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Ru<\/b><\/strong>0.3<\/b><\/sub><\/strong>\u00a0SAs-NC\u7535\u6781\u653e\u7535\u8fc7\u7a0b\u7684\u6027\u80fd\u8868\u5f81<\/b><\/strong> \uff08a\uff09Ru0.3<\/sub>\u00a0SAs-NC\u548c\u70ed\u89e3ZIF-8\u78b3\u7535\u6781\u653e\u7535\u540e\u7684XRD\u7ed3\u679c\u3002<\/p>\n \uff08b\uff09Ru0.3<\/sub>\u00a0SAs-NC\u7535\u6781\u5728\u653e\u7535\u548c\u5145\u7535\u540e\u7684XPS\u5149\u8c31\u3002<\/p>\n \uff08c\uff09Ru0.3<\/sub>\u00a0SAs-NC\u653e\u7535\u8fc7\u7a0b\u7684\u539f\u4f4dDEMS\u7ed3\u679c\u3002<\/p>\n \uff08d\uff09Ru0.3<\/sub>\u00a0SAs-NC\u7535\u6781\u5728\u4e0d\u540c\u5145\u653e\u7535\u9636\u6bb5\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08\u7535\u6d41\u5bc6\u5ea6\uff1a0.02 mA cm-2<\/sup>\uff09\u3002<\/p>\n \u56fe5 LOB\u4e2d\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6b63\u6781\u7684\u7ed3\u6784\u548c\u5f62<\/b><\/strong>\u8c8c<\/b><\/strong>\u6f14\u53d8<\/b><\/strong> 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\uff08h\uff09\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002\u7b49\u503c\u9762\u9ad8\u5ea6=0.002 a.u.<\/p>\n \uff08i\uff0cj\uff09\u70ed\u89e3ZIF-8\uff08i\uff09\u548cRu0.<\/sub>3<\/sub>\u00a0SAs-NC\uff08j\uff09\u7684\u603b\u6001\u5bc6\u5ea6\uff08DOS\uff09\u548c\u5c40\u90e8\u6001\u5bc6\u5ea6\uff08PDOS\uff09\u3002<\/p>\n \u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u901a\u8fc7\u591a\u5b54\u6846\u67b6\u7684\u7a7a\u95f4\u9650\u5236\u548cZn\u8282\u70b9\u7684\u79bb\u5b50\u7f6e\u6362\uff0c\u6210\u529f\u5408\u6210\u4e86\u4e0d\u540c\u8d1f\u8f7d\u91cf\u7684Ru SAs-NC\uff0c\u5e76\u4f5c\u4e3aLOBs\u7684\u7535\u50ac\u5316\u5242\u3002\u91c7\u7528HAADF-STEM\u548cXAFS\u5bf9\u6240\u5f97\u7684\u50ac\u5316\u5242\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7ed3\u6784\u8868\u5f81\u548c\u7406\u8bba\u9a8c\u8bc1\u3002\u7814\u7a76\u53d1\u73b0\uff0cRu0.3<\/sub>\u00a0SAs-NC\u50ac\u5316\u5242\u7684\u653e\u7535\u8fc7\u7535\u4f4d\u6700\u4f4e\uff0c\u4ec5\u4e3a0.17 V\uff0c\u5355\u539f\u5b50\u6d3b\u6027\u4f4d\u70b9\u8fd8\u53ef\u4ee5\u8c03\u8282Li2<\/sub>O2<\/sub>\u653e\u7535\u4ea7\u7269\u7684\u51e0\u4f55\u7ed3\u6784\u3001\u5c3a\u5bf8\u548c\u5206\u5e03\u3002\u800c\u539f\u4f4dDEMS\u7814\u7a76\u53d1\u73b0\u6c27\u8fd8\u539f\u503c\u4e3a2.14 e–<\/sup>\/O2<\/sub>\uff0c\u7535\u6c60\u6027\u80fd\u6700\u597d\u3002\u5173\u952e\u7684\u662f\uff0c\u901a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\u548cDFT\u8ba1\u7b97\uff0c\u8ba4\u8bc6\u5230\u9ad8\u8d1f\u8f7d\u5355\u5206\u6563Ru\u4f4d\u70b9\u5bf9\u7535\u50ac\u5316\u5242\u6027\u80fd\u63d0\u5347\u8d77\u7740\u5173\u952e\u4f5c\u7528\u3002\u8be5\u56e2\u961f\u7684\u53d1\u73b0\u4e0d\u4ec5\u4e3aLOBs\u5f00\u53d1\u4e86\u4f18\u826f\u7684\u7535\u50ac\u5316\u5242\uff0c\u800c\u4e14\u4e3a\u5728\u539f\u5b50\u5c3a\u5ea6\u4e0a\u5408\u7406\u8bbe\u8ba1\u548c\u7cbe\u786e\u8c03\u63a7\u9ad8\u6d3b\u6027\u7684\u50ac\u5316\u5242\u63d0\u4f9b\u4e86\u6307\u5bfc\u3002<\/p>\n<\/p>\n
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