d8\u5316\u66f2\u7ebf\u3002<\/p>\n

g) \u81ea\u4fee\u590d\u540e\u7684 PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u62c9\u4f38\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

h) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u7684\u81ea\u4fee\u590d\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe6.<\/p>\n

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b\u3001c) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u57fa\u4f20\u611f\u5668\u5bf9\u819d\u5173\u8282\u8fd0\u52a8\u4fe1\u53f7\u7684\u76d1\u6d4b\u3002<\/p>\n

d-f) PTCM-Gly5\u6709\u673a\u6c34\u51dd\u80f6\u57fa\u4f20\u611f\u5668\u5bf9\u9762\u90e8\u8868\u60c5\u548c\u58f0\u97f3\u4fe1\u53f7\u7684\u76d1\u6d4b\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aMXene\u2010Based Conductive Organohydrogels with Long\u2010Term Environmental Stability and Multifunctionality<\/a>\uff08Adv. Funct. Mater.,2020,DOI: 10.1002\/adfm.202005135\uff09<\/p>\n

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 <\/p>\n

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